*2018/07/06 08:59:33.73 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2004/09/05 18:22:38.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 7 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII NUMBER OF CHANNELS : 18 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 28 34 2 Pressure decibar 5.687 94.96 3 Temperature:Primary 'deg C (ITS90)' 7.3038 12.3629 4 Transmissivity %/metre 49.6 58.8 5 Fluorescence:URU:Seapoint mg/m^3 0.176 1.046 6 Salinity:T0:C0 PSS-78 32.1816 33.4393 7 Bottle_Number n/a 1 7 8 Number_of_bin_records n/a 121 121 9 Chlorophyll:Extracted mg/m^3 0.94 1.35 10 Flag:Chlorophyll:Extracted n/a 11 Oxygen:Dissolved mL/L 3.518 5.693 12 Flag:Oxygen:Dissolved n/a 13 Nitrate_plus_Nitrite umol/L 9.1 27 14 Flag:Nitrate_plus_Nitrite n/a 15 Silicate umol/L 19.4 38.9 16 Flag:Silicate n/a 17 Phosphate umol/L 1.07 2.09 18 Flag:Phosphate n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 7 F ' ' 1 3 -99 ' ' 9 F ' ' 4 4 -99 ' ' 6 F ' ' 1 5 -99 ' ' 8 F ' ' 3 6 -99 ' ' 9 F ' ' 4 7 -99 ' ' 3 I I 0 8 -99 ' ' 5 I I 0 9 -99 ' ' 7 F R4 2 10 -99 ' ' 2 NQ C ' ' 11 -99 ' ' 8 F ' ' 3 12 -99 ' ' 3 NQ C ' ' 13 -99 ' ' 6 F R4 1 14 -99 ' ' 2 NQ C ' ' 15 -99 ' ' 6 F R4 1 16 -99 ' ' 2 NQ C ' ' 17 -99 ' ' 7 F R4 2 18 -99 ' ' 2 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2004-25 AGENCY : IOS, Ocean Science and Productivity, Sidney, B.C. COUNTRY : Canada PROJECT : La Perouse SCIENTIST : Yelland D. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : West Coast Vancouver Island STATION : CS4 EVENT NUMBER : 33 LATITUDE : 50 49.18000 N ! (deg min) LONGITUDE : 129 13.17000 W ! (deg min) WATER DEPTH : 100 ALTIMETER (M) : 6.45 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0585 $TABLE: SENSORS ! Name Abs Depth Serial No ! ------------------------- -------------- ---------- temperature:primary ' ' 2106 conductivity:primary ' ' 1763 pressure ' ' 77511 temperature:secondary ' ' 2449 conductivity:secondary ' ' 1766 Fluorometer ' ' Seapoint transmissometer:primary ' ' 333DR altimeter: ' ' ' ' $END $REMARKS SOFTWARE VERSION SEASAVE WIN32 V 5.31A Comments from secondary file: Q:\Cruise_Data\2004-25\ctd\hydro\2004-25-0033.add ------------------------------------------------- Dissolved oxygen concentration determined using an automated titration system consisting of a Brinkman dosimat (model 665) and a PC 900 Colorimeter. $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 2.9 2005/02/19 16:30:40 847 847 CLEAN 4.7.1 2005/02/19 16:32:01 ? ? ADDSAMP 3.4 2005/02/21 09:06:54 847 847 BINAVE 4.1 2005/02/23 12:15:19 847 7 MERGE 3.3 2005/02/23 12:15:47 7 7 MERGE 3.3 2005/03/07 14:39:08 7 7 MERGE 3.3 2005/03/23 15:51:05 7 7 MERGE 3.3 2005/03/23 15:53:41 7 7 CALIB 11.4 2005/03/23 16:05:43 7 7 CLEAN 4.7.1 2005/03/23 16:07:18 ? ? SORT 3.5 2005/03/23 16:07:30 7 7 REMOVECH 7.0 2005/03/23 16:12:20 7 7 HDREDIT2 2.4 2005/03/23 16:33:26 ? ? CHANGE_FLAGS 1.0 2013/07/16 11:47:51 7 7 CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:31:26 7 7 CHANGE_FLAGS 2.0 2014/11/20 09:54:30 7 7 CLEAN 5.2.3 2018/07/06 08:59:33 ? ? $END $REMARKS -CLEAN functions: 2005/02/19 16:31:54 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: Q:\Cruise_Data\2004-25\CTD\hydro\post\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -MERGE *** Secondary file not found *** Primary file : Q:\Cruise_Data\2004-25\ctd\hydro\2004-25-0033.samavg Secondary file: Q:\Cruise_Data\2004-25\ctd\hydro\2004-25-0033.sal -The following MERGE parameters were used: 2005/03/07 14:39:08 2005/03/07 14:39: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Chlorophyll:Extracted, Flag:Chlorophyll:Extracted Primary file : Q:\Cruise_Data\2004-25\CTD\hydro\2004-25-0033.mrg1 Secondary file: Q:\Cruise_Data\2004-25\CTD\hydro\2004-25-0033.chl -The following MERGE parameters were used: 2005/03/23 15:51:05 2005/03/23 15:51: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Oxygen:Dissolved, Flag:Oxygen:Dissolved Primary file : Q:\Cruise_Data\2004-25\ctd\hydro\2004-25-0033.mrg2 Secondary file: Q:\Cruise_Data\2004-25\ctd\hydro\2004-25-0033.add Comments from secondary file: Q:\Cruise_Data\2004-25\ctd\hydro\2004-25-0033.add ------------------------------------------------- C.H. Culbertson's paper on Dissolved Oxygen in the 'Woce Hydrographic Program Operations and Methods - July 1991' -The following OXYCALC parameters were used Blank = 0.003 Sodium Thiosulfate concentration = 0.719 Volume of iodate standard (cm**3) = 9.98 Enter Normalitity of iodate standard = 0.01014000 -REMOVECH 2005/03/23 15:34:14 The following CHANNEL(S) were removed: Oxygen:Dissolved [mL/L] -The following MERGE parameters were used: 2005/03/23 15:53:41 2005/03/23 15:53: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate Primary file : Q:\Cruise_Data\2004-25\CTD\hydro\2004-25-0033.mrg3 Secondary file: Q:\Cruise_Data\2004-25\CTD\hydro\2004-25-0033.nut1 Comments from secondary file: Q:\Cruise_Data\2004-25\CTD\hydro\2004-25-0033.nut1 -------------------------------------------------- -SORT parameters: 2005/02/23 14:19:49 Sorted in ascending order of channel Sample_Number -The following CALIB parameters were used: Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\Cruise_Data\2004-25\ctd\doc\2004-25-recal.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 13 Salinity:T0:C0 PSS-78 10 -0.1700000E-02 0.1000000E+01 -CLEAN functions: 2005/03/23 16:07:17 20 Remove Sea-Bird comments from the header. -SORT parameters: 2005/03/23 16:07:30 Sorted in ascending order of channel Pressure -REMOVECH 2005/03/23 16:12:20 The following CHANNEL(S) were removed: Scan_Number Temperature:Secondary [deg C (ITS90)] Conductivity:Primary [S/m] Conductivity:Secondary [S/m] Altimeter [metres] Descent_Rate [m/s] Status:Pump Salinity:T1:C1 [PSS-78] Flag -HEADER EDITS: 2005/03/23 16:33:26 Applied edit header: Q:\Cruise_Data\2004-25\CTD\doc\2004-25-bot-hdr.txt Channel 2: Pressure [decibar] Units: dbars ==> decibar Format: F10.3 ==> F7.1 Channel 5: Fluorescence:URU:Seapoint [mg/m^3] Name: Fluorescence:Seapoint ==> Fluorescence:URU:Seapoint Channel 9: Chlorophyll:Extracted [mg/m^3] Units: ==> mg/m^3 Channel 11: Oxygen:Dissolved [mL/L] Format: F7.3 ==> F8.3 -CLEAN functions: 2018/07/06 08:59:33 20 Change Pad Value to -99 in All Channels. $END *COMMENTS Comments from secondary file: Q:\Cruise_Data\2004-25\ctd\hydro\2004-25-0033.add ------------------------------------------------- Oxygen flag c- bubbles in flask prior to titration. Analysis