*2014/11/20 09:54:25.71 *IOS HEADER VERSION 1.10 2011/10/26 2011/10/26 *FILE START TIME : UTC 2004/09/01 01:59:44.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 9 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII NUMBER OF CHANNELS : 18 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- --------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 359 367 2 Pressure decibar 4.4 119.3 3 Temperature:Primary 'deg C (ITS90)' 7.1247 11.748 4 Transmissivity %/metre 32.4 50.7 5 Fluorescence:URU:Seapoint mg/m^3 0.174 2.315 6 Bottle_Number n/a 1 9 7 Salinity:T0:C0 PSS-78 30.3533 33.0551 8 Number_of_bin_records n/a 72 121 9 Salinity:Bottle PSS-78 29.3783 33.0394 10 Flag:Salinity:Bottle n/a 11 Oxygen:Dissolved mL/L 2.315 6.136 12 Flag:Oxygen:Dissolved n/a 13 Nitrate_plus_Nitrite umol/L 10.4 29.9 14 Flag:Nitrate_plus_Nitrite n/a 15 Silicate umol/L 21.5 60.9 16 Flag:Silicate n/a 17 Phosphate umol/L 1.21 2.56 18 Flag:Phosphate n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 7 F ' ' 1 3 -99 ' ' 9 F ' ' 4 4 -99 ' ' 6 F ' ' 1 5 -99 ' ' 8 F ' ' 3 6 -99 ' ' 3 I I 0 7 -99 ' ' 9 F ' ' 4 8 ' ' ' ' 5 I I 0 9 -99 ' ' 9 F R4 4 10 0 ' ' 2 NQ C ' ' 11 -99 ' ' 8 F ' ' 3 12 0 ' ' 2 NQ C ' ' 13 -99 ' ' ' ' F6.1 R4 ' ' 14 0 ' ' 2 NQ C ' ' 15 -99 ' ' ' ' F6.1 R4 ' ' 16 0 ' ' 2 NQ C ' ' 17 -99 ' ' ' ' F7.2 R4 ' ' 18 0 ' ' 2 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2004-20 AGENCY : IOS, Ocean Science and Productivity, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Whitney F. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : N.E. Pacific STATION : SS7 EVENT NUMBER : 69 LATITUDE : 51 24.77000 N ! (deg min) LONGITUDE : 127 47.60000 W ! (deg min) WATER DEPTH : 124 ALTIMETER (M) : 4.13 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0585 $TABLE: SENSORS ! Name Abs Depth Serial No ! ------------------------- -------------- ---------- temperature:primary ' ' 2023 conductivity:primary ' ' 1763 pressure ' ' 77511 temperature:secondary ' ' 2106 conductivity:secondary ' ' 2102 Fluorometer ' ' Seapoint transmissometer:primary ' ' 732DR altimeter: ' ' ' ' $END $REMARKS SOFTWARE VERSION SEASAVE WIN32 V 5.31A Comments from secondary file: Q:\Cruise_Data\2004-20\CTD\hydro\2004-20-0069.addnew ---------------------------------------------------- Dissolved oxygen concentration determined using an automated titration system consisting of a Brinkman dosimat (model 665) and a PC 900 Colorimeter. $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 2.8 2004/09/24 08:30:05 1039 1039 CLEAN 4.7.1 2004/09/24 08:31:40 ? ? ADDSAMP 3.4 2004/10/05 11:30:39 1039 1039 BINAVE 4.0.1 2004/10/05 11:31:14 1039 9 MERGE 3.1 2004/10/05 11:41:20 9 9 MERGE 3.3 2004/11/30 13:24:47 9 9 CALIB 11.4 2004/12/13 15:40:01 9 9 CLEAN 4.7.1 2004/12/13 15:40:50 ? ? REMOVECH 6.0 2004/12/13 15:45:38 9 9 HDREDIT2 2.3 2004/12/13 15:47:01 ? ? MERGE 3.3 2004/12/13 15:57:56 9 9 SORT 3.5 2004/12/13 15:58:01 9 9 HDREDIT2 2.3 2004/12/13 17:05:25 ? ? HDREDIT2 2.3 2004/12/14 11:03:38 ? ? CHANGE_FLAGS 1.0 2013/07/29 14:29:46 9 9 CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:30:45 9 9 CHANGE_FLAGS 2.0 2014/11/20 09:54:25 9 9 $END $REMARKS -CLEAN functions: 2004/09/24 08:30:55 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: Q:\Cruise_Data\2004-20\CTD\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle Primary file : Q:\Cruise_Data\2004-20\ctd\hydro\2004-20-0069.samavg Secondary file: Q:\Cruise_Data\2004-20\ctd\hydro\2004-20-0069.sal -The following MERGE parameters were used: 2004/11/30 13:24:46 2004/11/30 13:24: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Oxygen:Dissolved, Flag:Dissolved_oxygen:volume Primary file : Q:\Cruise_Data\2004-20\CTD\hydro\2004-20-0069.mrg1 Secondary file: Q:\Cruise_Data\2004-20\CTD\hydro\2004-20-0069.addnew Comments from secondary file: Q:\Cruise_Data\2004-20\CTD\hydro\2004-20-0069.addnew ---------------------------------------------------- C.H. Culbertson's paper on Dissolved Oxygen in the 'Woce Hydrographic Program Operations and Methods - July 1991' -The following OXYCALC parameters were used Blank = 0.002 Sodium Thiosulfate concentration = 0.714 Volume of iodate standard (cm**3) = 9.98 Enter Normalitity of iodate standard = 0.01014000 -The following CHANNEL(S) were removed from file. Oxygen:Dissolved -HEADER EDITS: 2004/11/30 13:05:34 Channel 8: Oxygen:Dissolved [mL/L] Name ==> Oxygen:Dissolved Format: F7.3 ==> F8.3 -The following CALIB parameters were used: Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\Cruise_Data\2004-20\CTD\doc\2004-20-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 4 Temperature:Primary deg C (IT 10 0.1000000E-02 0.1000000E+01 14 Salinity:T0:C0 PSS-78 11 -0.8000000E-03 0.8000000E-06 Pressure 15 Salinity:T1:C1 PSS-78 11 -0.1370000E-01 0.6000000E-06 Pressure -CLEAN functions: 2004/12/13 15:40:46 20 Remove Sea-Bird comments from the header. -The following CHANNEL(S) were removed from file. Scan_Number Temperature:Secondary Conductivity:Primary Conductivity:Secondary Altimeter Status:Pump Descent_Rate Salinity:T1:C1 Flag -HEADER EDITS: 2004/12/13 15:47:01 Applied edit header: Q:\Cruise_Data\2004-20\CTD\doc\2004-20-bot-hdr.txt Channel 1: Sample_Number [n/a] Pad: -9 ==> -99 Channel 2: Pressure [dbars] Units ==> dbars Format: F10.3 ==> F7.1 Channel 5: Fluorescence:URU:Seapoint [mg/m^3] Name ==> Fluorescence:URU:Seapoint Channel 8: Number_of_bin_records [n/a] Format: F5.0 ==> I5 Channel 9: Salinity:Bottle [PSS-78] Units ==> PSS-78 Channel 11: Oxygen:Dissolved [mL/L] Pad: -99.99 ==> -99 -The following MERGE parameters were used: 2004/12/13 15:57:53 2004/12/13 15:57: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate Primary file : Q:\Cruise_Data\2004-20\CTD\che\2004-20-0069.hdr Secondary file: Q:\Cruise_Data\2004-20\CTD\che\2004-20-0069.nuts -SORT parameters: 2004/12/13 15:58:01 Sorted in ascending order of channel Pressure -HEADER EDITS: 2004/12/13 17:05:25 Applied edit header: H:\Cruise_Data\2004-20\CTD\che\Geographic Area.txt -HEADER EDITS: 2004/12/14 11:03:38 Applied edit header: O:\Data Processing\Header Comments\Name.txt Channel 12: Flag:Oxygen:Dissolved [] Name ==> Flag:Oxygen:Dissolved $END *COMMENTS Analysis methods: ----------------- Salinity samples are collected in glass bottles and analyzed on Guildline model 8410 Portasal