*2025/01/07 14:21:54.25 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2007/08/04 10:18:00.000 NUMBER OF RECORDS : 23 DATA DESCRIPTION : 'Bottle:Rosette:Up:NoStop and Stop as specified in' CONTINUED : ' SAMPLE METHOD' FILE TYPE : ASCII NUMBER OF CHANNELS : 38 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- -------------------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 516 538 2 Sample_Method n/a 3 Bottle_Number n/a 1 23 4 Pressure decibar 5.1 1012.6 5 Temperature 'deg C (ITS90)' -1.4241 2.1934 6 Salinity PSS-78 29.2788 34.8859 7 Oxygen:Dissolved:SBE mL/L 6.42 9.85 8 Fluorescence:Calibrated:Seapoint mg/m^3 0.35E-01 1.766 9 Transmissivity %/metre 85.03 89.63 10 Nitrate_plus_Nitrite:ISUS volts 0.723 1.189 11 PAR uE/m^2/sec 0 1.18 12 PAR:Reference uE/m^2/sec 11.537 13.46 13 Salinity:Bottle PSS-78 29.2573 34.8853 14 Flag:Salinity:Bottle n/a 15 Oxygen:Dissolved mL/L 6.355 9.688 16 Oxygen:Dissolved umol/kg 283.8 432.68 17 Flag:Oxygen:Dissolved n/a 18 Nitrate_plus_Nitrite umol/L 0 13.9 19 Flag:Nitrate_plus_Nitrite n/a 20 Silicate umol/L 3.1 31 21 Flag:Silicate n/a 22 Phosphate umol/L 0.62 1.72 23 Flag:Phosphate n/a 24 Ammonium umol/L 0 0.56 25 Flag:Ammonium n/a 26 Alkalinity:Total:Potentiometric umol/kg 2101.7 2300.3 27 Flag:Alkalinity:Total:Potentiometric n/a 28 Carbon:Dissolved:Inorganic umol/kg 1956.17 1956.17 29 Flag:Carbon:Dissolved:Inorganic n/a 30 Alkalinity:Total umol/kg 2103.39 2103.39 31 Flag:Alkalinity:Total n/a 32 Oxygen:Isotope:18 /mille -3.12 0.22 33 Flag:Oxygen:Isotope:18 n/a 34 Barium:Dissolved nmol/L 48 72 35 Flag:Barium:Dissolved n/a 36 Bacteria /mL 117455 1317230. 37 Picophytoplankton /mL 279 7051 38 Nanophytoplankton /mL 175 2172 $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' ' ' I5 I ' ' 2 ' ' ' ' 8 NQ C ' ' 3 -99 ' ' ' ' I5 I ' ' 4 -99 ' ' ' ' F7.1 R4 ' ' 5 -99 ' ' ' ' F9.4 R4 ' ' 6 -99 ' ' ' ' F9.4 R4 ' ' 7 -99 ' ' ' ' F7.2 R4 ' ' 8 -99 ' ' ' ' F8.3 R4 ' ' 9 -99 ' ' ' ' F7.2 R4 ' ' 10 -99 ' ' ' ' F7.3 R4 ' ' 11 -99 ' ' ' ' F11.3 R4 ' ' 12 -99 ' ' ' ' F11.3 R4 ' ' 13 -99 ' ' ' ' F9.4 R4 ' ' 14 ' ' ' ' 3 NQ C ' ' 15 -99 ' ' ' ' F8.3 R4 ' ' 16 -99 ' ' ' ' F7.2 R4 ' ' 17 ' ' ' ' 3 NQ C ' ' 18 -99 ' ' ' ' F6.1 R4 ' ' 19 ' ' ' ' 3 NQ C ' ' 20 -99 ' ' ' ' F6.1 R4 ' ' 21 ' ' ' ' 3 NQ C ' ' 22 -99 ' ' ' ' F7.2 R4 ' ' 23 ' ' ' ' 3 NQ C ' ' 24 -99 ' ' ' ' F7.2 R4 ' ' 25 ' ' ' ' 3 NQ C ' ' 26 -99 ' ' ' ' F8.2 R4 ' ' 27 ' ' ' ' 3 NQ C ' ' 28 -99 ' ' ' ' F8.2 R4 ' ' 29 ' ' ' ' 3 NQ C ' ' 30 -99 ' ' ' ' F8.2 R4 ' ' 31 ' ' ' ' 3 NQ C ' ' 32 -99 ' ' ' ' F7.2 R4 ' ' 33 ' ' ' ' 3 NQ C ' ' 34 -99 ' ' ' ' F7.1 R4 ' ' 35 ' ' ' ' 3 NQ C ' ' 36 -99 ' ' ' ' F11.2 R4 ' ' 37 -99 ' ' ' ' F10.2 R4 ' ' 38 -99 ' ' ' ' F10.2 R4 ' ' $END $REMARKS Flag channels were initialized with zeros. Non-zero values have the following significance: ------------------------------------------------------------------------------------------ 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable Measurement 3 = Questionable Measurement (Probably Good) 4 = Poor Measurement (Probably Bad) 5 = Measurement Not Reported (Bad) 6 = Mean of replicate measurements 7 = Manual chromatographic peak measurement 8 = Irregular digital chromatographic peak integration 9 = Sample was planned for this measurement from this bottle but was not collected ------------------------------------------------------------------------------------------ Sampling Methods are expressed with the following codes: -------------------------------------------------------------------------------------- ROS:UN - No Stop ROS:US - Stop for 30 seconds ROS:USM - Up Stop Mix (Stop 30s, up 1m, down 2m, up 1m, wait 30s, close bottle) -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2007-20 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C COUNTRY : Canada PROJECT : Joint Ocean Ice Study (JOIS incl JWACS and BGOS) SCIENTIST : McLaughlin F. PLATFORM : Louis S. St. Laurent *LOCATION STATION : BL-4 EVENT NUMBER : 29 LATITUDE : 71 30.13000 N ! (deg min) LONGITUDE : 151 39.41000 W ! (deg min) WATER DEPTH : 1010 *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------ ------ ---------- -------- --------- --------- SPRD2IS 5.1 2017/03/25 11:14:28 23 23 CLEAN 5.2.2 2017/03/25 11:15:50 23 23 SORT 3.6 2017/03/25 11:21:43 23 23 HDREDIT2 3.1.1 2017/04/01 12:39:40 ? ? CHANGE_FLAGS 2.0 2017/04/01 12:59:01 23 23 HDREDIT2 3.2 2025/01/07 14:21:54 ? ? $END $REMARKS -CLEAN functions: 2017/03/25 11:15:48 20 Reset #RECS, MIN & MAX values in header. Delete Empty Channels: 18 deleted. -SORT parameters: 2017/03/25 11:21:43 Sorted in ascending order of channel Pressure [decibar] -HEADER EDITS: 2017/04/01 12:39:40 Applied edit header: Z:\SHARE\DATA\Data Archive Process - 2017\Joe's work\2007-20\Headers\2007-20 CHE Header.txt -HEADER EDITS: 2025/01/07 14:21:54 - none. $END *INSTRUMENT $REMARKS A rosette, holding 24 ten-litre Niskin Bottles, with a CTD was used. $END *CALIBRATION $TABLE: CORRECTED CHANNELS !Name Units Fmla Pad Coefficients !--------------------------- ------------ ---- ------ ------------ Conductivity:Primary mS/cm 10 -99 () (0.18E-02 1) Conductivity:Secondary mS/cm 10 -99 () (0.16E-02 1) Fluorescence:URU:Seapoint mg/m^3 10 -99 () (-0.45E-02 0.7909) Transmissivity %/metre 10 -99 () (0.559E-01 0.525E-01) Transmissivity %/metre 10 -99 () (-1.084 19.36) PAR uE/m^2/sec 10 -99 () (0 1.5976) $END *COMMENTS CTD Data Processing Notes: -------------------------- For full details see report Physical and chemical data from the Canada Basin July 26 to August 31, 2007 cited below. Standard seabird processing steps and Matlab based routines were used. CTD Pressure: Lab calibration (29th Oct 2002) adjusted by applying -0.48dbar offset to the bias based on in-air surface readings of the CTD. CTD Temperature: Pre-cruise lab calibration was used after comparisons with dual sensor and post-cruise calibration information. CTD Conductivity: Pre-cruise lab calibration adjusted after comparisons with dual sensor, post-cruise calibrations and water sample data. Primary conductivity adjusted by bias of +0.0018 mS/cm . Secondary conductivity adjusted by bias of +0.0016 mS/cm. CTD Oxygen: Oxygen data are from a SeaBird SBE43 sensor with pumped flow in-line after the primary temperature and conductivity sensors. A lag of -8 seconds was applied to oxygen voltage in the Seabird processing step Align. Downcast CTD oxygen voltage and upcast temperature and salinity were used to calibrate CTD to water sample oxygen (upcast). The 107 casts required 6 calibration groups. Fitting method followed Seabirds Application Note 64-2 (“SBE 43 Dissolved Oxygen Sensor Calibration and Data Corrections using Winkler Titrations”). A remaining pressure dependent shape in the residual between water sample and CTD oxygen was removed by subtracting a mean curve. Parts of the mean curve were found by fitting sections of data from discreet pressure