*2023/01/17 10:24:31.38 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2007/08/20 22:54:41.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 20 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 20722C9F NUMBER OF CHANNELS : 44 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 237 256 2 Bottle_Number n/a 1 20 3 Pressure decibar 1.3 302.4 4 Temperature:Secondary 'deg C (ITS90)' 4.5678 13.642 5 Transmissivity %/metre 30.9 59 6 Fluorescence:URU:Seapoint mg/m^3 0.83E-01 9.246 7 PAR uE/m^2/sec 0 1166.7 8 Salinity:T1:C1 PSS-78 32.3504 33.9151 9 Oxygen:Dissolved:SBE mL/L 2.19 7.18 10 Oxygen:Dissolved:SBE umol/kg 95.3 312.9 11 Number_of_bin_records n/a 49 121 12 Nitrate_plus_Nitrite umol/L 4.1 39 13 Flag:Nitrate_plus_Nitrite n/a 14 Silicate umol/L 0.4 83.9 15 Flag:Silicate n/a 16 Phosphate umol/L 0.67 2.84 17 Flag:Phosphate n/a 18 Dimethyl_Sulphide nmol/L 0 18.24 19 Flag:Dimethyl_Sulphide n/a 20 Chlorophyll:Extracted mg/m^3 0.1 1.4 21 Flag:Chlorophyll:Extracted n/a 22 HPLC:Chl-c3 mg/m^3 0.83E-01 0.249 23 HPLC:Chlide-a mg/m^3 0 0.9E-02 24 HPLC:Chl-c2 mg/m^3 0.98E-01 0.195 25 HPLC:Peri mg/m^3 0.3E-01 0.58E-01 26 HPLC:Pheide-a mg/m^3 0 0 27 HPLC:But-fuco mg/m^3 0.7E-01 0.121 28 HPLC:Fuco mg/m^3 0.18 0.292 29 HPLC:Neo mg/m^3 0.9E-02 0.15E-01 30 HPLC:Pras mg/m^3 0 0 31 HPLC:Viola mg/m^3 0.8E-02 0.8E-02 32 HPLC:Hex-fuco mg/m^3 0.176 0.408 33 HPLC:Diadino mg/m^3 0.47E-01 0.94E-01 34 HPLC:Allo mg/m^3 0 0 35 HPLC:Diato mg/m^3 0 0.11E-01 36 HPLC:Zea mg/m^3 0.5E-02 0.6E-02 37 HPLC:Lut mg/m^3 0.9E-02 0.12E-01 38 HPLC:Chl-b mg/m^3 0.66E-01 0.137 39 HPLC:DVChl-a mg/m^3 0 0 40 HPLC:Chl-a mg/m^3 0.554 0.911 41 HPLC:Phe mg/m^3 0 0.65E-01 42 HPLC:B-Car mg/m^3 0.7E-02 0.11E-01 43 HPLC:TChl-a mg/m^3 0.56 0.911 44 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 7 F ' ' 1 8 -99 ' ' 9 F ' ' 4 9 -99 ' ' 7 F ' ' 2 10 -99 ' ' 6 F ' ' 1 11 -99 ' ' 5 I I 0 12 -99 ' ' 6 F R4 1 13 -99 ' ' 3 NQ C ' ' 14 -99 ' ' 6 F R4 1 15 -99 ' ' 3 NQ C ' ' 16 -99 ' ' 7 F R4 2 17 -99 ' ' 3 NQ C ' ' 18 -99 ' ' 7 F R4 2 19 -99 ' ' 3 NQ C ' ' 20 -99 ' ' 7 F R4 2 21 -99 ' ' 3 NQ C ' ' 22 -99 ' ' 8 F R4 3 23 -99 ' ' 8 F R4 3 24 -99 ' ' 8 F R4 3 25 -99 ' ' 8 F R4 3 26 -99 ' ' 8 F R4 3 27 -99 ' ' 8 F R4 3 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2007-15 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : N.E.Pacific STATION : P20 EVENT NUMBER : 35 LATITUDE : 49 33.98000 N ! (deg min) LONGITUDE : 138 39.80000 W ! (deg min) WATER DEPTH : 3944 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0443 $TABLE: SENSORS ! Name Abs Depth Serial No ! ------------------------- -------------- ---------- temperature:primary ' ' 2106 conductivity:primary ' ' 2424 pressure ' ' 63507 temperature:secondary ' ' 4752 conductivity:secondary ' ' 1763 Fluorometer ' ' Seapoint transmissometer:primary ' ' 953DR Oxygen:SBE ' ' 1119 altimeter: ' ' ' ' irradiance:primary ' ' 4656 $END $REMARKS SOFTWARE VERSION SEASAVE V 7.12 $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 3.0 2007/10/24 15:19:50 2147 2147 CLEAN 5.0.2 2007/10/24 15:26:38 ? ? ADDSAMP 3.4 2007/11/13 14:24:50 2147 2147 BINAVE 4.1.1 2007/11/13 14:25:59 2147 20 MERGE 3.3 2007/11/13 14:26:38 20 20 CLEAN 5.0.2 2007/11/29 09:51:31 ? ? CALIB 11.7 2007/11/29 09:51:42 20 20 SORT 3.5 2007/11/29 09:51:50 20 20 REMOVECH 8.0 2007/11/29 09:53:16 20 20 CHGUNITS 3.0 2007/11/29 09:53:46 20 20 REORDER 1.2.1 2007/11/29 09:53:53 ? ? HDREDIT2 2.5.1 2007/11/29 09:54:13 ? ? CALIB 11.7 2007/12/03 15:44:58 20 20 SORT 3.5 2008/04/09 15:58:56 20 20 MERGE 3.3 2008/04/09 16:00:00 20 20 SORT 3.5 2008/04/09 16:01:02 20 20 HDREDIT2 2.5.1 2008/04/09 16:02:45 ? ? CHANGE_FLAGS 1.0 2013/07/16 11:48:44 20 20 CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:33:06 20 20 