Salinometers which are standardized with IAPSO standard seawater. Oxygen samples are analyzed on an automated Winkler titration system following the procedures of Carpenter (1965). A Brinkmann model 665 Dosimat and model PC910 Colorimeter is controlled by Visual-Basic program to titrate the oxygen samples. Nutrient samples are analyzed fresh on board using a Technicon AAII auto- analyzer following methods described in Barwell-Clarke and Whitney (1996). Chlorophyll samples are collected in duplicate in calibrated polycarbonate bottles (~330ml), then filtered onto 25mm MFS GF/75 filters at <70mmHg vacuum. The filters are placed in glass scintillation vials and immediately frozen at -20ºC until analysis. The chlorophyll is extracted in 10 ml of 90% acetone for 24h at -20ºC, then brought to room temperature and the extract is decanted and measured using a Turner Designs 10-AU-005-CE fluorometer, which has been calibrated with solutions of commercially prepared chlorophyll. References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. J. Barwell-Clarke and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. ------------------------------------------------------------------- Salinity accuracy The post-cruise calibration suggests that the sensors were reading lower than was shown in the bottle comparison, but since there is likely a source of error besides sensor drift, the bottle comparison was used to recalibrate. There remains some doubt about the CTD salinity which may be low by up to 0.004psu. ------------------------------------------------------------------- *CALIBRATION $TABLE: CORRECTED CHANNELS !Name Units Fmla Pad Coefficients !--------------------- --------------- ---- ------ ------------ Temperature:Primary 'deg C (ITS90)' 10 -99 () (0.1E-02 1) Salinity:T0:C0 PSS-78 11 -99 (Pressure) (-0.8E-03 0.8E-06) Salinity:T1:C1 PSS-78 11 -99 (Pressure) (-0.137E-01 0.6E-06) $END !-1-- --2--- ---3---- --4-- ---5--- 6- ---7---- -8-- ---9---- - ---11-- - --13- - --15- - --17-- - !Samp Pressu Temperat Trans Fluores Bo Salinity Numb Salinity F Oxygen: F Nitra F Silic F Phosph F !le_ re ure: missi cence: tt :T0:C0 er_o :Bottle l Dissolv l te_ l ate l ate l !Numb Primary vity URU: ~u ~bin ~ ed ~ plus_ ~ ~ ~ !er Seapoin mb _rec l e Nitri t t t ! t er ords e d te e e e !---- ------ -------- ----- ------- -- -------- ---- -------- - ------- - ----- - ----- - ------ - *END OF HEADER 367 4.4 11.7480 32.4 2.315 9 30.3533 121 29.3783 0 6.136 0 10.4 0 21.5 0 1.21 0 366 10.7 10.9246 46.5 0.894 8 31.1960 121 -99.0000 0 5.867 0 13.6 0 24.3 0 1.48 0 365 20.5 10.6900 47.2 0.745 7 31.2642 121 -99.0000 0 5.517 0 14.7 0 26.3 0 1.59 0 364 30.6 10.2278 47.3 0.588 6 31.4584 121 -99.0000 0 5.138 0 16.4 0 29.0 0 1.69 0 363 50.2 9.0353 49.0 0.296 5 31.8845 121 -99.0000 0 3.813 0 21.8 0 38.3 0 1.94 0 362 75.2 7.5354 49.9 0.200 4 32.7870 121 -99.0000 0 2.679 0 28.3 0 54.2 0 2.36 0 361 103.1 7.2444 50.5 0.174 3 32.9516 120 32.9295 0 2.394 0 29.4 0 57.8 0 2.45 0 360 103.2 7.2594 50.7 0.181 2 32.9348 72 32.9172 0 2.429 0 29.3 0 57.6 0 2.45 0 359 119.3 7.1247 44.6 0.184 1 33.0551 121 33.0394 0 2.315 0 29.9 0 60.9 0 2.56 0