*2021/11/23 09:38:02.36 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2003/02/28 15:51:38.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 20 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII NUMBER OF CHANNELS : 51 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 254 273 2 Bottle_Number n/a 1 20 3 Pressure decibar 0.6 257 4 Temperature:Primary 'deg C (ITS90)' 7.2615 9.1021 5 Transmissivity %/metre 19 52.9 6 Fluorescence:URU:Seapoint mg/m^3 0.112 3.484 7 PAR uE/m^2/sec 2.2 81.5 8 PAR:Reference uE/m^2/sec 133.1 256.4 9 Salinity:T0:C0 PSS-78 25.5877 31.0433 10 Number_of_bin_records n/a 73 73 11 Salinity:Bottle PSS-78 30.9326 31.032 12 Flag:Salinity:Bottle n/a 13 Oxygen:Dissolved mL/L 3.064 7.029 14 Flag:Oxygen:Dissolved n/a 15 Nitrate_plus_Nitrite umol/L 24.8 30.6 16 Flag:Nitrate_plus_Nitrite n/a 17 Silicate umol/L 51.5 61.7 18 Flag:Silicate n/a 19 Phosphate umol/L 1.9 2.75 20 Flag:Phosphate n/a 21 Ammonium umol/L 0 0.34 22 Flag:Ammonium n/a 23 Chlorophyll:Extracted mg/m^3 0.22 2.63 24 Flag:Chlorophyll:Extracted n/a 25 HPLC:Chl-c3 mg/m^3 0 0 26 HPLC:Chlide-a mg/m^3 0 0 27 HPLC:MgDVP mg/m^3 0 0.3E-01 28 HPLC:Chl-c2 mg/m^3 0.44E-01 0.267 29 HPLC:Chl-c1 mg/m^3 0 0.82E-01 30 HPLC:Me-chlide mg/m^3 0 0 31 HPLC:Peri mg/m^3 0 0 32 HPLC:Pheide-a mg/m^3 0 0 33 HPLC:But-fuco mg/m^3 0 0.59E-01 34 HPLC:Fuco mg/m^3 0.327 1.324 35 HPLC:Neo mg/m^3 0 0.14E-01 36 HPLC:Pras mg/m^3 0 0.13E-01 37 HPLC:Viola mg/m^3 0 0 38 HPLC:Hex-fuco mg/m^3 0 0 39 HPLC:Diadino mg/m^3 0 0.75E-01 40 HPLC:Allo mg/m^3 0 0.12 41 HPLC:Diato mg/m^3 0 0.25E-01 42 HPLC:Zea mg/m^3 0 0.32E-01 43 HPLC:Lut mg/m^3 0 0 44 HPLC:Chl-b mg/m^3 0.71E-01 0.172 45 HPLC:C2mgdg mg/m^3 0 0 46 HPLC:DVChl-a mg/m^3 -99 -99 47 HPLC:Chl-a mg/m^3 0.65 2.829 48 HPLC:Phe mg/m^3 0 0 49 HPLC:B-Car mg/m^3 0 0.52E-01 50 HPLC:TChl-a mg/m^3 0.65 2.829 51 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 7 F ' ' 1 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 9 F ' ' 4 10 -99 ' ' 5 I I 0 11 -99 ' ' 9 F R4 4 12 -99 ' ' 3 NQ C ' ' 13 -99 ' ' 8 F ' ' 3 14 -99 ' ' 3 NQ C ' ' 15 -99 ' ' 6 F R4 1 16 -99 ' ' 3 NQ C ' ' 17 -99 ' ' 6 F R4 1 18 -99 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 -99 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 -99 ' ' 3 NQ C ' ' 23 -99 ' ' 7 F R4 2 24 -99 ' ' 3 NQ C ' ' 25 -99 ' ' 8 F R4 3 26 -99 ' ' 8 F R4 3 27 -99 ' ' 8 F R4 3 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2003-02 AGENCY : IOS, Ocean Science and Productivity, Sidney, BC COUNTRY : Canada PROJECT : Phytoplankton SCIENTIST : Pena A. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : West Coast Vancouver Island STATION : BIO2 EVENT NUMBER : 68 LATITUDE : 49 0.43000 N ! (deg min) LONGITUDE : 123 23.10000 W ! (deg min) WATER DEPTH : 172 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0550 $TABLE: SENSORS ! Name Abs Depth Serial No ! ------------------------- -------------- ---------- temperature:primary ' ' 2095 conductivity:primary ' ' 2280 pressure ' ' 75636 temperature:secondary ' ' 2710 conductivity:secondary ' ' 2278 Fluorometer ' ' Seapoint Oxygen:SBE ' ' 0047 transmissometer:primary ' ' 498DR irradiance ' ' primary surface ' ' 'degrees = 0.0' $END $REMARKS SOFTWARE VERSION SEASAVE WIN32 V 5.27C Comments from secondary file: H:\CTD\2003-02\Merge\2003-02-0068.clnoxy ---------------------------------------------------------------------- Dissolved oxygen concentration determined using an automated titration system consisting of a Brinkman dosimat (model 665) and a PC 900 Colorimeter. $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 2.5 2003/05/27 08:56:33 1460 1460 CLEAN 4.2 2003/05/27 08:57:59 ? ? CALIB 11.0 2003/06/24 14:51:21 1460 1460 REMOVECH 6.0 2003/06/24 14:52:02 1460 1460 HDREDIT2 1.6 2003/06/24 14:52:17 ? ? BINAVE 4.0.1 2003/07/17 09:46:40 1460 20 ADDSAMP 3.4 2003/07/17 11:22:35 20 20 MERGE 2.9 2003/07/18 10:54:50 20 20 MERGE 2.9 2003/07/18 11:05:38 20 20 