*2020/12/10 15:14:14.78 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2006/09/21 20:47:15.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 20 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : A2944BB9 NUMBER OF CHANNELS : 44 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 35 54 2 Bottle_Number n/a 1 20 3 Pressure decibar 5.8 299.8 4 Temperature:Secondary 'deg C (ITS90)' 6.1599 14.4029 5 Transmissivity %/metre 37.3 61.9 6 Fluorescence:URU:Seapoint mg/m^3 0.76E-01 1.906 7 PAR uE/m^2/sec 0.5 431.7 8 Salinity:T1:C1 PSS-78 32.096 34.0088 9 Oxygen:Dissolved:SBE mL/L 1.45 6.27 10 Oxygen:Dissolved:SBE umol/kg 63.1 273 11 Number_of_bin_records n/a 50 121 12 Nitrate_plus_Nitrite umol/L 1.7 33.9 13 Flag:Nitrate_plus_Nitrite n/a 14 Silicate umol/L 7.3 50.5 15 Flag:Silicate n/a 16 Phosphate umol/L 0.53 2.58 17 Flag:Phosphate n/a 18 Dimethyl_Sulphide nmol/L 0 3.1 19 Flag:Dimethyl_Sulphide n/a 20 Chlorophyll:Extracted mg/m^3 0.4E-01 1.27 21 Flag:Chlorophyll:Extracted n/a 22 HPLC:Chl-c3 mg/m^3 0 0.133 23 HPLC:Chlide-a mg/m^3 0 0 24 HPLC:Chl-c2 mg/m^3 0 0.172 25 HPLC:Peri mg/m^3 0 0.32E-01 26 HPLC:Pheide-a mg/m^3 0 0 27 HPLC:But-fuco mg/m^3 0 0.115 28 HPLC:Fuco mg/m^3 0 0.261 29 HPLC:Neo mg/m^3 0 0.31E-01 30 HPLC:Pras mg/m^3 0 0.38E-01 31 HPLC:Viola mg/m^3 0 0.23E-01 32 HPLC:Hex-fuco mg/m^3 0 0.323 33 HPLC:Diadino mg/m^3 0 0.86E-01 34 HPLC:Allo mg/m^3 0 0.43E-01 35 HPLC:Diato mg/m^3 0 0.11E-01 36 HPLC:Zea mg/m^3 0 0.25E-01 37 HPLC:Lut mg/m^3 0 0 38 HPLC:Chl-b mg/m^3 0 0.152 39 HPLC:DVChl-a mg/m^3 0 0 40 HPLC:Chl-a mg/m^3 0 1.225 41 HPLC:Phe mg/m^3 0 0 42 HPLC:B-Car mg/m^3 0 0.25E-01 43 HPLC:TChl-a mg/m^3 0 1.225 44 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 7 F ' ' 1 8 -99 ' ' 9 F ' ' 4 9 -99 ' ' 7 F ' ' 2 10 -99 ' ' 6 F ' ' 1 11 -99 ' ' 5 I I 0 12 -99 ' ' 7 F R4 2 13 -99 ' ' 3 NQ C ' ' 14 -99 ' ' 7 F R4 2 15 -99 ' ' 3 NQ C ' ' 16 -99 ' ' 8 F R4 3 17 -99 ' ' 3 NQ C ' ' 18 -99 ' ' 7 F R4 2 19 -99 ' ' 3 NQ C ' ' 20 -99 ' ' 7 F R4 2 21 -99 ' ' 3 NQ C ' ' 22 -99 ' ' 8 F R4 3 23 -99 ' ' 8 F R4 3 24 -99 ' ' 8 F R4 3 25 -99 ' ' 8 F R4 3 26 -99 ' ' 8 F R4 3 27 -99 ' ' 8 F R4 3 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2006-15 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : NE Pacific STATION : P4 EVENT NUMBER : 5 LATITUDE : 48 38.97000 N ! (deg min) LONGITUDE : 126 39.87000 W ! (deg min) WATER DEPTH : 1323 ALTIMETER (M) : 6.35 ! custom item *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0550 $TABLE: SENSORS ! Name Abs Depth Serial No ! ------------------------- -------------- ---------- temperature:primary ' ' 2668 conductivity:primary ' ' 2399 pressure ' ' 75636 temperature:secondary ' ' 2038 conductivity:secondary ' ' 2754 Fluorometer ' ' Seapoint transmissometer:primary ' ' 723DR Oxygen:SBE ' ' 0047 altimeter: ' ' ' ' irradiance:primary ' ' 4656 $END $REMARKS SOFTWARE VERSION SEASAVE WIN32 V 5.37D $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 3.0 2006/10/26 11:43:27 2301 2301 CLEAN 5.0 2006/10/26 15:43:18 ? ? ADDSAMP 3.4 2006/11/13 11:52:10 2301 2301 BINAVE 4.1.1 2006/11/13 11:53:29 2301 20 MERGE 3.3 2006/11/13 14:56:50 20 20 CLEAN 5.0 2006/11/13 14:56:56 ? ? CALIB 11.7 2006/11/15 17:12:36 20 20 SORT 3.5 2006/11/16 14:39:20 20 20 REMOVECH 7.0 2006/11/16 14:45:20 20 20 CHGUNITS 3.0 2006/11/16 14:46:22 20 20 REORDER 1.2.1 2006/11/16 14:48:17 ? ? HDREDIT2 2.5.1 2006/11/16 14:52:11 ? ? SORT 3.5 2008/04/09 16:41:19 20 20 MERGE 3.3 2008/04/09 