*2020/11/26 11:21:11.73 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2008/08/16 19:14:24.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 23 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : A57172BB NUMBER OF CHANNELS : 51 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ------------------------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 214 236 2 Bottle_Number n/a 1 23 3 Pressure decibar 1.5 302.1 4 Temperature:Primary 'deg C (ITS90)' 5.1278 15.4702 5 Transmissivity %/metre 28.9 57.5 6 Fluorescence:URU:Seapoint mg/m^3 0.75E-01 3.844 7 PAR uE/m^2/sec 0.5 1353 8 Salinity:T0:C0 PSS-78 32.3917 33.8793 9 Oxygen:Dissolved:SBE mL/L 2.63 7.05 10 Oxygen:Dissolved:SBE umol/kg 114.3 307.1 11 Number_of_bin_records n/a 87 241 12 Nitrate_plus_Nitrite umol/L 0.9 26.1 13 Flag:Nitrate_plus_Nitrite n/a 14 Silicate umol/L 5.1 44.2 15 Flag:Silicate n/a 16 Phosphate umol/L 0.52 1.9 17 Flag:Phosphate n/a 18 Dimethyl_Sulphide nmol/L 0 28.25 19 Flag:Dimethyl_Sulphide n/a 20 Dimethylsulfoniopropionate_Dissolved nmol/L -99 -99 21 Flag:Dimethylsulfoniopropionate_Dissolved n/a 22 Dimethylsulfoniopropionate_Total nmol/L -99 -99 23 Flag:Dimethylsulfoniopropionate_Total n/a 24 Chlorophyll:Extracted mg/m^3 0.7E-01 1.43 25 Flag:Chlorophyll:Extracted n/a 26 HPLC:Chl-c3 mg/m^3 0.77E-01 0.183 27 HPLC:Chlide-a mg/m^3 0 0 28 HPLC:MgDVP mg/m^3 0.7E-02 0.11E-01 29 HPLC:Chl-c2 mg/m^3 0.91E-01 0.167 30 HPLC:Chl-c1 mg/m^3 0 0.3E-02 31 HPLC:Me-chlide mg/m^3 0 0 32 HPLC:Peri mg/m^3 0.44E-01 0.81E-01 33 HPLC:Pheide-a mg/m^3 0 0 34 HPLC:But-fuco mg/m^3 0.52E-01 0.13 35 HPLC:Fuco mg/m^3 0.98E-01 0.157 36 HPLC:Neo mg/m^3 0.15E-01 0.26E-01 37 HPLC:Pras mg/m^3 0.11E-01 0.16E-01 38 HPLC:Viola mg/m^3 0.1E-01 0.12E-01 39 HPLC:Hex-fuco mg/m^3 0.34 0.553 40 HPLC:Diadino mg/m^3 0.43E-01 0.131 41 HPLC:Allo mg/m^3 0.2E-02 0.5E-02 42 HPLC:Diato mg/m^3 0.7E-02 0.23E-01 43 HPLC:Zea mg/m^3 0.7E-02 0.17E-01 44 HPLC:Lut mg/m^3 0.9E-02 0.17E-01 45 HPLC:Chl-b mg/m^3 0.98E-01 0.247 46 HPLC:DVChl-a mg/m^3 0 0 47 HPLC:Chl-a mg/m^3 0.735 1.011 48 HPLC:Phe mg/m^3 0 0 49 HPLC:B-Car mg/m^3 0.11E-01 0.16E-01 50 HPLC:TChl-a mg/m^3 0.735 1.011 51 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 7 F ' ' 1 8 -99 ' ' 9 F ' ' 4 9 -99 ' ' 7 F ' ' 2 10 -99 ' ' 6 F ' ' 1 11 -99 ' ' 5 I I 0 12 -99 ' ' 7 F R4 2 13 -99 ' ' 3 NQ C ' ' 14 -99 ' ' 7 F R4 2 15 -99 ' ' 3 NQ C ' ' 16 -99 ' ' 8 F R4 3 17 -99 ' ' 3 NQ C ' ' 18 -99 ' ' 7 F R4 2 19 -99 ' ' 3 NQ C ' ' 20 -99 ' ' 7 F R4 2 21 -99 ' ' 3 NQ C ' ' 22 -99 ' ' 7 F R4 2 23 -99 ' ' 3 NQ C ' ' 24 -99 ' ' 7 F R4 2 25 -99 ' ' 3 NQ C ' ' 26 -99 ' ' 8 F R4 3 27 -99 ' ' 8 F R4 3 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2008-27 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : P12 EVENT NUMBER : 39 LATITUDE : 48 58.19000 N ! (deg min) LONGITUDE : 130 40.03000 W ! (deg min) WATER DEPTH : 3227 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0443 $TABLE: SENSORS ! Name Abs Depth Serial No ! ------------------------- -------------- ---------- temperature:primary ' ' 4054 conductivity:primary ' ' 1766 pressure ' ' 63507 temperature:secondary ' ' 4700 conductivity:secondary ' ' 2173 Fluorometer ' ' Seapoint transmissometer:primary ' ' 1005DR Oxygen:SBE ' ' 1176 altimeter: ' ' ' ' irradiance:primary ' ' 4656 $END $REMARKS SOFTWARE VERSION SEASAVE V 7.16 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 