MERGE 2.9 2003/07/21 11:44:23 20 20 HDREDIT2 1.6 2003/07/21 11:52:21 ? ? CLEAN 4.3 2003/07/21 12:01:00 20 20 MERGE 3.1 2003/12/12 14:46:43 20 21 CLEAN 4.5 2003/12/15 14:16:02 21 21 SORT 3.4.1 2004/04/14 16:46:07 21 21 CLEAN 4.6.1 2004/04/16 10:01:27 20 20 HDREDIT2 2.1 2004/05/26 13:20:38 ? ? CHANGE_FLAGS 1.0 2013/07/16 11:47:14 20 20 CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:27:26 20 20 CHANGE_FLAGS 2.0 2014/11/20 09:53:44 20 20 SORT 3.6 2021/01/12 15:27:12 20 20 REORDER 1.3.1 2021/11/23 09:34:28 ? ? MERGE 3.5.1 2021/11/23 09:35:29 20 20 SORT 3.6 2021/11/23 09:36:43 20 20 CLEAN 5.2.4 2021/11/23 09:37:07 20 20 HDREDIT2 3.2 2021/11/23 09:37:40 ? ? HDREDIT2 3.2 2021/11/23 09:38:02 ? ? $END $REMARKS CLEAN functions: - Set event to last 4 characters of file name -The following CALIB parameters were used: Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\CTD\2003-02\doc\2003-02-rcal2.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 14 Salinity:T0:C0 PSS-78 10 0.3000000E-02 0.1000000E+01 -The following CHANNEL(S) were removed from file. Scan_Number Temperature:Secondary Conductivity:Primary Conductivity:Secondary Descent_Rate Status:Pump Salinity:T1:C1 Flag -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Bin value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following ADDSAMP parameters were used: Sample Number Lookup File: H:\CTD\2003-02\Merge\addsamp.dat Bottle Channel Name: Bottle_Number -The following MERGE parameters were used: Merge Channel: Sample_Number Merge Scheme Used: Interweave Records from Both Files Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Oxygen:Dissolved, Flag:Oxygen:Dissolved Primary file : H:\CTD\2003-02\Merge\2003-02-0068.sam Secondary file: H:\CTD\2003-02\Merge\2003-02-0068.clnoxy Comments from secondary file: H:\CTD\2003-02\Merge\2003-02-0068.clnoxy ---------------------------------------------------------------------- C.H. Culbertson's paper on Dissolved Oxygen in the 'Woce Hydrographic Program Operations and Methods - July 1991' CLEAN functions: - Reset #RECS, MIN & MAX values in header. -The following MERGE parameters were used: Merge Channel: Sample_Number Merge Scheme Used: Interweave Records from Both Files Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:bottle, Data Quality Primary file : H:\CTD\2003-02\merge\2003-02-0068.mrg Secondary file: H:\CTD\2003-02\merge\2003-02-0068.sal -The following MERGE parameters were used: Merge Channel: Sample_Number Merge Scheme Used: Interweave Records from Both Files Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Chlorophyll:Extracted [mg/m^3], Flag:Chlorophyll:Extracted [ ] Primary file : H:\CTD\2003-02\Merge\2003-02-0068.mrg2 Secondary file: H:\CTD\2003-02\Merge\2003-02-0068.ios CLEAN functions: - Reset #RECS, MIN & MAX values in header. - Change Pad Value to -99 in All Channels. - Set channel name post-colon letters to upper case. - Remove Sea-Bird comments from the header. -The following MERGE parameters were used: Merge Channel: Sample_Number Merge Scheme Used: Interweave Records from Both Files Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium Primary file : H:\Data Processing\2003-02\2003-02-0068.che Secondary file: H:\Data Processing\2003-02\2003-02-0068.nut CLEAN functions: - Reset #RECS, MIN & MAX values in header. - Delete Empty Channels: 0 deleted. -The following SORT parameters were used. Sorted by channel: Pressure Pressure channel sorted according to values in sort channel CLEAN functions: - Reset #RECS, MIN & MAX values in header. -SORT parameters: 2021/01/12 15:27:12 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/23 09:35:29 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2003\2003-002_Nov2021\Processing\ IOS\2003-002-0068.