*2021/11/23 15:09:44.02 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2005/04/05 20:49:53.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 16 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII NUMBER OF CHANNELS : 45 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 74 89 2 Bottle_Number n/a 1 16 3 Pressure decibar 2.2 313.8 4 Temperature:Primary 'deg C (ITS90)' 8.4447 9.5612 5 Transmissivity %/metre 29.9 54.8 6 Fluorescence:URU:Seapoint mg/m^3 0.114 4.5 7 PAR uE/m^2/sec 0.5 101.2 8 PAR:Reference uE/m^2/sec 234.4 253.3 9 Salinity:T0:C0 PSS-78 28.5383 30.9965 10 Oxygen:Dissolved:SBE mL/L 2.62 5.59 11 Oxygen:Dissolved:SBE umol/kg 114.1 244.3 12 Number_of_bin_records n/a 121 121 13 Oxygen:Dissolved mL/L -99.99 5.621 14 Flag:Oxygen:Dissolved n/a 15 Nitrate_plus_Nitrite umol/L 21.5 30.7 16 Flag:Nitrate_plus_Nitrite n/a 17 Silicate umol/L 39.3 64 18 Flag:Silicate n/a 19 Phosphate umol/L 2.1 3.11 20 Flag:Phosphate n/a 21 Chlorophyll:Extracted mg/m^3 0.38 4.49 22 Flag:Chlorophyll:Extracted n/a 23 HPLC:Chl-c3 mg/m^3 0 0.46E-01 24 HPLC:Chlide-a mg/m^3 0 0.75E-01 25 HPLC:Chl-c2 mg/m^3 0.37E-01 0.407 26 HPLC:Peri mg/m^3 0 0.43E-01 27 HPLC:Pheide-a mg/m^3 0 0 28 HPLC:But-fuco mg/m^3 0 0.25E-01 29 HPLC:Fuco mg/m^3 0.228 1.73 30 HPLC:Neo mg/m^3 0 0.19E-01 31 HPLC:Pras mg/m^3 0 0.34E-01 32 HPLC:Viola mg/m^3 0 0.18E-01 33 HPLC:Hex-fuco mg/m^3 0 0.4E-01 34 HPLC:Diadino mg/m^3 0.15E-01 0.109 35 HPLC:Allo mg/m^3 0 0.43E-01 36 HPLC:Diato mg/m^3 0 0.15E-01 37 HPLC:Zea mg/m^3 0 0.41E-01 38 HPLC:Lut mg/m^3 0 0 39 HPLC:Chl-b mg/m^3 0 0.164 40 HPLC:DVChl-a mg/m^3 -99 -99 41 HPLC:Chl-a mg/m^3 0.432 4.035 42 HPLC:Phe mg/m^3 0 0.153 43 HPLC:B-Car mg/m^3 0.14E-01 0.8E-01 44 HPLC:TChl-a mg/m^3 0.432 4.11 45 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 7 F ' ' 1 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 9 F ' ' 4 10 -99 ' ' 7 F ' ' 2 11 -99 ' ' 6 F ' ' 1 12 -99 ' ' 5 I I 0 13 -99 ' ' 8 F ' ' 3 14 -99 ' ' 3 NQ C ' ' 15 -99 ' ' 6 F R4 1 16 -99 ' ' 3 NQ C ' ' 17 -99 ' ' 6 F R4 1 18 -99 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 -99 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 -99 ' ' 3 NQ C ' ' 23 -99 ' ' 8 F R4 3 24 -99 ' ' 8 F R4 3 25 -99 ' ' 8 F R4 3 26 -99 ' ' 8 F R4 3 27 -99 ' ' 8 F R4 3 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2005-10 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : SoG-JdeF SCIENTIST : Masson D. PLATFORM : Vector *LOCATION GEOGRAPHIC AREA : SoG-JdeF STATION : 42 EVENT NUMBER : 24 LATITUDE : 49 1.90000 N ! (deg min) LONGITUDE : 123 25.91000 W ! (deg min) ALTIMETER (M) : 2.93 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0443 $TABLE: SENSORS ! Name Abs Depth Serial No ! ------------------------- -------------- ---------- temperature:primary ' ' 2449 conductivity:primary ' ' 2102 pressure ' ' 63507 temperature:secondary ' ' 2968 conductivity:secondary ' ' 1729 Fluorometer ' ' Seapoint transmissometer:primary ' ' 333DR Oxygen:SBE ' ' 0766 altimeter: ' ' ' ' irradiance:primary ' ' 4656 surface ' ' 'degrees = 0.0' $END $REMARKS SOFTWARE VERSION SEASAVE WIN32 V 5.32 Comments from secondary file: Q:\Cruise_Data\2005-10\ctd\hydro\2005-10-0024.add ------------------------------------------------- Dissolved oxygen concentration determined using an automated titration system consisting of a Brinkman dosimat (model 665) and a PC 900 Colorimeter. $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 2.9 2005/10/29 16:33:08 1936 1936 CLEAN 4.8 2005/10/29 16:34:18 ? ? ADDSAMP 3.4 2005/11/01 08:16:26 1936 1936 BINAVE 4.1 2005/11/01 08:17:06 1936 16 MERGE 3.3 2005/11/01 11:16:28 16 16 MERGE 3.3 2005/11/01 11:20:06 16 16 MERGE 3.3 2005/11/01 