*2021/11/23 13:39:39.20 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2004/08/21 15:08:29.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 20 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII NUMBER OF CHANNELS : 48 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- --------------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 11 30 2 Bottle_Number n/a 1 20 3 Pressure decibar 5 1299.6 4 Temperature:Primary 'deg C (ITS90)' 2.8198 17.4141 5 Transmissivity %/metre 25.8 60.2 6 Fluorescence:URU:Seapoint mg/m^3 0.156 2.029 7 Salinity:T0:C0 PSS-78 31.8256 34.4863 8 Number_of_bin_records n/a 97 121 9 Salinity:Bottle PSS-78 31.8475 34.4885 10 Flag:Salinity:Bottle n/a 11 Oxygen:Dissolved mL/L 0.31 6.53 12 Flag:Oxygen:Dissolved n/a 13 Nitrate_plus_Nitrite umol/L 0 46 14 Flag:Nitrate_plus_Nitrite n/a 15 Silicate umol/L 2 153 16 Flag:Silicate n/a 17 Phosphate umol/L 0.38 3.32 18 Flag:Phosphate n/a 19 Carbon:Dissolved:Inorganic umol/kg 1929.5 2385.9 20 Flag:Carbon:Dissolved:Inorganic n/a 21 Alkalinity:Total umol/kg 2155.1 2418.5 22 Flag:Alkalinity:Total n/a 23 Chlorophyll:Extracted mg/m^3 0.1 0.59 24 Flag:Chlorophyll:Extracted n/a 25 HPLC:Chl-c3 mg/m^3 0 0.24E-01 26 HPLC:Chlide-a mg/m^3 0 0 27 HPLC:MgDVP mg/m^3 0 0.8E-02 28 HPLC:Chl-c2 mg/m^3 0 0.4E-01 29 HPLC:Peri mg/m^3 0 0.33E-01 30 HPLC:Pheide-a mg/m^3 0 0 31 HPLC:But-fuco mg/m^3 0.6E-02 0.26E-01 32 HPLC:Fuco mg/m^3 0.7E-02 0.72E-01 33 HPLC:Neo mg/m^3 0 0.5E-02 34 HPLC:Pras mg/m^3 0 0.14E-01 35 HPLC:Viola mg/m^3 0 0.5E-02 36 HPLC:Hex-fuco mg/m^3 0.15E-01 0.41E-01 37 HPLC:Diadino mg/m^3 0 0.9E-02 38 HPLC:Allo mg/m^3 0 0 39 HPLC:Diato mg/m^3 0 0.5E-02 40 HPLC:Zea mg/m^3 0 0.6E-02 41 HPLC:Lut mg/m^3 0 0 42 HPLC:Chl-b mg/m^3 0.6E-02 0.92E-01 43 HPLC:DVChl-a mg/m^3 0 0.13E-01 44 HPLC:Chl-a mg/m^3 0.4E-01 0.337 45 HPLC:Phe mg/m^3 0 0 46 HPLC:B-Car mg/m^3 0 0.4E-02 47 HPLC:TChl-a mg/m^3 0.4E-01 0.337 48 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 9 F ' ' 4 8 -99 ' ' 5 I I 0 9 -99 ' ' 9 F R4 4 10 -99 ' ' 3 NQ C ' ' 11 -99 ' ' 8 F ' ' 3 12 -99 ' ' 3 NQ C ' ' 13 -99 ' ' 6 F R4 1 14 -99 ' ' 3 NQ C ' ' 15 -99 ' ' 6 F R4 1 16 -99 ' ' 3 NQ C ' ' 17 -99 ' ' 7 F R4 2 18 -99 ' ' 3 NQ C ' ' 19 -99 ' ' 8 F R4 2 20 -99 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 1 22 -99 ' ' 3 NQ C ' ' 23 -99 ' ' 7 F R4 2 24 -99 ' ' 3 NQ C ' ' 25 -99 ' ' 8 F R4 3 26 -99 ' ' 8 F R4 3 27 -99 ' ' 8 F R4 3 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2004-20 AGENCY : IOS, Ocean Science and Productivity, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Whitney F. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : N.E. Pacific STATION : P4 EVENT NUMBER : 7 LATITUDE : 48 38.82000 N ! (deg min) LONGITUDE : 126 40.04000 W ! (deg min) *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0585 $TABLE: SENSORS ! Name Abs Depth Serial No ! ------------------------- -------------- ---------- temperature:primary ' ' 2023 conductivity:primary ' ' 1763 pressure ' ' 77511 temperature:secondary ' ' 2106 conductivity:secondary ' ' 2102 Fluorometer ' ' Seapoint transmissometer:primary ' ' 732DR altimeter: ' ' ' ' $END $REMARKS SOFTWARE VERSION SEASAVE WIN32 V 5.31A Comments from secondary file: Q:\Cruise_Data\2004-20\ctd\hydro\2004-20-0007.add ------------------------------------------------- Dissolved oxygen concentration determined using an automated titration system consisting of a Brinkman dosimat (model 665) and a PC 900 Colorimeter. $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 2.8 2004/09/24 08:29:38 2395 2395 CLEAN 4.7.1 2004/09/24 08:30:58 ? ? ADDSAMP 3.4 2004/10/05 11:29:56 2395 2395 BINAVE 4.0.1 2004/10/05 11:30:53 2395 20 MERGE 3.1 2004/10/05 11:41:17 20 20 MERGE 