*2021/11/23 13:55:24.15 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2004/06/24 21:22:31.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 13 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII NUMBER OF CHANNELS : 43 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 221 233 2 Bottle_Number n/a 1 13 3 Pressure decibar 1.9 183.5 4 Temperature:Primary 'deg C (ITS90)' 8.6744 18.536 5 Transmissivity %/metre 40.9 56.1 6 PAR uE/m^2/sec 0.5 786 7 PAR:Reference uE/m^2/sec 2003.5 2480.7 8 Salinity:T0:C0 PSS-78 25.7018 30.5868 9 Oxygen:Dissolved:SBE mL/L 3.73 8.1 10 Number_of_bin_records n/a 121 121 11 Salinity:Bottle PSS-78 26.6208 30.5982 12 Flag:Salinity:Bottle n/a 13 Oxygen:Dissolved mL/L 3.741 8.079 14 Flag:Oxygen:Dissolved n/a 15 Nitrate_plus_Nitrite umol/L 0 28.4 16 Flag:Nitrate_plus_Nitrite n/a 17 Silicate umol/L 6.1 56.6 18 Flag:Silicate n/a 19 Phosphate umol/L 0.19 2.56 20 Flag:Phosphate n/a 21 Chlorophyll:Extracted mg/m^3 0.16 1.63 22 Flag:Chlorophyll:Extracted n/a 23 Fluorescence:URU mg/m^3 0.157 1.679 24 HPLC:Chl-c3 mg/m^3 0 0.149 25 HPLC:Chl-c2 mg/m^3 0.73E-01 0.221 26 HPLC:Peri mg/m^3 0 0.114 27 HPLC:But-fuco mg/m^3 0 0.52E-01 28 HPLC:Fuco mg/m^3 0.304 0.711 29 HPLC:Neo mg/m^3 0 0.24E-01 30 HPLC:Pras mg/m^3 0 0.42E-01 31 HPLC:Viola mg/m^3 0 0.41E-01 32 HPLC:Hex-fuco mg/m^3 0 0.52E-01 33 HPLC:Diadino mg/m^3 0.15E-01 0.56E-01 34 HPLC:Allo mg/m^3 0.7E-02 0.48E-01 35 HPLC:Diato mg/m^3 0 0.5E-02 36 HPLC:Zea mg/m^3 0.39E-01 0.273 37 HPLC:Lut mg/m^3 0 0 38 HPLC:Chl-b mg/m^3 0 0.162 39 HPLC:DVChl-a mg/m^3 -99 -99 40 HPLC:Chl-a mg/m^3 0.713 1.736 41 HPLC:B-Car mg/m^3 0.23E-01 0.62E-01 42 HPLC:TChl-a mg/m^3 0.713 1.736 43 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 7 F ' ' 1 7 -99 ' ' 7 F ' ' 1 8 -99 ' ' 9 F ' ' 4 9 -99 ' ' 7 F ' ' 2 10 -99 ' ' 5 I I 0 11 -99 ' ' 9 F R4 4 12 -99 ' ' 3 NQ C ' ' 13 -99 ' ' 8 F ' ' 3 14 -99 ' ' 3 NQ C ' ' 15 -99 ' ' 6 F R4 1 16 -99 ' ' 3 NQ C ' ' 17 -99 ' ' 6 F R4 1 18 -99 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 -99 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 -99 ' ' 3 NQ C ' ' 23 -99 ' ' 8 F ' ' 3 24 -99 ' ' 8 F R4 3 25 -99 ' ' 8 F R4 3 26 -99 ' ' 8 F R4 3 27 -99 ' ' 8 F R4 3 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2004-21 AGENCY : IOS, Ocean Science and Productivity, Sidney, B.C. COUNTRY : Canada PROJECT : JdeF/SoG SCIENTIST : Masson D. PLATFORM : Vector *LOCATION GEOGRAPHIC AREA : Juan de Fuca Strait /Strait of Georgia STATION : 6 EVENT NUMBER : 69 LATITUDE : 49 30.56000 N ! (deg min) LONGITUDE : 124 27.82000 W ! (deg min) WATER DEPTH : 189 ALTIMETER (M) : 8.79 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0585 $TABLE: SENSORS ! Name Abs Depth Serial No ! ------------------------- -------------- ---------- temperature:primary ' ' 2023 conductivity:primary ' ' 1763 pressure ' ' 77511 temperature:secondary ' ' 2095 conductivity:secondary ' ' 1764 Fluorometer ' ' Seapoint Oxygen:SBE ' ' 0047 transmissometer:primary ' ' 498DR irradiance ' ' primary altimeter: ' ' ' ' surface ' ' 'degrees = 0.0' $END $REMARKS SOFTWARE VERSION SEASAVE WIN32 V 5.30A Comments from secondary file: Q:\Cruise_Data\2004-21\ctd\hydro\2004-21-0069.add1 -------------------------------------------------- Dissolved oxygen concentration determined using an automated titration system consisting of a Brinkman dosimat (model 665) and a PC 900 Colorimeter. $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 2.8 2004/09/27 12:53:49 1573 1573 CLEAN 4.7.1 2004/09/27 12:54:34 ? ? ADDSAMP 3.4 2004/09/27 16:33:22 1573 1573 BINAVE 4.0.1 2004/09/27 16:38:33 1573 13 MERGE 3.1 2004/09/27 17:38:37 13 13 MERGE 3.1 2004/09/28 10:48:34 