ranges. The parts were then stitched together via spline interpolation to create a full profile mean curve. CTD Fluorometer: Fluorometer data are from a Seapoint sensor with pumped flow in-line after the secondary temperature and conductivity sensors. Calibration with bottle data performed using bottle chlorophyll values between 0.025 and 0.60 mg/m3. The number of observations used were 116 out of 141 with a standard deviation of 0.03 in the residuals. Coefficients used: Slope: 0.7909, Bias: -0.0045. Alignment of -4 seconds was used. Frequent single dropouts in fluorescence to 0 have been fixed by setting to neighbor value. ISUS: Data are uncalibrated. The voltage is proportional to nitrate. Transmissometer data are unprocessed, using calibration from 28 Aug 2006. PAR data are unprocessed, using corrected calibration from 13 Mar 2007. Altimeter data are unprocessed, using calibration from Mar 2005. Data Notes: - Spikes in temperature, conductivity and oxygen have been linearly interpolated over and where needed secondary values (when available) have replaced the primary values. Chemistry Sampling and Analysis Methods: --------------------------------------- For full details see report "Physical and chemical Data from the Canada Basin, July 26 to August 31, 2007." cited below. Salinity samples were collected in 200 mL type II glass bottles with disposable plastic inserts and screw caps. On board, samples were analyzed in a temperature-controlled lab on a Guildline AutoSalinometer Model 8400B (SN: 69086), which was standardized with IAPSO standard seawater. Onshore, 2 casts were analyzed November 2007 on the Guildline AutoSalinometer Model 8400B (SN: 68572), which was standardized with IAPSO standard seawater. Dissolved Oxygen: Oxygen samples were collected in glass flasks and analyzed on board on an automated Micro-Winkler titration system following the procedures of Carpenter (1965). The titration was performed with a Metrohn Dosimat 665 and the end point was detected using a Brinkmann probe Colorimeter PC910 (SN: 910-358). Software written at the Institute of Ocean Sciences, NewAutoOxy.exe, was used to calculate dissolved oxygen (ml/L). Oxygen data received correction post-cruise in May 2008 and February 2009 of 0.0 to 0.3 mL/L after recalibrating the volume of potassium iodide standard, identifing one unexplained drift in the uniform bottom water, and recalibrating flask volumes. Nutrient samples (nitrate plus nitrite, silicate and orthophosphate) were collected in polystyrene test tubes. If analysis could be performed on board within 24 hours the samples were stored at 4 degree C, if not they were frozen at -20 degree C. Note Surfactants for all three nutrients were misplaced during shipping. Palmolive dish detergent was an effective surfactant for nitrate and silicate but not for phosphate. Beginning August 12th with Cast 43, all phosphate samples were frozen in glass for analysis at the Institute of Ocean Sciences(IOS). Frozen samples were analyzed at IOS February and March 2008. Samples were not filtered. Samples were analyzed using a Technicon auto-analyzer following methods described in Barwell-Clarke and Whitney (1996). Ammonium samples were collected in 50 mL glass tubes, and analysed onboard following the Holmes et al. (1999) fluorometric protocol. Samples were kept in the dark for 5 to 8 hours at room temperature. Samples were then measured using a Turner Designs TD-700 