*2013/12/16 15:27:37.70 *IOS HEADER VERSION 1.10 2011/10/26 2011/10/26 *FILE START TIME : UTC 2003/06/11 03:31:11.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 24 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII NUMBER OF CHANNELS : 21 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 406 429 2 Pressure decibar 1 2002 3 Temperature:Primary 'deg C (ITS90)' 1.9797 10.947 4 Transmissivity %/metre 52.2 60.7 5 Fluorescence:URU:Seapoint mg/m^3 0.122 1.842 6 Oxygen:Dissolved:SBE mL/L 0.3822 6.7914 7 Bottle_Number n/a 1 24 8 Salinity:T0:C0 PSS-78 32.2643 34.5765 9 Number_of_bin_records n/a 120 121 10 Salinity:Bottle PSS-78 32.2615 34.5766 11 Flag:Salinity:Bottle n/a 12 Chlorophyll:Extracted mg/m^3 0.3E-01 0.61 13 Flag:Chlorophyll:Extracted n/a 14 Nitrate_plus_Nitrite umol/L 5.5 45.1 15 Flag:Nitrate_plus_Nitrite n/a 16 Silicate umol/L 9 175.2 17 Flag:Silicate n/a 18 Phosphate umol/L 0.86 3.22 19 Flag:Phosphate n/a 20 Oxygen:Dissolved mL/L 0.396 6.777 21 Flag:Oxygen:Dissolved newunits $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -9 ' ' 5 I I 0 2 -99 ' ' 7 F ' ' 1 3 -99 ' ' 9 F ' ' 4 4 -99 ' ' 6 F ' ' 1 5 -99 ' ' 8 F ' ' 3 6 -99 ' ' 7 F ' ' 2 7 -99 ' ' 3 I I 0 8 -99 ' ' 9 F ' ' 4 9 ' ' ' ' 5 I I 0 10 -99 ' ' 9 F R4 4 11 0 ' ' 2 NQ C ' ' 12 -99 ' ' 7 F R4 2 13 0 ' ' 2 NQ C ' ' 14 -99 ' ' ' ' F6.1 R4 ' ' 15 0 ' ' 2 NQ C ' ' 16 -99 ' ' ' ' F6.1 R4 ' ' 17 0 ' ' 2 NQ C ' ' 18 -99 ' ' ' ' F7.2 R4 ' ' 19 0 ' ' 2 NQ C ' ' 20 -99 ' ' 8 F ' ' 3 21 0 ' ' 2 NQ C ' ' $END $REMARKS Data quality is expressed with the following flags ---------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). ---------------------------------------------------------------------------- Comments from secondary file: H:\Data Processing\Oxygen redo\2003-11\2003-11-0071.clnadd ---------------------------------------------------------- Raw data in file oxydata\2003-11-\2003-11-0071.o2 VIO3 = 10.02 ! Volume of iodate standard (cm**) NIO3 = .01013204 ! Normality of iodate standard VREG = 2.0 ! Volume of sample displaced by reagents (cm**3) DOREG = 0.0017 ! Absolute amount of O2 added with reagents (ml) $END *ADMINISTRATION MISSION : 2003-11 AGENCY : IOS, Ocean Science and Productivity, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : N.E.Pacific STATION : ARGO 5 EVENT NUMBER : 71 LATITUDE : 53 30.01000 N ! (deg min) LONGITUDE : 138 0.02000 W ! (deg min) WATER DEPTH : 3258 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0550 $TABLE: SENSORS ! Name Abs Depth Serial No ! ------------------------- -------------- ---------- temperature:primary ' ' 2095 conductivity:primary ' ' 2102 pressure ' ' 75636 temperature:secondary ' ' 2710 conductivity:secondary ' ' 2278 Fluorometer ' ' Seapoint transmissometer:primary ' ' 333DR Oxygen:SBE ' ' 0047 $END $REMARKS SOFTWARE VERSION SEASAVE WIN32 V 5.27C Comments from secondary file: Q:\Cruise_Data\2003-11\hydro\2003-11-0071.add --------------------------------------------- Dissolved oxygen concentration determined using an automated titration system consisting of a Brinkman dosimat (model 665) and a PC 900 Colorimeter. Comments from secondary file: H:\Data Processing\Oxygen redo\2003-11\2003-11-0071.clnadd ---------------------------------------------------------- Dissolved oxygen concentration determined using an automated titration system