*2021/11/23 15:55:43.97 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2006/06/15 12:25:46.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 11 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : D4B382DF NUMBER OF CHANNELS : 44 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 136 146 2 Bottle_Number n/a 1 11 3 Pressure decibar 2 152 4 Temperature:Primary 'deg C (ITS90)' 8.7823 14.477 5 Transmissivity %/metre 40.1 57.1 6 Fluorescence:URU:Seapoint mg/m^3 0.125 2.92 7 PAR uE/m^2/sec 0 24 8 PAR:Reference uE/m^2/sec 41.5 62.3 9 Salinity:T0:C0 PSS-78 26.2553 30.2888 10 Oxygen:Dissolved:SBE mL/L 3.88 6.31 11 Oxygen:Dissolved:SBE umol/kg 169 276.3 12 Number_of_bin_records n/a 121 121 13 Salinity:Bottle PSS-78 27.6644 30.06 14 Flag:Salinity:Bottle n/a 15 Oxygen:Dissolved mL/L 3.925 6.335 16 Flag:Oxygen:Dissolved n/a 17 Nitrate_plus_Nitrite umol/L 3.8 29.7 18 Flag:Nitrate_plus_Nitrite n/a 19 Silicate umol/L 17.4 56.2 20 Flag:Silicate n/a 21 Phosphate umol/L 0.57 2.65 22 Flag:Phosphate n/a 23 Chlorophyll:Extracted mg/m^3 0.35 2.52 24 Flag:Chlorophyll:Extracted n/a 25 HPLC:Chl-c3 mg/m^3 0 0.69E-01 26 HPLC:Chl-c2 mg/m^3 0.11 0.269 27 HPLC:Peri mg/m^3 0.68E-01 0.115 28 HPLC:But-fuco mg/m^3 0 0.49E-01 29 HPLC:Fuco mg/m^3 0.19 0.315 30 HPLC:Neo mg/m^3 0.11E-01 0.38E-01 31 HPLC:Pras mg/m^3 0.42E-01 0.88E-01 32 HPLC:Viola mg/m^3 0.18E-01 0.34E-01 33 HPLC:Hex-fuco mg/m^3 0 0.25E-01 34 HPLC:Diadino mg/m^3 0.25E-01 0.48E-01 35 HPLC:Allo mg/m^3 0.91E-01 0.286 36 HPLC:Diato mg/m^3 0 0 37 HPLC:Zea mg/m^3 0.17E-01 0.37E-01 38 HPLC:Lut mg/m^3 0 0 39 HPLC:Chl-b mg/m^3 0.205 0.467 40 HPLC:DVChl-a mg/m^3 -99 -99 41 HPLC:Chl-a mg/m^3 1.154 2.668 42 HPLC:B-Car mg/m^3 0.29E-01 0.55E-01 43 HPLC:TChl-a mg/m^3 1.154 2.668 44 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 7 F ' ' 1 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 9 F ' ' 4 10 -99 ' ' 7 F ' ' 2 11 -99 ' ' 6 F ' ' 1 12 -99 ' ' 5 I I 0 13 -99 ' ' 9 F R4 4 14 -99 ' ' 3 NQ C ' ' 15 -99 ' ' 8 F ' ' 3 16 -99 ' ' 3 NQ C ' ' 17 -99 ' ' 6 F R4 1 18 -99 ' ' 3 NQ C ' ' 19 -99 ' ' 6 F R4 1 20 -99 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 -99 ' ' 3 NQ C ' ' 23 -99 ' ' 7 F R4 2 24 -99 ' ' 3 NQ C ' ' 25 -99 ' ' 8 F R4 3 26 -99 ' ' 8 F R4 3 27 -99 ' ' 8 F R4 3 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2006-21 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : SoG / JdeF SCIENTIST : Masson D. PLATFORM : Vector *LOCATION GEOGRAPHIC AREA : Strait of Georgia & Juan de Fuca Strait STATION : 16 EVENT NUMBER : 45 LATITUDE : 49 57.62000 N ! (deg min) LONGITUDE : 125 8.83000 W ! (deg min) ALTIMETER (M) : 6.72 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 443 $TABLE: SENSORS ! Name Abs Depth Serial No ! ------------------------- -------------- ---------- temperature:primary ' ' 2968 conductivity:primary ' ' 1766 pressure ' ' 63507 temperature:secondary ' ' 2106 conductivity:secondary ' ' 1729 Fluorometer ' ' Seapoint transmissometer:primary ' ' 723DR Oxygen:SBE ' ' 0766 altimeter: ' ' ' ' irradiance:primary ' ' 4565 surface ' ' 'degrees = 0.0' $END $REMARKS SOFTWARE VERSION SEASAVE WIN32 V 5.29B Dissolved oxygen concentration determined using an automated titration system consisting of a Brinkman dosimat (model 