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2003\2003-002_Nov2021\Processing\ IOS\2003-002-0068.hplc -SORT parameters: 2021/11/23 09:36:43 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/23 09:37:07 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/23 09:37:40 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2003\2003-002\Processing\Doc\ 2003-002-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 25: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 26: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 27: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 28: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:Chl-c1 [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:C2mgdg [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 50: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/11/23 09:38:02 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2003\2003-002\Processing\Doc\ 2003-002-bot-hdr2.txt $END *COMMENTS Comments from secondary file: H:\CTD\2003-02\merge\2003-02-0068.sal ------------------------------------------------------------------- Sample #254 – The original value, 30.6460,was removed because the bottle was fired during the downcast and after insufficient time for shed wakes to settle. The difference between the sample and CTD was an outlier when studied in COMPARE. Analysis methods: ----------------- Salinity samples are collected in glass bottles and analyzed on Guildline model 8410 Portasal Salinometers which are standardized with IAPSO standard seawater. Oxygen samples are analyzed on an automated Winkler titration system following the procedures of Carpenter (1965). A Brinkmann model 665 Dosimat and model PC910 Colorimeter is controlled by Visual-Basic program to titrate the oxygen samples. Nutrient samples are analyzed fresh on board using a Technicon AAII auto- analyzer following methods described in Barwell-Clarke and Whitney (1996). Chlorophyll samples are collected in duplicate in calibrated polycarbonate bottles (~330ml), then filtered onto 25mm MFS GF/75 filters at <70mmHg vacuum. The filters are placed in glass scintillation vials and immediately frozen at -20ēC until analysis. The chlorophyll is extracted in 10 ml of 90% acetone for 24h at -20ēC, then brought to room temperature and the extract is decanted and measured using a Turner Designs 10-AU-005-CE fluorometer, which has been calibrated with solutions of commercially prepared chlorophyll. HPLC samples were filtered onto 25mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~5 years after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a, and Me-Chlide. For further information see file QF 2003-002_HPLC*.xlsx. References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. J. Barwell-Clarke and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 3. Nemcek, N. and Peņa, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. Comments from secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2003\2003-002_Nov2021\Processing\IOS\2003-002-0068. hplc --------------------------------------------------------------------------- Sample_Number 266: HPLC: >10%CV for TChl-a, pigment detection poor <4 accessory pigments detected Sample_Number 270: HPLC: >10%CV for TChl-a *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------- -------- ---- ------ ------------ Salinity:T0:C0 PSS-78 10 -99 () (0.3E-02 1) $END !-1-- -2-- --3--- ---4---- --5-- ---6--- --7--- --8--- ---9---- -10- ---11--- 12 ---13-- 14 --15- 16 --17- 18 --19-- 20 --21-- 22 --23-- 24 ---25-- ---26-- ---27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- 51 !Samp Bott Pressu Temperat Trans Fluores PAR PAR: Salinity Numb Salinity Fl Oxygen: Fl Nitra Fl Silic Fl Phosph Fl Ammoni Fl Chloro Fl HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ re ure: missi cence: Refere :T0:C0 er_o :Bottle ag Dissolv ag te_ ag ate ag ate ag um ag phyll: ag Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b C2mgdg DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb Primary vity URU: nce ~bin ~o ed ~o plus_ ~t ~i ~p ~o Extrac ~a a chlide a fuco fuco : !er er Seapoin _rec tt lv Nitri ri ca ha ni ted ct HP ! t ords le ed te te te te um ed LC !