*2014/11/20 09:53:08.74 *IOS HEADER VERSION 1.10 2011/10/26 2011/10/26 *FILE START TIME : UTC 2001/10/01 04:12:27.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 23 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII NUMBER OF CHANNELS : 19 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- --------------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 254 276 2 Pressure decibar 2.5 2000.6 3 Temperature:Primary 'deg C (ITS90)' 1.9651 11.666 4 Transmissivity %/metre 36 60.1 5 Fluorescence:URU:Seapoint mg/m^3 -0.3E-02 1.954 6 Oxygen:Dissolved:SBE umol/kg 15.1 268 7 Salinity:T0:C0 PSS-78 32.3002 34.5797 8 Bottle_Number n/a 1 23 9 Oxygen:Dissolved mL/L 0.31 6.5 10 Salinity:Bottle PSS-78 32.3021 34.5789 11 Oxygen:Dissolved umol/kg 13.8 290.3 12 Oxygen:Dissolved:SBE mL/L 0.34 6.15 13 Nitrate_plus_Nitrite umol/L 4.7 45.5 14 Silicate umol/L 8.7 170.5 15 Phosphate umol/L 0.8 3.22 16 Carbon:Dissolved:Inorganic umol/kg 1982.3 2395.8 17 Flag:Carbon:Dissolved:Inorganic n/a 18 Alkalinity:Total umol/kg 2149.29 2417.88 19 Flag:Alkalinity:Total n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 7 F ' ' 1 3 -99 ' ' 9 F ' ' 4 4 -99 ' ' 6 F ' ' 1 5 -99 ' ' 8 F ' ' 3 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 9 F ' ' 4 8 -99 ' ' 3 I I 0 9 -99 ' ' 8 F ' ' 3 10 -99 ' ' ' ' f9.4 R4 ' ' 11 -99 ' ' 6 F ' ' 1 12 -99 ' ' 7 F ' ' 2 13 -99 ' ' 6 F R4 1 14 -99 ' ' 6 F R4 1 15 -99 ' ' 7 F R4 2 16 -99 ' ' ' ' F8.2 R4 ' ' 17 0 ' ' 3 NQ C ' ' 18 -99 ' ' ' ' F8.2 R4 ' ' 19 0 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2001-31 AGENCY : IOS, Ocean Science and Productivity, Sidney, B.C. COUNTRY : Canada PROJECT : Haida Eddies, Nestucca SCIENTIST : Mackas D. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : NE Pacific STATION : H01B EVENT NUMBER : 142 LATITUDE : 50 45.00000 N ! (deg min) LONGITUDE : 134 44.99000 W ! (deg min) WATER DEPTH : 3481 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0550 $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------- -------------- ---------- temperature ' ' primary conductivity ' ' primary pressure ' ' 75636 temperature ' ' secondary conductivity ' ' secondary Fluorometer ' ' Seapoint transmissometer ' ' primary irradiance ' ' 4615 Oxygen ' ' SBE $END $REMARKS SOFTWARE VERSION SEASAVE WIN32 V 5.21 Comments from secondary file: D:\DATA\2001\2001-31\21310142.dox --------------------------------------------------------------- Dissolved oxygen concentration determined using an automated titration system consisting of a Brinkman dosimat (model 665) and a PC 900 Colorimeter. $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 1.8 2001/10/30 16:01:43 2772 2772 BINAVE 4.0.1 2001/11/05 14:57:43 2772 23 CALIB 10.0 2001/11/05 15:44:53 23 23 REMOVECH 6.0 2001/11/05 16:05:02 23 23 HDREDIT2 1.1 2001/11/05 16:06:45 ? ? ADDSAMP 3.0 2001/11/15 14:20:44 23 23 MERGE 2.7 2001/11/15 14:28:51 23 23 MERGE 2.7 2001/11/15 14:34:55 23 23 CHGUNITS 1.1 2001/11/15 15:31:15 23 23 REORDER 1.1 2001/11/15 15:54:12 ? ? HDREDIT2 1.3 2002/03/19 12:20:15 ? ? CHGUNITS 1.3 2002/03/19 12:46:15 23 23 CALIB 10.2 2002/03/19 12:47:36 23 23 CLEAN 3.7 2002/03/19 14:00:45 23 23 MERGE 3.1 2004/04/05 11:20:38 23 23 HDREDIT2 1.9 2004/04/05 11:36:39 ? ? SORT 3.4.1 2004/04/05 11:37:59 23 23 CLEAN 4.5 2004/04/05 11:38:11 23 23 SORT 3.5 2005/07/29 16:20:20 23 23 MERGE 3.3 2005/07/29 16:21:38 23 23 SORT 3.5 2005/07/29 16:25:27 23 23 HDREDIT2 2.5 2005/07/29 16:26:52 ? ? HDREDIT2 2.5.1 2005/11/04 14:53:48 ? ? CHANGE_FLAGS 1.0 2013/07/29 14:28:39 23 23 CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:25:10 23 23 CHANGE_FLAGS 2.0 2014/11/20 09:53:08 23 23 $END $REMARKS -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.0 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following CALIB parameters were used: Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\CTD\2001-31\2131RCAL.