3.1 2008/11/09 15:50:12 4740 4740 CLEAN 5.0.2 2008/11/09 15:52:12 ? ? ADDSAMP 3.4 2008/11/09 15:58:21 4740 4740 BINAVE 4.1.1 2008/11/09 16:02:01 4740 23 MERGE 3.3 2008/11/17 17:01:36 23 23 CLEAN 5.0.2 2008/11/17 18:50:22 ? ? CALIB 11.7 2008/11/25 17:39:43 23 23 SORT 3.5 2008/11/26 15:50:29 23 23 REMOVECH 8.0 2008/11/26 16:01:29 23 23 CHGUNITS 3.0 2008/11/26 17:09:29 23 23 HDREDIT2 2.5.1 2008/11/27 11:55:15 ? ? HDREDIT2 2.5.1 2009/04/17 11:39:37 ? ? CHANGE_FLAGS 1.0 2013/07/16 11:49:13 23 23 CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:33:52 23 23 CHANGE_FLAGS 2.0 2014/11/20 09:56:17 23 23 SORT 3.6 2020/03/13 11:44:04 23 23 MERGE 3.5.1 2020/03/13 11:45:16 23 23 SORT 3.6 2020/03/13 11:46:42 23 23 CLEAN 5.2.4 2020/03/13 11:47:39 23 23 HDREDIT2 3.2 2020/03/13 13:03:43 ? ? SORT 3.6 2020/11/26 10:50:27 23 23 REORDER 1.3.1 2020/11/26 10:53:29 ? ? MERGE 3.5.1 2020/11/26 10:53:39 23 23 SORT 3.6 2020/11/26 10:56:55 23 23 CLEAN 5.2.4 2020/11/26 10:57:10 23 23 HDREDIT2 3.2 2020/11/26 10:59:25 ? ? HDREDIT2 3.2 2020/11/26 11:21:11 ? ? $END $REMARKS -CLEAN functions: 2008/11/09 15:51:43 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: Q:\Cruise_Data_Processing\2008-27\Processing\test\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2008/11/17 17:01:34 2008/11/17 17:01:34 2008/11/17 17:01: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : Q:\Cruise_Data_Processing\2008-27\Processing\hydro\2008-27-0039.samavg Secondary file: Q:\Cruise_Data_Processing\2008-27\Processing\hydro\2008-27-0039.mrgcln1 -CLEAN functions: 2008/11/17 18:50:21 20 Remove Sea-Bird comments from the header. Remove remark heading: "Comments from secondary" -CALIB parameters: 2008/11/25 17:39:43 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\Cruise_Data_Processing\2008-27\Processing\doc\2008-27-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 11 Oxygen:Dissolved:SBE mL/L 10 0.2000000E-02 0.1071000E+01 17 Salinity:T1:C1 PSS-78 10 0.1600000E-02 0.1000000E+01 -SORT parameters: 2008/11/26 15:50:29 Sorted in ascending order of channel Press* -REMOVECH 2008/11/26 16:01:29 10 channels removed. -CHANGE units: 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -HEADER EDITS: 2008/11/27 11:55:15 Applied edit header: Q:\Cruise_Data_Processing\2008-27\Processing\doc\2008-27-bot-hdr.txt Channel 2: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 5: Fluorescence:URU:Seapoint [mg/m^3] Name: Fluorescence:Seapoint ==> Fluorescence:URU:Seapoint Channel 6: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 7: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 11: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2009/04/17 11:39:37 Applied edit header: C:\My Documents\sample headers\add-comment.hdr -SORT parameters: 2020/03/13 11:44:04 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2020/03/13 11:45:16 Merge Channel: Sample_Number [n/a] Merge Scheme Used: Interweave Records from Both Files Overlap Scheme Used: Average Primary Channels to Include: ALL Secondary Channels to Include: Dimethylsulfoniopropionate_Dissolved [nmol/L], Flag:Dimethylsulfoniopropionate_Dissolved [n/a], Dimethylsulfoniopropionate_Total [nmol/L], Flag:Dimethylsulfoniopropionate_Total [n/a] Primary file : L:\Cruise_Data\DMSP\Joe's Work\2008-027\2008-027-0039.chesrt Secondary file: L:\Cruise_Data\DMSP\Joe's