CHANGE_FLAGS 2.0 2014/11/20 09:55:39 20 20 HDREDIT2 3.0.2 2015/01/18 16:33:26 ? ? HDREDIT2 3.2 2020/11/27 14:27:03 ? ? SORT 3.6 2020/11/27 15:23:17 20 20 REORDER 1.3.1 2020/11/27 15:28:05 ? ? MERGE 3.5.1 2020/11/27 15:28:15 20 20 SORT 3.6 2020/11/27 15:30:07 20 20 CLEAN 5.2.4 2020/11/27 15:30:16 20 20 HDREDIT2 3.2 2020/11/27 15:32:24 ? ? HDREDIT2 3.2 2020/11/27 15:33:22 ? ? HDREDIT2 3.2 2023/01/17 10:24:31 ? ? $END $REMARKS -CLEAN functions: 2007/10/24 15:26:15 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: Q:\Cruise_Data_Processing\2007-15\Processing\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2007/11/13 14:26:35 2007/11/13 14:26:35 2007/11/13 14:26: Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate Primary file : Q:\Cruise_Data_Processing\2007-15\Processing\hydro\2007-15-0035.samavg Secondary file: Q:\Cruise_Data_Processing\2007-15\Processing\hydro\2007-15-0035.mrgcln1 -CLEAN functions: 2007/11/29 09:51:30 20 Remove Sea-Bird comments from the header. Remove remark heading: "Comments from secondary" -CALIB parameters: 2007/11/29 09:51:42 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\Cruise_Data_Processing\2007-15\Processing\doc\2007-15-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 11 Oxygen:Dissolved:SBE mL/L 10 -0.1160000E-01 0.1086400E+01 -SORT parameters: 2007/11/29 09:51:50 Sorted in ascending order of channel Pressure [dbars] -REMOVECH 2007/11/29 09:53:16 10 channels removed. -CHANGE units: 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -HEADER EDITS: 2007/11/29 09:54:13 Applied edit header: Q:\Cruise_Data_Processing\2007-15\Processing\doc\2007-15-bot-hdr.txt Channel 2: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 4: Fluorescence:URU:Seapoint [mg/m^3] Name: Fluorescence:Seapoint ==> Fluorescence:URU:Seapoint Channel 6: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 8: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 -CALIB parameters: 2007/12/03 15:44:58 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\Cruise_Data_Processing\2007-15\Processing\doc\2007-15-recalp.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 2 Pressure decibar 10 0.1500000E+01 0.1000000E+01 -SORT parameters: 2008/04/09 15:58:56 Sorted in ascending order of channel Sample_Number -The following MERGE parameters were used: 2008/04/09 15:59:59 2008/04/09 15:59:59 2008/04/09 16:00: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Dimethyl_Sulphide [nmol/L], Flag:Dimethyl_Sulphide [ ] Primary file : c:\data\dms\2007-15\2007-15-0035.che2 Secondary file: c:\data\dms\2007-15\2007-15-0035.dms -SORT parameters: 2008/04/09 16:01:02 Sorted in ascending order of channel Pressure -HEADER EDITS: 2008/04/09 16:02:45 - none. -HEADER EDITS: 2015/01/18 16:33:26 -HEADER EDITS: 2020/11/27 14:27:03 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2007\2007-015-special-bot- hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 3: Pressure [decibar] Format: F11.2 ==> F7.1 Channel 14: Nitrate_plus_Nitrite [umol/L] Format: F6.1 ==> F7.2 Channel 16: Silicate [umol/L] Format: F6.1 ==> F7.2 Channel 18: Phosphate [umol/L] Format: F7.2 ==> F8.3 -SORT parameters: 2020/11/27 15:23:17 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2020/11/27 15:28:15 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2007\2007-015\Processing\IOS\2007- 015-0035.