*2021/12/01 10:57:37.25 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2008/09/12 06:18:50.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 16 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 2B69ED44 NUMBER OF CHANNELS : 47 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 168 183 2 Bottle_Number n/a 1 16 3 Pressure decibar 1.9 340.2 4 Temperature:Primary 'deg C (ITS90)' 8.5342 14.2636 5 Transmissivity %/metre 4.2 64.2 6 Fluorescence:URU:Seapoint mg/m^3 0.77E-01 4.932 7 PAR uE/m^2/sec 0 1.2 8 PAR:Reference uE/m^2/sec 10.4 10.4 9 Salinity:T0:C0 PSS-78 26.5925 31.0748 10 Oxygen:Dissolved:SBE mL/L 3.17 8.98 11 Oxygen:Dissolved:SBE umol/kg 138.1 393.3 12 Number_of_bin_records n/a 241 241 13 Salinity:Bottle PSS-78 31.0664 31.0664 14 Flag:Salinity:Bottle n/a 15 Oxygen:Dissolved mL/L 3.165 8.382 16 Flag:Oxygen:Dissolved n/a 17 Nitrate_plus_Nitrite umol/L 3.9 27.4 18 Flag:Nitrate_plus_Nitrite n/a 19 Silicate umol/L 35.5 59.4 20 Flag:Silicate n/a 21 Phosphate umol/L 0.72 2.55 22 Flag:Phosphate n/a 23 Chlorophyll:Extracted mg/m^3 0.25 25.42 24 Flag:Chlorophyll:Extracted n/a 25 HPLC:Chl-c3 mg/m^3 0 0.46 26 HPLC:Chlide-a mg/m^3 0 2.24 27 HPLC:Chl-c2 mg/m^3 0.17E-01 2.413 28 HPLC:Peri mg/m^3 0 0.59E-01 29 HPLC:Pheide-a mg/m^3 0 3.498 30 HPLC:But-fuco mg/m^3 0 0.128 31 HPLC:Fuco mg/m^3 0.56E-01 5.083 32 HPLC:Neo mg/m^3 0 0.11E-01 33 HPLC:Pras mg/m^3 0 0.57E-01 34 HPLC:Viola mg/m^3 0 0.1E-01 35 HPLC:Hex-fuco mg/m^3 0 0.27E-01 36 HPLC:Diadino mg/m^3 0 0.405 37 HPLC:Allo mg/m^3 0.12E-01 0.39E-01 38 HPLC:Diato mg/m^3 0 0.19E-01 39 HPLC:Zea mg/m^3 0 0.65E-01 40 HPLC:Lut mg/m^3 0 0.7E-02 41 HPLC:Chl-b mg/m^3 0 0.306 42 HPLC:DVChl-a mg/m^3 -99 -99 43 HPLC:Chl-a mg/m^3 0.211 6.026 44 HPLC:Phe mg/m^3 0 0.421 45 HPLC:B-Car mg/m^3 0 0.208 46 HPLC:TChl-a mg/m^3 0.211 8.265 47 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 7 F ' ' 1 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 9 F ' ' 4 10 -99 ' ' 7 F ' ' 2 11 -99 ' ' 6 F ' ' 1 12 -99 ' ' 5 I I 0 13 -99 ' ' 9 F R4 4 14 -99 ' ' 3 NQ C ' ' 15 -99 ' ' 8 F ' ' 3 16 -99 ' ' 3 NQ C ' ' 17 -99 ' ' 6 F R4 1 18 -99 ' ' 3 NQ C ' ' 19 -99 ' ' 6 F R4 1 20 -99 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 -99 ' ' 3 NQ C ' ' 23 -99 ' ' 7 F R4 2 24 -99 ' ' 3 NQ C ' ' 25 -99 ' ' 8 F R4 3 26 -99 ' ' 8 F R4 3 27 -99 ' ' 8 F R4 3 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2008-51 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : SoG/JdF SCIENTIST : Chandler P. PLATFORM : Vector *LOCATION GEOGRAPHIC AREA : Strait of Georgia / Juan de Fuca Strait STATION : 27 EVENT NUMBER : 48 LATITUDE : 49 19.11000 N ! (deg min) LONGITUDE : 123 47.93000 W ! (deg min) WATER DEPTH : 346 ALTIMETER (M) : 6.15 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0585 $TABLE: SENSORS ! Name Abs Depth Serial No ! ------------------------- -------------- ---------- temperature:primary ' ' 2374 conductivity:primary ' ' 1764 pressure ' ' 77511 temperature:secondary ' ' 2710 conductivity:secondary ' ' 2676 Fluorometer ' ' Seapoint transmissometer:primary ' ' 1050DR Oxygen:SBE ' ' 1117 altimeter: ' ' ' ' irradiance:primary ' ' 4601 surface ' ' 'degrees = 0.0' $END $REMARKS SOFTWARE VERSION SEASAVE V 7.18 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 3.1 2008/11/11 15:12:52 3856 3856 CLEAN 5.0.2 2008/11/11 15:43:43 ? ? ADDSAMP 3.4 2008/11/11 16:09:16 3856 3856 BINAVE 4.1.1 2008/11/11 16:15:10 3856 16 MERGE 3.3 2008/12/04 16:43:02 16 16 CLEAN 5.0.2 