3.3 2004/11/08 10:00:15 20 20 CALIB 11.4 2004/12/13 15:39:57 20 20 CLEAN 4.7.1 2004/12/13 15:40:46 ? ? REMOVECH 6.0 2004/12/13 15:45:35 20 20 HDREDIT2 2.3 2004/12/13 15:46:58 ? ? MERGE 3.3 2004/12/13 15:57:53 20 20 SORT 3.5 2004/12/13 15:57:58 20 20 HDREDIT2 2.3 2004/12/13 17:05:21 ? ? HDREDIT2 2.3 2004/12/14 11:02:06 ? ? SORT 3.5 2005/04/18 11:36:54 20 20 MERGE 3.3 2005/04/18 11:37:07 20 20 SORT 3.5 2005/04/18 11:59:18 20 20 MERGE 3.3 2005/05/31 14:38:44 20 20 REMOVECH 8.0 2010/04/11 15:53:16 20 20 SORT 3.5 2010/04/11 15:54:44 20 20 MERGE 3.3 2010/04/11 15:57:09 20 20 HDREDIT2 2.5.1 2010/04/11 16:03:15 ? ? SORT 3.5 2010/04/11 16:04:28 20 20 CHANGE_FLAGS 1.0 2013/07/29 14:29:45 20 20 CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:30:44 20 20 CHANGE_FLAGS 2.0 2014/11/20 09:54:23 20 20 SORT 3.6 2021/01/06 11:43:40 20 20 REORDER 1.3.1 2021/11/23 13:38:03 ? ? MERGE 3.5.1 2021/11/23 13:38:25 20 20 SORT 3.6 2021/11/23 13:38:43 20 20 $END $REMARKS -CLEAN functions: 2004/09/24 08:30:55 20 Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: Q:\Cruise_Data\2004-20\CTD\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle Primary file : Q:\Cruise_Data\2004-20\ctd\hydro\2004-20-0007.samavg Secondary file: Q:\Cruise_Data\2004-20\ctd\hydro\2004-20-0007.sal -The following MERGE parameters were used: 2004/11/08 10:00:15 Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Oxygen:Dissolved, Flag:Oxygen:Dissolved Primary file : Q:\Cruise_Data\2004-20\ctd\hydro\2004-20-0007.mrg1 Secondary file: Q:\Cruise_Data\2004-20\ctd\hydro\2004-20-0007.add Comments from secondary file: Q:\Cruise_Data\2004-20\ctd\hydro\2004-20-0007.add ------------------------------------------------- C.H. Culbertson's paper on Dissolved Oxygen in the 'Woce Hydrographic Program Operations and Methods - July 1991' -The following CALIB parameters were used: Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\Cruise_Data\2004-20\CTD\doc\2004-20-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 4 Temperature:Primary deg C (IT 10 0.1000000E-02 0.1000000E+01 14 Salinity:T0:C0 PSS-78 10 0.2500000E-02 0.1000000E+01 15 Salinity:T1:C1 PSS-78 10 -0.5000000E-02 0.1000000E+01 -CLEAN functions: 2004/12/13 15:40:46 20 Remove Sea-Bird comments from the header. -The following CHANNEL(S) were removed from file. Scan_Number Temperature:Secondary Conductivity:Primary Conductivity:Secondary Altimeter Status:Pump Descent_Rate Salinity:T1:C1 Flag -HEADER EDITS: 2004/12/13 15:46:58 Applied edit header: Q:\Cruise_Data\2004-20\CTD\doc\2004-20-bot-hdr.txt Channel 1: Sample_Number [n/a] Pad: -9 ==> -99 Channel 2: Pressure [dbars] Units ==> dbars Format: F10.3 ==> F7.1 Channel 5: Fluorescence:URU:Seapoint [mg/m^3] Name ==> Fluorescence:URU:Seapoint Channel 8: Number_of_bin_records [n/a] Format: F5.0 ==> I5 Channel 9: Salinity:Bottle [PSS-78] Units ==> PSS-78 Channel 11: Oxygen:Dissolved [mL/L] Pad: -99.99 ==> -99 -The following MERGE parameters were used: 2004/12/13 15:57:53 2004/12/13 15:57: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate Primary file : Q:\Cruise_Data\2004-20\CTD\che\2004-20-0007.hdr Secondary file: Q:\Cruise_Data\2004-20\CTD\che\2004-20-0007.nuts -SORT parameters: 2004/12/13 15:57:58 Sorted in ascending order of channel Pressure -HEADER EDITS: 2004/12/13 17:05:21 Applied edit header: H:\Cruise_Data\2004-20\CTD\che\Geographic Area.txt -HEADER EDITS: 2004/12/14 11:02:06 Applied edit header: O:\Data Processing\Header Comments\Name.txt -SORT parameters: 2005/04/18 11:36:54 Sorted in descending order of channel Sample_Number -The following MERGE parameters were used: 2005/04/18 11:37:07 Merge Channel: Sample_Number Merge Scheme Used: Interweave Records from Both