13 13 MERGE 3.1 2004/10/01 16:16:00 13 13 CALIB 11.4 2004/10/01 17:10:42 13 13 CLEAN 4.7.1 2004/10/04 16:02:08 ? ? SORT 3.4.1 2004/10/04 16:02:15 13 13 REMOVECH 6.0 2004/10/04 16:02:43 13 13 HDREDIT2 2.3 2004/10/04 16:05:40 ? ? SORT 3.5 2004/11/29 15:56:32 13 13 MERGE 3.3 2004/11/29 15:56:46 13 13 SORT 3.5 2004/11/29 15:59:35 13 13 CHANGE_FLAGS 1.0 2013/07/16 11:47:48 13 13 CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:31:03 13 13 CHANGE_FLAGS 2.0 2014/11/20 09:54:26 13 13 CLEAN 5.2.3 2018/07/06 08:59:18 ? ? SORT 3.6 2021/01/19 09:14:56 13 13 REORDER 1.3.1 2021/11/23 13:50:31 ? ? MERGE 3.5.1 2021/11/23 13:53:57 13 13 SORT 3.6 2021/11/23 13:54:06 13 13 CLEAN 5.2.4 2021/11/23 13:54:16 13 13 HDREDIT2 3.2 2021/11/23 13:55:05 ? ? HDREDIT2 3.2 2021/11/23 13:55:24 ? ? $END $REMARKS -CLEAN functions: 2004/09/27 12:54:01 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: Q:\Cruise_Data\2004-21\ctd\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle Primary file : Q:\Cruise_Data\2004-21\CTD\hydro\2004-21-0069.samavg Secondary file: Q:\Cruise_Data\2004-21\CTD\hydro\2004-21-0069.sal -The following MERGE parameters were used: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Oxygen:Dissolved, Flag:Oxygen:Dissolved Primary file : Q:\Cruise_Data\2004-21\ctd\hydro\2004-21-0069.mrg1 Secondary file: Q:\Cruise_Data\2004-21\ctd\hydro\2004-21-0069.add1 Comments from secondary file: Q:\Cruise_Data\2004-21\ctd\hydro\2004-21-0069.add1 -------------------------------------------------- C.H. Culbertson's paper on Dissolved Oxygen in the 'Woce Hydrographic Program Operations and Methods - July 1991' -The following OXYCALC parameters were used Blank = 0.002 Sodium Thiosulfate concentration = 0.725 Volume of iodate standard (cm**3) = 9.98 Enter Normalitity of iodate standard = 0.01013000 -HEADER EDITS: 2004/09/28 10:48:29 Channel 10: Flag:Oxygen:Dissolved [] Name ==> Flag:Oxygen:Dissolved -The following MERGE parameters were used: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Chlorophyll:Extracted, Flag:Chlorophyll:Extracted Primary file : Q:\Cruise_Data\2004-21\ctd\hydro\2004-21-0069.mrg2 Secondary file: Q:\Cruise_Data\2004-21\ctd\hydro\2004-21-0069.chl -The following CALIB parameters were used: Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\Cruise_Data\2004-21\ctd\doc\2004-21-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 9 Oxygen:Dissolved:SBE mL/L 10 0.7000000E-01 0.1043700E+01 16 Salinity:T0:C0 PSS-78 10 0.1500000E-02 0.1000000E+01 17 Salinity:T1:C1 PSS-78 10 -0.3000000E-02 0.1000000E+01 -CLEAN functions: 2004/10/04 16:02:06 20 Remove Sea-Bird comments from the header. -The following SORT parameters were used. Sorted by channel: Pressure Pressure channel sorted according to values in sort channel -The following CHANNEL(S) were removed from file. Scan_Number Temperature:Secondary Conductivity:Primary Conductivity:Secondary Altimeter Status:Pump Descent_Rate Salinity:T1:C1 Flag -HEADER EDITS: 2004/10/04 16:05:40 Applied edit header: O:\Data Processing\Header Comments\sal_oxy_chl_frozen_nut_ Channel 2: Pressure [dbar] Units ==> dbar Format: F10.3 ==> F7.1 Channel 5: Oxygen:Dissolved:SBE [mL/L] Format: F8.3 ==> F7.2 Channel 6: Fluorescence:URU [mg/m^3] Name ==> Fluorescence:URU Channel 7: PAR [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 8: PAR:Reference [uE/m^2/sec] Format: F11.3 ==> F7.1 Channel 11: Number_of_bin_records [n/a] Format: F5.0 ==> I5 Channel 12: Salinity:Bottle [PSS-78] Units ==> PSS-78 Channel 16: Chlorophyll:Extracted [mg/m^3] Units ==> mg/m^3 -SORT parameters: 2004/11/29 15:56:32 Sorted in descending order of channel Sample_Number -The following MERGE