consisting of a Brinkman dosimat (model 665) and a PC 900 Colorimeter. $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 2.5 2003/08/14 13:53:44 2904 2904 ADDSAMP 3.4 2003/08/21 09:16:27 2904 2904 BINAVE 4.0.1 2003/08/21 09:17:17 2904 24 MERGE 3.0 2003/08/31 13:10:08 24 24 MERGE 3.0 2003/08/31 13:13:25 24 24 MERGE 3.0 2003/08/31 13:14:33 24 24 CALIB 11.2 2003/09/22 08:37:28 24 24 CLEAN 4.4 2003/09/22 11:05:07 ? ? REMOVECH 6.0 2003/09/22 11:11:00 24 24 HDREDIT2 1.7 2003/09/22 12:07:22 ? ? MERGE 3.1 2003/10/06 16:22:16 24 24 HDREDIT2 1.8 2003/10/08 13:52:43 ? ? REVERSE 2.0 2004/01/02 16:48:48 24 24 SORT 3.4.1 2004/04/23 11:54:39 24 24 REMOVECH 7.0 2005/09/19 14:41:42 24 24 SORT 3.5 2005/09/19 14:42:09 24 24 MERGE 3.3 2005/09/19 15:55:02 24 24 SORT 3.5 2005/09/19 16:07:29 24 24 CALIB 11.5 2005/10/07 10:41:13 24 24 CHANGE_FLAGS 1.0 2013/07/16 11:47:17 24 24 CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:27:37 24 24 $END $REMARKS -The following ADDSAMP parameters were used: Sample Number Lookup File: Q:\Cruise_data\2003-11\hydro\addsamp.csv Bottle Channel Name: Bottle_Number -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:Bottle, Flag:Salinity:Bottle Primary file : Q:\Cruise_Data\2003-11\hydro\2003-11-0071.samavg Secondary file: Q:\Cruise_Data\2003-11\hydro\2003-11-0071.sal -The following MERGE parameters were used: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Chlorophyll:Extracted, Flag:Chlorophyll Primary file : Q:\Cruise_Data\2003-11\hydro\2003-11-0071.mrg1 Secondary file: Q:\Cruise_Data\2003-11\hydro\2003-11-0071.chl -The following MERGE parameters were used: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Oxygen:Dissolved, Flag:Oxygen:Dissolved Primary file : Q:\Cruise_Data\2003-11\hydro\2003-11-0071.mrg2 Secondary file: Q:\Cruise_Data\2003-11\hydro\2003-11-0071.add Comments from secondary file: Q:\Cruise_Data\2003-11\hydro\2003-11-0071.add --------------------------------------------- C.H. Culbertson's paper on Dissolved Oxygen in the 'Woce Hydrographic Program Operations and Methods - July 1991' -The following CALIB parameters were used: Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\Cruise_Data\2003-11\doc\2003-11-0550-rcal2.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 11 Oxygen:Dissolved:SBE mL/L 10 -0.3740000E-01 0.1138600E+01 CLEAN functions: - Remove Sea-Bird comments from the header. -The following CHANNEL(S) were removed from file. Scan_Number Temperature:Secondary Conductivity:Primary Conductivity:Secondary Oxygen:Voltage:SBE Descent_Rate Salinity:T1:C1 Flag -The following MERGE parameters were used: Merge Channel: Sample_Number Merge Scheme Used: Interweave Records from Both Files Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate Primary file : H:\Cruise_Data\2003-11\nuts\2003-11-0071.che Secondary file: H:\Cruise_Data\2003-11\nuts\2003-11-0071.rev -The following SORT parameters were used. Sorted by channel: Pressure Pressure channel sorted according to values in sort channel -REMOVECH 2005/09/19 14:41:42 The following CHANNEL(S) were removed: Oxygen:Dissolved [mL/L] Flag:Oxygen:Dissolved -SORT parameters: 2005/09/19 14:42:09 Sorted in ascending order of channel Sample_Number -The following MERGE parameters were used: 2005/09/19 15:55:02 2005/09/19 15:55:02 2005/09/19 15:55: Merge Channel: Sample_Number