*2021/11/23 15:22:46.93 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2005/09/15 23:21:24.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 13 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII NUMBER OF CHANNELS : 47 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 226 238 2 Bottle_Number n/a 1 13 3 Pressure decibar 1.4 185.3 4 Temperature:Primary 'deg C (ITS90)' 9.4816 15.656 5 Transmissivity %/metre 23.7 55.8 6 Fluorescence:URU:Seapoint mg/m^3 0.85E-01 6.08 7 PAR uE/m^2/sec 0 344.1 8 PAR:Reference uE/m^2/sec 737.3 888.6 9 Salinity:T0:C0 PSS-78 27.9657 30.8681 10 Oxygen:Dissolved:SBE mL/L 2.87 6.89 11 Oxygen:Dissolved:SBE umol/kg 125.1 301.7 12 Number_of_bin_records n/a 69 121 13 Salinity:Bottle PSS-78 29.4757 30.8527 14 Flag:Salinity:Bottle n/a 15 Oxygen:Dissolved mL/L 2.864 5.747 16 Flag:Oxygen:Dissolved n/a 17 Nitrate_plus_Nitrite umol/L 8.4 28.8 18 Flag:Nitrate_plus_Nitrite n/a 19 Silicate umol/L 26.9 61 20 Flag:Silicate n/a 21 Phosphate umol/L 0.98 2.65 22 Flag:Phosphate n/a 23 Chlorophyll:Extracted mg/m^3 0.16 5.23 24 Flag:Chlorophyll:Extracted n/a 25 HPLC:Chl-c3 mg/m^3 0 0.52E-01 26 HPLC:Chlide-a mg/m^3 0 0 27 HPLC:Chl-c2 mg/m^3 0.35E-01 0.227 28 HPLC:Peri mg/m^3 0 0.18E-01 29 HPLC:Pheide-a mg/m^3 0 0 30 HPLC:But-fuco mg/m^3 0 0.72E-01 31 HPLC:Fuco mg/m^3 0.103 0.62 32 HPLC:Neo mg/m^3 0 0.55E-01 33 HPLC:Pras mg/m^3 0.17E-01 0.106 34 HPLC:Viola mg/m^3 0 0.39E-01 35 HPLC:Hex-fuco mg/m^3 0 0.17E-01 36 HPLC:Diadino mg/m^3 0 0.39E-01 37 HPLC:Allo mg/m^3 0 0.161 38 HPLC:Diato mg/m^3 0 0 39 HPLC:Zea mg/m^3 0.19E-01 0.14 40 HPLC:Lut mg/m^3 0 0.18E-01 41 HPLC:Chl-b mg/m^3 0.97E-01 0.537 42 HPLC:DVChl-a mg/m^3 -99 -99 43 HPLC:Chl-a mg/m^3 0.429 2.808 44 HPLC:Phe mg/m^3 0 0 45 HPLC:B-Car mg/m^3 0 0.75E-01 46 HPLC:TChl-a mg/m^3 0.429 2.808 47 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 7 F ' ' 1 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 9 F ' ' 4 10 -99 ' ' 7 F ' ' 2 11 -99 ' ' 6 F ' ' 1 12 -99 ' ' 5 I I 0 13 -99 ' ' 9 F R4 4 14 -99 ' ' 3 NQ C ' ' 15 -99 ' ' 8 F ' ' 3 16 -99 ' ' 3 NQ C ' ' 17 -99 ' ' 6 F R4 1 18 -99 ' ' 3 NQ C ' ' 19 -99 ' ' 6 F R4 1 20 -99 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 -99 ' ' 3 NQ C ' ' 23 -99 ' ' 7 F R4 2 24 -99 ' ' 3 NQ C ' ' 25 -99 ' ' 8 F R4 3 26 -99 ' ' 8 F R4 3 27 -99 ' ' 8 F R4 3 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2005-25 AGENCY : IOS, Ocean Sciences Division, Sidney COUNTRY : Canada PROJECT : SoG/JdeF SCIENTIST : Pena A. PLATFORM : Vector *LOCATION GEOGRAPHIC AREA : Strait of Georgia /Juan de Fuca Strait STATION : 6 EVENT NUMBER : 73 LATITUDE : 49 30.62000 N ! (deg min) LONGITUDE : 124 27.99000 W ! (deg min) WATER DEPTH : 191 ALTIMETER (M) : 8.45 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0443 $TABLE: SENSORS ! Name Abs Depth Serial No ! ------------------------- -------------- ---------- temperature:primary ' ' 4484 conductivity:primary ' ' 3038 pressure ' ' 63507 temperature:secondary ' ' 2106 conductivity:secondary ' ' 1729 Fluorometer ' ' Seapoint transmissometer:primary ' ' 498DR Oxygen:SBE ' ' 0766 irradiance:primary ' ' 4565 altimeter: ' ' ' ' surface ' ' 'degrees = 0.0' $END $REMARKS SOFTWARE VERSION SEASAVE WIN32 V 5.35 Comments from secondary file: Q:\Cruise_Data\2005-25\CTD\hydro\2005-25-0073.add ------------------------------------------------- Dissolved oxygen concentration determined using an automated titration system consisting of a Brinkman dosimat (model 665) and a PC 900 Colorimeter. $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 2.9 2006/01/11 15:37:26 1520 1520 ADDSAMP 3.4 2006/01/13 09:32:26 1520 1520 BINAVE 4.1 2006/01/13 09:33:13 1520 13 MERGE 3.3 2006/01/13 16:01:06 13 13 MERGE 3.3 2006/02/06 15:36:32 13 13 MERGE 3.3 2006/02/06 15:36:48 13 13 MERGE 3.3 2006/02/06 15:37:16 13 13 CALIB 11.7 2006/02/06 16:55:02 13 13 CLEAN 4.8.1 2006/02/07 10:00:25 ? ? SORT 3.5 2006/02/07 10:03:26 