Files Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Alkalinity:Total, Flag:Alkalinity:Total, Carbon:Dissolved:Inorganic, Flag:Carbon:Dissolved:Inorganic Primary file : H:\Data Processing\2004\2004-20\Carbon\2004-20-0007.srtche Secondary file: H:\Data Processing\2004\2004-20\Carbon\2004-20-0007.ios -SORT parameters: 2005/04/18 11:59:18 Sorted in ascending order of channel Pressure -The following MERGE parameters were used: 2005/05/31 14:38:44 Merge Channel: Sample_Number Merge Scheme Used: Interweave Records from Both Files Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Chlorophyll:Extracted, Flag:Chlorophyll:Extracted Primary file : H:\Data Processing\2004\2004-20\Chl\2004-20-0007.srtmrg Secondary file: H:\Data Processing\2004\2004-20\Chl\2004-20-0007.ios -REMOVECH 2010/04/11 15:53:16 4 channels removed. -SORT parameters: 2010/04/11 15:54:44 Sorted in ascending order of channel Sample_Number -The following MERGE parameters were used: 2010/04/11 15:57:09 Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Average Primary Channels to Include: ALL Secondary Channels to Include: Carbon:Dissolved:Inorganic, Flag:Carbon:Dissolved:Inorganic, Alkalinity:Total, Flag:Alkalinity:Total Primary file : H:\Cruise_Data_Processing\Lisa Miller's Carbon Data\2004-20\2004-20-0007.chesrt Secondary file: H:\Cruise_Data_Processing\Lisa Miller's Carbon Data\2004-20\2004-20-0007.iossrt Comments from secondary file: H:\Cruise_Data_Processing\Lisa Miller's Carbon Data\2004-20\2004-20-0007.iossrt --------------------------------------------------------------------------- -SORT parameters: 2010/04/11 15:55:45 Sorted in ascending order of channel Sample_Number -HEADER EDITS: 2010/04/11 16:03:15 Applied edit header: H:\Cruise_Data_Processing\Lisa Miller's Carbon Data\DIC_ALK.txt -SORT parameters: 2010/04/11 16:04:28 Sorted in ascending order of channel Pressure -SORT parameters: 2021/01/06 11:43:40 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/23 13:38:25 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2004\2004-020_Nov2021\Processing\ ios\2004-020-0007.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2004\2004-020_Nov2021\Processing\ ios\2004-020-0007.hplc -SORT parameters: 2021/11/23 13:38:43 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/23 13:38:56 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/23 13:39:21 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2004\2004-020\Processing\Doc\ 2004-020-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 25: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 26: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 27: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 28: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 Channel 21: Alkalinity:Total [umol/kg] Format: F8.2 ==> F7.1 -HEADER EDITS: 2021/11/23 13:39:39 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2004\2004-020\Processing\Doc\ 2004-020-bot-hdr2.txt $END *COMMENTS Analysis methods: ----------------- Salinity samples are collected in glass bottles and analyzed on Guildline model 8410 Portasal Salinometers which are standardized with IAPSO standard seawater. Oxygen samples are analyzed on an automated Winkler titration system following the procedures of Carpenter (1965). A Brinkmann model 665 Dosimat and model PC910 Colorimeter is controlled by Visual-Basic program to titrate the oxygen samples. Nutrient samples are analyzed fresh on board using a Technicon AAII auto- analyzer following methods described in Barwell-Clarke and Whitney (1996). Chlorophyll samples are collected in duplicate in calibrated polycarbonate bottles (~330ml), then filtered onto 25mm MFS GF/75 filters at <70mmHg vacuum. The filters