*2021/11/23 14:38:03.34 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2005/03/03 10:09:37.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 13 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII NUMBER OF CHANNELS : 50 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 80 92 2 Bottle_Number n/a 1 13 3 Pressure decibar 2.2 112.5 4 Temperature:Secondary 'deg C (ITS90)' 8.2958 9.0751 5 Transmissivity %/metre 33.6 50.3 6 Fluorescence:URU:Seapoint mg/m^3 0.17 3.156 7 PAR uE/m^2/sec 0.5 1.3 8 PAR:Reference uE/m^2/sec 29.1 29.1 9 Salinity:T1:C1 PSS-78 32.1719 33.5756 10 Oxygen:Dissolved:SBE mL/L 3.16 7.02 11 Number_of_bin_records n/a 75 121 12 Salinity:Bottle PSS-78 33.5659 33.5659 13 Flag:Salinity:Bottle n/a 14 Oxygen:Dissolved mL/L -99.99 7.105 15 Flag:Oxygen:Dissolved n/a 16 Nitrate_plus_Nitrite umol/L 0.9 26.7 17 Flag:Nitrate_plus_Nitrite n/a 18 Silicate umol/L 2.7 37.2 19 Flag:Silicate n/a 20 Phosphate umol/L 0.5 2.13 21 Flag:Phosphate n/a 22 Chlorophyll:Extracted mg/m^3 2.83 3.23 23 Flag:Chlorophyll:Extracted n/a 24 HPLC:Chl-c3 mg/m^3 0.61E-01 0.62E-01 25 HPLC:Chlide-a mg/m^3 0.46E-01 0.5E-01 26 HPLC:MgDVP mg/m^3 0.8E-02 0.11E-01 27 HPLC:Chl-c2 mg/m^3 0.148 0.15 28 HPLC:Chl-c1 mg/m^3 0 0.7E-02 29 HPLC:Me-chlide mg/m^3 0 0 30 HPLC:Peri mg/m^3 0.9E-02 0.16E-01 31 HPLC:Pheide-a mg/m^3 0 0 32 HPLC:But-fuco mg/m^3 0 0 33 HPLC:Fuco mg/m^3 0.532 0.588 34 HPLC:Neo mg/m^3 0 0 35 HPLC:Pras mg/m^3 0 0 36 HPLC:Viola mg/m^3 0 0 37 HPLC:Hex-fuco mg/m^3 0.25E-01 0.26E-01 38 HPLC:Diadino mg/m^3 0.52E-01 0.56E-01 39 HPLC:Allo mg/m^3 0 0 40 HPLC:Diato mg/m^3 0 0.4E-02 41 HPLC:Zea mg/m^3 0 0 42 HPLC:Lut mg/m^3 0 0 43 HPLC:Chl-b mg/m^3 0 0 44 HPLC:C2mgdg mg/m^3 0 0.6E-02 45 HPLC:DVChl-a mg/m^3 0 0 46 HPLC:Chl-a mg/m^3 1.252 1.361 47 HPLC:Phe mg/m^3 0 0 48 HPLC:B-Car mg/m^3 0.26E-01 0.26E-01 49 HPLC:TChl-a mg/m^3 1.302 1.407 50 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 7 F ' ' 1 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 9 F ' ' 4 10 -99 ' ' 7 F ' ' 2 11 -99 ' ' 5 I I 0 12 -99 ' ' 9 F R4 4 13 -99 ' ' 3 NQ C ' ' 14 -99 ' ' 8 F ' ' 3 15 -99 ' ' 3 NQ C ' ' 16 -99 ' ' 6 F R4 1 17 -99 ' ' 3 NQ C ' ' 18 -99 ' ' 6 F R4 1 19 -99 ' ' 3 NQ C ' ' 20 -99 ' ' 7 F R4 2 21 -99 ' ' 3 NQ C ' ' 22 -99 ' ' 7 F R4 2 23 -99 ' ' 3 NQ C ' ' 24 -99 ' ' 8 F R4 3 25 -99 ' ' 8 F R4 3 26 -99 ' ' 8 F R4 3 27 -99 ' ' 8 F R4 3 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2005-02 AGENCY : IOS, Ocean Science and Productivity, Sidney, B.C. COUNTRY : Canada PROJECT : Optical Properties Off Vancouver Island SCIENTIST : Pena A. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : WCVI/Strait of Georgia STATION : LCB3 EVENT NUMBER : 17 LATITUDE : 48 34.51000 N ! (deg min) LONGITUDE : 125 29.99000 W ! (deg min) ALTIMETER (M) : 3.69 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0443 $TABLE: SENSORS ! Name Abs Depth Serial No ! ------------------------- -------------- ---------- temperature:primary ' ' 2668 conductivity:primary ' ' 2399 pressure ' ' 63507 temperature:secondary ' ' 2106 conductivity:secondary ' ' 1763 Fluorometer ' ' Seapoint transmissometer:primary ' ' 333DR Oxygen:SBE ' ' 0766 irradiance:primary ' ' 4656 altimeter: ' ' ' ' surface ' ' 'degrees = 0.0' $END $REMARKS SOFTWARE VERSION SEASAVE WIN32 V 5.32 Comments from secondary file: Q:\Cruise_Data\2005-02\ctd\hydro\2005-02-0017.add ------------------------------------------------- Dissolved oxygen concentration determined using an automated titration system consisting of a Brinkman dosimat (model 665) and a PC 900 Colorimeter. $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 2.9 2005/04/04 15:22:43 1526 1526 CLEAN 4.7.1 2005/04/04 15:24:49 1526 1526 ADDSAMP 3.4 2005/04/19 09:39:28 1526 1526 BINAVE 4.1 