13 13 REMOVECH 7.0 2006/02/07 10:06:17 13 13 CHGUNITS 2.1 2006/02/07 10:07:38 13 13 REORDER 1.2.1 2006/02/07 10:08:39 ? ? HDREDIT2 2.5.1 2006/02/07 10:16:02 ? ? HDREDIT2 2.5.1 2006/06/06 15:58:43 ? ? HDREDIT2 2.5.1 2006/12/12 18:02:21 ? ? CHANGE_FLAGS 1.0 2013/07/16 11:48:14 13 13 CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:32:16 13 13 CHANGE_FLAGS 2.0 2014/11/20 09:54:59 13 13 SORT 3.6 2021/01/12 16:26:00 13 13 REORDER 1.3.1 2021/11/23 15:21:40 ? ? MERGE 3.5.1 2021/11/23 15:21:47 13 13 SORT 3.6 2021/11/23 15:21:54 13 13 CLEAN 5.2.4 2021/11/23 15:22:02 13 13 HDREDIT2 3.2 2021/11/23 15:22:28 ? ? HDREDIT2 3.2 2021/11/23 15:22:46 ? ? $END $REMARKS -The following ADDSAMP parameters were used: Sample Number Lookup File: Q:\Cruise_Data\2005-25\CTD\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2006/01/13 16:01:05 2006/01/13 16:01:05 2006/01/13 16:01: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle Primary file : Q:\Cruise_Data\2005-25\CTD\hydro\2005-25-0073.samavg Secondary file: Q:\Cruise_Data\2005-25\CTD\hydro\2005-25-0073.sal -The following MERGE parameters were used: 2006/02/06 15:36:31 2006/02/06 15:36:31 2006/02/06 15:36: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Chlorophyll:Extracted, Flag:Chlorophyll:Extracted Primary file : Q:\Cruise_Data\2005-25\CTD\hydro\2005-25-0073.mrg1 Secondary file: Q:\Cruise_Data\2005-25\CTD\hydro\2005-25-0073.chl -The following MERGE parameters were used: 2006/02/06 15:36:47 2006/02/06 15:36:47 2006/02/06 15:36: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Oxygen:Dissolved, Flag:Oxygen:Dissolved Primary file : Q:\Cruise_Data\2005-25\CTD\hydro\2005-25-0073.mrg2 Secondary file: Q:\Cruise_Data\2005-25\CTD\hydro\2005-25-0073.add Comments from secondary file: Q:\Cruise_Data\2005-25\CTD\hydro\2005-25-0073.add ------------------------------------------------- C.H. Culbertson's paper on Dissolved Oxygen in the 'Woce Hydrographic Program Operations and Methods - July 1991' -The following MERGE parameters were used: 2006/02/06 15:37:15 2006/02/06 15:37:15 2006/02/06 15:37: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Nitrate, Flag:Nitrate, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate Primary file : Q:\Cruise_Data\2005-25\CTD\hydro\2005-25-0073.mrg3 Secondary file: Q:\Cruise_Data\2005-25\CTD\hydro\2005-25-0073.nuts -CALIB parameters: 2006/02/06 16:55:02 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\Cruise_Data\2005-25\CTD\doc\2005-25-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 3 Pressure dbars 10 0.4000000E+00 0.1000000E+01 11 Oxygen:Dissolved:SBE mL/L 10 0.1253000E+00 0.1394100E+01 -CLEAN functions: 2006/02/07 10:00:24 20 Change Pad Value to -99 in Channel: Oxygen:Dissolved:SBE [mL/L] Remove Sea-Bird comments from the header. -SORT parameters: 2006/02/07 10:03:26 Sorted in ascending order of channel Pressure [dbars] -REMOVECH 2006/02/07 10:06:17 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Altimeter [metres] Descent_Rate [m/s] Status:Pump Salinity:T1:C1 [PSS-78] Flag -CHANGE units: 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -HEADER EDITS: 2006/02/07 10:16:02 Applied edit header: Q:\Cruise_Data\2005-25\CTD\doc\2005-25-bot-hdr.txt Channel 2: Pressure [decibar] Units: dbars ==> decibar Format: F11.2 ==> F7.1 Channel 6: Fluorescence:URU:Seapoint [mg/m^3] Name: Fluorescence:Seapoint ==> Fluorescence:URU:Seapoint Channel 7: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 9: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 10: PAR:Reference [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 15: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 19: Nitrate [umol/L] Units: ==> umol/L Channel 21: Silicate [umol/L] Units: ==> umol/L Channel 23: Phosphate [umol/L] Units: ==> umol/L -HEADER EDITS: 2006/06/06 15:58:43 Channel 19: Nitrate_plus_Nitrite [umol/L] Name: Nitrate ==> Nitrate_plus_Nitrite Pad: ' ' ==> -99 Channel 20: Flag:Nitrate_plus_Nitrite [] Name: Flag:Nitrate ==> Flag:Nitrate_plus_Nitrite -HEADER EDITS: 2006/12/12 18:02:21 Applied edit header: Q:\Cruise_Data\Bottle Header Fix\fix-hdr-qual.txt -SORT parameters: 2021/01/12 16:26:00 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/23 15:21:47 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2005\2005-025_Nov2021\Processing\ IOS\2005-025-0073.