*2020/11/30 10:07:08.97 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2008/06/06 22:11:02.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 17 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 8206432 NUMBER OF CHANNELS : 51 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ------------------------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 337 353 2 Bottle_Number n/a 1 17 3 Pressure decibar 2.9 199 4 Temperature:Primary 'deg C (ITS90)' 5.4448 7.3062 5 Transmissivity %/metre 48.9 58.5 6 Fluorescence:URU:Seapoint mg/m^3 0.66E-01 1.032 7 PAR uE/m^2/sec 0 789 8 Salinity:T0:C0 PSS-78 32.5744 33.7715 9 Oxygen:Dissolved:SBE mL/L 4.25 7.31 10 Oxygen:Dissolved:SBE umol/kg 185 318.2 11 Number_of_bin_records n/a 121 121 12 Nitrate_plus_Nitrite umol/L 11.6 29.1 13 Flag:Nitrate_plus_Nitrite n/a 14 Silicate umol/L 16.8 48.1 15 Flag:Silicate n/a 16 Phosphate umol/L 1.14 2.03 17 Flag:Phosphate n/a 18 Dimethyl_Sulphide nmol/L 0 1.12 19 Flag:Dimethyl_Sulphide n/a 20 Dimethylsulfoniopropionate_Dissolved nmol/L -99 -99 21 Flag:Dimethylsulfoniopropionate_Dissolved n/a 22 Dimethylsulfoniopropionate_Total nmol/L -99 -99 23 Flag:Dimethylsulfoniopropionate_Total n/a 24 Chlorophyll:Extracted mg/m^3 0.1 0.51 25 Flag:Chlorophyll:Extracted n/a 26 HPLC:Chl-c3 mg/m^3 0.38E-01 0.42E-01 27 HPLC:Chlide-a mg/m^3 0.6E-02 0.12E-01 28 HPLC:MgDVP mg/m^3 0.4E-02 0.1E-01 29 HPLC:Chl-c2 mg/m^3 0.51E-01 0.57E-01 30 HPLC:Chl-c1 mg/m^3 0 0.4E-02 31 HPLC:Me-chlide mg/m^3 0 0.15E-01 32 HPLC:Peri mg/m^3 0 0 33 HPLC:Pheide-a mg/m^3 0 0 34 HPLC:But-fuco mg/m^3 0.41E-01 0.47E-01 35 HPLC:Fuco mg/m^3 0.122 0.126 36 HPLC:Neo mg/m^3 0.8E-02 0.12E-01 37 HPLC:Pras mg/m^3 0.17E-01 0.19E-01 38 HPLC:Viola mg/m^3 0.12E-01 0.17E-01 39 HPLC:Hex-fuco mg/m^3 0.1 0.106 40 HPLC:Diadino mg/m^3 0.54E-01 0.61E-01 41 HPLC:Allo mg/m^3 0 0 42 HPLC:Diato mg/m^3 0.7E-02 0.11E-01 43 HPLC:Zea mg/m^3 0.19E-01 0.28E-01 44 HPLC:Lut mg/m^3 0.4E-02 0.9E-02 45 HPLC:Chl-b mg/m^3 0.76E-01 0.79E-01 46 HPLC:DVChl-a mg/m^3 0 0 47 HPLC:Chl-a mg/m^3 0.426 0.445 48 HPLC:Phe mg/m^3 0 0 49 HPLC:B-Car mg/m^3 0.9E-02 0.9E-02 50 HPLC:TChl-a mg/m^3 0.448 0.452 51 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 7 F ' ' 1 8 -99 ' ' 9 F ' ' 4 9 -99 ' ' 7 F ' ' 2 10 -99 ' ' 6 F ' ' 1 11 -99 ' ' 5 I I 0 12 -99 ' ' 7 F R4 2 13 -99 ' ' 3 NQ C ' ' 14 -99 ' ' 7 F R4 2 15 -99 ' ' 3 NQ C ' ' 16 -99 ' ' 8 F R4 3 17 -99 ' ' 3 NQ C ' ' 18 -99 ' ' 7 F R4 2 19 -99 ' ' 3 NQ C ' ' 20 -99 ' ' 7 F R4 2 21 -99 ' ' 3 NQ C ' ' 22 -99 ' ' 7 F R4 2 23 -99 ' ' 3 NQ C ' ' 24 -99 ' ' 7 F R4 2 25 -99 ' ' 3 NQ C ' ' 26 -99 ' ' 8 F R4 3 27 -99 ' ' 8 F R4 3 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2008-26 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : P20 EVENT NUMBER : 45 LATITUDE : 49 34.00000 N ! (deg min) LONGITUDE : 138 39.86000 W ! (deg min) *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0443 $TABLE: SENSORS ! Name Abs Depth Serial No ! ------------------------- -------------- ---------- temperature:primary ' ' 4054 conductivity:primary ' ' 1766 pressure ' ' 63507 temperature:secondary ' ' 4700 conductivity:secondary ' ' 2173 Fluorometer ' ' Seapoint transmissometer:primary ' ' 1005DR Oxygen:SBE ' ' 1176 altimeter: ' ' ' ' irradiance:primary ' ' 4656 $END $REMARKS SOFTWARE VERSION SEASAVE V 7.16 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 3.1 2008/06/25 15:56:07 2057 2057 CLEAN 5.0.2 2008/06/25 15:57:34 ? ? ADDSAMP 3.4 2008/07/02 16:58:27 2057 2057 BINAVE 4.1.1 2008/11/06 14:39:42 2057 17 MERGE 3.3 2008/11/06 14:50:42 17 17 CLEAN 5.0.2 2008/11/06 14:50:53 ? ? CALIB 11.7 2008/11/06 14:57:48 17 17 SORT 3.5 2008/11/06 14:58:06 17 17 REMOVECH 8.0 2008/11/06 14:59:41 17 17 CHGUNITS 3.0 2008/11/06 15:01:05 17 17 REORDER 1.2.1 2008/11/18 14:11:44 ? ? HDREDIT2 2.5.1 2008/11/18 14:13:00 ? ? HDREDIT2 2.5.1 2011/07/04 15:00:18 ? ? HDREDIT2 2.5.1 2011/07/05 08:40:29 ? ? CHANGE_FLAGS 1.0 2013/07/16 11:49:11 17 17 CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:33:50 17 17 HDREDIT2 2.6 2013/12/18 14:58:57 ? ? CHANGE_FLAGS 2.0 2014/11/20 09:56:15 17 17 SORT 3.6 2020/03/12 12:16:07 17 17 MERGE 3.5.1 2020/03/12 12:16:58 17 17 SORT 3.6 2020/03/12 12:23:39 17 17 CLEAN 5.2.4 2020/03/12 12:47:13 17 17 HDREDIT2 3.2 2020/03/12 14:19:17 ? ? SORT 3.6 2020/11/26 11:48:50 17 17 REORDER 1.3.1 2020/11/26 12:00:13 ? ? MERGE 3.5.1 2020/11/26 12:00:50 17 17 SORT 3.6 2020/11/26 12:03:45 17 17 CLEAN 5.2.4 2020/11/26 12:03:56 17 17 HDREDIT2 3.2 2020/11/30 10:06:22 ? ? HDREDIT2 3.2 2020/11/30 10:07:08 ? ? $END $REMARKS -CLEAN functions: 2008/06/25 15:57:03 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: Q:\Cruise_Data_Processing\2008-26\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2008/11/06 14:50:37 2008/11/06 14:50:37 2008/11/06 14:50: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Dimethyl_Sulphide, Flag:Dimethyl_Sulphide Primary file : Q:\Cruise_Data_Processing\2008-26\Processing\hydro\2008-26-0045.samavg Secondary file: Q:\Cruise_Data_Processing\2008-26\Processing\hydro\2008-26-0045.mrgcln1 -CLEAN functions: 2008/11/06 14:50:51 20 Remove Sea-Bird comments from the header. Remove remark heading: "Comments from secondary" -CALIB parameters: 2008/11/06 14:57:48 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\Cruise_Data_Processing\2008-26\Processing\doc\2008-26-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 11 Oxygen:Dissolved:SBE mL/L 10 -0.1000000E-01 0.1070800E+01 16 Salinity:T0:C0 PSS-78 10 0.3000000E-02 0.1000000E+01 -SORT parameters: 2008/11/06 14:58:06 Sorted in ascending order of channel Press* -REMOVECH 2008/11/06 14:59:41 10 channels removed. -CHANGE units: 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -HEADER EDITS: 2008/11/18 14:13:00 Applied edit header: Q:\Cruise_Data_Processing\2008-26\Processing\doc\2008-26-bot-hdr.txt Channel 2: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 5: Fluorescence:URU:Seapoint [mg/m^3] Name: Fluorescence:Seapoint ==> Fluorescence:URU:Seapoint Channel 6: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 8: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 -HEADER EDITS: 2011/07/04 15:00:18 - none. -HEADER EDITS: 2011/07/05 08:40:29 Channel 12: Chlorophyll:Extracted [mg/m^3] Units: umol/L ==> mg/m^3 -HEADER EDITS: 2013/12/18 14:58:57 - none. -SORT parameters: 2020/03/12 12:16:07 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2020/03/12 12:16:58 Merge Channel: Sample_Number [n/a] Merge Scheme Used: Interweave Records from Both Files Overlap Scheme Used: Average Primary Channels to Include: ALL Secondary Channels to Include: Dimethylsulfoniopropionate_Dissolved [nmol/L], Flag:Dimethylsulfoniopropionate_Dissolved [n/a], Dimethylsulfoniopropionate_Total [nmol/L], Flag:Dimethylsulfoniopropionate_Total [n/a] Primary file : L:\Cruise_Data\DMSP\Joe's Work\2008-026\2008-026-0045.chesrt Secondary file: L:\Cruise_Data\DMSP\Joe's Work\2008-026\2008-026-0045.ios -SORT parameters: 2020/03/12 12:23:39 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2020/03/12 12:47:12 20 Reset #RECS, MIN & MAX values in header. Change character data from " " to "0" in channels Flag* -HEADER EDITS: 2020/03/12 14:19:17 Applied edit header: L:\Cruise_Data\DMSP\Joe's Work\DMSP Header Comments for NO Analysis.txt -SORT parameters: 2020/11/26 11:48:50 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2020/11/26 12:00:50 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2008\2008-026\Processing\IOS\2008- 026-0045.