*2014/11/20 09:53:08.18 *IOS HEADER VERSION 1.10 2011/10/26 2011/10/26 *FILE START TIME : UTC 2001/09/22 11:52:31.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 23 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII NUMBER OF CHANNELS : 19 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- --------------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 46 68 2 Pressure decibar 4.1 2001 3 Temperature:Primary 'deg C (ITS90)' 1.8696 12.141 4 Transmissivity %/metre 36.5 60.3 5 Fluorescence:URU:Seapoint mg/m^3 0 1.985 6 Oxygen:Dissolved:SBE umol/kg 16.7 294.8 7 Salinity:T0:C0 PSS-78 32.2145 34.5945 8 Bottle_Number n/a 1 23 9 Oxygen:Dissolved mL/L 0.29 6.57 10 Salinity:Bottle PSS-78 32.2251 34.5955 11 Oxygen:Dissolved umol/kg 13 293.2 12 Oxygen:Dissolved:SBE mL/L 0.39 6.77 13 Nitrate_plus_Nitrite umol/L 3.2 45.1 14 Silicate umol/L 10.6 170.1 15 Phosphate umol/L 0.72 3.3 16 Carbon:Dissolved:Inorganic umol/kg 1959.1 1959.1 17 Flag:Carbon:Dissolved:Inorganic n/a 18 Alkalinity:Total umol/kg 2168.92 2168.92 19 Flag:Alkalinity:Total n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 7 F ' ' 1 3 -99 ' ' 9 F ' ' 4 4 -99 ' ' 6 F ' ' 1 5 -99 ' ' 8 F ' ' 3 6 -99 ' ' 6 F ' ' 1 7 -99 ' ' 9 F ' ' 4 8 -99 ' ' 3 I I 0 9 -99 ' ' 8 F ' ' 3 10 -99 ' ' ' ' f9.4 R4 ' ' 11 -99 ' ' 6 F ' ' 1 12 -99 ' ' 7 F ' ' 2 13 -99 ' ' 6 F R4 1 14 -99 ' ' 6 F R4 1 15 -99 ' ' 7 F R4 2 16 -99 ' ' ' ' F8.2 R4 ' ' 17 0 ' ' 3 NQ C ' ' 18 -99 ' ' ' ' F8.2 R4 ' ' 19 0 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2001-31 AGENCY : IOS, Ocean Science and Productivity, Sidney, B.C. COUNTRY : Canada PROJECT : Haida Eddies, Nestucca SCIENTIST : Mackas D. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : NE Pacific STATION : HOOA EVENT NUMBER : 44 LATITUDE : 53 29.98000 N ! (deg min) LONGITUDE : 138 20.00000 W ! (deg min) *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0550 $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------- -------------- ---------- temperature ' ' primary conductivity ' ' primary pressure ' ' 75636 temperature ' ' secondary conductivity ' ' secondary Fluorometer ' ' Seapoint transmissometer ' ' primary irradiance ' ' 4615 Oxygen ' ' SBE $END $REMARKS SOFTWARE VERSION SEASAVE WIN32 V 5.21 Comments from secondary file: D:\DATA\2001\2001-31\21310044.dox --------------------------------------------------------------- Dissolved oxygen concentration determined using an automated titration system consisting of a Brinkman dosimat (model 665) and a PC 900 Colorimeter. $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 1.8 2001/10/30 16:01:34 2783 2783 BINAVE 4.0.1 2001/11/05 14:57:40 2783 23 CALIB 10.0 2001/11/05 15:44:52 23 23 REMOVECH 6.0 2001/11/05 16:05:02 23 23 HDREDIT2 1.1 2001/11/05 16:06:44 ? ? ADDSAMP 3.0 2001/11/15 14:20:42 23 23 MERGE 2.7 2001/11/15 14:28:49 23 23 MERGE 2.7 2001/11/15 14:34:53 23 23 CHGUNITS 1.1 2001/11/15 15:31:13 23 23 REORDER 1.1 2001/11/15 15:48:21 ? ? HDREDIT2 1.3 2002/03/19 12:20:13 ? ? CHGUNITS 1.3 2002/03/19 12:46:14 23 23 CALIB 10.2 2002/03/19 12:47:35 23 23 CLEAN 3.7 2002/03/19 14:00:44 23 23 MERGE 3.1 2004/04/05 11:20:37 23 23 HDREDIT2 1.9 2004/04/05 11:36:38 ? ? SORT 3.4.1 2004/04/05 11:37:58 23 23 CLEAN 4.5 2004/04/05 11:38:10 23 23 SORT 3.5 2005/07/29 16:20:20 23 23 MERGE 3.3 2005/07/29 