665) and a PC 900 Colorimeter. $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 3.0 2006/09/08 15:24:57 1331 1331 CLEAN 5.0 2006/09/08 15:27:21 ? ? ADDSAMP 3.4 2006/09/08 16:23:52 1331 1331 BINAVE 4.1.1 2006/09/08 16:24:55 1331 11 MERGE 3.3 2006/09/28 12:52:10 11 11 CLEAN 5.0 2006/09/28 12:52:29 11 11 CALIB 11.7 2006/10/11 14:19:58 11 11 SORT 3.5 2006/10/11 14:20:25 11 11 REMOVECH 7.0 2006/10/11 14:20:33 11 11 CHGUNITS 3.0 2006/10/11 14:25:21 11 11 REORDER 1.2.1 2006/10/11 14:25:43 ? ? HDREDIT2 2.5.1 2006/10/11 14:35:41 ? ? CHANGE_FLAGS 1.0 2013/07/16 11:48:26 11 11 CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:32:36 11 11 CHANGE_FLAGS 2.0 2014/11/20 09:55:14 11 11 SORT 3.6 2021/01/13 10:17:52 11 11 REORDER 1.3.1 2021/11/23 15:54:09 ? ? MERGE 3.5.1 2021/11/23 15:54:17 11 11 SORT 3.6 2021/11/23 15:54:24 11 11 CLEAN 5.2.4 2021/11/23 15:54:31 11 11 HDREDIT2 3.2 2021/11/23 15:54:54 ? ? HDREDIT2 3.2 2021/11/23 15:55:43 ? ? $END $REMARKS -CLEAN functions: 2006/09/08 15:26:58 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: Q:\Cruise_Data\2006-21\CTD\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2006/09/28 12:52:09 2006/09/28 12:52:09 2006/09/28 12:52: Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate Primary file : Q:\Cruise_Data\2006-21\CTD\hydro\2006-21-0045.samavg Secondary file: Q:\Cruise_Data\2006-21\CTD\hydro\2006-21-0045.mrg4 -The following MERGE parameters were used: 2006/09/26 12:04:44 2006/09/26 12:04:44 2006/09/26 12:04: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle Primary file : Q:\Cruise_Data\2006-21\CTD\hydro\2006-21-0045.cst Secondary file: Q:\Cruise_Data\2006-21\CTD\hydro\2006-21-0045.sal -The following MERGE parameters were used: 2006/09/26 12:04:51 2006/09/26 12:04:51 2006/09/26 12:04: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Chlorophyll:Extracted, Flag:Chlorophyll:Extracted Primary file : Q:\Cruise_Data\2006-21\CTD\hydro\2006-21-0045.mrg1 Secondary file: Q:\Cruise_Data\2006-21\CTD\hydro\2006-21-0045.chl -The following MERGE parameters were used: 2006/09/26 12:06:13 2006/09/26 12:06:13 2006/09/26 12:06: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Oxygen:Dissolved, Flag:Oxygen:Dissolved Primary file : Q:\Cruise_Data\2006-21\CTD\hydro\2006-21-0045.mrg2 Secondary file: Q:\Cruise_Data\2006-21\CTD\hydro\2006-21-0045.add C.H. Culbertson's paper on Dissolved Oxygen in the 'Woce Hydrographic Program Operations and Methods - July 1991' -The following MERGE parameters were used: 2006/09/26 12:12:34 2006/09/26 12:12:34 2006/09/26 12:12: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate Primary file : Q:\Cruise_Data\2006-21\CTD\hydro\2006-21-0045.mrg3 Secondary file: Q:\Cruise_Data\2006-21\CTD\hydro\2006-21-0045.nuts -CLEAN functions: 2006/09/28 12:52:28 20 Reset #RECS, MIN & MAX values in header. Remove Sea-Bird comments from the header. Remove remark heading: "Comments from secondary" -CALIB parameters: 2006/10/11 14:19:58 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\Cruise_Data\2006-21\CTD\doc\2006-21-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 11 Oxygen:Dissolved:SBE mL/L 10 0.4120000E-01 0.1086600E+01 -SORT parameters: 2006/10/11 14:20:25 Sorted in ascending order of channel Pressure -REMOVECH 