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2008\2008-026\Processing\IOS\2008- 026-0045.hplc -SORT parameters: 2020/11/26 12:03:45 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2020/11/26 12:03:56 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2020/11/30 10:06:22 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2008\2008-026-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 12: Nitrate_plus_Nitrite [umol/L] Format: F6.1 ==> F7.2 Channel 26: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 27: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 28: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:Chl-c1 [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 50: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2020/11/30 10:07:08 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2008\2008-026-bot-hdr2.txt $END *COMMENTS Sample_Number 337: DMSP: Sample collected but not analyzed Sample_Number 339: DMSP: Sample collected but not analyzed Sample_Number 341: DMSP: Sample collected but not analyzed Sample_Number 346: DMSP: Sample collected but not analyzed Sample_Number 348: DMSP: Sample collected but not analyzed Sample_Number 353: DMSP: Sample collected but not analyzed Analysis methods: ----------------- Chlorophyll samples were analyzed at sea using a Chemistry Turner Designs fluorometer which was calibrated in May 2007 using pure chlorophyll a. Chlorophyll precision was determined by analyzing replicate samples drawn from one Niskin. For details see worksheet “Precision” in file QF 2008-26CHL.xls. HPLC samples were filtered onto 25mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~2 weeks after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide For further information see file QF 2008-026_HPLC*.xlsx. Oxygen samples were analyzed on an automated Winkler titration system following the procedures of Carpenter (1965). Samples were analyzed at sea using an automated titration system consisting of a Brinkman Dosimat (model 665) and a PC 900 Colorimeter. For details on precision see file 2008-26-duplicates-DO.xls. Salinity samples were collected in glass bottles and analyzed on a Guildline model 8400B Autosal or a Guildline Portasal 8410A. Salinometers are standardized with IAPSO standard seawater. See file 2008-26-sal-duplicates.xls for information on precision, and note the warning given below. Nutrient samples were collected in plastic tubes and analyzed fresh at sea using a Technicon AAII autoanalyzer following methods described in Barwell-Clarke and Whitney (1996). For details on nutrient duplicates and precision see file QF 2008-26nuts.xls. DMS data are provided by C.S. Wong and researchers are asked to contact him before using them. The minimum detectable level for DMS is 0.10 nM, so “0” values should be interpreted as <0.10. For details on the collection and analysis of the DMS data see file 2008-26 DMS Report.doc. DMSP-D and DMSP-T: Contamination in the blanks resulted in all data being discarded. For details on analysis and raw data, see document "2008-26 dmsp QF summary_10Dec2019.xlsx". . References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. J. Barwell-Clarke and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 3. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. WARNING: The salinity analyses done on a Portasal salinometer at sea are considered unreliable. Many duplicate samples were run using an Autosal at IOS and the Portasal. The results showed that the Portasal read much lower than the Autosal for those samples analyzed on the Portasal on June 5th. For other days the Portasal was low by an average of 0.0016 but there was a lot of noise in the comparison with many values within 0.001 of the Autosal, while others looked unstable. (For more detail see file 2008-26-bottle-salinity-port-auto-dups.xls.) Autosal values have been selected for Salinity:Bottle where possible. Where there are no Autosal values, the Portasal values were used, but were all flagged "c", except for those from June 5th which have been flagged "d". *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- -------- ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (-0.1E-01 1.0708) Salinity:T0:C0 PSS-78 10 -99 () (0.3E-02 1) $END !