*2021/11/23 10:41:56.87 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2004/04/29 19:06:37.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 18 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII NUMBER OF CHANNELS : 46 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 161 178 2 Bottle_Number n/a 1 18 3 Pressure decibar 1.7 340 4 Temperature:Primary 'deg C (ITS90)' 8.208 11.4157 5 Transmissivity %/metre 20.6 54.2 6 Fluorescence:URU:Seapoint mg/m^3 0.196 14.539 7 PAR uE/m^2/sec 0.5 646.8 8 PAR:Reference uE/m^2/sec 2400.1 2427.1 9 Salinity:T0:C0 PSS-78 28.2699 31.0629 10 Oxygen:Dissolved:SBE mL/L 2.31 8.04 11 Number_of_bin_records n/a 59 121 12 Salinity:Bottle PSS-78 30.5518 31.0527 13 Flag:Salinity:Bottle n/a 14 Oxygen:Dissolved mL/L -99.99 7.98 15 Flag:Oxygen:Dissolved n/a 16 Nitrate_plus_Nitrite umol/L 2 24.7 17 Flag:Nitrate_plus_Nitrite n/a 18 Silicate umol/L 14.5 71.9 19 Flag:Silicate n/a 20 Phosphate umol/L 0.7 2.98 21 Flag:Phosphate n/a 22 Chlorophyll:Extracted mg/m^3 0.89 10.25 23 Flag:Chlorophyll:Extracted n/a 24 HPLC:Chl-c3 mg/m^3 0.97E-01 0.186 25 HPLC:Chlide-a mg/m^3 0 0.607 26 HPLC:Chl-c2 mg/m^3 0.438 1.377 27 HPLC:Peri mg/m^3 0.4E-01 0.57E-01 28 HPLC:Pheide-a mg/m^3 0 0.863 29 HPLC:But-fuco mg/m^3 0 0.31E-01 30 HPLC:Fuco mg/m^3 1.468 4.052 31 HPLC:Neo mg/m^3 0 0.11E-01 32 HPLC:Pras mg/m^3 0 0.8E-02 33 HPLC:Viola mg/m^3 0 0.8E-02 34 HPLC:Hex-fuco mg/m^3 0 0 35 HPLC:Diadino mg/m^3 0.71E-01 0.363 36 HPLC:Allo mg/m^3 0 0.42E-01 37 HPLC:Diato mg/m^3 0.1E-01 0.33E-01 38 HPLC:Zea mg/m^3 0 0.27E-01 39 HPLC:Lut mg/m^3 0 0 40 HPLC:Chl-b mg/m^3 0 0.118 41 HPLC:DVChl-a mg/m^3 -99 -99 42 HPLC:Chl-a mg/m^3 3.397 8.56 43 HPLC:Phe mg/m^3 0 0.356 44 HPLC:B-Car mg/m^3 0.54E-01 0.159 45 HPLC:TChl-a mg/m^3 3.397 9.167 46 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 7 F ' ' 1 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 9 F ' ' 4 10 -99 ' ' 7 F ' ' 2 11 -99 ' ' 5 I I 0 12 -99 ' ' 9 F R4 4 13 -99 ' ' 3 NQ C ' ' 14 -99 ' ' 8 F ' ' 3 15 -99 ' ' 3 NQ C ' ' 16 -99 ' ' 6 F R4 1 17 -99 ' ' 3 NQ C ' ' 18 -99 ' ' 6 F R4 1 19 -99 ' ' 3 NQ C ' ' 20 -99 ' ' 7 F R4 2 21 -99 ' ' 3 NQ C ' ' 22 -99 ' ' 7 F R4 2 23 -99 ' ' 3 NQ C ' ' 24 -99 ' ' 8 F R4 3 25 -99 ' ' 8 F R4 3 26 -99 ' ' 8 F R4 3 27 -99 ' ' 8 F R4 3 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2004-08 AGENCY : IOS, Ocean Science and Productivity, Sidney, B.C. COUNTRY : Canada PROJECT : SoG / JdeF SCIENTIST : Pena A. PLATFORM : Vector *LOCATION GEOGRAPHIC AREA : Juan de Fuca Strait/Strait of Georgia STATION : 27 EVENT NUMBER : 44 LATITUDE : 49 19.03000 N ! (deg min) LONGITUDE : 123 47.97000 W ! (deg min) WATER DEPTH : 347 ALTIMETER (M) : 10.06 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0550 $TABLE: SENSORS ! Name Abs Depth Serial No ! ------------------------- -------------- ---------- temperature:primary ' ' 2038 conductivity:primary ' ' 2173 pressure ' ' 75636 temperature:secondary ' ' 2968 conductivity:secondary ' ' 1729 Fluorometer ' ' Seapoint Oxygen:SBE ' ' 0615 transmissometer:primary ' ' 498DR altimeter: ' ' ' ' irradiance ' ' primary surface ' ' 'degrees = 0.0' $END $REMARKS SOFTWARE VERSION SEASAVE WIN32 V 5.30A Dissolved oxygen concentration determined using an automated titration system consisting of a Brinkman dosimat (model 665) and a PC 900 Colorimeter. $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 2.7 2004/05/21 16:01:38 2063 2063 CLEAN 4.6.2 2004/05/21 16:02:53 ? ? ADDSAMP 3.4 2004/05/22 