11:25:57 16 16 MERGE 3.3 2005/11/01 11:29:03 16 16 CALIB 11.6 2005/11/05 11:47:04 16 16 CLEAN 4.8.1 2005/11/05 13:41:45 ? ? SORT 3.5 2005/11/05 13:42:10 16 16 REMOVECH 7.0 2005/11/05 13:42:40 16 16 CHGUNITS 2.1 2005/11/05 13:43:57 16 16 REORDER 1.2.1 2005/11/05 14:15:46 ? ? HDREDIT2 2.5.1 2005/11/05 14:18:05 ? ? HDREDIT2 2.5.1 2006/06/06 15:48:19 ? ? CHANGE_FLAGS 1.0 2013/07/29 14:30:02 16 16 CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:32:03 16 16 CHANGE_FLAGS 2.0 2014/11/20 09:54:45 16 16 SORT 3.6 2021/01/19 11:46:57 16 16 REORDER 1.3.1 2021/11/23 15:08:39 ? ? MERGE 3.5.1 2021/11/23 15:08:48 16 16 SORT 3.6 2021/11/23 15:08:56 16 16 CLEAN 5.2.4 2021/11/23 15:09:04 16 16 HDREDIT2 3.2 2021/11/23 15:09:27 ? ? HDREDIT2 3.2 2021/11/23 15:09:44 ? ? $END $REMARKS -CLEAN functions: 2005/10/29 16:34:10 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: Q:\Cruise_Data\2005-10\CTD\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -MERGE *** Secondary file not found *** Primary file : Q:\Cruise_Data\2005-10\CTD\hydro\2005-10-0024.samavg Secondary file: Q:\Cruise_Data\2005-10\CTD\hydro\2005-10-0024.sal -The following MERGE parameters were used: 2005/11/01 11:20:05 2005/11/01 11:20:05 2005/11/01 11:20: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Chlorophyll:Extracted, Flag:Chlorophyll:Extracted Primary file : Q:\Cruise_Data\2005-10\CTD\hydro\2005-10-0024.mrg1 Secondary file: Q:\Cruise_Data\2005-10\CTD\hydro\2005-10-0024.chl -The following MERGE parameters were used: 2005/11/01 11:25:57 2005/11/01 11:25:57 2005/11/01 11:25: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Oxygen:Dissolved, Flag:Oxygen:Dissolved Primary file : Q:\Cruise_Data\2005-10\ctd\hydro\2005-10-0024.mrg2 Secondary file: Q:\Cruise_Data\2005-10\ctd\hydro\2005-10-0024.add Comments from secondary file: Q:\Cruise_Data\2005-10\ctd\hydro\2005-10-0024.add ------------------------------------------------- C.H. Culbertson's paper on Dissolved Oxygen in the 'Woce Hydrographic Program Operations and Methods - July 1991' -The following MERGE parameters were used: 2005/11/01 11:29:02 2005/11/01 11:29:02 2005/11/01 11:29: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Nitrate, Flag:Nitrate, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate Primary file : Q:\Cruise_Data\2005-10\CTD\hydro\2005-10-0024.mrg3 Secondary file: Q:\Cruise_Data\2005-10\CTD\hydro\2005-10-0024.nuts -CALIB parameters: 2005/11/05 11:47:04 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\Cruise_Data\2005-10\CTD\doc\2005-10-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 12 Oxygen:Dissolved:SBE mL/L 10 0.4900000E-01 0.1370500E+01 -CLEAN functions: 2005/11/05 13:41:45 20 Remove Sea-Bird comments from the header. -SORT parameters: 2005/11/05 13:42:10 Sorted in ascending order of channel Pressure -REMOVECH 2005/11/05 13:42:40 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Altimeter [metres] Oxygen:Voltage:SBE [volts] Status:Pump Descent_Rate [m/s] Salinity:T1:C1 [PSS-78] Flag -CHANGE units: 'Oxygen:Dissolved:SBE' changed from mL/L to umol/kg -HEADER EDITS: 2005/11/05 14:18:05 Applied edit header: Q:\Cruise_Data\2005-10\CTD\doc\2005-10-bot-hdr.txt Channel 2: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 6: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 5: Fluorescence:URU:Seapoint [mg/m^3] Name: Fluorescence:Seapoint ==> Fluorescence:URU:Seapoint Channel 13: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 15: Oxygen:Dissolved [mL/L] Pad: -99.99 ==> -99 Channel 9: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 10: PAR:Reference [uE/m^2/sec] Format: F11.3 ==> F7.1 -HEADER EDITS: 2006/06/06 15:48:19 Channel 17: Nitrate_plus_Nitrite [umol/L] Name: Nitrate ==> Nitrate_plus_Nitrite Channel 18: Flag:Nitrate_plus_Nitrite [] Name: Flag:Nitrate ==> Flag:Nitrate_plus_Nitrite -SORT parameters: 2021/01/19 11:46:57 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/23 15:08:48 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2005\2005-010_Nov2021\Processing\ IOS\2005-010-0024.