16:41:27 20 20 SORT 3.5 2008/04/09 16:41:42 20 20 HDREDIT2 2.5.1 2008/04/09 16:42:25 ? ? CHANGE_FLAGS 1.0 2013/07/16 11:48:22 20 20 CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:32:32 20 20 CHANGE_FLAGS 2.0 2014/11/20 09:55:09 20 20 HDREDIT2 3.1.1 2019/10/28 14:32:28 ? ? SORT 3.6 2020/11/30 09:37:01 20 20 REORDER 1.3.1 2020/11/30 09:37:51 ? ? MERGE 3.5.1 2020/12/10 15:11:18 20 20 SORT 3.6 2020/12/10 15:12:25 20 20 CLEAN 5.2.4 2020/12/10 15:12:46 20 20 HDREDIT2 3.2 2020/12/10 15:13:51 ? ? HDREDIT2 3.2 2020/12/10 15:14:14 ? ? $END $REMARKS -CLEAN functions: 2006/10/26 15:43:14 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: Q:\Cruise_Data\2006-15\ctd files\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2006/11/13 14:56:50 2006/11/13 14:56:50 2006/11/13 14:56: Merge Channel: Bottle_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle, Chlorophyll:Extracted, Flag:Chlorophyll:Extracted, Oxygen:Dissolved, Flag:Oxygen:Dissolved, Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate Primary file : Q:\Cruise_Data\2006-15\CTD files\hydro\2006-15-0005.samavg Secondary file: Q:\Cruise_Data\2006-15\CTD files\hydro\2006-15-0005.mrgcln1 -CLEAN functions: 2006/11/13 14:56:56 20 Remove Sea-Bird comments from the header. Remove remark heading: "Comments from secondary" -CALIB parameters: 2006/11/15 17:12:36 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\Cruise_Data\2006-13\CTD\doc\2006-13-recal1-bot.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 3 Pressure dbars 10 0.1200000E+01 0.1000000E+01 11 Oxygen:Dissolved:SBE mL/L 10 0.4530000E-01 0.1023000E+01 17 Salinity:T1:C1 PSS-78 10 -0.1300000E-02 0.1000000E+01 -SORT parameters: 2006/11/16 14:39:20 Sorted in ascending order of channel Pressure -REMOVECH 2006/11/16 14:45:20 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Altimeter [metres] Descent_Rate [m/s] Status:Pump Salinity:T0:C0 [PSS-78] Flag -CHANGE units: 'Oxygen:Dissolved:SBE [mL/L]' changed from mL/L to umol/kg -HEADER EDITS: 2006/11/16 14:52:11 Applied edit header: O:\Data Processing\Header Comments\sal_oxy_chl_fresh_nut_analysis.txt Channel 2: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 5: Fluorescence:URU:Seapoint [mg/m^3] Name: Fluorescence:Seapoint ==> Fluorescence:URU:Seapoint Channel 6: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 8: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 -SORT parameters: 2008/04/09 16:41:19 Sorted in ascending order of channel Sample_Number -The following MERGE parameters were used: 2008/04/09 16:41:27 Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Dimethyl_Sulphide [nmol/L], Flag:Dimethyl_Sulphide [ ] Primary file : c:\data\dms\2006-15\2006-15-0005.che2 Secondary file: c:\data\dms\2006-15\2006-15-0005.dms -SORT parameters: 2008/04/09 16:41:42 Sorted in ascending order of channel Pressure -HEADER EDITS: 2008/04/09 16:42:25 - none. -HEADER EDITS: 2019/10/28 14:32:28 - none. -SORT parameters: 2020/11/30 09:37:01 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2020/12/10 15:11:18 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Gyr-de [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2006\2006-015\Processing\IOS\2006- 015-0005.