*2021/11/23 10:27:02.26 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2004/03/03 14:58:01.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 23 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII NUMBER OF CHANNELS : 47 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 105 127 2 Bottle_Number n/a 1 23 3 Pressure decibar 2.2 521.2 4 Temperature:Secondary 'deg C (ITS90)' 4.9117 9.2671 5 Transmissivity %/metre 39.3 60.9 6 Fluorescence:URU:Seapoint mg/m^3 0.126 1.18 7 PAR uE/m^2/sec 0.5 24.1 8 PAR:Reference uE/m^2/sec 12.5 79 9 Salinity:T1:C1 PSS-78 31.8592 34.1124 10 Oxygen:Dissolved:SBE mL/L 0.7 6.72 11 Number_of_bin_records n/a 118 121 12 Salinity:Bottle PSS-78 33.8368 34.1095 13 Flag:Salinity:Bottle n/a 14 Oxygen:Dissolved mL/L -99.99 6.777 15 Flag:Oxygen:Dissolved n/a 16 Nitrate_plus_Nitrite umol/L 2.9 41.9 17 Flag:Nitrate_plus_Nitrite n/a 18 Silicate umol/L 3.6 88.4 19 Flag:Silicate n/a 20 Phosphate umol/L 0.62 2.98 21 Flag:Phosphate n/a 22 Chlorophyll:Extracted mg/m^3 0.1E-01 1.04 23 Flag:Chlorophyll:Extracted n/a 24 HPLC:Chl-c3 mg/m^3 0.81E-01 0.98E-01 25 HPLC:Chlide-a mg/m^3 0 0 26 HPLC:MgDVP mg/m^3 0.14E-01 0.15E-01 27 HPLC:Chl-c2 mg/m^3 0.11 0.122 28 HPLC:Peri mg/m^3 0.22E-01 0.26E-01 29 HPLC:Pheide-a mg/m^3 0 0 30 HPLC:But-fuco mg/m^3 0.64E-01 0.76E-01 31 HPLC:Fuco mg/m^3 0.132 0.141 32 HPLC:Neo mg/m^3 0.8E-02 0.14E-01 33 HPLC:Pras mg/m^3 0.21E-01 0.25E-01 34 HPLC:Viola mg/m^3 0.12E-01 0.12E-01 35 HPLC:Hex-fuco mg/m^3 0.196 0.229 36 HPLC:Diadino mg/m^3 0.35E-01 0.36E-01 37 HPLC:Allo mg/m^3 0.68E-01 0.85E-01 38 HPLC:Diato mg/m^3 0 0 39 HPLC:Zea mg/m^3 0.12E-01 0.12E-01 40 HPLC:Lut mg/m^3 0 0 41 HPLC:Chl-b mg/m^3 0.78E-01 0.9E-01 42 HPLC:DVChl-a mg/m^3 -99 -99 43 HPLC:Chl-a mg/m^3 1.008 1.043 44 HPLC:Phe mg/m^3 0 0 45 HPLC:B-Car mg/m^3 0.14E-01 0.17E-01 46 HPLC:TChl-a mg/m^3 1.008 1.043 47 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 7 F ' ' 1 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 9 F ' ' 4 10 -99 ' ' 7 F ' ' 2 11 -99 ' ' 5 I I 0 12 -99 ' ' 9 F R4 4 13 -99 ' ' 3 NQ C ' ' 14 -99 ' ' 8 F ' ' 3 15 -99 ' ' 3 NQ C ' ' 16 -99 ' ' 6 F R4 1 17 -99 ' ' 3 NQ C ' ' 18 -99 ' ' 6 F R4 1 19 -99 ' ' 3 NQ C ' ' 20 -99 ' ' 7 F R4 2 21 -99 ' ' 3 NQ C ' ' 22 -99 ' ' 7 F R4 2 23 -99 ' ' 3 NQ C ' ' 24 -99 ' ' 8 F R4 3 25 -99 ' ' 8 F R4 3 26 -99 ' ' 8 F R4 3 27 -99 ' ' 8 F R4 3 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2004-04 AGENCY : IOS, Ocean Science and Productivity, Sidney, B.C. COUNTRY : Canada PROJECT : Bio_Moorings SCIENTIST : Pena A. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : WCVI/Strait of Georgia STATION : BIO1 EVENT NUMBER : 18 LATITUDE : 48 31.88000 N ! (deg min) LONGITUDE : 126 12.39000 W ! (deg min) WATER DEPTH : 290 ALTIMETER (M) : 11.7 ! custom item $REMARKS Altimeter value is distance from bottom and is calculated as the median of the deepest 2 metres of data. $END *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0585 $TABLE: SENSORS ! Name Abs Depth Serial No ! ------------------------- -------------- ---------- temperature:primary ' ' 2710 conductivity:primary ' ' 1763 pressure ' ' 77511 temperature:secondary ' ' 2095 conductivity:secondary ' ' 1764 Fluorometer ' ' Seapoint Oxygen:SBE ' ' 0047 transmissometer:primary ' ' 333DR altimeter: ' ' ' ' irradiance ' ' primary surface ' ' 'degrees = 0.0' $END $REMARKS SOFTWARE VERSION SEASAVE WIN32 V 5.30A Comments from secondary file: Q:\Cruise_Data\2004-04\hydro\2004-04-0018.add --------------------------------------------- Dissolved oxygen concentration determined using an automated titration system consisting of a Brinkman dosimat (model 665) and a PC 900 Colorimeter. $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 