15:42:08 2063 2063 BINAVE 4.0.1 2004/06/07 13:22:06 2063 18 MERGE 3.1 2004/06/07 16:48:44 18 18 MERGE 3.1 2004/06/07 16:49:02 18 18 CALIB 11.4 2004/06/07 16:49:46 18 18 CLEAN 4.6.2 2004/06/07 16:50:04 18 18 SORT 3.4.1 2004/06/07 16:50:09 18 18 REMOVECH 6.0 2004/06/07 16:51:38 18 18 HDREDIT2 2.1 2004/06/07 17:01:40 ? ? MERGE 3.3 2004/11/29 14:48:24 18 18 MERGE 3.3 2006/05/19 16:10:45 18 18 CLEAN 5.0 2006/05/24 08:19:44 18 18 CHANGE_FLAGS 1.0 2013/07/16 11:47:38 18 18 CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:30:04 18 18 CHANGE_FLAGS 2.0 2014/11/20 09:54:14 18 18 CLEAN 5.2.3 2018/07/06 08:58:27 ? ? SORT 3.6 2021/01/19 08:32:12 18 18 REORDER 1.3.1 2021/11/23 10:40:29 ? ? MERGE 3.5.1 2021/11/23 10:40:54 18 18 SORT 3.6 2021/11/23 10:41:01 18 18 CLEAN 5.2.4 2021/11/23 10:41:08 18 18 HDREDIT2 3.2 2021/11/23 10:41:36 ? ? HDREDIT2 3.2 2021/11/23 10:41:56 ? ? $END $REMARKS CLEAN functions: - Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: Q:\Cruise_Data\2004-08\ctd\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle Primary file : Q:\Cruise_Data\2004-08\ctd\hydro\2004-08-0044.samavg Secondary file: Q:\Cruise_Data\2004-08\ctd\hydro\2004-08-0044.sal -The following MERGE parameters were used: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Oxygen:Dissolved, Flag:Oxygen:Dissolved Primary file : Q:\Cruise_Data\2004-08\CTD\hydro\2004-08-0044.mrg1 Secondary file: Q:\Cruise_Data\2004-08\CTD\hydro\2004-08-0044.add C.H. Culbertson's paper on Dissolved Oxygen in the 'Woce Hydrographic Program Operations and Methods - July 1991' -The following CALIB parameters were used: Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\Cruise_Data\2004-08\ctd\doc\2004-08-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 11 Oxygen:Dissolved:SBE mL/L 10 0.6080000E-01 0.1015400E+01 CLEAN functions: - Interpolation by Record Number, in Pressure - Set event to last 4 characters of file name -The following SORT parameters were used. Sorted by channel: Pressure Pressure channel sorted according to values in sort channel -The following CHANNEL(S) were removed from file. Scan_Number Temperature:Secondary Conductivity:Primary Conductivity:Secondary Altimeter Salinity:T1:C1 Descent_Rate Oxygen:Voltage:SBE Status:Pump Flag -The following MERGE parameters were used: 2004/11/29 14:48:22 2004/11/29 14:48: Merge Channel: Sample_Number Merge Scheme Used: Interweave Records from Both Files Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Nitrate_plus_Nitrite [umol/L], Flag:Nitrate_plus_Nitrite [ ], Silicate [umol/L], Flag:Silicate [ ], Phosphate [umol/L], Flag:Phosphate [ ] Primary file : H:\Data Processing\2004\2004-08\2004-08-0044.che Secondary file: H:\Data Processing\2004\2004-08\2004-08-0044.nut -The following MERGE parameters were used: 2006/05/19 16:10:45 2006/05/19 16:10:45 2006/05/19 16:10: Merge Channel: Sample_Number Merge Scheme Used: Interweave Records from Both Files Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Chlorophyll:Extracted, Flag:Chlorophyll:Extracted Primary file : Q:\Cruise_Data\2004-08\2004-08-0044.che1 Secondary file: Q:\Cruise_Data\2004-08\2004-08-0044.chcln -CLEAN functions: 2006/05/24 08:19:42 20 Reset #RECS, MIN & MAX values in header. Remove Sea-Bird comments from the header. Remove remark heading: "Comments from secondary" -CLEAN functions: 2018/07/06 08:58:27 20 Change Pad Value to -99 in All Channels. -SORT parameters: 2021/01/19 08:32:12 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/23 10:40:54 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2004\2004-008_Nov2021\Processing\ IOS\2004-008-0044.