2008/12/04 16:43:13 ? ? CALIB 11.7 2008/12/04 16:59:59 16 16 SORT 3.5 2008/12/09 14:34:23 16 16 REMOVECH 8.0 2008/12/09 14:36:46 16 16 CHGUNITS 3.0 2008/12/09 14:37:06 16 16 REORDER 1.2.1 2008/12/09 14:43:01 ? ? HDREDIT2 2.5.1 2008/12/11 13:12:58 ? ? HDREDIT2 2.5.1 2009/04/17 13:18:24 ? ? CHANGE_FLAGS 1.0 2013/07/16 11:49:20 16 16 CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:34:00 16 16 CHANGE_FLAGS 2.0 2014/11/20 09:56:26 16 16 CLEAN 5.2.4 2021/02/04 16:28:04 16 16 SORT 3.6 2021/02/05 10:16:36 16 16 REORDER 1.3.1 2021/12/01 10:53:50 ? ? MERGE 3.5.1 2021/12/01 10:55:23 16 16 SORT 3.6 2021/12/01 10:55:31 16 16 CLEAN 5.2.4 2021/12/01 10:56:19 16 16 HDREDIT2 3.2 2021/12/01 10:57:03 ? ? HDREDIT2 3.2 2021/12/01 10:57:37 ? ? $END $REMARKS -CLEAN functions: 2008/11/11 15:43:03 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: Q:\Cruise_Data_Processing\2008-51\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2008/12/04 16:43:01 2008/12/04 16:43:01 2008/12/04 16:43: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : Q:\Cruise_Data_Processing\2008-51\Processing\hydro\2008-51-0048.samavg Secondary file: Q:\Cruise_Data_Processing\2008-51\Processing\hydro\2008-51-0048.mrgcln1 -CLEAN functions: 2008/12/04 16:43:12 20 Remove Sea-Bird comments from the header. Remove remark heading: "Comments from secondary" -CALIB parameters: 2008/12/04 16:59:59 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\Cruise_Data_Processing\2008-51\Processing\doc\2008-51-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 11 Oxygen:Dissolved:SBE mL/L 10 0.7700000E-01 0.1062700E+01 -SORT parameters: 2008/12/09 14:34:23 Sorted in ascending order of channel Press* -REMOVECH 2008/12/09 14:36:46 10 channels removed. -CHANGE units: 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -HEADER EDITS: 2008/12/11 13:12:58 Applied edit header: Q:\Cruise_Data_Processing\2008-51\Processing\doc\2008-51-bot-hdr.txt Channel 2: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 5: Fluorescence:URU:Seapoint [mg/m^3] Name: Fluorescence:Seapoint ==> Fluorescence:URU:Seapoint Channel 6: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 8: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 9: PAR:Reference [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 13: Salinity:Bottle [PSS-78] Units: ==> PSS-78 Channel 15: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2009/04/17 13:18:24 Applied edit header: C:\My Documents\sample headers\add-comment.hdr -CLEAN functions: 2021/02/04 16:28:04 20 Reset #RECS, MIN & MAX values in header. Insert Pad Values in Channel: Fluorescence:URU:Seapoint [mg/m^3] where channel Fluorescence:URU:Seapoint [mg/m^3] is in the range 4.94 to 5 4 data records in pad range. -SORT parameters: 2021/02/05 10:16:36 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/12/01 10:55:23 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2008\2008-051_Nov2021\Processing\ IOS\2008-051-0048.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2008\2008-051_Nov2021\Processing\ IOS\2008-051-0048.hplc -SORT parameters: 2021/12/01 10:55:31 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/12/01 10:56:19 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/12/01 10:57:03 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2008\2008-051\Processing\Doc\ 2008-051-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 25: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 26: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 