2.7 2004/03/26 09:24:51 2783 2783 CLEAN 4.5 2004/03/26 09:25:32 ? ? ADDSAMP 3.4 2004/04/13 13:48:28 2783 2783 BINAVE 4.0.1 2004/04/13 13:52:37 2783 23 MERGE 3.1 2004/05/07 15:29:43 23 23 MERGE 3.1 2004/05/13 17:03:24 23 23 MERGE 3.1 2004/05/13 17:03:36 23 23 MERGE 3.1 2004/05/13 17:03:43 23 23 CALIB 11.4 2004/05/13 17:27:15 23 23 CLEAN 4.6.1 2004/05/13 17:27:23 ? ? SORT 3.4.1 2004/05/13 17:27:33 23 23 REMOVECH 6.0 2004/05/13 17:27:39 23 23 HDREDIT2 2.0 2004/05/13 17:34:03 ? ? CHANGE_FLAGS 1.0 2013/07/16 11:47:35 23 23 CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:29:43 23 23 CHANGE_FLAGS 2.0 2014/11/20 09:54:09 23 23 CLEAN 5.2.3 2018/07/06 08:57:46 ? ? SORT 3.6 2021/01/07 11:01:09 23 23 REORDER 1.3.1 2021/11/23 10:11:10 ? ? MERGE 3.5.1 2021/11/23 10:11:54 23 23 SORT 3.6 2021/11/23 10:13:45 23 23 CLEAN 5.2.4 2021/11/23 10:16:42 23 23 HDREDIT2 3.2 2021/11/23 10:26:20 ? ? HDREDIT2 3.2 2021/11/23 10:27:02 ? ? $END $REMARKS CLEAN functions: - Set event to last 4 characters of file name -The following ADDSAMP parameters were used: Sample Number Lookup File: Q:\Cruise_Data\2004-04\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle Primary file : Q:\Cruise_Data\2004-04\hydro\2004-04-0018.samavg Secondary file: Q:\Cruise_Data\2004-04\hydro\2004-04-0018.sal -The following MERGE parameters were used: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Chlorophyll:Extracted, Flag:Chlorophyll:Extracted Primary file : Q:\Cruise_Data\2004-04\hydro\2004-04-0018.mrg1 Secondary file: Q:\Cruise_Data\2004-04\hydro\2004-04-0018.chl -The following MERGE parameters were used: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Oxygen:Dissolved, Flag:Oxygen:Dissolved Primary file : Q:\Cruise_Data\2004-04\hydro\2004-04-0018.mrg2 Secondary file: Q:\Cruise_Data\2004-04\hydro\2004-04-0018.add Comments from secondary file: Q:\Cruise_Data\2004-04\hydro\2004-04-0018.add --------------------------------------------- C.H. Culbertson's paper on Dissolved Oxygen in the 'Woce Hydrographic Program Operations and Methods - July 1991' -The following MERGE parameters were used: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate Primary file : Q:\Cruise_Data\2004-04\hydro\2004-04-0018.mrg3 Secondary file: Q:\Cruise_Data\2004-04\hydro\2004-04-0018.nutsort Comments from secondary file: Q:\Cruise_Data\2004-04\hydro\2004-04-0018.nutsort ------------------------------------------------- -The following SORT parameters were used. Sorted by channel: Sample_Number Pressure channel sorted according to values in sort channel -The following CALIB parameters were used: Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\Cruise_Data\2004-04\doc\2004-04-recal1.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 13 Oxygen:Dissolved:SBE mL/L 10 0.2910000E-01 0.1052600E+01 CLEAN functions: - Remove Sea-Bird comments from the header. -The following SORT parameters were used. Sorted by channel: Pressure Pressure channel sorted according to values in sort channel -The following CHANNEL(S) were removed from file. Scan_Number Temperature:Primary Conductivity:Primary Conductivity:Secondary Altimeter Oxygen:Voltage:SBE Status:Pump Descent_Rate Salinity:T0:C0 Flag -CLEAN functions: 2018/07/06 08:57:46 20 Change Pad Value to -99 in All Channels. -SORT parameters: 2021/01/07 11:01:09 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/23 10:11:54 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2004\2004-004_Nov2021\Processing\ IOS\2004-004-0018.