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2004\2004-008_Nov2021\Processing\ IOS\2004-008-0044.hplc -SORT parameters: 2021/11/23 10:41:01 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/23 10:41:08 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/23 10:41:36 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2004\2004-008\Processing\Doc\ 2004-008-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 24: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 25: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 26: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 27: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 28: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/11/23 10:41:56 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2004\2004-008\Processing\Doc\ 2004-008-bot-hdr2.txt $END *COMMENTS Analysis methods: ----------------- Salinity samples are collected in glass bottles and analyzed on Guildline model 8410 Portasal Salinometers which are standardized with IAPSO standard seawater. Oxygen samples are analyzed on an automated Winkler titration system following the procedures of Carpenter (1965). A Brinkmann model 665 Dosimat and model PC910 Colorimeter is controlled by Visual-Basic program to titrate the oxygen samples. Nutrient samples are analyzed frozen using a Technicon AAII autoanalyzer following methods described in Barwell-Clarke and Whitney (1996). Chlorophyll samples are collected in duplicate in calibrated polycarbonate bottles (~330ml), then filtered onto 25mm MFS GF/75 filters at <70mmHg vacuum. The filters are placed in glass scintillation vials and immediately frozen at -20ēC until analysis. The chlorophyll is extracted in 10 ml of 90% acetone for 24h at -20ēC, then brought to room temperature and the extract is decanted and measured using a Turner Designs 10-AU-005-CE fluorometer, which has been calibrated with solutions of commercially prepared chlorophyll. HPLC samples were filtered onto 25mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 1-2 hours or for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~36-45 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, and Chlide-a. For further information see file QF 2004-008_HPLC*.xlsx. References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. J. Barwell-Clarke and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 3. Nemcek, N. and Peņa, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. Sample_Number 178: CHL variability >10% Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2004\2004-008_Nov2021\Processing\IOS\2004-008-0044. hplc --------------------------------------------------------------------------- Sample_Number 174: HPLC: one rep lost due to software upgrade Sample_Number 177: HPLC: >10%CV for TChl-a *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- ------ ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (0.608E-01 1.0154) $END !-1-- -2-- --3--- ---4---- --5-- ---6--- --7--- --8--- ---9---- --10-- -11- ---12--- 13 ---14-- 15 --16- 17 --18- 19 --20-- 21 --22-- 23 ---24-- ---25-- ---26-- ---27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- 46 !Samp Bott Pressu Temperat Trans Fluores PAR PAR: Salinity Oxygen Numb Salinity Fl Oxygen: Fl Nitra Fl Silic Fl Phosph Fl Chloro Fl HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ re ure: missi cence: Refere :T0:C0 : er_o :Bottle ag Dissolv ag te_ ag ate ag ate ag phyll: ag Chl-c3 Chlide- Chl-c2 Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb Primary vity URU: nce Dissol ~bin ~o ed ~o plus_ ~t ~i ~p Extrac ~a a a fuco fuco : !er er Seapoin ved: _rec tt lv Nitri ri ca ha ted ct HP ! t SBE ords le ed te te te te ed LC !