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2007\2007-015\Processing\IOS\2007- 015-0035.hplc -SORT parameters: 2020/11/27 15:30:07 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2020/11/27 15:30:16 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2020/11/27 15:32:24 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2007\2007-015-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 12: Nitrate_plus_Nitrite [umol/L] Format: F6.1 ==> F7.2 Channel 22: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 23: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 24: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 25: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 26: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 27: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 28: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2020/11/27 15:33:22 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2007\2007-015-bot-hdr2.txt -HEADER EDITS: 2023/01/17 10:24:31 Applied edit header: D:\Telework\2007-015\2007-015-hdr-update.txt Channel 12: Nitrate_plus_Nitrite [umol/L] Format: F7.2 ==> F6.1 Channel 14: Silicate [umol/L] Format: F7.2 ==> F6.1 Channel 16: Phosphate [umol/L] Format: F8.3 ==> F7.2 $END *COMMENTS All phosphate data are flagged “d” because new equipment caused contamination ranging from 0.07 to -0.33 uM PO4. Phosphate data were recovered by comparing to archived data below 1000m at each station and correcting accordingly. Sample_Number 238: Nitrate: replicates taken but 1 value rejected Analysis methods: Salinity samples are collected in glass bottles and analyzed at IOS on Guildline model 8400B Autosal Salinometers which are standardized with IAPSO standard seawater. Oxygen samples are analyzed at sea on an automated Winkler titration system following the procedures of Carpenter (1965). A Brinkmann model 665 Dosimat and model PC910 Colorimeter is controlled by Visual-Basic program to titrate the oxygen samples. Nutrient samples were analyzed fresh at sea using an Astoria autoanalyzer. Chlorophyll samples are collected in calibrated polycarbonate bottles (~330ml), then filtered onto 25mm MFS GF/75 filters at <70mmHg vacuum. The filters are placed in glass scintillation vials and immediately frozen at -20ºC until analysis. The chlorophyll is extracted in 10 ml of 90% acetone for 24h at -20ºC, then brought to room temperature and the extract is decanted and measured using a Turner Designs Model 10 fluorometer, which has been calibrated with solutions of commercially prepared chlorophyll. Chlorophyll samples were analyzed on board ship. The minimum detectable level for DMS is 0.10 nM, so “0†values should be interpreted as <0.10. For details on the collection and analysis of the DMS data see file 2007-15 DMS Report.doc. Dissolved inorganic carbon (DIC) was determined using coulometric analysis. Total alkalinity (Alk) was determined by potentiometric titration. Complete documentation on DIC and ALK sampling, analysis and precision estimates can be found in the Carbon Excel file from the cruise located in the cruise "DOC" directory. HPLC samples were filtered onto 25mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~3 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a and Chlide-a For further information see file QF 2007-015_HPLC*.xlsx. References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. J. Barwell-Clarke and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 3. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2007\2007-015\Processing\IOS\2007-015-0035.hplc --------------------------------------------------------------------------- Sample_Number 253: HPLC: >10%CV for TChl-a *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- --------- ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (-0.116E-01 1.0864) Pressure decibar 10 -99 () (1.5 1) $END !