Work\2008-027\2008-027-0039.ios -SORT parameters: 2020/03/13 11:46:42 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2020/03/13 11:47:39 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag* -HEADER EDITS: 2020/03/13 13:03:43 Applied edit header: L:\Cruise_Data\DMSP\Joe's Work\2008-027\DMSP Header Comments for NO Analysis. txt -SORT parameters: 2020/11/26 10:50:27 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2020/11/26 10:53:39 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2008\2008-027\Processing\IOS\2008- 027-0039.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2008\2008-027\Processing\IOS\2008- 027-0039.hplc -SORT parameters: 2020/11/26 10:56:55 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2020/11/26 10:57:10 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2020/11/26 10:59:25 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2008\2008-027-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 12: Nitrate_plus_Nitrite [umol/L] Format: F6.1 ==> F7.2 Channel 26: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 27: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 28: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:Chl-c1 [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 50: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2020/11/26 11:21:11 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2008\2008-027-bot-hdr2.txt $END *COMMENTS Sample_Number 215: DMSP: Sample collected but not analyzed Sample_Number 216: DMSP: Sample collected but not analyzed Sample_Number 218: DMSP: Sample collected but not analyzed Sample_Number 229: DMSP: Sample collected but not analyzed Sample_Number 235: DMSP: Sample collected but not analyzed Sample_Number 236: DMSP: Sample collected but not analyzed Analysis methods: ----------------- Chlorophyll samples were analyzed at sea using a Chemistry Turner 10 AU fluorometer which was calibrated on April 23, 2008 using pure chlorophyll a. Chlorophyll precision was determined by analyzing replicate samples drawn from one Niskin. For details see worksheet “Precision” in file QF 2008-27CHL M.xls. HPLC samples were filtered onto 25mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~2 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF 2008-027_HPLC*.xlsx. Oxygen samples were analyzed on an automated Winkler titration system following the procedures of Carpenter (1965). Samples were analyzed at sea using an automated titration system consisting of a Brinkman Dosimat (model 665) and a PC 910 Colorimeter. For details on precision see file 2008-27-duplicates-DO.xls. Salinity samples were collected in glass bottles and analyzed on a Guildline model 8400B Autosal at IOS or a Guildline Portasal 8410A at sea. Salinometers are standardized with IAPSO standard seawater. See file 2008-27-sal-duplicates.xls for information on precision and note the warning below. Nutrient samples were analyzed from frozen samples using an Astoria system following methods described in Barwell-Clarke and Whitney (1996). For details on nutrient duplicates and precision see file QF2008-27nuts M.xls. DMS data are provided by C.S. Wong and researchers are asked to contact him before using them. The minimum detectable level for DMS is 0.10 nM, so “0” values should be interpreted as <0.10. For details on the collection and analysis of the DMS data see file 2008-27 DMS Report.doc. DMSP-D and DMSP-T: Contamination in the blanks resulted in all data being discarded. For details on analysis and raw data, see document "2008-27 dmsp QF summary_10Dec2019.xlsx". . References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. J. Barwell-Clarke and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 3. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. WARNING: There were problems with both salinometers. Variations in the performance of the Portasal were fairly random from day to day, while the Autosal results were fairly steady for the analysis of samples from the first half of the cruise, but there may have been a shift later and the analyst reported problems with stability near the end. Studying multiple bottles fired at a single stop suggests that the Autosal is good to ±0.005 and the scatter in COMPARE looks similar. For the Portasal the multiple bottle study suggests the data is good to ±0.008, but the larger comparison between bottles and CTD showed more scatter, ~ ±0.015. Duplicate studies suggest that the Portasal was reading lower than the Autosal by ~0.007 with a standard deviation of 0.003, but the wider comparisons of bottles and CTD data suggests the Portasal is lower than the Autosal by ~0.003. Given the uncertainty in the comparisons no attempt was made to make the Autosal and POrtasal results match. Similarly, the only recalibration to CTD salinity was to make the secondary salinity match the primary salinity. Recalibration may be applied later if factory recalibration indicates that there was significant drift. Autosal values have been selected for Salinity:Bottle where possible. Where there are no Autosal values, the Portasal values were used, but were all flagged "c", except for those that had more severe flags attached for other reasons. NOTE: April 2009 Post-cruise calibrations show primary CTD salinity is within 0.001. *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- -------- ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (0.2E-02 1.071) Salinity:T1:C1 PSS-78 10 -99 () (0.16E-02 1) $END !-1-- -2-- --3--- ---4---- --5-- ---6--- --7--- ---8---- --9--- --10- -11- --12-- 13 --14-- 15 ---16-- 17 --18-- 19 --20-- 21 --22-- 23 --24-- 25 ---26-- ---27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- 51 !Samp Bott Pressu Temperat Trans Fluores PAR Salinity Oxygen Oxyge Numb Nitrat Fl Silica Fl Phospha Fl Dimeth Fl Dimeth Fl Dimeth Fl Chloro Fl HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ re ure: missi cence: :T0:C0 : n: er_o e_ ag te ag te ag yl_ ag ylsulf ag ylsulf ag phyll: ag Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb Primary vity URU: Dissol Disso ~bin plus_ ~t ~i ~p Sulphi ~p ~piona ~o ~oprop ~T Extrac ~a a chlide a fuco fuco : !er er Seapoin ved: lved: _rec Nitrit ri ca ha de hi te_Dis lv ionate ot ted ct HP ! t SBE SBE ords e te te te de solved ed _Total al ed LC !