*2021/11/23 09:38:02.10 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2003/02/25 23:40:09.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 22 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII NUMBER OF CHANNELS : 51 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 67 88 2 Bottle_Number n/a 1 22 3 Pressure decibar 0.5 452.3 4 Temperature:Primary 'deg C (ITS90)' 5.257 9.3625 5 Transmissivity %/metre 34.2 61.4 6 Fluorescence:URU:Seapoint mg/m^3 0.8E-01 7.086 7 PAR uE/m^2/sec 2.2 83.8 8 PAR:Reference uE/m^2/sec 263 340.5 9 Salinity:T0:C0 PSS-78 31.9037 34.0747 10 Number_of_bin_records n/a 73 73 11 Salinity:Bottle PSS-78 33.8867 34.0745 12 Flag:Salinity:Bottle n/a 13 Oxygen:Dissolved mL/L 1.026 7.434 14 Flag:Oxygen:Dissolved n/a 15 Nitrate_plus_Nitrite umol/L 5.1 40.9 16 Flag:Nitrate_plus_Nitrite n/a 17 Silicate umol/L 6.1 79.9 18 Flag:Silicate n/a 19 Phosphate umol/L 0.75 2.93 20 Flag:Phosphate n/a 21 Ammonium umol/L 0.4E-01 0.1 22 Flag:Ammonium n/a 23 Chlorophyll:Extracted mg/m^3 0.4 6.66 24 Flag:Chlorophyll:Extracted n/a 25 HPLC:Chl-c3 mg/m^3 0 0.65E-01 26 HPLC:Chlide-a mg/m^3 0 0.7E-01 27 HPLC:MgDVP mg/m^3 0 0.81E-01 28 HPLC:Chl-c2 mg/m^3 0.3E-01 0.722 29 HPLC:Chl-c1 mg/m^3 0 0.302 30 HPLC:Me-chlide mg/m^3 0 0.8E-01 31 HPLC:Peri mg/m^3 0 0.66E-01 32 HPLC:Pheide-a mg/m^3 0 0.312 33 HPLC:But-fuco mg/m^3 0.44E-01 0.65E-01 34 HPLC:Fuco mg/m^3 0.114 3.368 35 HPLC:Neo mg/m^3 0 0.31E-01 36 HPLC:Pras mg/m^3 0 0.5E-01 37 HPLC:Viola mg/m^3 0 0.34E-01 38 HPLC:Hex-fuco mg/m^3 0.47E-01 0.107 39 HPLC:Diadino mg/m^3 0 0.336 40 HPLC:Allo mg/m^3 0 0.197 41 HPLC:Diato mg/m^3 0 0.18E-01 42 HPLC:Zea mg/m^3 0 0.33E-01 43 HPLC:Lut mg/m^3 0 0 44 HPLC:Chl-b mg/m^3 0.91E-01 0.253 45 HPLC:C2mgdg mg/m^3 0 0 46 HPLC:DVChl-a mg/m^3 -99 -99 47 HPLC:Chl-a mg/m^3 0.502 7.605 48 HPLC:Phe mg/m^3 0 0.26 49 HPLC:B-Car mg/m^3 0 0.151 50 HPLC:TChl-a mg/m^3 0.502 7.675 51 Flag:HPLC ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 7 F ' ' 1 8 -99 ' ' 7 F ' ' 1 9 -99 ' ' 9 F ' ' 4 10 -99 ' ' 5 I I 0 11 -99 ' ' 9 F R4 4 12 -99 ' ' 3 NQ C ' ' 13 -99 ' ' 8 F ' ' 3 14 -99 ' ' 3 NQ C ' ' 15 -99 ' ' 6 F R4 1 16 -99 ' ' 3 NQ C ' ' 17 -99 ' ' 6 F R4 1 18 -99 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 -99 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 -99 ' ' 3 NQ C ' ' 23 -99 ' ' 7 F R4 2 24 -99 ' ' 3 NQ C ' ' 25 -99 ' ' 8 F R4 3 26 -99 ' ' 8 F R4 3 27 -99 ' ' 8 F R4 3 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2003-02 AGENCY : IOS, Ocean Science and Productivity, Sidney, BC COUNTRY : Canada PROJECT : Phytoplankton SCIENTIST : Pena A. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : West Coast Vancouver Island STATION : BI01 EVENT NUMBER : 19 LATITUDE : 48 32.15000 N ! (deg min) LONGITUDE : 126 11.81000 W ! (deg min) WATER DEPTH : 456 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0550 $TABLE: SENSORS ! Name Abs Depth Serial No ! ------------------------- -------------- ---------- temperature:primary ' ' 2095 conductivity:primary ' ' 2280 pressure ' ' 75636 temperature:secondary ' ' 2710 conductivity:secondary ' ' 2278 Fluorometer ' ' Seapoint Oxygen:SBE ' ' 0047 transmissometer:primary ' ' 498DR irradiance ' ' primary surface ' ' 'degrees = 0.0' $END $REMARKS SOFTWARE VERSION SEASAVE WIN32 V 5.27C Comments from secondary file: H:\CTD\2003-02\Merge\2003-02-0019.clnoxy ---------------------------------------------------------------------- Dissolved