are placed in glass scintillation vials and immediately frozen at -20ēC until analysis. The chlorophyll is extracted in 10 ml of 90% acetone for 24h at -20ēC, then brought to room temperature and the extract is decanted and measured using a Turner Designs 10-AU-005-CE fluorometer, which has been calibrated with solutions of commercially prepared chlorophyll. HPLC samples were filtered onto 25mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~6 years after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, and Chlide-a. For further information see file QF 2004-020_HPLC*.xlsx. Dissolved inorganic carbon (DIC) was determined using coulometric analysis. Total alkalinity (Alk) was determined by potentiometric titration. Complete documentation on DIC and ALK sampling, analysis and precision estimates can be found in the Carbon Excel file from the cruise located in the cruise "DOC" directory. . References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. J. Barwell-Clarke and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 3. Nemcek, N. and Peņa, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. ------------------------------------------------------------------- Salinity accuracy The post-cruise calibration suggests that the sensors were reading lower than was shown in the bottle comparison, but since there is likely a source of error besides sensor drift, the bottle comparison was used to recalibrate. There remains some doubt about the CTD salinity which may be low by up to 0.004psu. ------------------------------------------------------------------- Comments from secondary file: H:\Cruise_Data_Processing\Lisa Miller's Carbon Data\2004-20\2004-20-0007.iossrt --------------------------------------------------------------------------- Sample_Number 14: Alk: Large difference from replicate niskin Sample_Number 13: Alk: Large difference from replicate niskin Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2004\2004-020_Nov2021\Processing\ios\2004-020-0007. hplc --------------------------------------------------------------------------- Sample_Number 25: HPLC: Tchl-a values low compared to Turner values Sample_Number 26: HPLC: Tchl-a values low compared to Turner values Sample_Number 27: HPLC: Tchl-a values low compared to Turner values Sample_Number 28: HPLC: Tchl-a values low compared to Turner values Sample_Number 29: HPLC: Tchl-a values low compared to Turner values Sample_Number 30: HPLC: Tchl-a values low compared to Turner values *CALIBRATION $TABLE: CORRECTED CHANNELS !Name Units Fmla Pad Coefficients !--------------------- --------------- ---- ------ ------------ Temperature:Primary 'deg C (ITS90)' 10 -99 () (0.1E-02 1) Salinity:T0:C0 PSS-78 10 -99 () (0.25E-02 1) Salinity:T1:C1 PSS-78 10 -99 () (-0.5E-02 1) $END !-1-- -2-- --3--- ---4---- --5-- ---6--- ---7---- -8-- ---9---- 10 ---11-- 12 --13- 14 --15- 16 --17-- 18 ---19-- 20 --21-- 22 --23-- 24 ---25-- ---26-- ---27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- 48 !Samp Bott Pressu Temperat Trans Fluores Salinity Numb Salinity Fl Oxygen: Fl Nitra Fl Silic Fl Phosph Fl Carbon: Fl Alkali Fl Chloro Fl HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ re ure: missi cence: :T0:C0 er_o :Bottle ag Dissolv ag te_ ag ate ag ate ag Dissolv ag nity: ag phyll: ag Chl-c3 Chlide- MgDVP Chl-c2 Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb Primary vity URU: ~bin ~o ed ~o plus_ ~t ~i ~p ed: ~g Total ~T Extrac ~a a a fuco fuco : !er er Seapoin _rec tt lv Nitri ri ca ha Inorgan an ot ted ct HP ! t ords le ed te te te te ic ic al ed LC !