parameters were used: 2004/11/29 15:56:45 2004/11/29 15:56: Merge Channel: Sample_Number Merge Scheme Used: Interweave Records from Both Files Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Nitrate_plus_Nitrite [umol/L], Flag:Nitrate_plus_Nitrite [ ], Silicate [umol/L], Flag:Silicate [ ], Phosphate [umol/L], Flag:Phosphate [ ] Primary file : H:\Data Processing\2004\2004-21\2004-21-0069.srt_che Secondary file: H:\Data Processing\2004\2004-21\2004-21-0069.nut -SORT parameters: 2004/11/29 15:59:35 Sorted in ascending order of channel Pressure -CLEAN functions: 2018/07/06 08:59:17 20 Change Pad Value to -99 in All Channels. -SORT parameters: 2021/01/19 09:14:56 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/23 13:53:57 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2004\2004-021_Nov2021\Processing\ IOS\2004-021-0069.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2004\2004-021_Nov2021\Processing\ IOS\2004-021-0069.hplc -SORT parameters: 2021/11/23 13:54:06 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/23 13:54:16 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/23 13:55:05 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2004\2004-021\Processing\Doc\ 2004-021-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 24: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 25: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 26: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 27: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 28: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/11/23 13:55:24 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2004\2004-021\Processing\Doc\ 2004-021-bot-hdr2.txt $END *COMMENTS Comments from secondary file: Q:\Cruise_Data\2004-21\CTD\hydro\2004-21-0069.sal ------------------------------------------------- Samples 222 and 232 are flagged because of uncertainties in the sample numbers. The two sample numbers appear to have been reversed in the analysis stage. They have been changed and agree better with the CTD and with nearby bottles. Comments from secondary file: Q:\Cruise_Data\2004-21\ctd\hydro\2004-21-0069.chl ------------------------------------------------- Average of two samples is reported. Variability is assessed as the % (std dev/mean*100). Samples 229 and 230 - variability >10% Analysis methods: ----------------- Salinity samples are collected in glass bottles and analyzed on Guildline model 8410 Portasal Salinometers which are standardized with IAPSO standard seawater. Oxygen samples are analyzed on an automated Winkler titration system following the procedures of Carpenter (1965). A Brinkmann model 665 Dosimat and model PC910 Colorimeter is controlled by Visual-Basic program to titrate the oxygen samples. Nutrient samples are analyzed frozen using a Technicon AAII autoanalyzer following methods described in Barwell-Clarke and Whitney (1996). Chlorophyll samples are collected in duplicate in calibrated polycarbonate bottles (~330ml), then filtered onto 25mm MFS GF/75 filters at <70mmHg vacuum. The filters are placed in glass scintillation vials and immediately frozen at -20ēC until analysis. The chlorophyll is extracted in 10 ml of 90% acetone for 24h at -20ēC, then brought to room temperature and the extract is decanted and measured using a Turner Designs 10-AU-005-CE fluorometer, which has been calibrated with solutions of commercially prepared chlorophyll. HPLC samples were filtered onto 25mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 1-2 hours or for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~40 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a and DVchl-a. For further information see file QF 2004-021_HPLC*.xlsx. References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. J. Barwell-Clarke and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 3. Nemcek, N. and Peņa, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- -------- ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (0.7E-01 1.0437) Salinity:T0:C0 PSS-78 10 -99 () (0.15E-02 1) Salinity:T1:C1 PSS-78 10 -99 () (-0.3E-02 1) $END !