-1-- -2-- --3--- ---4---- --5-- ---6--- --7--- ---8---- --9--- --10- -11- --12- 13 --14- 15 --16-- 17 --18-- 19 --20-- 21 ---22-- ---23-- ---24-- ---25-- ---26-- ---27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- 44 !Samp Bott Pressu Temperat Trans Fluores PAR Salinity Oxygen Oxyge Numb Nitra Fl Silic Fl Phosph Fl Dimeth Fl Chloro Fl HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ re ure: missi cence: :T1:C1 : n: er_o te_ ag ate ag ate ag yl_ ag phyll: ag Chl-c3 Chlide- Chl-c2 Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb Secondar vity URU: Dissol Disso ~bin plus_ ~t ~i ~p Sulphi ~p Extrac ~a a a fuco fuco : !er er y Seapoin ved: lved: _rec Nitri ri ca ha de hi ted ct HP ! t SBE SBE ords te te te te de ed LC !---- ---- ------ -------- ----- ------- ------ -------- ------ ----- ---- ----- -- ----- -- ------ -- ------ -- ------ -- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 256 20 1.3 13.6420 40.8 1.018 1166.7 32.3504 6.55 285.3 121 4.1 0 0.4 0 0.68 4 17.76 0 0.78 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 252 16 3.6 13.5965 43.1 0.996 470.1 32.3512 6.56 286.1 51 4.3 0 0.4 0 0.68 4 17.02 0 0.79 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 253 17 3.6 13.6212 42.9 1.044 485.1 32.3506 6.55 285.6 55 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 0.083 0.006 0.098 0.048 0.000 0.070 0.180 0.009 0.000 0.008 0.176 0.089 0.000 0.009 0.005 0.011 0.066 0.000 0.554 0.000 0.010 0.560 36 254 18 3.6 13.6052 43.1 1.100 519.2 32.3509 6.56 286.0 49 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 255 19 3.7 13.6045 43.1 1.089 670.5 32.3509 6.55 285.7 120 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 251 15 9.1 13.5276 43.1 1.349 163.5 32.3525 6.57 286.3 121 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 0.089 0.009 0.113 0.058 0.000 0.071 0.193 0.012 0.000 0.008 0.185 0.094 0.000 0.011 0.006 0.012 0.072 0.000 0.594 0.000 0.011 0.603 6 250 14 9.2 13.5333 43.2 1.619 167.9 32.3521 6.57 286.3 121 4.2 0 0.4 0 0.67 4 18.24 0 0.82 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 249 13 16.1 13.4290 43.7 2.525 101.8 32.3569 6.59 287.2 121 4.6 0 0.4 0 0.67 4 17.56 0 0.79 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 248 12 18.9 12.6390 30.9 9.246 86.0 32.3789 6.94 302.3 121 4.7 0 0.5 0 0.71 4 16.55 6 1.40 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 247 11 24.2 9.9634 45.2 4.896 35.4 32.4637 7.18 312.6 120 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 0.249 0.000 0.195 0.030 0.000 0.121 0.292 0.015 0.000 0.008 0.408 0.047 0.000 0.000 0.006 0.009 0.137 0.000 0.911 0.065 0.007 0.911 6 246 10 24.3 9.9475 45.3 5.001 35.3 32.4645 7.18 312.9 58 9.1 0 10.2 0 1.05 4 2.97 0 1.16 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 244 8 30.1 8.6570 53.0 2.204 21.0 32.5099 7.11 309.8 121 9.8 0 14.5 0 1.16 4 1.01 0 0.64 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 245 9 30.2 8.6234 53.0 1.671 20.3 32.5099 7.11 309.8 121 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 243 7 39.3 7.9941 55.0 1.035 11.7 32.5376 7.02 305.7 121 12.1 0 16.6 0 1.22 4 0.51 0 0.50 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 242 6 48.3 7.2483 56.3 0.725 4.0 32.5658 7.03 306.2 121 12.2 0 17.9 0 1.27 4 0.37 0 0.38 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 241 5 74.7 6.2745 58.6 0.281 0.9 32.6205 7.03 306.2 121 14.1 0 18.4 0 1.34 4 0.19 0 0.14 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 240 4 99.1 5.9025 58.7 0.169 0.3 32.6340 6.85 298.2 121 16.4 0 20.7 0 1.44 4 0.23 0 0.10 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 239 3 174.8 5.4036 58.7 0.083 0.0 33.8037 4.03 175.0 121 28.8 0 54.2 0 2.22 4 0.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 238 2 198.7 5.1105 58.8 0.083 0.0 33.8119 3.49 151.7 121 31.4 2 61.7 6 2.41 46 0.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 237 1 302.4 4.5678 59.0 0.085 0.0 33.9151 2.19 95.3 121 39.0 0 83.9 0 2.84 4 0.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0