Merge Scheme Used: Interweave Records from Both Files Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Oxygen:Dissolved, Flag:Oxygen:Dissolved Primary file : H:\Data Processing\Oxygen redo\2003-11\2003-11-0071.srtrem Secondary file: H:\Data Processing\Oxygen redo\2003-11\2003-11-0071.clnadd Comments from secondary file: H:\Data Processing\Oxygen redo\2003-11\2003-11-0071.clnadd ---------------------------------------------------------- C.H. Culbertson's paper on Dissolved Oxygen in the 'Woce Hydrographic Program Operations and Methods - July 1991' -The following OXYCALC parameters were used Blank = 0.005 Sodium Thiosulfate concentration = 0.729 Volume of iodate standard (cm**3) = 10.02 Enter Normalitity of iodate standard = 0.01013000 -REMOVECH 2005/08/31 11:08:13 The following CHANNEL(S) were removed: Dissolved_oxygen:volume [mL/L] -CLEAN functions: 2005/09/19 15:49:21 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. -SORT parameters: 2005/09/19 16:07:29 Sorted in ascending order of channel Pressure -The following CALIB parameters were used: Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\Cruise_Data\2003-11\2003-11-recal4.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 6 Oxygen:Dissolved:SBE mL/L 10 0.0000000E+00 0.9800000E+00 $END *COMMENTS Comments from secondary file: Q:\Cruise_Data\2003-11\hydro\2003-11-0071.sal --------------------------------------------- Sample # 415 - vent open on recovery Comments from secondary file: Q:\Cruise_Data\2003-11\hydro\2003-11-0071.chl --------------------------------------------- Chlorophyll: Philippe Tortell and Nina Nemcek filtered and analyzed chl onboard Chlorophyll analyzed using Chemistry fluorometer calibrated Aug. '02. Comments from secondary file: Q:\Cruise_Data\2003-11\hydro\2003-11-0071.add --------------------------------------------- 415 Bad measurement, vent open on recovery 406 Salinity outlier - lower than CTD and sample 407 at same depth by 0.01. ========================================================================== February 25, 2004 Chlorophyll value at 75 dbar was changed to 0.18. Previous value was 0.06. Nina Nemcek had found the error and reported it to Marie Robert. ========================================================================== Analysis methods: ----------------- Salinity samples are collected in glass bottles and analyzed on Guildline model 8410 Portasal Salinometers which are standardized with IAPSO standard seawater. Oxygen samples are analyzed on an automated Winkler titration system following the procedures of Carpenter (1965). A Brinkmann model 665 Dosimat and model PC910 Colorimeter is controlled by Visual-Basic program to titrate the oxygen samples. Nutrient samples are analyzed fresh on board using a Technicon AAII auto- analyzer following methods described in Barwell-Clarke and Whitney (1996). Chlorophyll samples are collected in duplicate in calibrated polycarbonate bottles (~330ml), then filtered onto 25mm MFS GF/75 filters at <70mmHg vacuum. The filters are placed in glass scintillation vials and immediately frozen at -20ºC until analysis. The chlorophyll is extracted in 10 ml of 90% acetone for 24h at -20ºC, then brought to room temperature and the extract is decanted and measured using a Turner Designs 10-AU-005-CE fluorometer, which has been calibrated