-1-- -2-- --3--- ---4---- --5-- ---6--- --7--- ---8---- --9--- --10- -11- --12-- 13 --14-- 15 ---16-- 17 --18-- 19 --20-- 21 --22-- 23 --24-- 25 ---26-- ---27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- 51 !Samp Bott Pressu Temperat Trans Fluores PAR Salinity Oxygen Oxyge Numb Nitrat Fl Silica Fl Phospha Fl Dimeth Fl Dimeth Fl Dimeth Fl Chloro Fl HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ re ure: missi cence: :T0:C0 : n: er_o e_ ag te ag te ag yl_ ag ylsulf ag ylsulf ag phyll: ag Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb Primary vity URU: Dissol Disso ~bin plus_ ~t ~i ~p Sulphi ~p ~piona ~o ~oprop ~T Extrac ~a a chlide a fuco fuco : !er er Seapoin ved: lved: _rec Nitrit ri ca ha de hi te_Dis lv ionate ot ted ct HP ! t SBE SBE ords e te te te de solved ed _Total al ed LC !---- ---- ------ -------- ----- ------- ------ -------- ------ ----- ---- ------ -- ------ -- ------- -- ------ -- ------ -- ------ -- ------ -- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 353 17 2.9 7.3037 48.9 0.280 789.0 32.5744 7.30 317.7 121 11.60 0 16.90 0 1.140 0 1.12 0 -99.00 1 -99.00 1 0.49 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 352 16 6.5 7.2976 51.8 0.298 430.3 32.5750 7.31 318.1 121 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 350 14 6.7 7.2951 53.1 0.289 388.1 32.5755 7.31 318.2 121 11.70 0 16.90 0 1.140 0 0.00 0 -99.00 0 -99.00 0 0.47 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 351 15 6.7 7.2962 53.3 0.295 370.6 32.5754 7.30 318.0 121 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 0.038 0.006 0.010 0.057 0.003 0.000 0.000 0.000 0.047 0.125 0.008 0.019 0.012 0.102 0.058 0.000 0.011 0.022 0.008 0.076 0.000 0.445 0.000 0.009 0.452 6 349 13 9.8 7.3062 53.3 0.286 267.7 32.5756 7.30 317.6 121 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 0.040 0.012 0.004 0.051 0.000 0.000 0.000 0.000 0.046 0.122 0.012 0.017 0.013 0.106 0.061 0.000 0.009 0.019 0.009 0.076 0.000 0.437 0.000 0.009 0.448 6 348 12 10.0 7.3049 53.3 0.283 266.0 32.5756 7.29 317.4 121 11.80 0 16.90 0 1.150 0 0.25 0 -99.00 1 -99.00 1 0.49 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 347 11 15.6 7.2901 53.2 0.491 175.9 32.5756 7.30 317.6 121 11.70 0 16.90 0 1.140 0 0.73 0 -99.00 0 -99.00 0 0.49 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 346 10 19.5 7.2749 53.0 0.667 136.0 32.5752 7.29 317.5 121 11.70 0 16.90 0 1.150 0 1.06 6 -99.00 1 -99.00 1 0.47 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 344 8 24.6 7.2816 53.0 0.734 114.1 32.5754 7.30 317.8 121 11.70 0 16.90 0 1.140 0 1.07 0 -99.00 0 -99.00 0 0.46 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 345 9 24.6 7.2748 53.1 0.736 115.6 32.5754 7.30 317.8 121 -99.00 9 -99.00 9 -99.000 9 -99.00 0 -99.00 0 -99.00 0 -99.00 0 0.042 0.009 0.010 0.055 0.004 0.015 0.000 0.000 0.041 0.126 0.011 0.019 0.017 0.100 0.054 0.000 0.007 0.028 0.004 0.079 0.000 0.426 0.000 0.009 0.449 6 343 7 30.3 7.2658 53.1 0.859 109.1 32.5751 7.30 317.7 121 11.70 0 16.80 0 1.150 0 1.04 0 -99.00 0 -99.00 0 0.45 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 342 6 40.2 7.2531 53.2 0.950 39.5 32.5751 7.29 317.5 121 11.70 0 16.80 0 1.140 0 1.04 0 -99.00 0 -99.00 0 0.43 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 341 5 48.9 7.2440 53.7 1.032 25.3 32.5750 7.28 316.8 121 11.80 0 16.80 0 1.150 0 0.94 0 -99.00 1 -99.00 1 0.51 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 340 4 74.0 6.7922 55.8 0.694 5.0 32.5843 7.27 316.3 121 12.30 0 17.40 0 1.210 0 0.57 0 -99.00 0 -99.00 0 0.39 6 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 339 3 100.2 5.7830 58.2 0.192 1.2 32.6130 7.25 315.5 121 14.10 6 19.10 6 1.300 6 0.00 0 -99.00 1 -99.00 1 0.10 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 338 2 176.5 5.7094 58.5 0.066 0.1 33.7280 5.07 220.3 121 24.90 0 39.30 0 1.770 0 0.00 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 337 1 199.0 5.4448 58.3 0.066 0.0 33.7715 4.25 185.0 121 29.10 0 48.10 0 2.030 0 0.00 0 -99.00 1 -99.00 1 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0