2006/10/11 14:20:33 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Altimeter [metres] Descent_Rate [m/s] Status:Pump Salinity:T1:C1 [PSS-78] Flag -CHANGE units: 'Oxygen:Dissolved:SBE [mL/L]' changed from mL/L to umol/kg -HEADER EDITS: 2006/10/11 14:35:41 Applied edit header: Q:\Cruise_Data\2006-21\CTD\doc\2006-21-bot-hdr.txt Channel 2: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 5: Fluorescence:URU:Seapoint [mg/m^3] Name: Fluorescence:Seapoint ==> Fluorescence:URU:Seapoint Channel 6: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 8: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 9: PAR:Reference [uE/m^2/sec] Format: F11.3 ==> F7.1 -SORT parameters: 2021/01/13 10:17:52 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/23 15:54:17 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2006\2006-021_Nov2021\Processing\ IOS\2006-021-0045.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2006\2006-021_Nov2021\Processing\ IOS\2006-021-0045.hplc -SORT parameters: 2021/11/23 15:54:24 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/23 15:54:31 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/23 15:54:54 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2006\2006-021\Processing\Doc\ 2006-021-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 25: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 26: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 27: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 28: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/11/23 15:55:43 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2006\2006-021\Processing\Doc\ 2006-021-bot-hdr2.txt $END *COMMENTS Analysis methods: ----------------- Salinity samples are collected in glass bottles and analyzed on Guildline model 8400B Autosal Salinometers which are standardized with IAPSO standard seawater. Oxygen samples are analyzed on an automated Winkler titration system following the procedures of Carpenter (1965). A Brinkmann model 665 Dosimat and model PC910 Colorimeter is controlled by Visual-Basic program to titrate the oxygen samples. Nutrient samples are analyzed frozen using a Technicon AAII autoanalyzer following methods described in Barwell-Clarke and Whitney (1996). Chlorophyll samples are collected in duplicate in calibrated polycarbonate bottles (~330ml), then filtered onto 25mm MFS GF/75 filters at <70mmHg vacuum. The filters are placed in glass scintillation vials and immediately frozen at -20ēC until analysis. The chlorophyll is extracted in 10 ml of 90% acetone for 24h at -20ēC, then brought to room temperature and the extract is decanted and measured using a Turner Designs 10-AU-005-CE fluorometer, which has been calibrated with solutions of commercially prepared chlorophyll. Average of two samples is reported. Variability is assessed as the % (std dev/mean*100). HPLC samples were filtered onto 25mm GF/F filters and stored at -80C prior to analysis. Replicates were extracted in 95% methanol by different methods, either -20C soakfor 24 hours or 1-4 hr soak after sonication and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~14-20 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a and DVchl-a. For further information see file QF 2006-021_HPLC*.xlsx. References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. J. Barwell-Clarke and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 3. Nemcek, N. and Peņa, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- ------ ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (0.412E-01 1.0866) $END !