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2004\2004-004_Nov2021\Processing\ IOS\2004-004-0018.hplc -SORT parameters: 2021/11/23 10:13:45 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/23 10:16:42 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/23 10:26:20 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2004\2004-004\Processing\Doc\ 2004-004-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 24: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 25: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 26: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 27: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 28: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/11/23 10:27:02 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2004\2004-004\Processing\Doc\ 2004-004-bot-hdr2.txt $END *COMMENTS Comments from secondary file: Q:\Cruise_Data\2004-04\hydro\2004-04-0018.chl --------------------------------------------- Sample #115: Variability of duplicates >10%. Sample #124: One replicate only. Analysis methods: ----------------- Salinity samples are collected in glass bottles and analyzed on Guildline model 8410 Portasal Salinometers which are standardized with IAPSO standard seawater. Oxygen samples are analyzed on an automated Winkler titration system following the procedures of Carpenter (1965). A Brinkmann model 665 Dosimat and model PC910 Colorimeter is controlled by Visual-Basic program to titrate the oxygen samples. Nutrient samples were stored frozen and analysed at IOS. Nutrient samples are analyzed frozen using a Technicon AAII autoanalyzer following methods described in Barwell-Clarke and Whitney (1996). Chlorophyll samples are collected in duplicate in calibrated polycarbonate bottles (~330ml), then filtered onto 25mm MFS GF/75 filters at <70mmHg vacuum. The filters are placed in glass scintillation vials and immediately frozen at -20ēC until analysis. The chlorophyll is extracted in 10 ml of 90% acetone for 24h at -20ēC, then brought to room temperature and the extract is decanted and measured using a Turner Designs 10-AU-005-CE fluorometer, which has been calibrated with solutions of commercially prepared chlorophyll. HPLC samples were filtered onto 25mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~4 years after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, and Chlide-a. For further information see file QF 2004-004_HPLC*.xlsx. References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. J. Barwell-Clarke and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 3. Nemcek, N. and Peņa, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2004\2004-004_Nov2021\Processing\IOS\2004-004-0018. hplc --------------------------------------------------------------------------- Sample_Number 118: HPLC: only single rep available Sample_Number 120: HPLC: only single rep available *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- ------ ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (0.291E-01 1.0526) $END !-1-- -2-- --3--- ---4---- --5-- ---6--- --7--- --8--- ---9---- --10-- -11- ---12--- 13 ---14-- 15 --16- 17 --18- 19 --20-- 21 --22-- 23 ---24-- ---25-- ---26-- ---27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- 47 !Samp Bott Pressu Temperat Trans Fluores PAR PAR: Salinity Oxygen Numb Salinity Fl Oxygen: Fl Nitra Fl Silic Fl Phosph Fl Chloro Fl HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ re ure: missi cence: Refere :T1:C1 : er_o :Bottle ag Dissolv ag te_ ag ate ag ate ag phyll: ag Chl-c3 Chlide- MgDVP Chl-c2 Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb Secondar vity URU: nce Dissol ~bin ~o ed ~o plus_ ~t ~i ~p Extrac ~a a a fuco fuco : !er er y Seapoin ved: _rec tt lv Nitri ri ca ha ted ct HP ! t SBE ords le ed te te te te ed LC !