*2018/07/06 08:51:14.91 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2005/05/27 09:33:16.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 11 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII NUMBER OF CHANNELS : 22 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 22 32 2 Pressure decibar 4.867 189.87 3 Temperature:Primary 'deg C (ITS90)' 6.9719 11.8322 4 Transmissivity %/metre 33.9 59.9 5 Fluorescence:URU:Seapoint mg/m^3 0.71E-01 5.52 6 Oxygen:Dissolved:SBE mL/L 2.363 7.258 7 Oxygen:Dissolved:SBE umol/kg 102.7748 316.4088 8 Salinity:T0:C0 PSS-78 31.5352 33.7392 9 Bottle_Number n/a 1 11 10 Number_of_bin_records n/a 121 121 11 Salinity:Bottle PSS-78 31.6893 33.7146 12 Flag:Salinity:Bottle n/a 13 Oxygen:Dissolved mL/L 2.375 7.261 14 Flag:Oxygen:Dissolved n/a 15 Nitrate_plus_Nitrite umol/L 0.9 31.3 16 Flag:Nitrate_plus_Nitrite n/a 17 Silicate umol/L 4.1 51 18 Flag:Silicate n/a 19 Phosphate umol/L 0.41 2.46 20 Flag:Phosphate n/a 21 Chlorophyll:Extracted mg/m^3 1.585 2.723 22 Flag:Chlorophyll:Extracted n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 7 F ' ' 1 3 -99 ' ' 9 F ' ' 4 4 -99 ' ' 6 F ' ' 1 5 -99 ' ' 8 F ' ' 3 6 -99 ' ' 7 F ' ' 2 7 -99 ' ' 6 F ' ' 1 8 -99 ' ' 9 F ' ' 4 9 -99 ' ' 3 I I 0 10 -99 ' ' 5 I I 0 11 -99 ' ' 9 F R4 4 12 -99 ' ' 2 NQ C ' ' 13 -99 ' ' 8 F ' ' 3 14 -99 ' ' 2 NQ C ' ' 15 -99 ' ' 6 F R4 1 16 -99 ' ' 2 NQ C ' ' 17 -99 ' ' 6 F R4 1 18 -99 ' ' 2 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 -99 ' ' 2 NQ C ' ' 21 -99 ' ' 8 F R4 3 22 -99 ' ' 2 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2005-11 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : La Perouse SCIENTIST : Mackas D. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : WCVI STATION : CS09 EVENT NUMBER : 9 LATITUDE : 51 12.46000 N ! (deg min) LONGITUDE : 128 27.92000 W ! (deg min) *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0443 $TABLE: SENSORS ! Name Abs Depth Serial No ! ------------------------- -------------- ---------- temperature:primary ' ' 4484 conductivity:primary ' ' 3038 pressure ' ' 63507 temperature:secondary ' ' 2023 conductivity:secondary ' ' 2399 Fluorometer ' ' Seapoint transmissometer:primary ' ' 732DR Oxygen:SBE ' ' 0047 $END $REMARKS SOFTWARE VERSION SEASAVE WIN32 V 5.32 Comments from secondary file: Q:\Cruise_Data\2005-11\CTD\hydro\2005-11-0009.addsort ----------------------------------------------------- Dissolved oxygen concentration determined using an automated titration system consisting of a Brinkman dosimat (model 665) and a PC 900 Colorimeter. $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 2.9 2005/09/15 13:09:19 1331 1331 CLEAN 4.8 2005/09/15 13:11:17 ? ? ADDSAMP 3.4 2005/09/16 13:28:33 1331 1331 BINAVE 4.1 2005/09/16 13:29:07 1331 11 MERGE 3.3 2005/09/16 14:01:30 11 11 MERGE 3.3 2005/09/19 08:56:40 11 11 MERGE 3.3 2005/09/19 08:56:54 11 11 CALIB 11.5 2005/09/20 13:43:45 11 11 CLEAN 4.8 2005/09/20 15:57:44 ? ? MERGE 3.3 2005/10/06 13:08:07 11 11 SORT 3.5 2005/10/06 13:08:51 11 11 REMOVECH 7.0 2005/10/06 13:09:11 11 11 CHGUNITS 2.1 2005/10/06 13:09:31 11 11 REORDER 1.2.1 2005/10/10 11:01:28 ? ? HDREDIT2 2.5 2005/10/10 11:03:28 ? ? HDREDIT2 2.5.1 2006/06/06 15:49:40 ? ? CHANGE_FLAGS 1.0 2013/07/16 11:48:04 11 11 CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:32:04 11 11 CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/18 15:51:05 11 11 CHANGE_FLAGS 2.0 2014/11/20 09:54:46 11 11 CLEAN 5.2.3 2018/07/06 08:51:14 ? ? $END $REMARKS -CLEAN functions: 2005/09/15 13:11:14 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: Q:\Cruise_Data\2005-11\CTD\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2005/09/16 14:01:30 2005/09/16 14:01:30 2005/09/16 14:01: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle Primary file : Q:\Cruise_Data\2005-11\CTD\hydro\2005-11-0009.samavg Secondary file: Q:\Cruise_Data\2005-11\CTD\hydro\2005-11-0009.sal -The following MERGE parameters were used: 2005/09/19 08:56:40 2005/09/19 08:56:40 2005/09/19 08:56: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Oxygen:Dissolved, Flag:Oxygen:Dissolved Primary file : Q:\Cruise_Data\2005-11\CTD\hydro\2005-11-0009.mrg1 Secondary file: Q:\Cruise_Data\2005-11\CTD\hydro\2005-11-0009.addsort Comments from secondary file: Q:\Cruise_Data\2005-11\CTD\hydro\2005-11-0009.addsort ----------------------------------------------------- C.H. Culbertson's paper on Dissolved Oxygen in the 'Woce Hydrographic Program Operations and Methods - July 1991' -The following OXYCALC parameters were used Blank = 0.004 Sodium Thiosulfate concentration = 0.725 Volume of iodate standard (cm**3) = 9.98 Enter Normalitity of iodate standard = 0.01013000 -CLEAN functions: 2005/09/19 08:54:29 Reset #RECS, MIN & MAX values in header. -SORT parameters: 2005/09/19 08:56:21 Sorted in ascending order of channel Sample_Number -The following MERGE parameters were used: 2005/09/19 08:56:54 2005/09/19 08:56:54 2005/09/19 08:56: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Nitrate, Flag:Nitrate, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate Primary file : Q:\Cruise_Data\2005-11\CTD\hydro\2005-11-0009.mrg2 Secondary file: Q:\Cruise_Data\2005-11\CTD\hydro\2005-11-0009.nut Comments from secondary file: Q:\Cruise_Data\2005-11\CTD\hydro\2005-11-0009.nut ------------------------------------------------- -SORT parameters: 2005/09/16 14:03:51 Sorted in ascending order of channel Sample_Number -The following CALIB parameters were used: Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\Cruise_Data\2005-11\CTD\doc\2005-11-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 11 Oxygen:Dissolved:SBE mL/L 10 -0.4070000E-01 0.1214200E+01 -CLEAN functions: 2005/09/20 15:57:44 20 Remove Sea-Bird comments from the header. -The following MERGE parameters were used: 2005/10/06 13:08:07 2005/10/06 13:08:07 2005/10/06 13:08: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Chlorophyll:Extracted, Flag:Chlorophyll:Extracted Primary file : Q:\Cruise_Data\2005-11\CTD\hydro\2005-11-0009.mrgcln Secondary file: Q:\Cruise_Data\2005-11\CTD\hydro\2005-11-0009.chl -SORT parameters: 2005/10/06 13:08:51 Sorted in ascending order of channel Pressure -REMOVECH 2005/10/06 13:09:11 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Status:Pump Descent_Rate [m/s] Salinity:T1:C1 [PSS-78] Flag -CHANGE units: 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -HEADER EDITS: 2005/10/10 11:03:28 Applied edit header: Q:\Cruise_Data\2005-11\CTD\doc\2005-11-BOT-HDR.TXT Channel 2: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 5: Fluorescence:URU:Seapoint [mg/m^3] Name: Fluorescence:Seapoint ==> Fluorescence:URU:Seapoint Channel 6: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 11: Salinity:Bottle [PSS-78] Units: ==> PSS-78 Channel 13: Oxygen:Dissolved [mL/L] Pad: -99 ==> -99.99 Channel 15: Nitrate [umol/L] Units: ==> umol/L Channel 17: Silicate [umol/L] Units: ==> umol/L Channel 19: Phosphate [umol/L] Units: ==> umol/L -HEADER EDITS: 2006/06/06 15:49:40 Channel 15: Nitrate_plus_Nitrite [umol/L] Name: Nitrate ==> Nitrate_plus_Nitrite Channel 16: Flag:Nitrate_plus_Nitrite [] Name: Flag:Nitrate ==> Flag:Nitrate_plus_Nitrite -CLEAN functions: 2018/07/06 08:51:14 20 Change Pad Value to -99 in All Channels. $END *COMMENTS Comments from secondary file: Q:\Cruise_Data\2005-11\CTD\hydro\2005-11-0009.addsort ----------------------------------------------------- Oxygen flag c- small air bubble in flask. Oxygen samples 22-28, 31 and 32 were run through the DOXX program to modify flask volumes. The at-sea computer taken for sample analysis had the incorrect flask.vol file. In place of the actual flask number in use, the analyst used flask numbers that the flask.vol file did contain, so the samples could be titrated. Analysis methods: ----------------- Salinity samples are collected in glass bottles and analyzed on a Guildline model Autosal Salinometer which are standardized with IAPSO standard seawater. Oxygen samples are analyzed on an automated Winkler titration system following the procedures of Carpenter (1965). A Brinkmann model 665 Dosimat and model PC910 Colorimeter is controlled by Visual-Basic program to titrate the oxygen samples. Nutrient samples were collected in plastic test tubes. Nutrient samples were analyzed by Wendy Richardson fresh on board using a Technicon AAII auto-analyzer following methods described in Barwell-Clarke and Whitney (1996). Chlorophyll-a was analyzed on board JP Tully using the Chemistry Turner Designs Fluorometer. The fluorometer was calibrated against pure chlorophyll a (from Sigma) on February 17, 2005. Some of the 90 % acetone blanks seemed high - indicating that the cuvettes might not have been properly rinsed between samples References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. J. Barwell-Clarke and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- ------ ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (-0.407E-01 1.2142) $END !-1-- --2--- ---3---- --4-- ---5--- --6--- --7-- ---8---- 9- -10- ---11--- - ---13-- - --15- - --17- - --19-- - ---21-- - !Samp Pressu Temperat Trans Fluores Oxygen Oxyge Salinity Bo Numb Salinity F Oxygen: F Nitra F Silic F Phosph F Chlorop F !le_ re ure: missi cence: : n: :T0:C0 tt er_o :Bottle l Dissolv l te_ l ate l ate l hyll: l !Numb Primary vity URU: Dissol Disso ~u ~bin ~ ed ~ plus_ ~ ~ ~ Extract ~ !er Seapoin ved: lved: mb _rec l e Nitri t t t ed e ! t SBE SBE er ords e d te e e e d !---- ------ -------- ----- ------- ------ ----- -------- -- ---- -------- - ------- - ----- - ----- - ------ - ------- - *END OF HEADER 32 4.9 11.8322 33.9 5.520 7.26 316.4 31.6867 11 121 31.6893 0 7.261 3 0.9 0 4.1 0 0.41 0 2.723 0 31 9.4 11.6272 35.7 5.199 7.22 314.9 31.6611 10 121 -99.0000 0 7.182 0 1.2 0 4.4 0 0.45 0 2.535 0 30 20.3 10.1293 50.4 2.809 6.42 279.7 31.5352 9 121 -99.0000 0 6.425 0 5.4 0 8.4 0 0.84 0 1.585 0 29 28.9 10.1149 55.8 1.069 6.28 273.8 31.5941 8 121 -99.0000 0 6.269 0 5.2 0 8.6 0 0.87 0 -99.000 0 28 49.6 9.1781 59.4 0.235 5.84 254.3 31.8369 7 121 -99.0000 0 5.857 0 10.0 0 16.3 0 1.24 0 -99.000 0 27 74.6 8.9472 59.9 0.099 5.66 246.6 32.0394 6 121 -99.0000 0 5.674 0 10.8 0 17.0 0 1.24 0 -99.000 0 26 99.5 8.5606 59.5 0.080 4.76 207.1 32.4679 5 121 -99.0000 0 4.675 0 16.4 0 25.2 0 1.57 0 -99.000 0 25 124.7 7.9512 58.8 0.073 3.57 155.5 33.1328 4 121 -99.0000 0 3.607 0 23.5 0 33.3 0 1.93 0 -99.000 0 24 150.3 7.3575 56.8 0.076 2.74 119.0 33.5454 3 121 -99.0000 0 2.863 0 28.5 0 44.4 0 2.26 0 -99.000 0 23 175.6 7.0369 53.0 0.071 2.38 103.6 33.7149 2 121 33.7146 0 2.441 0 30.8 0 50.6 0 2.43 0 -99.000 0 22 189.9 6.9719 50.3 0.071 2.36 102.8 33.7392 1 121 -99.0000 0 2.375 0 31.3 0 51.0 0 2.46 0 -99.000 0