oxygen concentration determined using an automated titration system consisting of a Brinkman dosimat (model 665) and a PC 900 Colorimeter. $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 2.5 2003/05/27 08:56:25 1606 1606 CLEAN 4.2 2003/05/27 08:57:47 ? ? CALIB 11.0 2003/06/24 14:51:08 1606 1606 REMOVECH 6.0 2003/06/24 14:51:51 1606 1606 HDREDIT2 1.6 2003/06/24 14:52:09 ? ? BINAVE 4.0.1 2003/07/17 09:46:37 1606 22 ADDSAMP 3.4 2003/07/17 11:22:34 22 22 MERGE 2.9 2003/07/18 10:54:49 22 22 MERGE 2.9 2003/07/18 11:05:37 22 22 MERGE 2.9 2003/07/21 11:44:22 22 22 HDREDIT2 1.6 2003/07/21 11:52:20 ? ? CLEAN 4.3 2003/07/21 11:54:42 22 22 MERGE 3.1 2003/12/12 14:46:41 22 22 CLEAN 4.5 2003/12/15 14:16:00 22 22 SORT 3.4.1 2004/04/14 16:45:30 22 22 HDREDIT2 2.1 2004/05/26 13:20:24 ? ? CHANGE_FLAGS 1.0 2013/07/16 11:47:13 22 22 CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:27:26 22 22 CHANGE_FLAGS 2.0 2014/11/20 09:53:43 22 22 SORT 3.6 2021/01/12 15:27:12 22 22 REORDER 1.3.1 2021/11/23 09:34:28 ? ? MERGE 3.5.1 2021/11/23 09:35:29 22 22 SORT 3.6 2021/11/23 09:36:42 22 22 CLEAN 5.2.4 2021/11/23 09:37:07 22 22 HDREDIT2 3.2 2021/11/23 09:37:40 ? ? HDREDIT2 3.2 2021/11/23 09:38:02 ? ? $END $REMARKS CLEAN functions: - Set event to last 4 characters of file name -The following CALIB parameters were used: Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\CTD\2003-02\doc\2003-02-rcal2.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 14 Salinity:T0:C0 PSS-78 10 0.3000000E-02 0.1000000E+01 -The following CHANNEL(S) were removed from file. Scan_Number Temperature:Secondary Conductivity:Primary Conductivity:Secondary Descent_Rate Status:Pump Salinity:T1:C1 Flag -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.00 Minimum bin value = 0.000 Bin value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following ADDSAMP parameters were used: Sample Number Lookup File: H:\CTD\2003-02\Merge\addsamp.dat Bottle Channel Name: Bottle_Number -The following MERGE parameters were used: Merge Channel: Sample_Number Merge Scheme Used: Interweave Records from Both Files Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Oxygen:Dissolved, Flag:Oxygen:Dissolved Primary file : H:\CTD\2003-02\Merge\2003-02-0019.sam Secondary file: H:\CTD\2003-02\Merge\2003-02-0019.clnoxy Comments from secondary file: H:\CTD\2003-02\Merge\2003-02-0019.clnoxy ---------------------------------------------------------------------- C.H. Culbertson's paper on Dissolved Oxygen in the 'Woce Hydrographic Program Operations and Methods - July 1991' CLEAN functions: - Reset #RECS, MIN & MAX values in header. -The following MERGE parameters were used: Merge Channel: Sample_Number Merge Scheme Used: Interweave Records from Both Files Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Salinity:bottle, Data Quality Primary file : H:\CTD\2003-02\merge\2003-02-0019.mrg Secondary file: H:\CTD\2003-02\merge\2003-02-0019.sal -The following MERGE parameters were used: Merge Channel: Sample_Number Merge Scheme Used: Interweave Records from Both Files Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Chlorophyll:Extracted [mg/m^3], Flag:Chlorophyll:Extracted [ ] Primary file : H:\CTD\2003-02\Merge\2003-02-0019.mrg2 Secondary file: H:\CTD\2003-02\Merge\2003-02-0019.ios CLEAN functions: - Reset #RECS, MIN & MAX values in header. - Change Pad Value to -99 in All Channels. - Set channel