---- ---- ------ -------- ----- ------- -------- ---- -------- -- ------- -- ----- -- ----- -- ------ -- ------- -- ------ -- ------ -- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 30 20 5.0 17.4141 25.8 0.587 31.8256 121 31.8475 0 5.868 0 0.0 0 6.2 0 0.38 0 1929.50 0 2155.1 3 0.38 0 0.000 0.000 0.005 0.019 0.019 0.000 0.006 0.027 0.000 0.010 0.000 0.017 0.006 0.000 0.000 0.000 0.000 0.052 0.000 0.217 0.000 0.000 0.217 3 29 19 11.0 16.8078 26.4 0.969 31.9684 121 31.9691 0 5.997 0 0.2 0 8.0 0 0.45 0 1937.60 0 2162.9 3 0.59 0 0.009 0.000 0.008 0.031 0.033 0.000 0.007 0.072 0.005 0.014 0.005 0.025 0.009 0.000 0.000 0.000 0.000 0.092 0.000 0.337 0.000 0.004 0.337 3 28 18 20.7 16.4666 26.9 0.720 32.2633 121 32.2962 0 6.080 0 0.0 0 2.0 0 0.41 0 1955.10 0 2174.2 3 0.37 0 0.016 0.000 0.000 0.021 0.016 0.000 0.026 0.034 0.000 0.000 0.000 0.038 0.004 0.000 0.000 0.006 0.000 0.027 0.013 0.176 0.000 0.000 0.190 3 27 17 30.3 13.3365 32.9 2.029 32.4215 121 32.4289 0 6.526 0 0.9 0 4.2 0 0.55 0 1969.70 0 2182.7 3 0.38 0 0.024 0.000 0.000 0.040 0.016 0.000 0.026 0.070 0.000 0.000 0.000 0.041 0.005 0.000 0.005 0.004 0.000 0.046 0.013 0.226 0.000 0.000 0.239 3 26 16 50.6 9.6731 51.7 0.521 32.4942 121 32.4950 0 6.530 0 5.9 0 8.2 0 0.86 0 2008.60 0 2163.4 3 0.27 0 0.019 0.000 0.000 0.011 0.000 0.000 0.012 0.027 0.000 0.000 0.000 0.040 0.003 0.000 0.000 0.000 0.000 0.034 0.000 0.131 0.000 0.000 0.131 3 25 15 76.6 8.2641 59.6 0.257 32.6811 121 32.6586 0 6.068 0 11.9 0 12.0 0 1.13 0 2038.40 0 2206.1 3 0.10 0 0.000 0.000 0.000 0.000 0.000 0.000 0.008 0.007 0.000 0.000 0.000 0.015 0.000 0.000 0.000 0.000 0.000 0.006 0.000 0.040 0.000 0.000 0.040 3 24 14 103.6 7.7319 59.6 0.244 33.0693 121 33.0447 0 5.048 0 18.9 0 20.1 0 1.49 0 2091.80 0 2217.8 3 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 23 13 125.0 7.3214 59.7 0.168 33.4934 121 33.4874 0 4.647 0 24.3 0 28.3 0 1.76 0 2140.80 0 2250.1 3 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 22 12 150.0 7.0101 59.7 0.156 33.6640 121 33.6673 0 3.862 0 26.7 0 34.9 0 1.91 0 2165.40 0 2260.1 3 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 21 11 175.1 7.0451 59.7 0.160 33.8056 121 33.8044 0 3.433 0 29.1 0 39.6 0 2.05 0 2185.50 0 2271.2 3 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 20 10 201.0 6.9904 59.8 0.156 33.8973 121 33.8954 0 2.645 0 32.5 0 45.6 0 2.26 0 2211.10 0 2280.0 3 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 19 9 253.0 6.6536 59.8 0.158 33.9584 121 33.9575 0 2.190 0 35.0 0 52.1 0 2.44 0 2231.60 0 2284.8 3 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 18 8 308.1 6.2046 59.8 0.159 34.0060 121 34.0029 0 1.587 0 38.3 0 61.1 0 2.67 0 2258.70 0 2293.5 3 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 17 7 400.8 5.5840 60.1 0.161 34.0512 121 34.0508 0 1.081 0 41.0 0 73.1 0 2.90 0 2287.10 0 2310.7 3 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 16 6 599.3 4.6856 60.0 0.162 34.1762 121 34.1764 0 0.501 0 44.4 0 96.7 0 3.17 0 2329.90 0 2337.3 3 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 15 5 798.8 4.1861 59.9 0.165 34.2740 121 34.2740 0 0.310 0 45.5 0 112.3 0 3.26 0 2346.80 0 2366.3 3 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 13 3 1000.2 3.5603 59.7 0.165 34.3829 97 34.3847 0 0.493 0 46.0 0 131.5 0 3.29 0 2367.70 6 2382.2 36 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 14 4 1000.2 3.5603 59.7 0.165 34.3830 120 34.3830 0 0.574 0 45.9 0 131.7 0 3.32 0 2367.90 0 2378.7 3 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 12 2 1252.3 2.9419 60.2 0.161 34.4708 121 34.4709 0 0.802 0 45.9 0 149.7 0 3.25 0 2380.50 0 2406.3 3 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 11 1 1299.6 2.8198 60.1 0.163 34.4863 121 34.4885 0 0.803 0 45.8 0 153.0 0 3.23 0 2385.90 0 2418.5 3 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0