2005/04/19 09:39:53 1526 13 MERGE 3.3 2005/04/19 10:14:06 13 13 MERGE 3.3 2005/04/19 10:16:46 13 13 CALIB 11.4 2005/04/19 15:27:16 13 13 CLEAN 4.7.1 2005/04/20 14:54:36 ? ? SORT 3.5 2005/04/20 14:54:51 13 13 REMOVECH 7.0 2005/04/20 15:29:08 13 13 HDREDIT2 2.4 2005/04/20 16:09:56 ? ? SORT 3.5 2005/05/29 12:17:09 13 13 MERGE 3.3 2005/05/29 12:17:13 13 13 CALIB 11.4 2005/05/29 13:08:13 13 13 SORT 3.5 2005/05/29 13:43:51 13 13 SORT 3.5 2005/07/05 16:56:15 13 13 MERGE 3.3 2005/07/05 16:56:45 13 13 SORT 3.5 2005/07/05 17:00:34 13 13 CHANGE_FLAGS 1.0 2013/07/29 14:29:57 13 13 CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:31:56 13 13 CHANGE_FLAGS 2.0 2014/11/20 09:54:39 13 13 CLEAN 5.2.3 2018/07/06 08:45:41 ? ? SORT 3.6 2021/03/22 08:36:50 13 13 REORDER 1.3.1 2021/11/23 14:37:00 ? ? MERGE 3.5.1 2021/11/23 14:37:08 13 13 SORT 3.6 2021/11/23 14:37:15 13 13 CLEAN 5.2.4 2021/11/23 14:37:22 13 13 HDREDIT2 3.2 2021/11/23 14:37:46 ? ? HDREDIT2 3.2 2021/11/23 14:38:03 ? ? $END $REMARKS -CLEAN functions: 2005/04/04 15:24:37 20 Interpolation by Channel 1: Scan_Number [n/a] in Pressure Change Pad Value to -99 in Channel: Oxygen:Dissolved:SBE [mL/L] Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: Q:\Cruise_Data\2005-02\ctd\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 0.50 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: 2005/04/19 10:14:05 2005/04/19 10:14: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Chlorophyll:Extracted, Flag:Chlorophyll:Extracted Primary file : Q:\Cruise_Data\2005-02\ctd\hydro\2005-02-0017.samavg Secondary file: Q:\Cruise_Data\2005-02\ctd\hydro\2005-02-0017.chl -The following MERGE parameters were used: 2005/04/19 10:16:46 2005/04/19 10:16: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Oxygen:Dissolved, Flag:Oxygen:Dissolved Primary file : Q:\Cruise_Data\2005-02\ctd\hydro\2005-02-0017.mrg1 Secondary file: Q:\Cruise_Data\2005-02\ctd\hydro\2005-02-0017.add Comments from secondary file: Q:\Cruise_Data\2005-02\ctd\hydro\2005-02-0017.add ------------------------------------------------- C.H. Culbertson's paper on Dissolved Oxygen in the 'Woce Hydrographic Program Operations and Methods - July 1991' -The following CALIB parameters were used: Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\Cruise_Data\2005-02\ctd\doc\2005-02-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 11 Oxygen:Dissolved:SBE mL/L 10 0.1110000E+00 0.1463000E+01 -CLEAN functions: 2005/04/20 14:54:36 20 Remove Sea-Bird comments from the header. -SORT parameters: 2005/04/20 14:54:51 Sorted in ascending order of channel Pressure -REMOVECH 2005/04/20 15:29:08 The following CHANNEL(S) were removed: Scan_Number Temperature:Primary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Oxygen:Voltage:SBE [volts] Altimeter [metres] Descent_Rate [m/s] Salinity:T0:C0 [PSS-78] Flag -HEADER EDITS: 2005/04/20 16:09:56 Applied edit header: Q:\Cruise_Data\2005-02\ctd\doc\2005-02-bot-hdr.txt Channel 2: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 5: Fluorescence:URU:Seapoint [mg/m^3] Name: Fluorescence:Seapoint ==> Fluorescence:URU:Seapoint Channel 6: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 7: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 8: PAR:Reference [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 12: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 13: Flag:Chlorophyll:Extracted [n/a] Units: ==> n/a Channel 15: Flag:Oxygen:Dissolved [n/a] Units: newunits ==> n/a -SORT parameters: 2005/05/29 12:17:09 Sorted in ascending order of channel Sample_Number -The following MERGE parameters were used: 2005/05/29 12:17:13 2005/05/29 12:17:13 2005/05/29 12:17: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle Primary file : Q:\Cruise_Data\2005-02\ctd\hydro\2005-02-0017.pche2 Secondary file: Q:\Cruise_Data\2005-02\ctd\hydro\2005-02-0017.sal -The following CALIB parameters were used: Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\Cruise_Data\2005-02\ctd\doc\2005-02-recal2.