16:21:37 23 23 SORT 3.5 2005/07/29 16:25:26 23 23 HDREDIT2 2.5 2005/07/29 16:26:51 ? ? HDREDIT2 2.5.1 2005/11/04 14:53:17 ? ? CHANGE_FLAGS 1.0 2013/07/16 11:46:44 23 23 CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:25:09 23 23 CHANGE_FLAGS 2.0 2014/11/20 09:53:08 23 23 $END $REMARKS -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.0 Minimum bin value = 0.000 Average value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following CALIB parameters were used: Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = Q:\CTD\2001-31\2131RCAL.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 8 Chl_fluorescence:Seapoint ug/l 10 -0.1200000E+00 0.1000000E+01 11 Salinity:T0:C0 PSS-78 10 -0.4000000E-02 0.1000000E+01 12 Salinity:T1:C1 PSS-78 10 -0.1400000E-01 0.1000000E+01 -The following CHANNEL(S) were removed from file. Scan_Number Temperature:Secondary Conductivity:Primary Conductivity:Secondary Irradiance (PAR) Salinity:T1:C1 Flag -The following ADDSAMP parameters were used: Sample Number Lookup File: D:\DATA\2001\2001-31\addsamp.csv Bottle Channel Name: Bottle_Number -The following MERGE parameters were used: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: Pressure, Temperature:Primary, Transmissivity, Chl_fluorescence:Seapoint, Irradiance (PAR), Oxygen:SBE:Mass, Salinity:T0:C0, Bottle_Number Secondary Channels to Include: Oxygen:Dissolved:volume Primary file : D:\DATA\2001\2001-31\21310044.sam Secondary file: D:\DATA\2001\2001-31\21310044.dox Comments from secondary file: D:\DATA\2001\2001-31\21310044.dox --------------------------------------------------------------- C.H. Culbertson's paper on Dissolved Oxygen in the 'Woce Hydrographic Program Operations and Methods - July 1991' -The following OXYCALC parameters were used Blank = 0.002 Sodium Thiosulfate concentration = 0.720 Volume of iodate standard (cm**3) = 10.02 Enter Normalitity of iodate standard = 0.01013364 -The following MERGE parameters were used: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: Pressure, Temperature:Primary, Transmissivity, Chl_fluorescence:Seapoint, Irradiance (PAR), Oxygen:SBE:Mass, Salinity:T0:C0, Bottle_Number, Oxygen:Dissolved:volume Secondary Channels to Include: salinity:bottle Primary file : D:\DATA\2001\2001-31\21310044.mrg Secondary file: D:\DATA\2001\2001-31\21310044.sal CHANGE units: - Units changed from ml/l to umol/l CHANGE units: - Units changed from umol/kg to ml/l -The following CALIB parameters were used: Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = M:\Data\oxy\2131\2131oxy.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 6 Oxygen:SBE:Mass umol/kg 10 0.0000000E+00 0.1560000E+01 12 Oxygen:SBE:Volume ml/l 10 0.0000000E+00 0.1560000E+01 CLEAN functions: - Reset #RECS, MIN & MAX values in header. - Set last 4 characters of file name to event -The following MERGE parameters were used: Merge Channel: Sample_Number Merge Scheme Used: Interweave Records from Both Files Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Nitrate_plus_Nitrite, Silicate, Phosphate, Ammonium Primary file : H:\New_Archive\2001\2001-31\hydro\21310044.che Secondary file: H:\New_Archive\2001\2001-31\hydro\21310044.srt_nut Comments from secondary file: H:\New_Archive\2001\2001-31\hydro\21310044.srt_nut -------------------------------------------------- -The