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2005\2005-025_Nov2021\Processing\ IOS\2005-025-0073.hplc -SORT parameters: 2021/11/23 15:21:54 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/23 15:22:02 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/23 15:22:28 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2005\2005-025\Processing\Doc\ 2005-025-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 25: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 26: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 27: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 28: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/11/23 15:22:46 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2005\2005-025\Processing\Doc\ 2005-025-bot-hdr2.txt $END *COMMENTS Comments from secondary file: Q:\Cruise_Data\2005-25\CTD\hydro\2005-25-0073.chl ------------------------------------------------- Sample_Number 232: Extracted Chlorophyll: variability >10% Sample_Number 233: Extracted Chlorophyll: variability >10% Sample_Number 235: Extracted Chlorophyll: variability >10% Sample_Number 237: Extracted Chlorophyll: variability >10% Comments from secondary file: Q:\Cruise_Data\2005-25\CTD\hydro\2005-25-0073.nuts -------------------------------------------------- Nutrient Sample Number 226: salt crystals on rim of glass tube Nutrient Sample Number 227: salt crystals on rim of glass tube Nutrient Sample Number 228: salt crystals on rim of glass tube Nutrient Sample Number 229: salt crystals on rim of glass tube Nutrient Sample Number 230: salt crystals on rim of glass tube Nutrient Sample Number 231: salt crystals on rim of glass tube Nutrient Sample Number 232: salt crystals on rim of glass tube Nutrient Sample Number 233: salt crystals on rim of glass tube Nutrient Sample Number 235: Transferred glass tube to fit tray Analysis methods: ----------------- Salinity samples are collected in glass bottles and analyzed on a Guildline Autosal 8400 Salinometer which was standardized with IAPSO standard seawater. Oxygen samples are analyzed on an automated Winkler titration system following the procedures of Carpenter (1965). A Brinkmann model 665 Dosimat and model PC910 Colorimeter is controlled by Visual-Basic program to titrate the oxygen samples. Nutrient samples are analyzed frozen using a Technicon AAII autoanalyzer following methods described in Barwell-Clarke and Whitney (1996). Chlorophyll samples are collected in duplicate in calibrated polycarbonate bottles (~330ml), then filtered onto 25mm MFS GF/75 filters at <70mmHg vacuum. The filters are placed in glass scintillation vials and immediately frozen at -20ēC until analysis. The chlorophyll is extracted in 10 ml of 90% acetone for 24h at -20ēC, then brought to room temperature and the extract is decanted and measured using a Turner Designs 10-AU-005-CE fluorometer, which has been calibrated with solutions of commercially prepared chlorophyll. HPLC samples were filtered onto 25mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~26 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a and Chlide-a. For further information see file QF 2005-025_HPLC*.xlsx. References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. J. Barwell-Clarke and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 3. Nemcek, N. and Peņa, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. ------------------------------------------------------------------------------ Many of the chlorophyll data for this cruise had high variabilities, greater than 30%, which could not be easily explained by natural variability, sampling, or analytical errors. These data were removed. Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2005\2005-025_Nov2021\Processing\IOS\2005-025-0073. hplc --------------------------------------------------------------------------- Sample_Number 234: HPLC: one rep discarded due to poor pigment detection *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- ------- ---- ------ ------------ Pressure dbars 10 -99 () (0.4 1) Oxygen:Dissolved:SBE mL/L 10 -99 () (0.1253 1.3941) $END !-1-- -2-- --3--- ---4---- --5-- ---6--- --7--- --8--- ---9---- --10-- --11- -12- ---13--- 14 ---15-- 16 --17- 18 --19- 20 --21-- 22 --23-- 24 ---25-- ---26-- ---27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- 47 !Samp Bott Pressu Temperat Trans Fluores PAR PAR: Salinity Oxygen Oxyge Numb Salinity Fl Oxygen: Fl Nitra Fl Silic Fl Phosph Fl Chloro Fl HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ re ure: missi cence: Refere :T0:C0 : n: er_o :Bottle ag Dissolv ag te_ ag ate ag ate ag phyll: ag Chl-c3 Chlide- Chl-c2 Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb Primary vity URU: nce Dissol Disso ~bin ~o ed ~o plus_ ~t ~i ~p Extrac ~a a a fuco fuco : !er er Seapoin ved: lved: _rec tt lv Nitri ri ca ha ted ct HP ! t SBE SBE ords le ed te te te te ed LC !---- ---- ------ -------- ----- ------- ------ ------ -------- ------ ----- ---- -------- -- ------- -- ----- -- ----- -- ------ -- ------ -- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 238 13 1.4 15.6560 23.7 6.080 344.1 833.4 27.9657 6.89 301.7 121 -99.0000 0 -99.000 0 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 236 11 5.6 14.6911 33.5 4.286 81.0 838.8 28.0684 6.25 273.4 69 -99.0000 0 5.747 0 9.6 0 29.8 0 1.10 0 -99.00 0 0.052 0.000 0.227 0.018 0.000 0.072 0.620 0.055 0.106 0.039 0.017 0.039 0.161 0.000 0.140 0.018 0.537 -99.000 2.808 0.000 0.075 2.808 6 237 12 5.6 14.6732 33.6 4.268 81.0 838.8 28.0716 6.26 273.8 120 -99.0000 0 5.651 0 8.4 0 26.9 0 0.98 0 5.23 3 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 235 10 10.3 12.2708 50.6 1.577 28.0 845.1 28.7098 4.57 199.6 121 -99.0000 0 4.265 0 21.0 0 45.1 0 2.09 0 1.47 3 0.016 0.000 0.063 0.000 0.000 0.038 0.252 0.011 0.034 0.000 0.000 0.000 0.038 0.000 0.058 0.000 0.180 -99.000 0.991 0.000 0.023 0.991 6 234 9 20.4 10.9898 54.9 0.757 5.9 854.2 29.1925 3.78 165.0 121 -99.0000 0 3.767 0 24.9 0 50.3 0 2.15 0 -99.00 0 0.000 0.000 0.035 0.000 0.000 0.000 0.103 0.000 0.017 0.000 0.000 0.000 0.000 0.000 0.019 0.000 0.097 -99.000 0.429 0.000 0.000 0.429 2 233 8 30.5 10.8163 55.8 0.302 1.7 875.9 29.3692 3.61 157.5 121 -99.0000 0 3.592 0 19.6 0 40.2 0 1.48 0 0.26 3 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 232 7 40.3 10.5662 55.6 0.234 0.5 888.6 29.4606 3.47 151.7 121 29.4757 0 3.432 0 24.6 0 48.5 0 2.14 0 0.16 3 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 231 6 50.2 10.0671 55.4 0.135 0.2 882.4 29.6652 3.29 143.8 121 -99.0000 0 3.220 0 27.5 0 50.3 0 2.50 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 230 5 75.4 9.8609 54.1 0.095 0.0 862.0 30.2428 3.22 140.3 121 -99.0000 0 3.197 0 28.1 0 46.7 0 2.42 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 229 4 100.1 10.0630 51.6 0.099 0.0 837.8 30.6127 3.15 137.5 121 -99.0000 0 3.192 0 23.6 0 41.3 0 1.38 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 228 3 125.2 9.7607 52.2 0.085 0.0 810.9 30.7636 3.13 136.5 121 -99.0000 0 3.094 0 25.3 0 48.8 0 2.15 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 227 2 150.6 9.5671 52.7 0.087 0.0 774.8 30.8148 3.00 131.0 121 -99.0000 0 2.969 0 27.4 0 56.6 0 2.53 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 226 1 185.3 9.4816 48.3 0.092 0.0 737.3 30.8681 2.87 125.1 121 30.8527 0 2.864 0 28.8 0 61.0 0 2.65 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0