---- ---- ------ -------- ----- ------- ------ ------ -------- ---- -------- -- ------- -- ----- -- ----- -- ------ -- ------ -- ------ -- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 273 20 0.6 7.2615 30.3 2.314 81.5 250.6 25.5877 73 -99.0000 0 7.029 0 24.8 0 58.0 0 1.90 0 0.34 0 2.43 6 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 271 18 4.6 7.3064 32.8 2.583 21.8 256.4 26.1300 73 -99.0000 0 6.840 0 25.0 0 57.2 0 1.90 0 0.29 0 2.63 6 0.000 0.000 0.030 0.251 0.082 0.000 0.000 0.000 0.045 1.085 0.000 0.013 0.000 0.000 0.075 0.120 0.000 0.025 0.000 0.172 0.000 -99.000 2.829 0.000 0.040 2.829 6 272 19 4.6 7.3541 33.1 2.847 21.5 256.4 26.4874 73 -99.0000 0 -99.000 0 -99.0 0 -99.0 0 -99.00 0 -99.00 0 2.55 3 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 270 17 10.3 7.6621 39.0 3.484 5.4 255.4 27.9875 73 -99.0000 0 6.332 0 27.3 0 56.1 0 2.15 0 0.05 0 2.58 6 0.000 0.000 0.013 0.267 0.069 0.000 0.000 0.000 0.059 1.324 0.014 0.013 0.000 0.000 0.054 0.068 0.013 0.032 0.000 0.136 0.000 -99.000 2.695 0.000 0.052 2.695 36 269 16 14.8 8.0918 47.9 2.162 3.4 254.4 29.0182 73 -99.0000 0 -99.000 0 -99.0 0 -99.0 0 -99.00 0 -99.00 0 1.26 6 0.000 0.000 0.009 0.143 0.000 0.000 0.000 0.000 0.013 0.734 0.000 0.000 0.000 0.000 0.032 0.043 0.025 0.000 0.000 0.131 0.000 -99.000 1.572 0.000 0.021 1.572 6 268 15 20.1 8.2564 52.9 1.469 2.7 254.4 29.4441 73 -99.0000 0 5.559 0 29.7 0 57.6 0 2.45 0 0.01 0 0.70 3 0.000 0.000 0.000 0.091 0.000 0.000 0.000 0.000 0.000 0.452 0.000 0.000 0.000 0.000 0.015 0.027 0.000 0.000 0.000 0.092 0.000 -99.000 0.968 0.000 0.000 0.968 6 266 13 25.0 8.3492 52.2 0.895 2.5 251.3 29.6225 73 -99.0000 0 -99.000 0 29.7 0 56.9 0 2.46 0 0.00 0 0.48 6 0.000 0.000 0.000 0.044 0.000 0.000 0.000 0.000 0.000 0.327 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.071 0.000 -99.000 0.650 0.000 0.000 0.650 36 267 14 25.1 8.3500 52.2 0.903 2.5 252.4 29.6239 73 -99.0000 0 -99.000 0 -99.0 0 -99.0 0 -99.00 0 -99.00 0 0.55 3 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 265 12 30.4 8.4440 51.3 0.407 2.4 248.5 29.9040 73 -99.0000 0 5.196 0 29.4 0 55.7 0 2.25 0 0.00 0 0.24 3 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 264 11 35.0 8.4246 50.9 0.360 2.3 244.6 29.9709 73 -99.0000 0 -99.000 0 -99.0 0 -99.0 0 -99.00 0 -99.00 0 0.22 6 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 263 10 40.3 8.4439 50.2 0.287 2.3 238.7 30.0403 73 -99.0000 0 5.265 0 29.0 0 54.2 0 2.41 0 0.00 0 0.22 3 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 262 9 45.1 8.4430 50.3 0.248 2.2 230.9 30.0733 73 -99.0000 0 -99.000 0 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 261 8 50.0 8.4512 50.1 0.233 2.2 221.4 30.0886 73 -99.0000 0 5.261 0 28.7 0 54.0 6 2.27 6 0.01 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 260 7 74.9 8.4643 49.7 0.204 2.2 203.5 30.2046 73 -99.0000 0 5.301 0 27.7 0 51.5 0 2.20 0 0.05 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 259 6 100.1 8.4894 47.4 0.216 2.2 187.9 30.3216 73 -99.0000 0 5.286 0 28.2 0 52.5 0 2.41 0 0.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 258 5 125.4 8.5051 40.7 0.362 2.2 178.0 30.4378 73 -99.0000 0 5.047 0 27.3 0 51.5 0 2.31 0 0.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 254 1 161.5 8.8306 42.7 0.144 2.2 133.1 30.7117 73 -99.0000 5 4.302 0 29.3 0 56.0 0 2.46 0 0.01 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 257 4 174.9 8.9086 44.9 0.126 2.2 154.6 30.7890 73 -99.0000 0 3.790 0 29.8 0 57.5 0 2.55 0 0.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 256 3 199.6 9.0208 45.1 0.112 2.2 146.9 30.9260 73 30.9326 0 3.372 0 30.6 0 60.6 0 2.55 0 0.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 255 2 257.0 9.1021 19.0 0.129 2.2 139.2 31.0433 73 31.0320 0 3.064 0 30.5 0 61.7 0 2.75 0 0.02 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0