name post-colon letters to upper case. - Remove Sea-Bird comments from the header. -The following MERGE parameters were used: Merge Channel: Sample_Number Merge Scheme Used: Interweave Records from Both Files Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Nitrate_plus_Nitrite, Flag:Nitrate_plus_Nitrite, Silicate, Flag:Silicate, Phosphate, Flag:Phosphate, Ammonium, Flag:Ammonium Primary file : H:\Data Processing\2003-02\2003-02-0019.che Secondary file: H:\Data Processing\2003-02\2003-02-0019.nut CLEAN functions: - Reset #RECS, MIN & MAX values in header. - Delete Empty Channels: 0 deleted. -The following SORT parameters were used. Sorted by channel: Pressure Pressure channel sorted according to values in sort channel -SORT parameters: 2021/01/12 15:27:12 Sorted in ascending order of channel Sample_Number [n/a] -The following MERGE parameters were used: 2021/11/23 09:35:29 Merge Channel: sample_number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: HPLC:Chl-c3 [ ], HPLC:Chlide-a [ ], HPLC:MgDVP [ ], HPLC:Chl-c2 [ ], HPLC:Chl-c1 [ ], HPLC:Me-chlide [ ], HPLC:Peri [ ], HPLC:Pheide-a [ ], HPLC:But-fuco [ ], HPLC:Fuco [ ], HPLC:Neo [ ], HPLC:Pras [ ], HPLC:Viola [ ], HPLC:Hex-fuco [ ], HPLC:Diadino [ ], HPLC:Allo [ ], HPLC:Diato [ ], HPLC:Zea [ ], HPLC:Lut [ ], HPLC:Chl-b [ ], HPLC:C2mgdg, HPLC:DVChl-a [ ], HPLC:Chl-a [ ], HPLC:Phe [ ], HPLC:B-Car [ ], HPLC:TChl-a [ ], Flag:HPLC [ ] Primary file : C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2003\2003-002_Nov2021\Processing\ IOS\2003-002-0019.che2 Secondary file: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2003\2003-002_Nov2021\Processing\ IOS\2003-002-0019.hplc -SORT parameters: 2021/11/23 09:36:42 Sorted in ascending order of channel Pressure [decibar] -CLEAN functions: 2021/11/23 09:37:07 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Change character data from " " to "0" in channels Flag:* -HEADER EDITS: 2021/11/23 09:37:40 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2003\2003-002\Processing\Doc\ 2003-002-bot-hdr1.txt Channel 2: Bottle_Number [n/a] Format: I3 ==> I5 Channel 25: HPLC:Chl-c3 [mg/m^3] Units: ==> mg/m^3 Channel 26: HPLC:Chlide-a [mg/m^3] Units: ==> mg/m^3 Channel 27: HPLC:MgDVP [mg/m^3] Units: ==> mg/m^3 Channel 28: HPLC:Chl-c2 [mg/m^3] Units: ==> mg/m^3 Channel 29: HPLC:Chl-c1 [mg/m^3] Units: ==> mg/m^3 Channel 30: HPLC:Me-chlide [mg/m^3] Units: ==> mg/m^3 Channel 31: HPLC:Peri [mg/m^3] Units: ==> mg/m^3 Channel 32: HPLC:Pheide-a [mg/m^3] Units: ==> mg/m^3 Channel 33: HPLC:But-fuco [mg/m^3] Units: ==> mg/m^3 Channel 34: HPLC:Fuco [mg/m^3] Units: ==> mg/m^3 Channel 35: HPLC:Neo [mg/m^3] Units: ==> mg/m^3 Channel 36: HPLC:Pras [mg/m^3] Units: ==> mg/m^3 Channel 37: HPLC:Viola [mg/m^3] Units: ==> mg/m^3 Channel 38: HPLC:Hex-fuco [mg/m^3] Units: ==> mg/m^3 Channel 39: HPLC:Diadino [mg/m^3] Units: ==> mg/m^3 Channel 40: HPLC:Allo [mg/m^3] Units: ==> mg/m^3 Channel 41: HPLC:Diato [mg/m^3] Units: ==> mg/m^3 Channel 42: HPLC:Zea [mg/m^3] Units: ==> mg/m^3 Channel 43: HPLC:Lut [mg/m^3] Units: ==> mg/m^3 Channel 44: HPLC:Chl-b [mg/m^3] Units: ==> mg/m^3 Channel 45: HPLC:C2mgdg [mg/m^3] Units: ==> mg/m^3 Channel 46: HPLC:DVChl-a [mg/m^3] Units: ==> mg/m^3 Channel 47: HPLC:Chl-a [mg/m^3] Units: ==> mg/m^3 Channel 48: HPLC:Phe [mg/m^3] Units: ==> mg/m^3 Channel 49: HPLC:B-Car [mg/m^3] Units: ==> mg/m^3 Channel 50: HPLC:TChl-a [mg/m^3] Units: ==> mg/m^3 -HEADER