27: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 28: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/12/01 10:57:37 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2008\2008-051\Processing\Doc\ 2008-051-bot-hdr2.txt $END *COMMENTS Salinity Sample #168: Outlier in comparison to CTD salinity; 3 readings - increasing. Chlorophyll Sample #183: Probable dilution factor miscalculation. Analysis methods: ----------------- Chlorophyll samples are collected in duplicate in calibrated polycarbonate bottles (~330ml), then filtered onto 25mm MFS GF/75 filters at <70mmHg vacuum. The filters are placed in glass scintillation vials and immediately frozen at -20ēC until analysis. The chlorophyll is extracted in 10 ml of 90% acetone for 24h at -20ēC, then brought to room temperature and the extract is decanted and measured using a Turner Designs 10-AU-005-CE fluorometer, which has been calibrated with solutions made from commercially prepared pure chlorophyll a. Fluorometer readings are taken before and after acidification of the extract with two drops of 1.5N HCl. Average of two samples is reported. Variability is assessed as the % (std dev/mean*100) and samples are flagged if >10%. HPLC samples were filtered onto 25mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~1 month after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a and Chlide-a For further information see file QF 2008-051_HPLC*.xlsx. Oxygen samples are analyzed on an automated Winkler titration system following the procedures of Carpenter (1965). Samples were analyzed at sea using an automated titration system consisting of a Brinkman Dosimat (model 665) and a PC 900 Colorimeter. Salinity samples were collected in glass bottles and analyzed on a Guildline model 8400B Autosal at IOS. Salinometers are standardized with IAPSO standard seawater. Nutrient samples were collected in plastic tubes and stored frozen and later analysed at IOS using an Astoria analyzer following methods described in Barwell-Clarke and Whitney (1996). There were no nutrient duplicates. References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. J. Barwell-Clarke and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 3. Nemcek, N. and Peņa, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. NOTE: The salinity appears to have been low by about 0.012 units, but there were some problems with the salinometer, so no recalibration has been applied pending results of a post-cruise calibration of the temperature and conductivity sensors. UPDATE (April 2009): Post-cruise calibration reports indicate that the drifts in the T and C sensors were very low and that the combined effect on salinity would lead to errors of <0.001 for this cruise. So no recalibration is required. Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2008\2008-051_Nov2021\Processing\IOS\2008-051-0048. hplc --------------------------------------------------------------------------- Sample_Number 180: HPLC: one replicate dropped due to insufficient pigment detection *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- ------ ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (0.77E-01 1.0627) $END !