-1-- -2-- --3--- ---4---- --5-- ---6--- --7--- --8--- ---9---- --10-- --11- -12- ---13--- 14 ---15-- 16 --17- 18 --19- 20 --21-- 22 --23-- 24 ---25-- ---26-- ---27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- 44 !Samp Bott Pressu Temperat Trans Fluores PAR PAR: Salinity Oxygen Oxyge Numb Salinity Fl Oxygen: Fl Nitra Fl Silic Fl Phosph Fl Chloro Fl HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ re ure: missi cence: Refere :T0:C0 : n: er_o :Bottle ag Dissolv ag te_ ag ate ag ate ag phyll: ag Chl-c3 Chl-c2 Peri But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Car TChl-a ag !Numb Numb Primary vity URU: nce Dissol Disso ~bin ~o ed ~o plus_ ~t ~i ~p Extrac ~a fuco fuco : !er er Seapoin ved: lved: _rec tt lv Nitri ri ca ha ted ct HP ! t SBE SBE ords le ed te te te te ed LC !---- ---- ------ -------- ----- ------- ------ ------ -------- ------ ----- ---- -------- -- ------- -- ----- -- ----- -- ------ -- ------ -- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 146 11 2.0 14.4770 40.1 2.920 24.0 62.3 26.2553 6.31 276.3 121 -99.0000 0 6.335 0 3.8 0 17.4 0 0.57 0 2.52 0 0.069 0.269 0.115 0.049 0.315 0.038 0.088 0.034 0.025 0.048 0.286 0.000 0.033 0.000 0.467 -99.000 2.668 0.055 2.668 6 145 10 4.6 14.2289 42.0 2.749 9.6 60.2 26.4732 6.20 271.6 121 -99.0000 0 6.074 0 7.2 0 24.0 0 0.83 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 144 9 9.7 12.2979 47.0 1.884 2.6 58.1 27.7242 5.39 235.5 121 27.6644 0 5.395 0 11.8 0 28.9 0 1.36 0 1.54 0 0.000 0.171 0.106 0.025 0.275 0.031 0.056 0.024 0.000 0.039 0.163 0.000 0.037 0.000 0.290 -99.000 1.720 0.050 1.720 6 143 8 20.0 10.8914 50.9 1.122 0.4 56.1 28.6917 4.70 205.2 121 -99.0000 0 4.689 0 19.0 0 40.6 0 1.96 0 0.87 0 0.000 0.110 0.068 0.000 0.190 0.011 0.042 0.018 0.000 0.025 0.091 0.000 0.017 0.000 0.205 -99.000 1.154 0.029 1.154 6 142 7 30.3 10.4885 52.1 0.888 0.1 54.0 29.0271 4.56 199.0 121 -99.0000 0 4.532 0 23.2 0 47.0 0 1.98 0 0.69 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 141 6 40.2 10.0417 53.6 0.589 0.0 51.9 29.3401 4.40 191.9 121 -99.0000 0 4.315 0 23.0 0 44.3 0 2.23 0 0.35 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 140 5 50.4 9.8089 54.4 0.468 0.0 49.8 29.4936 4.30 187.7 121 -99.0000 0 4.299 0 24.6 0 48.4 0 2.34 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 139 4 75.4 8.9648 57.1 0.161 0.0 47.8 29.9646 3.99 174.3 121 -99.0000 0 3.956 0 29.3 6 54.8 6 2.59 6 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 138 3 100.7 8.9523 56.8 0.167 0.0 45.7 30.0112 3.97 173.2 121 -99.0000 0 3.942 0 24.1 0 46.2 0 2.54 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 137 2 125.7 8.9316 56.7 0.156 0.0 43.6 30.0332 3.97 173.0 121 30.0600 0 3.958 0 29.7 0 55.8 0 2.53 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 136 1 152.0 8.7823 55.8 0.125 0.0 41.5 30.2888 3.88 169.0 121 -99.0000 0 3.925 0 26.4 0 56.2 0 2.65 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0