with solutions of commercially prepared chlorophyll. References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. J. Barwell-Clarke and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. Comments from secondary file: H:\Data Processing\Oxygen redo\2003-11\2003-11-0071.clnadd ---------------------------------------------------------- This cast was run through the DOXX program for calculating dissolved oxygen values. The standard values defaulted to an incorrect number; should be 0.729. *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------------- ------ ---- ------ ------------ Oxygen:Dissolved:SBE mL/L 10 -99 () (-0.374E-01 1.1386) Oxygen:Dissolved:SBE mL/L 10 -99 () (0 0.98) $END !-1-- --2--- ---3---- --4-- ---5--- --6--- 7- ---8---- -9-- ---10--- - --12-- - --14- - --16- - --18-- - ---20-- - !Samp Pressu Temperat Trans Fluores Oxygen Bo Salinity Numb Salinity F Chloro F Nitra F Silic F Phosph F Oxygen: F !le_ re ure: missi cence: : tt :T0:C0 er_o :Bottle l phyll: l te_ l ate l ate l Dissolv l !Numb Primary vity URU: Dissol ~u ~bin ~ Extrac ~ plus_ ~ ~ ~ ed ~ !er Seapoin ved: mb _rec l ted e Nitri t t t e ! t SBE er ords e d te e e e d !---- ------ -------- ----- ------- ------ -- -------- ---- -------- - ------ - ----- - ----- - ------ - ------- - *END OF HEADER 429 1.0 10.9470 52.7 0.632 6.61 24 32.2646 121 32.2666 0.20 5.7 9.1 0.89 6.628 428 9.6 10.4330 52.2 0.880 6.71 23 32.2643 121 32.2615 0.29 5.5 9.0 0.86 6.674 427 14.5 10.2445 52.8 0.924 6.71 22 32.2760 121 -99.0000 -99.00 -99.0 -99.0 -99.00 -99.000 426 24.9 9.4724 52.7 1.415 6.79 21 32.2887 120 32.2897 0.37 6.3 9.6 0.90 6.777 423 34.4 9.1405 53.1 1.691 6.78 18 32.2908 121 -99.0000 -99.00 -99.0 -99.0 -99.00 -99.000 425 34.5 9.1358 53.1 1.687 6.79 20 32.2919 121 -99.0000 -99.00 -99.0 -99.0 -99.00 -99.000 424 34.8 9.1364 53.0 1.682 6.79 19 32.2916 121 -99.0000 -99.00 -99.0 -99.0 -99.00 -99.000 422 49.4 8.2264 53.2 1.842 6.69 17 32.3162 121 32.3209 0.61 8.7 11.1 1.03 6.689 421 74.6 7.1973 58.1 0.481 6.19 16 32.4327 121 32.4506 0.18 13.8 17.0 1.32 6.337 420 99.7 6.5181 59.0 0.152 5.11 15 32.8787 121 32.8807 0.03 21.1 28.0 1.74 5.206 419 124.4 6.2903 59.1 0.124 3.86 14 33.3146 121 33.3216 -99.00 27.1 39.9 2.09 3.894 418 150.2 6.4436 59.1 0.122 3.07 13 33.6079 121 33.6072 -99.00 30.2 45.8 2.26 3.105 417 174.7 6.3837 59.3 0.132 2.73 12 33.7450 121 33.7426 -99.00 31.8 49.5 2.34 2.735 416 199.0 6.2368 59.4 0.123 2.51 11 33.8264 121 33.8301 -99.00 33.1 53.4 2.41 2.501 415 249.9 5.7983 59.7 0.126 2.05 10 33.9120 121 33.9138 4 -99.00 36.0 62.1 2.59 2.090 414 300.0 5.3190 60.0 0.125 1.73 9 33.9317 121 33.9341 -99.00 38.2 69.4 2.72 1.770 413 399.4 4.6521 60.4 0.125 1.20 8 33.9883 121 33.9899 -99.00 41.4 84.6 2.94 1.228 412 599.2 3.9719 60.6 0.128 0.56 7 34.1279 121 34.1296 -99.00 43.9 110.1 3.15 0.586 411 800.2 3.5676 60.6 0.128 0.41 6 34.2519 121 34.2554 -99.00 44.5 128.8 3.20 0.409 410 999.7 3.1332 60.6 0.130 0.38 5 34.3469 121 34.3487 -99.00 44.9 141.4 3.22 0.396 409 1249.8 2.6988 60.7 0.130 0.43 4 34.4232 121 34.4237 -99.00 45.1 155.6 3.22 0.456 408 1499.4 2.4140 60.7 0.127 0.60 3 34.4839 121 34.4851 -99.00 44.7 165.2 3.19 0.563 407 2001.8 1.9797 60.7 0.124 1.25 2 34.5765 121 34.5766 -99.00 43.1 175.2 3.06 1.250 406 2002.0 1.9798 60.7 0.123 1.25 1 34.5765 121 34.5652 3 -99.00 43.0 173.8 3.06 1.315