fluorometer. Oxygen Isotopes Samples were collected into 30 ml glass vials. Once at room temperature, the caps were retightened and wrapped with parafilm for storage. The bulk of the samples (623) were analyzed January to March 2008 at Oregon State University's COAS Stable Isotope Lab using a Thermo Finnigan Delta Plus XL isotope ratio mass spectrometer with precision between +/- <0.05%.Samples from 9 stations (92) were analyzed at Hokkaido University using a mass spectrometer. Samples were analyzed December 2007. Barium samples were collected in ~20 ml plastic vials. Once at room temperature the caps were retightened for storage. Barium concentrations were determined at Oregon State University, using isotope-dilution and a VG Thermo Excel Inductively coupled quadrupole mass spectrometer as previously described with minor modifications (Falkner et al., 1994). Dissolved Inorganic Carbon (DIC) and Alkalinity: DIC and Alkalinity were collected into 250 or 500 mL glass bottles. Samples were kept at 4 degree C until analysis and preserved with HgCl2. Alkalinity ("Alkalinity:Total") and DIC ("Carbon:Dissolved:Inorganic") were measured from the same sample bottle at select stations. In addition, more frequent samples of Alkalinity were collected at most stations and have been labelled "Alkalinity:Total:Potentiometric" to distinguish this set of separate samples, even though both sets of Alkalinity samples were measured using potentiometric titration. DIC was analyzed at the Institute of Ocean Sciences using a SOMMA (Single-Operator Multi-Metabolic Analyzer) - Coulometer system to determine DIC. Alkalinity samples were analyzed at the Institute of Ocean Sciences using an automated potentiometric titration system to determine the total alkalinity. Total Chlorophyll-a (>0.7um) samples were collected into 2 L brown Nalgene sample bottles, immediately placed in dark bags and stored in a fridge. Samples were filtered onto 25mm GF/F filters using low vacuum filtration. The filters were put in scintillation vials and either extracted immediately or frozen at -20 degree C until analysis. All samples were analyzed on board. For analysis, 10 ml of 90% acetone was added to the scintillation vial which was then put into a -20 degree C freezer for 24 hours. The samples were allowed to adjust to room temperature for an hour before being read with the fluorometer. Chlorophyll-a and phaeo-pigment levels were measured with a Turner Designs 10 AU-005 Field Fluorometer SN:5152FRXX calibrated with a commercially pure chl-a standard (Sigma). The sample was acidified with 2 drops of 1N hydrochloric acid to obtain the phaeo-pigment reading. Chlorophyll estimates and phaeopigment estimates are calculated following the procedure in JGOFS manual (1994) cited below. Phytoplankton and bacterioplankton were collected in 2 ml capacity cryogenic vial and fixed with 0.2 ml of 10% paraformaldehyde by vortex mixing. Samples were maintained for at least 15 min at laboratory temperature to allow fixation, and then stored at -80 degree C until analysis at the Bedford Institute of Oceanography. Cell concentrations of picophytoplankton, nanophytoplankton, and bacterioplankton (i.e. non-autofluorescent picoplankton) in thawed samples were analyzed by flow cytometry (Becton Dickinson FACSort) following protocols in routine use (Li and Dickie, 2001). Iodine 129 samples were collected into 1 L PVC bottles Samples and returned to the