-1-- -2-- --3--- ---4---- --5-- ---6--- --7--- --8--- ---9---- --10-- --11- -12- ---13--- 14 ---15-- 16 --17- 18 --19- 20 --21-- 22 --23-- 24 ---25-- ---26-- ---27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- 47 !Samp Bott Pressu Temperat Trans Fluores PAR PAR: Salinity Oxygen Oxyge Numb Salinity Fl Oxygen: Fl Nitra Fl Silic Fl Phosph Fl Chloro Fl HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ re ure: missi cence: Refere :T0:C0 : n: er_o :Bottle ag Dissolv ag te_ ag ate ag ate ag phyll: ag Chl-c3 Chlide- Chl-c2 Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb Primary vity URU: nce Dissol Disso ~bin ~o ed ~o plus_ ~t ~i ~p Extrac ~a a a fuco fuco : !er er Seapoin ved: lved: _rec tt lv Nitri ri ca ha ted ct HP ! t SBE SBE ords le ed te te te te ed LC !---- ---- ------ -------- ----- ------- ------ ------ -------- ------ ----- ---- -------- -- ------- -- ----- -- ----- -- ------ -- ------ -- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 183 16 1.9 14.2636 4.2 4.932 1.2 10.4 26.5925 8.98 393.3 241 -99.0000 0 8.382 0 3.9 0 35.5 0 0.72 0 25.42 4 0.460 2.240 2.413 0.000 3.498 0.128 5.083 0.000 0.057 0.010 0.027 0.405 0.039 0.019 0.065 0.007 0.265 -99.000 6.026 0.421 0.208 8.265 6 182 15 5.5 12.7614 40.9 4.820 0.1 10.4 27.8336 5.47 239.0 241 -99.0000 0 5.472 0 16.7 0 47.7 0 1.71 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 181 14 10.2 11.0044 50.9 2.876 0.0 10.4 28.6765 4.04 176.6 241 -99.0000 0 3.772 0 22.0 0 51.0 0 2.07 0 2.08 0 0.100 0.000 0.160 0.059 0.000 0.000 0.560 0.011 0.016 0.000 0.000 0.026 0.028 0.000 0.033 0.000 0.306 -99.000 1.548 0.000 0.033 1.548 6 180 13 20.0 9.7131 63.5 0.259 0.0 10.4 29.4499 3.54 154.3 241 -99.0000 0 3.666 0 24.8 0 50.0 0 2.30 0 0.25 0 0.000 0.000 0.017 0.037 0.000 0.000 0.056 0.000 0.000 0.000 0.000 0.000 0.012 0.000 0.000 0.000 0.000 -99.000 0.211 0.000 0.000 0.211 2 179 12 30.1 9.5165 63.4 0.187 0.0 10.4 29.6118 3.54 154.3 241 -99.0000 0 3.511 0 26.0 0 50.1 0 2.36 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 178 11 40.4 9.2936 64.2 0.119 0.0 10.4 29.9357 3.51 153.2 241 -99.0000 0 3.499 0 26.3 0 48.7 0 2.37 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 177 10 50.4 9.2912 63.5 0.109 0.0 10.4 30.0689 3.47 151.4 241 -99.0000 0 3.387 0 26.7 0 49.1 0 2.33 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 176 9 75.6 9.1841 62.0 0.088 0.0 10.4 30.3965 3.29 143.5 241 -99.0000 0 3.753 0 27.4 0 50.2 0 2.34 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 175 8 100.2 9.0407 61.1 0.081 0.0 10.4 30.5971 3.39 147.8 241 -99.0000 0 3.516 0 27.1 0 51.2 0 2.41 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 174 7 125.3 8.7444 61.5 0.079 0.0 10.4 30.7110 3.50 152.8 241 -99.0000 0 3.490 0 26.5 0 53.1 0 2.44 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 173 6 150.2 8.5747 61.9 0.079 0.0 10.4 30.7529 3.46 151.0 241 -99.0000 0 3.456 0 27.2 0 57.5 0 2.43 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 172 5 175.4 8.5342 61.3 0.078 0.0 10.4 30.7978 3.46 150.7 241 -99.0000 0 3.474 0 27.2 0 58.0 0 2.40 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 171 4 200.7 8.6303 59.5 0.078 0.0 10.4 30.8686 3.43 149.5 241 -99.0000 0 3.404 0 27.0 0 57.7 0 1.87 3 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 170 3 250.6 8.6225 58.5 0.077 0.0 10.4 30.9484 3.38 147.4 241 -99.0000 0 3.653 0 26.7 0 57.5 0 2.43 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 169 2 301.6 8.7543 53.2 0.077 0.0 10.4 31.0117 3.28 143.0 241 -99.0000 0 3.258 0 27.0 0 58.4 0 2.55 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 168 1 340.2 8.8651 48.4 0.079 0.0 10.4 31.0748 3.17 138.1 241 31.0664 0 3.165 0 27.1 0 59.4 0 1.96 3 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0