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2006\2006-015\Processing\IOS\2006- 015-0005.hplc -SORT parameters: 2020/12/10 15:12:25 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2020/12/10 15:12:46 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2020/12/10 15:13:51 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2006\2006-015-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 12: Nitrate_plus_Nitrite [umol/L] Format: F6.1 ==> F7.2 Channel 22: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 23: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 24: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 25: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 26: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 27: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 28: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2020/12/10 15:14:14 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2006\2006-015-bot-hdr2.txt $END *COMMENTS Analysis methods: ----------------- Salinity samples are collected in glass bottles and analyzed on Guildline model 8410 Portasal Salinometers which are standardized with IAPSO standard seawater. Oxygen samples are analyzed on an automated Winkler titration system following the procedures of Carpenter (1965). A Brinkmann model 665 Dosimat and model PC910 Colorimeter is controlled by Visual-Basic program to titrate the oxygen samples. Nutrient samples are analyzed fresh on board using a Technicon AAII auto- analyzer following methods described in Barwell-Clarke and Whitney (1996). Chlorophyll samples are collected in duplicate in calibrated polycarbonate bottles (~330ml), then filtered onto 25mm MFS GF/75 filters at <70mmHg vacuum. The filters are placed in glass scintillation vials and immediately frozen at -20ºC until analysis. The chlorophyll is extracted in 10 ml of 90% acetone for 24h at -20ºC, then brought to room temperature and the extract is decanted and measured using a Turner Designs 10-AU-005-CE fluorometer, which has been calibrated with solutions of commercially prepared chlorophyll. HPLC samples were filtered onto 25mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~1.5 years after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a and Chlide-a For further information see file QF 2006-015_HPLC*.xlsx. The minimum detectable level for DMS is 0.10 nM, so “0” values should be interpreted as <0.10. For details on the collection and analysis of the DMS data see file 2006-15 DMSSF6 Report.doc. References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. J. Barwell-Clarke and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 3. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2006\2006-015\Processing\IOS\2006-015-0005.hplc --------------------------------------------------------------------------- Sample_Number 41: HPLC: >10%CV for TChl-a *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- -------- ---- ------ ------------ Pressure dbars 10 -99 () (1.2 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (0.453E-01 1.023) Salinity:T1:C1 PSS-78 10 -99 () (-0.13E-02 1) $END !-1-- -2-- --3--- ---4---- --5-- ---6--- --7--- ---8---- --9--- --10- -11- --12-- 13 --14-- 15 ---16-- 17 --18-- 19 --20-- 21 ---22-- ---23-- ---24-- ---25-- ---26-- ---27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- 44 !Samp Bott Pressu Temperat Trans Fluores PAR Salinity Oxygen Oxyge Numb Nitrat Fl Silica Fl Phospha Fl Dimeth Fl Chloro Fl HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ re ure: missi cence: :T1:C1 : n: er_o e_ ag te ag te ag yl_ ag phyll: ag Chl-c3 Chlide- Chl-c2 Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb Secondar vity URU: Dissol Disso ~bin plus_ ~t ~i ~p Sulphi ~p Extrac ~a a a fuco fuco : !er er y Seapoin ved: lved: _rec Nitrit ri ca ha de hi ted ct HP ! t SBE SBE ords e te te te de ed LC !