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 10 Salinity:T1:C1 PSS-78 10 0.4400000E-02 0.1000000E+01 -SORT parameters: 2005/05/29 13:43:51 Sorted in ascending order of channel Pressure -SORT parameters: 2005/07/05 16:56:15 Sorted in descending order of channel Sample_Number -The following MERGE parameters were used: 2005/07/05 16:56:44 2005/07/05 16:56:44 2005/07/05 16:56: Merge Channel: Sample_Number Merge Scheme Used: Interweave Records from Both Files Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate Primary file : H:\Data Processing\2005\2005-02\NUts\2005-02-0017.srt_che Secondary file: H:\Data Processing\2005\2005-02\NUts\2005-02-0017.ios -SORT parameters: 2005/07/05 17:00:34 Sorted in ascending order of channel Pressure -CLEAN functions: 2018/07/06 08:45:41 20 Change Pad Value to -99 in All Channels. -SORT parameters: 2021/03/22 08:36:50 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/23 14:37:08 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2005\2005-002_Nov2021\Processing\ IOS\2005-002-0017.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2005\2005-002_Nov2021\Processing\ IOS\2005-002-0017.hplc -SORT parameters: 2021/11/23 14:37:15 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/23 14:37:22 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/23 14:37:46 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2005\2005-002\Processing\Doc\ 2005-002-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 24: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 25: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 26: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 27: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 28: HPLC:Chl-c1 [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:C2mgdg [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/11/23 14:38:03 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2005\2005-002\Processing\Doc\ 2005-002-bot-hdr2.txt $END *COMMENTS Analysis methods: ----------------- Salinity samples are collected in glass bottles and analyzed on Guildline model 8410 Portasal Salinometers which are standardized with IAPSO standard seawater. Oxygen samples are analyzed on an automated Winkler titration system following the procedures of Carpenter (1965). A Brinkmann model 665 Dosimat and model PC910 Colorimeter is controlled by Visual-Basic program to titrate the oxygen samples. Nutrient samples are analyzed frozen using a Technicon AAII autoanalyzer following methods described in Barwell-Clarke and Whitney (1996). Chlorophyll samples are collected in duplicate in calibrated polycarbonate bottles (~330ml), then filtered onto 25mm MFS GF/75 filters at <70mmHg vacuum. The filters are placed in glass scintillation vials and immediately frozen at -20ēC until analysis. The chlorophyll is extracted in 10 ml of 90% acetone for 24h at -20ēC, then brought to room temperature and the extract is decanted and measured using a Turner Designs 10-AU-005-CE fluorometer, which has been calibrated with solutions of commercially prepared chlorophyll. HPLC samples were filtered onto 25mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~3 years after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a and DVchl-a, and Chlide-a and Me-chlide. For further information see file QF 2005-002_HPLC*.xlsx. References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. J. Barwell-Clarke and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 3. Nemcek, N. and