-1-- -2-- --3--- ---4---- --5-- --6--- --7--- ---8---- --9--- -10- ---11--- 12 ---13-- 14 --15- 16 --17- 18 --19-- 20 --21-- 22 ---23-- ---24-- ---25-- ---26-- ---27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- 43 !Samp Bott Pressu Temperat Trans PAR PAR: Salinity Oxygen Numb Salinity Fl Oxygen: Fl Nitra Fl Silic Fl Phosph Fl Chloro Fl Fluores HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ re ure: missi Refere :T0:C0 : er_o :Bottle ag Dissolv ag te_ ag ate ag ate ag phyll: ag cence: Chl-c3 Chl-c2 Peri But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Car TChl-a ag !Numb Numb Primary vity nce Dissol ~bin ~o ed ~o plus_ ~t ~i ~p Extrac ~a URU fuco fuco : !er er ved: _rec tt lv Nitri ri ca ha ted ct HP ! SBE ords le ed te te te te ed LC !---- ---- ------ -------- ----- ------ ------ -------- ------ ---- -------- -- ------- -- ----- -- ----- -- ------ -- ------ -- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 233 13 1.9 18.5360 44.3 786.0 2003.5 25.7018 6.73 121 -99.0000 0 6.866 0 0.0 0 7.0 0 0.19 0 0.79 3 0.577 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 232 12 6.2 16.9321 43.6 250.1 2027.0 26.5536 7.11 121 26.6208 3 7.324 0 0.0 0 6.1 0 0.25 0 1.07 0 1.061 0.073 0.112 0.039 0.000 0.304 0.022 0.037 0.041 0.052 0.044 0.047 0.000 0.273 0.000 0.162 -99.000 1.314 0.062 1.314 6 231 11 11.4 13.1629 40.9 88.3 2039.0 28.2619 8.10 121 -99.0000 0 8.079 0 1.0 0 7.5 0 0.56 0 1.63 0 1.679 0.149 0.221 0.114 0.052 0.711 0.024 0.042 0.028 0.034 0.056 0.048 0.000 0.119 0.000 0.162 -99.000 1.736 0.056 1.736 6 230 10 21.0 10.6441 52.7 13.0 2065.8 29.1138 4.59 121 -99.0000 0 4.671 0 20.9 0 44.3 0 1.93 0 0.40 3 0.572 0.000 0.073 0.000 0.011 0.347 0.000 0.000 0.000 0.000 0.015 0.007 0.005 0.039 0.000 0.000 -99.000 0.713 0.023 0.713 6 229 9 31.3 10.1194 54.5 3.3 2087.7 29.4103 4.38 121 -99.0000 0 4.448 0 24.5 0 49.1 0 2.17 0 0.29 3 0.318 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 228 8 41.2 9.8997 55.2 1.3 2212.0 29.5188 4.06 121 -99.0000 0 4.083 0 25.5 0 49.8 0 2.09 0 0.16 0 0.233 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 227 7 51.5 9.4442 56.0 0.7 2136.6 29.7236 3.90 121 -99.0000 0 3.921 0 26.5 0 50.5 0 2.31 0 -99.00 0 0.200 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 226 6 76.3 8.6744 56.1 0.5 2171.4 30.0029 4.09 121 -99.0000 0 4.084 0 26.9 0 47.0 0 2.43 0 -99.00 0 0.176 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 225 5 101.4 8.8686 54.2 0.5 2260.7 30.2429 4.27 121 -99.0000 0 4.325 0 26.2 0 44.0 0 2.27 0 -99.00 0 0.171 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 224 4 126.8 8.9466 54.3 0.5 2357.6 30.3722 4.28 121 -99.0000 0 4.299 0 26.2 0 44.9 0 2.21 0 -99.00 0 0.164 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 223 3 151.3 8.9537 54.2 0.5 2328.8 30.4603 4.07 121 -99.0000 0 3.853 0 27.5 0 49.6 0 2.29 0 -99.00 0 0.162 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 222 2 176.2 8.9841 52.1 0.5 2480.7 30.5789 3.76 121 30.5896 3 3.760 0 28.0 0 54.9 0 2.48 0 -99.00 0 0.161 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 221 1 183.5 8.9896 52.2 0.5 2417.8 30.5868 3.73 121 30.5982 0 3.741 0 28.4 0 56.6 0 2.56 0 -99.00 0 0.157 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0