Laboratory of the Atlantic Environmental Radioactivity Unit (AERU) at the Bedford Institute of Oceanography (BIO). In the laboratory, a NaI carrier was added to a 200 mL aliquot of the seawater sample, it was slightly acidified, purified using multiple hexane extractions and iodine was precipitated as NaI. The NaI precipitate was shipped to the IsoTrace Laboratory at the University of Toronto where 129I analyses were performed by accelerator mass spectrometry (Smith et al. 1998; 1999; 2005). Cesium 137 samples were collected into four 10 L plastic carboys from approximately 40 L of seawater. The water samples were passed through a potassium ferrocyanide (KCFC) packed resin column in the laboratory (AERU) which quantitatively extracts 137Cs from seawater (Smith et al. 1990; Smith & Ellis 1995). The KCFC resin was deployed in a standard geometry and measured using a hyperpure Ge detector having an efficiency of 25%. Particulate organic carbon (POC) samples were collected into 2 L Nalgene bottles. Onboard ship, 4 L samples were filtered onto 47 mm GF75 filters that had been pre-combusted at 500 degree C for 4 hours. The filtration was performed within 4 hours of sampling unless otherwise noted. Samples were analyzed at the University of British Columbia. The filters were first dried for 24 hours at 50 degree C, then fumed with HCl for 48 hours, dried again at 50 degree C for 24 hours, and then wrapped in aluminum foil and pressed into pellets. The pellets were run through the CN analyzer where the POC was determined. Total suspended solids samples were collected into 2 L Nalgene bottles. Onboard ship, 4 to 6 L were filtered onto 47 mm 0.4 µm polycarbonate nucleopore filters, that had been rinsed acid cleaned, rinsed with DMQ water, dried at 50 °C and pre-weighed to 0.001 mg. The filters were rinsed with 3% Ammonium carbonate solution after filtration was complete. The filters were then placed in a labeled 50 mm plastic petrie dish and frozen at -20 °C. The filtration was performed within 4 hours of sampling unless otherwise noted. Samples were analyzed at the University of British Columbia. Once in the lab, the TSS samples were dried at 50 °C for 24 hours and then weighed. The TSS concentration was equal to the final weight minus the initial weight divided by the volume of water filtered. References: 1. McLaughlin, F., Proshutinsky, A., Carmack, E.C., Shimada, K., Brown, K., Corkum, M., Dempsey, M., Drost, H., Eert, J., Guay, C., Gueguen, C., Hutchings, J., Itoh, M., Jackson, J., Kane, T., Krishfield, R., Li, B., Lovejoy, C., Maclean, H., Nelson, J., Nelson, R., Orlich, A., Smith, J., Steel, M., White, L., Wrohan, I., and Zimmermann, S. 2017. Physical and chemical data from the Canada Basin July 26 to August 31, 2007. Can. Data Rep. Hydrogr. Ocean Sci. 189: xx + xxx p. (in preparation). 2. Owens, W. B., and R. C. Millard Jr., 1985, A new algorithm for CTD oxygen calibration. J. Physical Oceanography., 15, 621-631. 3. Carpenter, J.H., 1965. The Chesapeake Bay Institute technique for the Winkler dissolved oxygen method, Limnol. Oceanogr., 10, 141-3. 4. J. Barwell-Clarke and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 5. Falkner, K.K., MacDonald, R.W., Carmack, E.C., and Weingartner, T. 1994. The potential of barium as a tracer of Arctic water masses, p. 63-76. In: O.M. Johannessen, R.D. Muench and J.E. Overland [eds.]