Peņa, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2005\2005-002_Nov2021\Processing\IOS\2005-002-0017. hplc --------------------------------------------------------------------------- Sample_Number 87: HPLC: TChl-a low compared to Turner values, all pigments may be underestimated Sample_Number 91: HPLC: TChl-a low compared to Turner values, all pigments may be underestimated *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- -------- ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (0.111 1.463) Salinity:T1:C1 PSS-78 10 -99 () (0.44E-02 1) $END !-1-- -2-- --3--- ---4---- --5-- ---6--- --7--- --8--- ---9---- --10-- -11- ---12--- 13 ---14-- 15 --16- 17 --18- 19 --20-- 21 --22-- 23 ---24-- ---25-- ---26-- ---27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- 50 !Samp Bott Pressu Temperat Trans Fluores PAR PAR: Salinity Oxygen Numb Salinity Fl Oxygen: Fl Nitra Fl Silic Fl Phosph Fl Chloro Fl HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ re ure: missi cence: Refere :T1:C1 : er_o :Bottle ag Dissolv ag te_ ag ate ag ate ag phyll: ag Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b C2mgdg DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb Secondar vity URU: nce Dissol ~bin ~o ed ~o plus_ ~t ~i ~p Extrac ~a a chlide a fuco fuco : !er er y Seapoin ved: _rec tt lv Nitri ri ca ha ted ct HP ! t SBE ords le ed te te te te ed LC !---- ---- ------ -------- ----- ------- ------ ------ -------- ------ ---- -------- -- ------- -- ----- -- ----- -- ------ -- ------ -- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 92 13 2.2 9.0748 42.0 3.036 1.3 29.1 32.1719 7.01 121 -99.0000 0 7.057 0 0.9 0 2.9 0 0.51 0 3.15 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 90 11 4.2 9.0739 42.2 2.968 0.8 29.1 32.1726 7.01 121 -99.0000 0 7.002 0 1.1 0 2.7 0 0.51 0 3.23 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 91 12 4.2 9.0747 42.0 2.992 0.8 29.1 32.1723 7.02 121 -99.0000 0 -99.990 0 -99.0 0 -99.0 0 -99.00 0 -99.00 0 0.062 0.046 0.008 0.150 0.007 0.000 0.009 0.000 0.000 0.588 0.000 0.000 0.000 0.025 0.052 0.000 0.000 0.000 0.000 0.000 0.006 0.000 1.361 0.000 0.026 1.407 46 89 10 8.7 9.0751 42.0 3.156 0.6 29.1 32.1720 7.01 121 -99.0000 0 7.105 0 1.0 0 2.9 0 0.50 0 3.14 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 88 9 14.8 9.0635 43.0 2.890 0.5 29.1 32.1769 6.98 121 -99.0000 0 7.054 0 1.2 0 3.2 0 0.53 0 3.05 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 86 7 19.8 9.0165 43.5 2.803 0.5 29.1 32.1871 6.91 75 -99.0000 0 6.860 0 1.9 0 3.6 0 0.54 0 3.09 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 87 8 20.2 9.0162 43.4 2.775 0.5 29.1 32.1872 6.91 120 -99.0000 0 -99.990 0 -99.0 0 -99.0 0 -99.00 0 -99.00 0 0.061 0.050 0.011 0.148 0.000 0.000 0.016 0.000 0.000 0.532 0.000 0.000 0.000 0.026 0.056 0.000 0.004 0.000 0.000 0.000 0.000 0.000 1.252 0.000 0.026 1.302 46 85 6 25.9 9.0001 44.1 2.394 0.5 29.1 32.1940 6.83 121 -99.0000 0 6.798 0 2.8 0 4.1 0 0.60 0 3.08 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 84 5 28.9 8.9914 44.1 2.361 0.5 29.1 32.2015 6.76 121 -99.0000 0 6.674 0 3.1 0 5.0 0 0.65 0 2.83 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 83 4 50.0 8.9657 50.3 0.375 0.5 29.1 32.7341 5.29 121 -99.0000 0 5.332 0 14.0 0 16.6 0 1.29 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 82 3 73.2 8.8598 46.8 0.294 0.5 29.1 32.9993 4.52 121 -99.0000 0 4.556 0 19.0 0 23.8 0 1.61 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 81 2 99.1 8.4282 39.7 0.187 0.5 29.1 33.5004 3.28 121 -99.0000 0 3.297 0 25.3 0 34.9 0 2.07 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 80 1 112.5 8.2958 33.6 0.170 0.5 29.1 33.5756 3.16 121 33.5659 0 3.146 0 26.7 0 37.2 0 2.13 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0