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2005\2005-010_Nov2021\Processing\ IOS\2005-010-0024.hplc -SORT parameters: 2021/11/23 15:08:56 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/23 15:09:04 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/23 15:09:27 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2005\2005-010\Processing\Doc\ 2005-010-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 23: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 24: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 25: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 26: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 27: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 28: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/11/23 15:09:44 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2005\2005-010\Processing\Doc\ 2005-010-bot-hdr2.txt $END *COMMENTS Comments from secondary file: Q:\Cruise_Data\2005-10\CTD\hydro\2005-10-0024.chl ------------------------------------------------- Average of two samples is reported. Comments from secondary file: Q:\Cruise_Data\2005-10\ctd\hydro\2005-10-0024.add ------------------------------------------------- *There is no sample analysis for oxygen sample 74. Autooxy program froze *during titration. *Oxygen samples 97 through 106 belong in 2005-10-0028.add. Oxygen sample *97 is unredeemable due to a problem with the colorimeter. Analysis methods: ----------------- Salinity samples are collected in glass bottles and analyzed on a Guildline Autosal 8400 Salinometer which was standardized with IAPSO standard seawater. Oxygen samples are analyzed on an automated Winkler titration system following the procedures of Carpenter (1965). A Brinkmann model 665 Dosimat and model PC910 Colorimeter is controlled by Visual-Basic program to titrate the oxygen samples. Nutrient samples are analyzed frozen using a Technicon AAII autoanalyzer following methods described in Barwell-Clarke and Whitney (1996). Chlorophyll samples are collected in duplicate in calibrated polycarbonate bottles (~330ml), then filtered onto 25mm MFS GF/75 filters at <70mmHg vacuum. The filters are placed in glass scintillation vials and immediately frozen at -20ēC until analysis. The chlorophyll is extracted in 10 ml of 90% acetone for 24h at -20ēC, then brought to room temperature and the extract is decanted and measured using a Turner Designs 10-AU-005-CE fluorometer, which has been calibrated with solutions of commercially prepared chlorophyll. HPLC samples were filtered onto 25mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 1-2 hours or for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~25-35 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a and DVchl-a, and Chlide-a. For further information see file QF 2005-010_HPLC*.xlsx. References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. J. Barwell-Clarke and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 3. Nemcek, N. and Peņa, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2005\2005-010_Nov2021\Processing\IOS\2005-010-0024. hplc --------------------------------------------------------------------------- Sample_Number 86: HPLC: >10%CV for TChl-a Sample_Number 87: HPLC: >30%CV for TChl-a Sample_Number 88: HPLC: >10%CV for TChl-a *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- ------ ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (0.49E-01 1.3705) $END !