. The Polar Oceans and Their Role in Shaping the Global Environment: The Nansen Centennial Volume, AGU Geophys. Monograph Series, AGU Books, Washington, DC. 6. Li, W.K.W., and Dickie, P.M. 2001. Monitoring phytoplankton, bacterioplankton, and virioplankton in a coastal inlet (Bedford Basin) by flow cytometry. Cytometry 44: 236-246. 7. Smith, J.N., Ellis, K.M. and Kilius, L.R. 1998. 129I and 137Cs tracer measurementsin the Arctic Ocean. Deep-Sea Research I. 45(6):959-984. 8. Smith, J.N., Ellis, K.M. and Boyd, T.M. 1999. Circulation features in the Central Arctic Ocean revealed by nuclear fuel reprocessing tracers from SCICEX 95 and 96, 1999. Journal of Geophysical Research. 104(C12):29,663-29,677. 9. Smith, J.N., Jones, E.P., Moran, S.B., Smethie Jr., W.M. and Kieser, W.E. 2005. 129I/CFC-11 Transit times for Denmark Strait Overflow Water in the Labrador and Irminger Seas. Journal of Geophysical Research. 110, C05006, doi:10.1029/2004JC002516. 10. Holmes, R.M., Aminot, A., Kérouel, R., Hooker, B.A. and Peterson, B.J. (1999). A simple and precise method for measuring ammonium in marine and freshwater ecosystems. Can. J. Fish. Aquat. Sci., 56: 1801-1808. 11. JGOFS. 1994. Protocols for the Joint Global Ocean Flux Study (JGOFS) core measurements, Manual and guides 29, Scientific Committee on Ocean Research, United Nations Educational, Scientific and Cultural Organization, Paris, 170 pp. . !-1-- ---2--- -3-- --4--- ---5---- ---6---- --7--- ---8--- --9--- --10-- ----11---- ----12---- ---13--- 14 ---15-- --16-- 17 --18- 19 --20- 21 --22-- 23 --24-- 25 ---26-- 27 ---28-- 29 ---30-- 31 --32-- 33 --34-- 35 ----36---- ----37--- ----38--- !Samp Sample_ Bott Pressu Temperat Salinity Oxygen Fluores Transm Nitrat PAR PAR: Salinity Fl Oxygen: Oxygen Fl Nitra Fl Silic Fl Phosph Fl Ammoni Fl Alkalin Fl Carbon: Fl Alkalin Fl Oxygen Fl Barium Fl Bacteria Picophyto Nanophyto !le_ Method le_ re ure : cence: issivi e_ Reference :Bottle ag Dissolv : ag te_ ag ate ag ate ag um ag ity: ag Dissolv ag ity: ag : ag : ag plankton plankton !Numb Numb Dissol Calibra ty plus_ ~o ed Dissol ~o plus_ ~t ~i ~p ~o Total: ~e ed: ~g Total ~T Isotop ~p Dissol ~o !er er ved: ted:Sea Nitrit tt ved lv Nitri ri ca ha ni Potenti tr Inorgan an ot e:18 e: ved lv ! SBE point e:ISUS le ed te te te te um ometric ic ic ic al 18 ed !---- ------- ---- ------ -------- -------- ------ ------- ------ ------ ---------- ---------- -------- -- ------- ------ -- ----- -- ----- -- ------ -- ------ -- ------- -- ------- -- ------- -- ------ -- ------ -- ---------- --------- --------- *END OF HEADER 536 UN 21 5.1 2.1934 29.2935 8.88 0.164 86.88 0.723 1.180 13.460 29.2858 0 9.265 413.79 0 0.0 0 3.1 0 0.62 0 0.01 0 2101.70 0 -99.00 0 -99.00 0 -3.12 0 70.0 0 379279.00 3626.00 953.00 537 UN 22 5.1 2.1732 29.3394 8.88 0.169 87.18 0.747 1.165 13.460 29.2764 0 -99.000 -99.00 0 -99.0 0 -99.0 0 -99.00 0 0.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.0 0 -99.00 -99.00 -99.00 538 UN 23 5.1 1.9957 29.2788 8.92 0.174 87.26 0.738 1.152 13.460 29.2573 0 -99.000 -99.00 0 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 1956.17 0 2103.39 0 -99.00 0 -99.0 0 -99.00 -99.00 -99.00 535 UN 20 21.9 -1.1393 31.0233 9.85 0.238 86.07 0.753 0.180 13.460 31.0940 0 9.688 432.68 0 0.0 0 4.0 0 0.72 0 0.01 0 2208.10 0 -99.00 0 -99.00 0 -2.84 0 72.0 0 521772.00 7051.00 1443.00 534 UN 19 33.9 -1.2890 31.5569 9.17 1.766 85.03 0.816 0.055 13.460 31.5979 0 9.072 405.15 0 0.7 0 6.6 0 0.86 0 0.15 0 2229.20 0 -99.00 0 -99.00 0 -2.51 0 71.0 0 651689.00 5331.00 2172.00 533 UN 18 37.8 0.0778 31.7647 8.87 1.239 85.74 0.798 0.027 13.460 31.7555 0 9.212 411.42 0 1.2 0 8.2 0 0.89 0 0.31 0 2226.90 0 -99.00 0 -99.00 0 -2.11 0 72.0 0 832583.00 4753.00 1175.00 532 UN 17 60.6 0.3237 32.3925 8.76 0.110 86.48 0.860 0.000 13.460 32.3590 0 -99.000 -99.00 0 4.4 0 15.4 0 1.15 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.0 0 -99.00 -99.00 -99.00 531 UN 16 86.7 -0.5144 32.6168 8.18 0.074 86.71 0.914 0.000 13.460 32.6104 0 8.287 370.11 0 -99.0 5 -99.0 5 -99.00 5 0.00 0 2273.10 0 -99.00 0 -99.00 0 -1.67 0 70.0 0 1317230.00 279.00 175.00 530 UN 15 128.9 -1.2024 32.9519 7.26 0.066 88.24 1.114 0.000 13.460 32.9422 0 7.312 326.55 0 9.9 0 21.6 0 1.51 0 0.56 0 2286.60 0 -99.00 0 -99.00 0 -1.68 0 71.0 0 390916.00 -99.00 -99.00 529 UN 14 147.3 -1.4241 33.1644 6.82 0.054 89.30 1.160 0.000 13.460 33.1496 0 6.813 304.28 0 13.6 0 31.0 0 1.72 0 0.14 0 2284.40 0 -99.00 0 -99.00 0 -1.57 0 70.0 0 117455.00 -99.00 -99.00 528 UN 13 168.3 -1.3222 33.5145 6.90 0.059 88.42 1.163 0.000 13.460 33.4878 0 -99.000 -99.00 0 13.8 0 30.9 0 1.68 0 -99.00 0 2300.30 0 -99.00 0 -99.00 0 -99.00 0 -99.0 0 229279.00 -99.00 -99.00 527 UN 12 182.4 -1.0353 33.8162 6.55 0.061 88.84 1.177 0.000 13.460 33.7938 0 6.517 291.05 0 13.9 0 25.9 0 1.51 0 0.03 0 2295.40 0 -99.00 0 -99.00 0 -0.87 0 61.0 0 215728.00 -99.00 -99.00 526 UN 11 194.7 -0.7244 34.1138 6.45 0.052 89.53 1.170 0.000 13.460 34.0848 0 6.436 287.45 0 13.6 0 21.4 0 1.32 0 0.00 0 2291.90 0 -99.00 0 -99.00 0 -0.68 0 55.0 0 152327.00 -99.00 -99.00 525 UN 10 211.9 -0.0863 34.4919 6.42 0.056 89.10 1.165 0.000 13.460 34.4780 0 6.371 284.51 0 13.3 0 15.9 0 1.14 0 0.00 0 2294.30 0 -99.00 0 -99.00 0 -0.14 0 48.0 0 193731.00 -99.00 -99.00 524 UN 9 226.2 0.1899 34.6218 6.45 0.050 89.46 1.150 0.000 13.460 34.6181 0 6.355 283.80 0 13.2 0 13.7 0 1.06 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.0 0 -99.00 -99.00 -99.00 523 UN 8 269.4 0.6045 34.7687 6.63 0.048 89.16 1.130 0.000 11.537 34.7639 0 6.588 294.21 0 12.8 0 10.3 0 0.96 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.0 0 -99.00 -99.00 -99.00 522 UN 7 353.1 0.7179 34.8223 6.75 0.037 89.48 1.163 0.000 11.537 34.8218 0 6.725 300.34 0 12.7 0 8.7 0 0.91 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.0 0 -99.00 -99.00 -99.00 521 UN 6 406.9 0.6827 34.8341 6.80 0.036 89.32 1.140 0.000 11.537 34.8328 0 6.772 302.45 0 12.6 0 8.6 0 0.91 0 0.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.0 0 -99.00 -99.00 -99.00 520 UN 5 457.9 0.6365 34.8442 6.83 0.035 89.58 1.157 0.000 11.537 34.8437 0 6.815 304.35 0 12.5 0 8.2 0 0.90 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.0 0 -99.00 -99.00 -99.00 519 UN 4 508.1 0.5404 34.8511 6.85 0.035 89.63 1.161 0.000 11.537 34.8503 0 6.855 306.12 0 12.5 0 7.8 0 0.90 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.0 0 -99.00 -99.00 -99.00 518 UN 3 611.1 0.3831 34.8605 6.89 0.046 88.63 1.122 0.000 11.537 34.8601 0 6.877 307.14 0 12.5 0 7.8 0 0.92 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.0 0 -99.00 -99.00 -99.00 517 UN 2 813.1 0.0755 34.8740 6.93 0.047 89.29 1.143 0.000 11.537 34.8742 0 6.939 309.90 0 12.5 0 8.0 0 0.93 0 -99.00 0 2297.70 0 -99.00 0 -99.00 0 0.22 0 -99.0 0 -99.00 -99.00 -99.00 516 UN 1 1012.6 -0.0768 34.8859 6.92 0.047 85.53 1.189 0.000 11.537 34.8853 0 6.899 308.10 0 12.8 0 9.0 0 0.95 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.00 0 -99.0 0 -99.00 -99.00 -99.00