---- ---- ------ -------- ----- ------- ------ ------ -------- ------ ---- -------- -- ------- -- ----- -- ----- -- ------ -- ------ -- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 178 18 1.7 11.4157 26.3 2.964 646.8 2402.2 28.2699 8.04 120 -99.0000 0 7.980 0 2.0 0 14.5 0 0.70 0 7.97 3 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 176 16 5.2 10.4986 20.9 14.539 193.4 2400.3 28.4967 7.58 59 -99.0000 0 7.570 0 5.6 0 22.6 0 1.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 177 17 5.2 10.5019 20.6 14.369 190.9 2400.4 28.4933 7.57 120 -99.0000 0 -99.990 0 -99.0 0 -99.0 0 -99.00 0 10.25 0 0.186 0.607 1.377 0.040 0.863 0.031 4.052 0.011 0.008 0.008 0.000 0.363 0.042 0.033 0.027 0.000 0.118 -99.000 8.560 0.356 0.159 9.167 36 175 15 10.0 9.4391 33.3 10.218 30.6 2400.1 28.9663 5.86 117 -99.0000 0 5.942 0 -99.0 0 -99.0 0 -99.00 0 8.16 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 174 14 14.9 8.9178 46.0 3.412 8.7 2401.3 29.2584 5.68 118 -99.0000 0 -99.990 0 -99.0 0 -99.0 0 -99.00 0 3.21 0 0.097 0.000 0.438 0.057 0.000 0.000 1.468 0.000 0.000 0.000 0.000 0.071 0.000 0.010 0.000 0.000 0.000 -99.000 3.397 0.000 0.054 3.397 2 173 13 15.0 8.9175 45.9 3.920 8.6 2402.7 29.2585 5.67 69 -99.0000 0 -99.990 0 16.2 0 37.2 0 1.91 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 172 12 24.9 8.7623 45.4 3.061 1.6 2406.5 29.4303 5.15 121 -99.0000 0 5.186 0 18.8 0 46.4 0 2.33 0 2.53 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 171 11 34.9 8.7612 53.1 0.765 0.7 2410.1 29.5858 4.71 120 -99.0000 0 -99.990 0 20.5 0 48.3 0 2.27 0 0.89 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 170 10 50.2 8.6302 53.6 0.547 0.6 2404.5 29.7435 4.28 121 -99.0000 0 4.270 0 23.8 0 54.3 0 2.55 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 169 9 75.0 8.2080 54.2 0.261 0.5 2403.7 29.9170 4.77 119 -99.0000 0 4.772 0 23.8 6 55.1 6 2.37 6 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 168 8 100.0 8.2157 53.6 0.256 0.5 2407.5 29.9882 4.78 119 -99.0000 0 4.795 0 23.7 0 58.2 0 2.39 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 167 7 124.9 8.2592 51.6 0.221 0.5 2412.8 30.1588 4.89 121 -99.0000 0 4.957 0 21.2 0 47.7 0 2.16 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 166 6 150.0 8.5778 45.1 0.241 0.5 2418.0 30.4538 4.84 119 -99.0000 0 4.870 0 20.5 0 45.5 0 2.05 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 165 5 174.7 8.5957 44.0 0.228 0.5 2423.2 30.5340 4.83 120 -99.0000 0 4.856 0 20.0 6 44.3 6 2.15 6 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 164 4 200.1 8.6075 43.7 0.216 0.5 2427.1 30.5510 4.74 120 30.5518 0 4.760 0 20.4 0 46.9 0 2.23 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 163 3 249.7 8.7845 46.4 0.210 0.5 2422.5 30.6784 3.93 120 30.7222 0 3.686 0 23.1 0 60.0 0 2.58 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 162 2 299.9 9.3431 49.7 0.205 0.5 2426.8 30.9404 2.73 120 30.9688 0 2.788 0 24.4 0 69.2 0 2.68 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 161 1 340.0 9.5463 49.6 0.196 0.5 2408.6 31.0629 2.31 117 31.0527 0 2.353 0 24.7 0 71.9 0 2.98 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0