-1-- -2-- --3--- ---4---- --5-- ---6--- --7--- --8--- ---9---- --10-- --11- -12- ---13-- 14 --15- 16 --17- 18 --19-- 20 --21-- 22 ---23-- ---24-- ---25-- ---26-- ---27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- 45 !Samp Bott Pressu Temperat Trans Fluores PAR PAR: Salinity Oxygen Oxyge Numb Oxygen: Fl Nitra Fl Silic Fl Phosph Fl Chloro Fl HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ re ure: missi cence: Refere :T0:C0 : n: er_o Dissolv ag te_ ag ate ag ate ag phyll: ag Chl-c3 Chlide- Chl-c2 Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb Primary vity URU: nce Dissol Disso ~bin ed ~o plus_ ~t ~i ~p Extrac ~a a a fuco fuco : !er er Seapoin ved: lved: _rec lv Nitri ri ca ha ted ct HP ! t SBE SBE ords ed te te te te ed LC !---- ---- ------ -------- ----- ------- ------ ------ -------- ------ ----- ---- ------- -- ----- -- ----- -- ------ -- ------ -- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 89 16 2.2 8.6594 37.5 4.277 101.2 252.6 28.5436 5.59 244.3 121 5.479 0 21.5 0 39.3 0 2.10 0 4.14 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 88 15 4.9 8.6581 37.7 4.500 40.3 251.2 28.5383 5.51 240.7 121 5.621 0 22.6 0 40.3 0 2.10 0 4.49 0 0.027 0.075 0.407 0.000 0.000 0.012 1.730 0.000 0.000 0.000 0.000 0.109 0.000 0.000 0.000 0.000 0.000 -99.000 4.035 0.152 0.080 4.110 36 87 14 11.0 8.6708 39.6 4.193 7.3 249.2 28.6502 5.09 222.5 121 5.320 0 23.7 0 40.3 0 2.22 0 -99.00 0 0.046 0.039 0.242 0.043 0.000 0.025 0.983 0.019 0.034 0.018 0.040 0.078 0.043 0.000 0.041 0.000 0.164 -99.000 2.629 0.153 0.059 2.668 46 86 13 20.5 8.7073 53.6 0.409 1.6 247.1 29.5398 4.14 180.9 121 4.145 0 29.6 0 50.6 0 2.62 0 0.68 0 0.000 0.000 0.037 0.000 0.000 0.000 0.228 0.000 0.000 0.000 0.000 0.015 0.024 0.015 0.000 0.000 0.010 -99.000 0.432 0.000 0.014 0.432 36 85 12 29.7 8.7263 54.8 0.212 0.8 244.6 29.7400 4.06 177.3 121 3.730 0 30.7 0 52.7 0 2.66 0 0.49 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 84 11 40.1 8.6337 52.7 0.229 0.6 242.9 29.8646 4.35 189.8 121 4.224 0 29.6 0 50.9 0 2.54 0 0.38 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 83 10 51.1 8.5434 51.1 0.251 0.5 242.9 29.9063 4.48 195.6 121 4.540 0 28.8 0 50.7 0 2.50 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 82 9 74.1 8.4551 52.4 0.158 0.5 244.1 30.0207 4.54 197.9 121 4.737 0 28.8 0 51.8 0 2.43 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 81 8 100.2 8.4447 52.4 0.185 0.5 245.2 30.1570 5.07 220.9 121 5.082 0 25.1 0 45.9 0 2.18 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 80 7 124.8 8.4629 48.6 0.174 0.5 242.9 30.2824 4.79 208.9 121 4.765 0 26.6 0 50.8 0 2.32 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 79 6 149.9 8.5061 44.2 0.214 0.5 240.9 30.3369 4.73 206.4 121 4.814 0 25.9 0 48.2 0 2.29 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 78 5 175.2 8.6398 44.0 0.166 0.5 234.4 30.4909 4.25 185.3 121 4.248 0 27.6 0 51.5 0 2.47 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 77 4 200.5 8.7662 39.1 0.156 0.5 240.0 30.5980 3.92 171.1 121 3.982 0 28.0 0 55.6 0 2.52 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 76 3 249.5 9.3145 49.8 0.114 0.5 253.3 30.8570 3.08 134.3 121 3.078 0 29.3 0 59.9 0 2.82 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 75 2 299.5 9.4678 31.3 0.126 0.5 253.3 30.9559 2.76 120.3 121 2.731 0 29.6 0 62.9 0 3.11 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 74 1 313.8 9.5612 29.9 0.127 0.5 253.3 30.9965 2.62 114.1 121 -99.990 0 29.6 0 64.0 0 2.90 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0