---- ---- ------ -------- ----- ------- ------ ------ -------- ------ ---- -------- -- ------- -- ----- -- ----- -- ------ -- ------ -- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 121 17 2.2 9.2363 41.9 1.016 14.5 56.1 31.8592 6.72 121 -99.0000 0 6.777 0 2.9 0 5.1 0 0.62 0 0.87 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 127 23 2.2 9.2488 39.3 1.138 24.1 76.8 31.8666 6.72 119 -99.0000 0 -99.990 0 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 120 16 4.8 9.2347 49.2 1.061 5.5 49.8 31.8610 6.72 118 -99.0000 0 6.756 0 2.9 0 3.6 0 0.62 0 0.86 0 0.081 0.000 0.014 0.110 0.026 0.000 0.064 0.132 0.008 0.025 0.012 0.196 0.036 0.085 0.000 0.012 0.000 0.078 -99.000 1.043 0.000 0.017 1.043 2 126 22 5.7 9.2446 46.9 1.033 10.4 79.0 31.8628 6.71 121 -99.0000 0 -99.990 0 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 119 15 10.1 9.2415 52.5 1.109 2.6 47.8 31.8650 6.72 121 -99.0000 0 6.768 0 2.9 0 4.3 0 0.62 0 1.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 125 21 12.5 9.2437 52.7 1.089 3.2 72.7 31.8685 6.71 120 -99.0000 0 -99.990 0 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 118 14 17.0 9.2671 54.4 1.115 2.0 45.7 32.0983 6.65 121 -99.0000 0 6.727 0 3.8 0 7.0 0 0.70 0 1.04 0 0.098 0.000 0.015 0.122 0.022 0.000 0.076 0.141 0.014 0.021 0.012 0.229 0.035 0.068 0.000 0.012 0.000 0.090 -99.000 1.008 0.000 0.014 1.008 2 117 13 22.3 9.2447 55.0 1.180 1.6 47.8 32.1738 6.62 121 -99.0000 0 6.657 0 4.8 0 7.0 0 0.75 0 0.78 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 124 20 23.3 9.2424 55.5 1.118 1.9 70.6 32.1768 6.61 120 -99.0000 0 -99.990 0 -99.0 0 -99.0 0 -99.00 0 0.68 3 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 116 12 27.7 9.2245 56.2 0.985 1.3 51.9 32.1905 6.58 121 -99.0000 0 6.622 0 4.7 0 6.7 0 0.76 0 0.59 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 115 11 32.3 9.2238 56.9 0.870 1.1 47.8 32.1947 6.55 121 -99.0000 0 6.602 0 4.9 0 6.7 0 0.77 0 0.70 3 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 123 19 34.8 9.2241 56.6 0.927 1.2 74.7 32.1928 6.58 121 -99.0000 0 -99.990 0 -99.0 0 -99.0 0 -99.00 0 0.46 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 122 18 46.9 9.2191 58.7 0.549 0.8 68.5 32.2167 6.48 120 -99.0000 0 -99.990 0 -99.0 0 -99.0 0 -99.00 0 0.25 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 114 10 59.9 9.0956 59.0 0.264 0.6 49.8 32.4512 5.72 121 -99.0000 0 5.886 0 10.4 0 13.3 0 1.12 0 0.11 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 113 9 74.6 9.0346 58.2 0.180 0.6 41.5 32.7520 4.96 121 -99.0000 0 5.028 0 15.8 0 18.9 0 1.45 0 0.07 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 112 8 99.8 8.3201 59.2 0.148 0.6 35.3 33.1966 4.15 120 -99.0000 0 4.199 0 22.5 0 26.4 0 1.87 0 0.03 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 111 7 125.6 8.0476 59.2 0.136 0.6 34.8 33.4636 3.46 121 -99.0000 0 3.554 0 26.1 0 32.1 0 2.01 0 0.02 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 110 6 150.0 7.8322 58.8 0.130 0.6 33.2 33.6768 2.93 121 -99.0000 0 2.973 0 28.6 0 37.7 0 2.17 0 0.01 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 109 5 174.6 7.6941 58.2 0.129 0.6 33.2 33.7730 2.65 121 -99.0000 0 2.728 0 30.1 0 40.7 0 2.25 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 108 4 201.7 7.6435 59.1 0.126 0.6 31.1 33.8333 2.49 121 33.8368 0 2.553 0 31.1 0 42.1 0 2.24 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 107 3 250.7 7.2509 59.8 0.130 0.6 24.9 33.9353 2.20 121 33.9331 0 2.285 0 32.9 0 47.3 0 2.41 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 106 2 299.9 6.8191 60.9 0.130 0.6 22.8 33.9861 1.92 121 33.9860 0 2.039 0 34.8 0 53.5 0 2.50 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 105 1 521.2 4.9117 59.8 0.145 0.5 12.5 34.1124 0.70 121 34.1095 0 0.777 0 41.9 0 88.4 0 2.98 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0