---- ---- ------ -------- ----- ------- ------ -------- ------ ----- ---- ------ -- ------ -- ------- -- ------ -- ------ -- ------ -- ------ -- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 236 23 1.5 15.4702 28.9 0.493 1353.0 32.3929 6.31 275.0 241 1.00 0 5.30 0 0.520 0 24.96 0 -99.00 1 -99.00 1 0.94 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 233 20 5.4 15.4251 37.2 0.962 784.0 32.3919 6.32 275.7 112 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 235 22 5.5 15.4346 37.5 0.689 710.5 32.3929 6.32 275.5 240 1.00 0 5.30 0 0.530 0 26.11 0 -99.00 1 -99.00 1 1.03 0 0.077 0.000 0.011 0.091 0.000 0.000 0.044 0.000 0.052 0.098 0.015 0.011 0.012 0.340 0.131 0.004 0.023 0.016 0.013 0.098 0.000 0.735 0.000 0.016 0.735 6 232 19 5.6 15.3678 36.5 1.079 849.1 32.3917 6.30 274.5 87 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 234 21 5.6 15.4402 37.6 0.819 745.6 32.3922 6.30 274.5 92 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 231 18 10.4 14.7216 35.7 1.968 245.7 32.4107 6.51 283.9 241 0.90 0 5.10 0 0.530 0 27.97 0 -99.00 0 -99.00 0 1.27 0 0.116 0.000 0.007 0.118 0.003 0.000 0.051 0.000 0.072 0.116 0.017 0.012 0.010 0.440 0.088 0.002 0.010 0.017 0.009 0.131 0.000 0.859 0.000 0.013 0.859 6 230 17 15.5 14.2337 36.3 2.973 111.1 32.4204 6.51 283.9 241 1.40 0 5.60 0 0.560 0 27.73 0 -99.00 0 -99.00 0 1.43 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 228 15 20.2 13.6802 38.9 3.293 62.9 32.4456 6.51 283.5 171 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 229 16 20.3 13.7518 39.0 3.308 65.1 32.4399 6.50 283.4 240 2.00 0 7.10 0 0.620 0 28.25 6 -99.00 1 -99.00 1 1.34 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 227 14 24.9 13.2769 40.1 3.844 35.3 32.4649 6.59 287.1 241 4.10 0 7.60 0 0.720 0 23.76 0 -99.00 0 -99.00 0 1.37 0 0.183 0.000 0.007 0.167 0.000 0.000 0.081 0.000 0.130 0.157 0.026 0.016 0.010 0.553 0.043 0.005 0.007 0.007 0.017 0.247 0.000 1.011 0.000 0.011 1.011 6 226 13 30.1 12.4453 41.6 3.630 23.5 32.4857 6.68 291.2 240 5.00 0 8.10 0 0.780 0 21.20 0 -99.00 0 -99.00 0 1.32 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 224 11 30.2 12.4508 41.6 3.636 24.6 32.4848 6.67 290.5 138 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 225 12 30.2 12.4434 41.6 3.610 24.1 32.4852 6.66 290.1 144 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 222 9 40.4 10.1878 48.3 2.229 6.9 32.5188 7.05 307.1 144 6.10 6 9.10 6 0.890 6 9.34 0 -99.00 0 -99.00 0 0.82 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 223 10 40.4 10.1853 48.3 2.244 6.8 32.5192 7.05 307.0 240 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 221 8 49.8 8.8933 52.5 1.236 3.3 32.5321 7.05 307.0 241 7.50 0 10.60 0 0.980 0 0.80 0 -99.00 0 -99.00 0 0.54 6 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 220 7 75.0 7.3014 56.3 0.331 1.0 32.5517 6.93 301.8 241 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 219 6 75.2 7.2911 56.4 0.319 1.0 32.5513 6.91 300.8 241 10.00 0 12.60 0 1.160 0 0.25 0 -99.00 0 -99.00 0 0.19 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 218 5 100.4 6.3386 57.3 0.155 0.6 32.6226 6.80 296.1 241 13.10 0 15.70 0 1.260 0 0.21 0 -99.00 1 -99.00 1 0.07 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 217 4 149.9 6.2921 57.5 0.088 0.5 33.4442 5.32 231.2 241 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 216 3 173.5 6.3049 57.5 0.077 0.5 33.7787 4.71 205.0 241 23.80 0 37.40 0 1.750 0 0.25 0 -99.00 1 -99.00 1 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 215 2 200.2 6.0858 57.5 0.075 0.5 33.8332 4.21 183.0 241 26.10 0 44.20 0 1.900 0 0.00 0 -99.00 1 -99.00 1 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 214 1 302.1 5.1278 57.5 0.078 0.5 33.8793 2.63 114.3 241 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0