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 8 Chl_fluorescence:Seapoint ug/l 10 -0.1200000E+00 0.1000000E+01 11 Salinity:T0:C0 PSS-78 10 -0.4000000E-02 0.1000000E+01 12 Salinity:T1:C1 PSS-78 10 -0.1400000E-01 0.1000000E+01 -The following CHANNEL(S) were removed from file. Scan_Number Temperature:Secondary Conductivity:Primary Conductivity:Secondary Irradiance (PAR) Salinity:T1:C1 Flag -The following ADDSAMP parameters were used: Sample Number Lookup File: D:\DATA\2001\2001-31\addsamp.csv Bottle Channel Name: Bottle_Number -The following MERGE parameters were used: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: Pressure, Temperature:Primary, Transmissivity, Chl_fluorescence:Seapoint, Irradiance (PAR), Oxygen:SBE:Mass, Salinity:T0:C0, Bottle_Number Secondary Channels to Include: Oxygen:Dissolved:volume Primary file : D:\DATA\2001\2001-31\21310142.sam Secondary file: D:\DATA\2001\2001-31\21310142.dox Comments from secondary file: D:\DATA\2001\2001-31\21310142.dox --------------------------------------------------------------- C.H. Culbertson's paper on Dissolved Oxygen in the 'Woce Hydrographic Program Operations and Methods - July 1991' -The following OXYCALC parameters were used Blank = 0.002 Sodium Thiosulfate concentration = 0.720 Volume of iodate standard (cm**3) = 10.02 Enter Normalitity of iodate standard = 0.01013364 -The following MERGE parameters were used: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: Pressure, Temperature:Primary, Transmissivity, Chl_fluorescence:Seapoint, Irradiance (PAR), Oxygen:SBE:Mass, Salinity:T0:C0, Bottle_Number, Oxygen:Dissolved:volume Secondary Channels to Include: salinity:bottle Primary file : D:\DATA\2001\2001-31\21310142.mrg Secondary file: D:\DATA\2001\2001-31\21310142.sal CHANGE units: - Units changed from ml/l to umol/l CHANGE units: - Units changed from umol/kg to ml/l -The following CALIB parameters were used: Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = M:\Data\oxy\2131\2131oxy.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 6 Oxygen:SBE:Mass umol/kg 10 0.0000000E+00 0.1560000E+01 12 Oxygen:SBE:Volume ml/l 10 0.0000000E+00 0.1560000E+01 CLEAN functions: - Reset #RECS, MIN & MAX values in header. - Set last 4 characters of file name to event -The following MERGE parameters were used: Merge Channel: Sample_Number Merge Scheme Used: Interweave Records from Both Files Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Nitrate_plus_Nitrite, Silicate, Phosphate, Ammonium Primary file : H:\New_Archive\2001\2001-31\hydro\21310142.che Secondary file: H:\New_Archive\2001\2001-31\hydro\21310142.srt_nut Comments from secondary file: H:\New_Archive\2001\2001-31\hydro\21310142.srt_nut -------------------------------------------------- -The following SORT parameters were used. Sorted by channel: Sample_Number Pressure channel sorted according to values in sort channel -The following SORT parameters were used. Sorted by channel: Pressure Pressure channel sorted according to values in sort channel CLEAN functions: - Reset #RECS, MIN & MAX values in header. - Change Pad Value to -99 in All Channels. - Delete Empty Channels: 1 deleted. - Remove Sea-Bird comments from the header. -SORT parameters: 2005/07/29 16:20:20 Sorted in descending order of channel Sample_Number -The following MERGE parameters were used: 2005/07/29 16:21:37 2005/07/29 16:21:37 2005/07/29 16:21: Merge Channel: Sample_Number Merge Scheme Used: Interweave Records from Both Files Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Carbon:Dissolved:Inorganic, Flag:Carbon:Dissolved:Inorganic, Alkalinity:Total, Flag:Alkalinity:Total, pH, Flag:pH Primary file : H:\Data Processing\Carbon\Haida\2001-31\2001-31-0142.srtche Secondary file: H:\Data Processing\Carbon\Haida\2001-31\2001-31-0142.srtios Comments from secondary file: H:\Data Processing\Carbon\Haida\2001-31\2001-31-0142.srtios ----------------------------------------------------------- -SORT parameters: 2005/07/29 16:21:20 Sorted in descending order of channel Sample_Number -SORT parameters: 2005/07/29 16:25:27 Sorted in ascending order of channel Pressure -HEADER EDITS: 2005/07/29 16:26:52 Applied edit header: H:\Data Processing\Carbon\Haida\2001-31\DIC_ALK.txt -HEADER EDITS: 2005/11/04 14:53:48 Applied edit header: O:\Data Processing\Header Comments\quality_flags.txt $END *COMMENTS The SBE Oxygen data should be considered to be within +/- 5%. Collection method: ------------------ A rosette, holding 24 ten-litre water samplers, with a CTD was used. Analysis methods: ----------------- Salinity samples are collected in glass bottles and analyzed on Guildline model 8410 Portasal Salinometers which are standardized with IAPSO standard seawater. Oxygen samples are analyzed on an automated Winkler titration system following the procedures of Carpenter (1965). A Brinkmann model 665 Dosimat and model PC910 Colorimeter is controlled by Visual-Basic program to titrate the oxygen samples. Nutrient samples for Station CS01 (samples 1 to 19) were analysed fresh at sea. All other samples were analysed frozen. All samples were analyzed using a Technicon AAII autoanalyzer following methods described in Barwell-Clarke and Whitney (1996). References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. J. Barwell-Clarke and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. Dissolved inorganic carbon (DIC) and total alkalinity (Alk) samples were collected in 500 mL glass bottles, according to the DOE Handbook of Methods (1994), poisoned with 100 microL of saturated HgCl2, and kept at 4 C during transport back to shore for analysis at the Institute of Ocean Sciences. Total dissolved inorganic carbon was determined by coulometric titration with photometric detection using a SOMMA (Johnson et al., 1985; 1987), and Alk was determined by potentiometric titration in an open cell with 0.1 M HCl (Dickson et al., 2003; Haraldsson et al., 1997). The accuracy was assured by calibrating against Certified Reference Materials, CRM’s (DOE, 1994; Dickson 2001; Dickson et al., 2003), supplied by Andrew Dickson (Scripps Institution of Oceanography, San Diego, USA) and analyzed once a day. The measured and certified values of the CRMs differed by 0.7-1.1 µmol kg-1 for DIC and between 0.9 and 2.4 µmol kg-1 for AT. DIC analytical precision: 1.1 umol/kg. Alk analytical precision: 2.3 ueq/kg. *CALIBRATION $TABLE: CORRECTED CHANNELS !Name Units Fmla Pad Coefficients !