---- ---- ------ -------- ----- ------- ------ -------- ------ ----- ---- ------ -- ------ -- ------- -- ------ -- ------ -- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 54 20 5.8 14.4029 37.3 1.046 283.7 32.0960 5.96 259.8 121 1.70 0 7.30 0 0.550 0 2.49 0 1.22 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 53 19 5.9 14.3903 43.4 1.523 356.9 32.1009 5.95 259.6 120 -99.00 0 -99.00 0 -99.000 0 -99.00 0 1.23 0 0.133 0.000 0.172 0.032 0.000 0.115 0.261 0.025 0.035 0.022 0.323 0.086 0.043 0.011 0.025 0.000 0.152 0.000 1.225 0.000 0.024 1.225 6 52 18 6.3 14.3803 47.7 1.332 431.7 32.1017 5.95 259.5 50 1.90 0 7.50 0 0.550 0 3.10 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 50 16 10.1 14.3690 49.2 1.838 145.6 32.1022 5.96 259.8 121 1.80 0 7.50 0 0.530 0 1.84 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 51 17 10.1 14.3687 49.5 1.906 115.1 32.1020 5.95 259.3 121 -99.00 0 -99.00 0 -99.000 0 -99.00 0 1.27 0 0.128 0.000 0.154 0.032 0.000 0.097 0.221 0.031 0.038 0.023 0.300 0.069 0.037 0.007 0.023 0.000 0.148 0.000 1.127 0.000 0.025 1.127 6 49 15 16.5 14.3418 49.0 1.754 131.7 32.1038 5.95 259.6 121 1.90 0 7.50 0 0.550 0 2.14 0 1.26 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 48 14 21.6 14.2759 50.2 1.727 65.8 32.1063 5.95 259.4 121 3.00 0 8.40 0 0.680 0 1.72 6 1.21 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 47 13 25.5 13.2038 55.6 1.016 41.1 32.2240 5.98 260.5 120 -99.00 0 -99.00 0 -99.000 0 -99.00 0 0.88 0 0.109 0.000 0.120 0.022 0.000 0.071 0.227 0.015 0.022 0.012 0.202 0.039 0.016 0.004 0.019 0.000 0.123 0.000 0.879 0.000 0.019 0.879 6 46 12 25.7 13.2133 55.7 1.061 43.3 32.2252 5.97 260.0 75 2.70 0 7.80 0 0.650 0 1.30 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 45 11 29.8 10.8593 60.4 0.423 26.2 32.4055 6.16 268.3 121 6.70 6 10.70 6 1.010 6 0.47 0 0.34 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 44 10 34.7 9.9715 61.2 0.273 17.7 32.4477 6.26 272.4 121 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 43 9 42.7 9.3823 61.2 0.273 8.4 32.4692 6.25 272.4 121 8.80 0 8.80 0 1.040 0 0.18 0 0.16 0 0.022 0.000 0.020 0.000 0.000 0.020 0.060 0.000 0.000 0.000 0.041 0.008 0.000 0.000 0.000 0.000 0.035 0.000 0.162 0.000 0.000 0.162 0 42 8 52.7 8.5163 60.9 0.244 4.0 32.4940 6.27 273.0 121 10.00 0 9.30 0 1.120 0 0.00 0 0.13 0 0.022 0.000 0.015 0.000 0.000 0.020 0.039 0.000 0.000 0.000 0.039 0.000 0.000 0.000 0.000 0.000 0.033 0.000 0.141 0.000 0.000 0.141 0 40 6 75.7 7.5505 61.6 0.136 1.4 32.7419 5.33 232.0 121 15.70 0 17.60 0 1.450 0 0.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 41 7 76.0 7.6466 61.4 0.135 1.3 32.7616 5.19 225.8 121 -99.00 0 -99.00 0 -99.000 0 -99.00 0 0.09 0 0.000 0.000 0.000 0.000 0.000 0.011 0.011 0.000 0.000 0.000 0.013 0.000 0.000 0.000 0.000 0.000 0.010 0.000 0.055 0.000 0.000 0.055 36 39 5 100.2 7.9144 61.0 0.085 0.7 33.4103 3.42 148.8 121 25.70 0 31.40 0 2.040 0 0.00 0 0.04 0 0.000 0.000 0.000 0.000 0.000 0.000 0.008 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0 38 4 151.1 7.7389 61.3 0.076 0.5 33.8881 2.13 92.7 121 -99.00 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 37 3 176.2 7.4256 61.2 0.076 0.5 33.9469 1.75 76.1 121 33.30 0 47.00 0 2.520 0 0.00 0 -99.00 0 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