EDITS: 2021/11/23 09:38:02 Applied edit header: C:\Users\Samantha\OneDrive\Documents\SH ios\HPLC\2003\2003-002\Processing\Doc\ 2003-002-bot-hdr2.txt $END *COMMENTS Analysis methods: ----------------- Salinity samples are collected in glass bottles and analyzed on Guildline model 8410 Portasal Salinometers which are standardized with IAPSO standard seawater. Oxygen samples are analyzed on an automated Winkler titration system following the procedures of Carpenter (1965). A Brinkmann model 665 Dosimat and model PC910 Colorimeter is controlled by Visual-Basic program to titrate the oxygen samples. Nutrient samples are analyzed fresh on board using a Technicon AAII auto- analyzer following methods described in Barwell-Clarke and Whitney (1996). Chlorophyll samples are collected in duplicate in calibrated polycarbonate bottles (~330ml), then filtered onto 25mm MFS GF/75 filters at <70mmHg vacuum. The filters are placed in glass scintillation vials and immediately frozen at -20ēC until analysis. The chlorophyll is extracted in 10 ml of 90% acetone for 24h at -20ēC, then brought to room temperature and the extract is decanted and measured using a Turner Designs 10-AU-005-CE fluorometer, which has been calibrated with solutions of commercially prepared chlorophyll. HPLC samples were filtered onto 25mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours in the lab and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~5 years after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a, and Me-Chlide. For further information see file QF 2003-002_HPLC*.xlsx. References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. J. Barwell-Clarke and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 3. Nemcek, N. and Peņa, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------- -------- ---- ------ ------------ Salinity:T0:C0 PSS-78 10 -99 () (0.3E-02 1) $END !-1-- -2-- --3--- ---4---- --5-- ---6--- --7--- --8--- ---9---- -10- ---11--- 12 ---13-- 14 --15- 16 --17- 18 --19-- 20 --21-- 22 --23-- 24 ---25-- ---26-- ---27-- ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- 51 !Samp Bott Pressu Temperat Trans Fluores PAR PAR: Salinity Numb Salinity Fl Oxygen: Fl Nitra Fl Silic Fl Phosph Fl Ammoni Fl Chloro Fl HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ re ure: missi cence: Refere :T0:C0 er_o :Bottle ag Dissolv ag te_ ag ate ag ate ag um ag phyll: ag Chl-c3 Chlide- MgDVP Chl-c2 Chl-c1 Me- Peri Pheide- But- Fuco Neo Pras Viola Hex- Diadino Allo Diato Zea Lut Chl-b C2mgdg DVChl-a Chl-a Phe Car TChl-a ag !Numb Numb Primary vity URU: nce ~bin ~o ed ~o plus_ ~t ~i ~p ~o Extrac ~a a chlide a fuco fuco : !er er Seapoin _rec tt lv Nitri ri ca ha ni ted ct HP ! t ords le ed te te te te um ed LC !---- ---- ------ -------- ----- ------- ------ ------ -------- ---- -------- -- ------- -- ----- -- ----- -- ------ -- ------ -- ------ -- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 88 22 0.5 9.0599 34.2 6.790 83.8 273.1 31.9056 73 -99.0000 0 7.434 0 5.1 0 8.3 0 0.75 0 0.06 0 6.00 6 0.035 0.070 0.081 0.722 0.301 0.000 0.038 0.000 0.053 3.368 0.000 0.041 0.034 0.105 0.336 0.197 0.013 0.033 0.000 0.244 0.000 -99.000 7.605 0.260 0.151 7.675 6 86 20 5.1 9.0678 38.7 6.814 20.8 268.3 31.9040 73 -99.0000 0 7.420 0 5.3 0 9.0 0 0.82 0 0.08 0 6.66 6 0.065 0.060 0.081 0.707 0.301 0.080 0.059 0.000 0.044 3.136 0.014 0.038 0.012 0.087 0.293 0.164 0.018 0.018 