--------------------------- --------- ---- ------ ------------ Chl_fluorescence:Seapoint ug/l 10 -9.9 () (-0.12 1) Salinity:T0:C0 PSS-78 10 -9.9 () (-0.4E-02 1) Salinity:T1:C1 PSS-78 10 -9.9 () (-0.14E-01 1) Oxygen:SBE:Mass umol/kg 10 -9.9 () (0 1.56) Oxygen:SBE:Volume ml/l 10 -9.9 () (0 1.56) $END !-1-- --2--- ---3---- --4-- ---5--- --6-- ---7---- 8- ---9--- ---10--- --11- --12-- --13- --14- --15-- ---16-- 17 ---18-- 19 !Samp Pressu Temperat Trans Fluores Oxyge Salinity Bo Oxygen: Salinity Oxyge Oxygen Nitra Silic Phosph Carbon: Fl Alkalin Fl !le_ re ure: missi cence: n: :T0:C0 tt Dissolv :Bottle n: : te_ ate ate Dissolv ag ity: ag !Numb Primary vity URU: Disso ~u ed Disso Dissol plus_ ed: ~g Total ~T !er Seapoin lved: mb lved ved: Nitri Inorgan an ot ! t SBE er SBE te ic ic al !---- ------ -------- ----- ------- ----- -------- -- ------- -------- ----- ------ ----- ----- ------ ------- -- ------- -- *END OF HEADER 276 2.5 11.6660 36.0 1.648 267.2 32.3002 23 6.440 32.3021 287.4 6.13 4.7 8.7 0.82 1991.30 0 2149.29 0 275 9.4 11.4963 45.2 1.808 268.0 32.3012 22 6.500 -99.0000 290.3 6.15 4.8 10.1 0.81 1992.70 0 2163.51 0 274 19.1 11.4682 45.2 1.954 267.2 32.3016 21 6.350 -99.0000 283.4 6.13 4.8 11.1 0.80 1982.30 0 2174.43 0 273 29.2 11.4591 46.5 1.856 266.4 32.3012 20 6.320 -99.0000 282.0 6.12 4.9 11.0 0.80 1987.00 0 2174.71 0 272 50.5 8.3970 55.7 0.420 257.6 32.5339 19 6.120 -99.0000 273.4 5.91 11.7 17.5 1.20 2039.60 0 2184.00 0 271 76.0 7.2073 58.5 0.032 225.3 32.7990 18 5.350 -99.0000 238.9 5.18 17.9 27.7 1.53 2087.10 0 2195.43 0 270 100.4 6.7636 58.8 0.006 195.8 33.1239 17 4.680 -99.0000 209.1 4.49 22.7 30.8 1.79 2128.70 0 2219.42 0 269 125.7 6.6401 59.1 0.004 167.5 33.4893 16 4.010 -99.0000 178.8 3.85 26.3 36.3 1.95 2158.10 0 2237.48 0 268 149.1 7.0113 58.9 0.001 119.2 33.7978 15 2.860 -99.0000 127.7 2.75 30.7 44.2 2.19 2205.70 0 2254.98 0 267 172.7 6.7806 58.9 0.001 110.8 33.8890 14 2.650 -99.0000 118.1 2.54 32.5 48.3 2.28 2218.30 0 2264.06 0 266 200.3 6.5170 59.1 -0.003 99.1 33.9281 13 2.360 -99.0000 105.4 2.28 34.0 52.6 2.40 2229.30 0 2267.00 0 265 251.2 5.9262 59.5 0.002 81.6 33.9553 12 2.020 -99.0000 90.0 1.87 36.6 61.0 2.58 2255.60 0 2289.43 0 264 299.8 5.5030 59.6 0.000 72.7 33.9629 11 1.860 -99.0000 83.1 1.67 41.3 79.7 2.90 2269.70 0 2281.39 0 263 401.2 4.8086 59.9 0.001 51.5 34.0122 10 1.200 -99.0000 53.7 1.19 41.4 80.8 2.90 2299.50 0 2296.09 0 262 501.5 4.4874 60.1 0.003 33.1 34.0871 9 0.760 -99.0000 34.1 0.76 42.8 91.2 3.02 2322.60 0 2318.94 0 261 600.1 4.2224 59.9 0.003 22.5 34.1577 8 0.520 -99.0000 23.3 0.51 44.1 99.1 3.11 2339.20 0 2326.00 0 260 800.8 3.7058 60.0 0.005 15.4 34.2793 7 0.310 -99.0000 14.1 0.36 44.8 115.6 3.21 2365.90 0 2353.34 0 259 1000.4 3.2671 59.9 0.004 15.1 34.3633 6 0.320 34.3622 14.5 0.34 45.0 132.2 3.22 2378.40 0 2373.07 0 258 1001.4 3.2658 59.9 0.006 15.1 34.3637 5 0.310 34.3621 13.8 0.34 45.1 134.7 3.21 2377.90 0 2367.57 0 257 1248.5 2.7736 59.9 0.006 18.3 34.4282 4 0.370 34.4263 16.4 0.42 45.5 147.8 3.19 2393.70 0 2380.87 0 256 1498.2 2.4405 59.8 0.003 27.6 34.4929 3 0.680 34.4930 30.2 0.64 44.9 156.2 3.17 2395.80 0 2391.18 0 255 1749.0 2.1529 59.8 0.003 42.9 34.5445 2 0.930 34.5448 41.7 0.98 44.1 165.3 3.08 2391.90 0 2402.54 0 254 2000.6 1.9651 59.9 0.002 57.6 34.5797 1 1.320 34.5789 59.0 1.33 43.0 170.5 3.03 2390.90 0 2417.88 0