methods: ----------------- Salinity samples are collected in glass bottles and analyzed on Guildline model 8410 Portasal Salinometers which are standardized with IAPSO standard seawater. Oxygen samples are analyzed on an automated Winkler titration system following the procedures of Carpenter (1965). A Brinkmann model 665 Dosimat and model PC910 Colorimeter is controlled by Visual-Basic program to titrate the oxygen samples. Nutrient samples are analyzed fresh on board using a Technicon AAII auto- analyzer following methods described in Barwell-Clarke and Whitney (1996). The nutrients were analysed fresh at sea, by Wendy Richardson Precision was determined by analyzing replicate samples drawn from one Niskin. Pooled standard deviation of pairs of samples (Sp) was calculated by: Sp = SQRT{sum (d*d)/2k} where k = no. of pairs and d = difference between pairs Sp for nitrate for the range 1.5 to 45.3 uM was 0.08 Sp for silicate for the range 10.6 to 153.2 uM was 0.16 Sp for phosphate for the range 0.44 to 3.25 uM was 0.017 Accuracy was determined by using commercially available standards from WAKO Chemicals (Sagami Chemical Company of Japan). The values were within 0.77 % of the 20 uM Nitrate Standard and 0.72 % of the 100 uM Silicate standard. Chlorophyll samples are collected in calibrated polycarbonate bottles (~330ml), then filtered onto 25mm MFS GF/75 filters at <70mmHg vacuum. The filters are placed in glass scintillation vials and immediately frozen at -20ºC until analysis. The chlorophyll is extracted in 10 ml of 90% acetone for 24h at -20ºC, then brought to room temperature and the extract is decanted and measured using a Turner Designs 10-AU-005-CE fluorometer, which has been calibrated with solutions of commercially prepared chlorophyll. NOTE: All Chlorophyll samples were filtered within 4 hours of being sampled unless otherwise reported. Only 1 sample per cast was collected in duplicate. References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. J. Barwell-Clarke and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------- -------- ---- ------ ------------ Salinity:T0:C0 PSS-78 10 -99 () (-0.17E-02 1) $END !-1-- --2--- ---3---- --4-- ---5--- ---6---- 7- -8-- --9--- - ---11-- 12 --13- - --15- - --17-- - !Samp Pressu Temperat Trans Fluores Salinity Bo Numb Chloro F Oxygen: Fl Nitra F Silic F Phosph F !le_ re ure: missi cence: :T0:C0 tt er_o phyll: l Dissolv ag te_ l ate l ate l !Numb Primary vity URU: ~u ~bin Extrac ~ ed ~o plus_ ~ ~ ~ !er Seapoin mb _rec ted e lv Nitri t t t ! t er ords d ed te e e e !---- ------ -------- ----- ------- -------- -- ---- ------ - ------- -- ----- - ----- - ------ - *END OF HEADER 34 5.7 12.3629 49.6 0.979 32.1816 7 121 1.35 0 5.660 3 9.1 0 19.4 0 1.07 0 33 10.4 11.7413 50.8 0.963 32.2599 6 121 1.18 0 5.693 3 9.7 0 19.8 0 1.17 0 32 20.7 11.4825 52.3 0.977 32.2880 5 121 0.94 0 5.468 3 11.6 0 20.3 0 1.26 0 31 31.5 10.8907 53.5 1.046 32.3578 4 121 -99.00 0 5.405 3 12.5 0 20.7 0 1.32 0 30 51.1 8.2129 58.8 0.341 32.7748 3 121 -99.00 0 4.900 3 18.9 0 24.4 0 1.63 0 29 77.3 7.8019 57.9 0.222 33.1242 2 121 -99.00 0 3.935 3 23.8 0 33.8 0 1.92 0 28 95.0 7.3038 57.8 0.176 33.4393 1 121 -99.00 0 3.518 3 27.0 0 38.9 0 2.09 0