0.000 0.250 0.000 -99.000 6.873 0.000 0.142 7.014 6 87 21 5.5 9.0652 37.4 7.086 18.9 269.2 31.9037 73 -99.0000 0 -99.000 0 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 85 19 10.1 9.0573 40.6 6.825 8.2 265.9 31.9088 73 -99.0000 0 7.404 0 5.6 0 8.7 0 0.78 0 0.10 0 6.25 6 0.025 0.058 0.078 0.664 0.302 0.028 0.066 0.312 0.046 3.077 0.031 0.050 0.023 0.107 0.279 0.160 0.009 0.016 0.000 0.253 0.000 -99.000 6.822 0.000 0.133 6.908 6 84 18 14.6 9.0752 46.0 4.824 4.7 266.8 31.9803 73 -99.0000 0 6.952 0 6.9 0 10.1 0 0.82 0 0.04 0 3.98 6 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 83 17 19.8 9.3348 55.2 1.728 3.4 266.2 32.2141 73 -99.0000 0 6.714 0 7.2 0 7.7 0 0.89 0 0.06 0 1.49 6 0.000 0.000 0.008 0.137 0.037 0.000 0.000 0.000 0.065 0.664 0.000 0.037 0.000 0.094 0.036 0.013 0.000 0.011 0.000 0.144 0.000 -99.000 1.676 0.000 0.030 1.676 6 82 16 25.2 9.3625 57.4 1.321 3.1 266.1 32.2768 73 -99.0000 0 6.640 0 6.8 0 7.4 0 0.87 0 0.06 0 0.57 6 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 81 15 30.0 9.3410 58.1 1.019 2.7 263.0 32.2815 73 -99.0000 0 6.655 0 6.8 0 6.9 6 0.87 6 0.06 0 0.40 6 0.000 0.000 0.000 0.036 0.000 0.000 0.000 0.000 0.049 0.114 0.000 0.011 0.000 0.047 0.000 0.000 0.000 0.000 0.000 0.109 0.000 -99.000 0.525 0.000 0.000 0.525 6 80 14 35.1 9.3187 58.0 1.098 2.6 265.5 32.2829 73 -99.0000 0 -99.000 0 -99.0 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 79 13 35.3 9.3193 58.1 1.074 2.6 265.8 32.2828 73 -99.0000 0 6.635 0 6.7 0 7.5 0 0.86 0 0.09 0 0.41 6 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 78 12 40.2 9.3170 58.3 1.036 2.5 266.1 32.2833 73 -99.0000 0 6.671 0 6.7 0 6.1 0 0.85 0 0.09 0 0.56 6 0.000 0.000 0.000 0.030 0.000 0.000 0.000 0.000 0.048 0.117 0.000 0.000 0.000 0.059 0.000 0.000 0.000 0.000 0.000 0.091 0.000 -99.000 0.502 0.000 0.000 0.502 6 77 11 50.0 9.2935 58.5 0.944 2.3 268.3 32.2860 73 -99.0000 0 6.631 0 6.8 0 8.2 0 0.86 0 0.10 0 0.52 3 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 76 10 74.9 8.9254 60.5 0.396 2.2 270.0 32.3541 73 -99.0000 0 6.419 0 9.7 0 9.1 0 1.01 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 75 9 100.3 8.0532 60.5 0.222 2.2 274.0 32.7574 73 -99.0000 0 5.497 0 16.2 0 17.5 0 1.42 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 74 8 125.2 8.0159 60.8 0.088 2.2 278.7 33.3596 73 -99.0000 0 4.097 0 24.4 0 28.4 0 1.91 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 73 7 149.5 7.9153 60.8 0.085 2.2 285.5 33.5959 73 -99.0000 0 3.463 0 27.4 0 33.0 0 2.10 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 72 6 175.4 7.8557 60.9 0.082 2.2 291.4 33.7552 73 -99.0000 0 2.932 0 29.7 0 37.4 0 2.20 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 71 5 199.4 7.7182 61.0 0.080 2.2 299.1 33.8891 73 33.8867 0 2.427 0 31.4 0 43.2 0 2.37 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 70 4 249.9 7.0790 61.4 0.086 2.2 308.9 33.9813 73 33.9763 0 2.000 0 30.5 0 46.4 0 2.48 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 69 3 299.9 6.6082 61.4 0.084 2.2 319.2 34.0050 73 34.0006 0 1.766 0 35.7 0 55.9 0 2.62 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 68 2 400.1 5.7081 59.2 0.086 2.2 332.2 34.0416 73 34.0406 0 1.259 0 38.1 0 71.6 0 2.83 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 67 1 452.3 5.2570 60.2 0.087 2.2 340.5 34.0747 73 34.0745 0 1.026 0 40.9 0 79.9 0 2.93 0 -99.00 0 -99.00 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0