following SORT parameters were used. Sorted by channel: Sample_Number Pressure channel sorted according to values in sort channel -The following SORT parameters were used. Sorted by channel: Pressure Pressure channel sorted according to values in sort channel CLEAN functions: - Reset #RECS, MIN & MAX values in header. - Change Pad Value to -99 in All Channels. - Delete Empty Channels: 1 deleted. - Remove Sea-Bird comments from the header. -SORT parameters: 2005/07/29 16:20:20 Sorted in descending order of channel Sample_Number -The following MERGE parameters were used: 2005/07/29 16:21:37 Merge Channel: Sample_Number Merge Scheme Used: Interweave Records from Both Files Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Carbon:Dissolved:Inorganic, Flag:Carbon:Dissolved:Inorganic, Alkalinity:Total, Flag:Alkalinity:Total, pH, Flag:pH Primary file : H:\Data Processing\Carbon\Haida\2001-31\2001-31-0044.srtche Secondary file: H:\Data Processing\Carbon\Haida\2001-31\2001-31-0044.srtios Comments from secondary file: H:\Data Processing\Carbon\Haida\2001-31\2001-31-0044.srtios ----------------------------------------------------------- -SORT parameters: 2005/07/29 16:21:19 Sorted in descending order of channel Sample_Number -SORT parameters: 2005/07/29 16:25:26 Sorted in ascending order of channel Pressure -HEADER EDITS: 2005/07/29 16:26:51 Applied edit header: H:\Data Processing\Carbon\Haida\2001-31\DIC_ALK.txt -HEADER EDITS: 2005/11/04 14:53:17 Applied edit header: O:\Data Processing\Header Comments\quality_flags.txt $END *COMMENTS The SBE Oxygen data should be considered to be within +/- 5%. Collection method: ------------------ A rosette, holding 24 ten-litre water samplers, with a CTD was used. Analysis methods: ----------------- Salinity samples are collected in glass bottles and analyzed on Guildline model 8410 Portasal Salinometers which are standardized with IAPSO standard seawater. Oxygen samples are analyzed on an automated Winkler titration system following the procedures of Carpenter (1965). A Brinkmann model 665 Dosimat and model PC910 Colorimeter is controlled by Visual-Basic program to titrate the oxygen samples. Nutrient samples for Station CS01 (samples 1 to 19) were analysed fresh at sea. All other samples were analysed frozen. All samples were analyzed using a Technicon AAII autoanalyzer following methods described in Barwell-Clarke and Whitney (1996). References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. J. Barwell-Clarke and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. Comments from secondary file: H:\Data Processing\Carbon\Haida\2001-31\2001-31-0044.srtios ----------------------------------------------------------- Sample_Number 67.: Large difference between Alk replicates Dissolved inorganic carbon (DIC) and total alkalinity (Alk) samples were collected in 500 mL glass bottles, according to the DOE Handbook of Methods (1994), poisoned with 100 microL of saturated HgCl2, and kept at 4 C during transport back to shore for analysis at the Institute of Ocean Sciences. Total dissolved inorganic carbon was determined by coulometric titration with photometric detection using a SOMMA (Johnson et al., 1985; 1987), and Alk was determined by potentiometric titration in an open cell with 0.1 M HCl (Dickson et al., 2003; Haraldsson et al., 1997). The accuracy was assured by calibrating against Certified Reference Materials, CRM’s (DOE, 1994; Dickson 2001; Dickson et al., 2003), supplied by Andrew Dickson (Scripps Institution of Oceanography, San Diego, USA) and analyzed once a day. The measured and certified values of the CRMs differed by 0.7-1.1 µmol kg-1 for DIC and between 0.9 and 2.4 µmol kg-1 for AT. DIC analytical precision: 1.1 umol/kg. Alk analytical precision: 2.3 ueq/kg. *CALIBRATION $TABLE: CORRECTED CHANNELS !Name Units Fmla Pad Coefficients !--------------------------- --------- ---- ------ ------------ Chl_fluorescence:Seapoint ug/l 10 -9.9 () (-0.12 1) Salinity:T0:C0 PSS-78 10 -9.9 () (-0.4E-02 1) Salinity:T1:C1 PSS-78 10 -9.9 () (-0.14E-01 1) Oxygen:SBE:Mass umol/kg 10 -9.9 () (0 1.56) Oxygen:SBE:Volume ml/l 10 -9.9 () (0 1.56) $END !-1-- --2--- ---3---- --4-- ---5--- --6-- ---7---- 8- ---9--- ---10--- --11- --12-- --13- --14- --15-- ---16-- 17 ---18-- 19 !Samp Pressu Temperat Trans Fluores Oxyge Salinity Bo Oxygen: Salinity Oxyge Oxygen Nitra Silic Phosph Carbon: Fl Alkalin Fl !le_ re ure: missi cence: n: :T0:C0 tt Dissolv :Bottle n: : te_ ate ate Dissolv ag ity: ag !Numb Primary vity URU: Disso ~u ed Disso Dissol plus_ ed: ~g Total ~T !er Seapoin lved: mb lved ved: Nitri Inorgan an ot ! t SBE er SBE te ic ic al !---- ------ -------- ----- ------- ----- -------- -- ------- -------- ----- ------ ----- ----- ------ ------- -- ------- -- *END OF HEADER 68 4.1 12.1394 36.5 1.977 287.4 32.2145 23 6.300 32.2251 281.4 6.60 3.3 10.9 0.72 -99.00 0 -99.00 0 67 11.7 12.1410 46.1 1.979 287.5 32.2170 22 6.330 -99.0000 282.7 6.60 3.2 10.6 0.73 1959.10 6 2168.92 63 66 19.9 12.1338 46.2 1.985 288.0 32.2173 21 6.270 -99.0000 279.9 6.61 3.2 10.8 0.73 -99.00 0 -99.00 0 65 31.8 11.5019 47.7 1.742 290.9 32.2728 20 6.290 -99.0000 280.9 6.68 4.2 11.3 0.79 -99.00 0 -99.00 0 64 51.2 7.2963 56.3 0.504 294.8 32.5807 19 6.570 -99.0000 293.2 6.77 12.2 16.5 1.27 -99.00 0 -99.00 0 63 76.1 6.6288 58.6 0.101 274.9 32.7083 18 6.180 -99.0000 275.7 6.32 16.3 21.3 1.51 -99.00 0 -99.00 0 62 98.5 6.6243 59.1 0.030 231.3 32.9770 17 5.230 -99.0000 233.5 5.32 20.3 27.8 1.73 -99.00 0 -99.00 0 61 124.8 6.3114 59.1 0.015 198.0 33.2942 16 4.430 -99.0000 197.8 4.56 24.9 34.7 1.97 -99.00 0 -99.00 0 60 149.2 6.6034 59.0 0.001 133.7 33.7203 15 3.010 -99.0000 134.4 3.07 30.5 44.9 2.26 -99.00 0 -99.00 0 59 173.1 6.4083 59.2 0.000 123.2 33.8489 14 2.750 -99.0000 122.8 2.84 32.1 49.0 2.37 -99.00 0 -99.00 0 58 199.0 6.1218 59.3 0.004 112.0 33.8998 13 2.500 -99.0000 111.7 2.57 34.0 54.4 2.47 -99.00 0 -99.00 0 57 248.2 5.6162 59.2 0.004 98.1 33.9214 12 2.210 -99.0000 98.8 2.26 36.2 61.9 2.58 -99.00 0 -99.00 0 56 300.7 5.1527 59.6 0.004 71.9 33.9596 11 1.620 -99.0000 72.2 1.65 38.9 71.3 2.82 -99.00 0 -99.00 0 55 401.4 4.6101 59.9 0.006 48.4 34.0281 10 1.070 -99.0000 47.7 1.11 41.7 86.6 3.04 -99.00 0 -99.00 0 54 501.4 4.2540 60.2 0.006 33.7 34.0954 9 0.720 -99.0000 32.2 0.78 43.2 96.7 3.15 -99.00 0 -99.00 0 53 600.8 4.0623 60.2 0.006 24.8 34.1610 8 0.580 -99.0000 25.7 0.58 43.7 104.8 3.21 -99.00 0 -99.00 0 52 799.5 3.6252 60.2 0.008 16.8 34.2801 7 0.340 -99.0000 15.2 0.39 45.0 121.6 3.27 -99.00 0 -99.00 0 50 999.7 3.2138 60.2 0.009 16.7 34.3572 5 0.290 34.3588 13.0 0.39 44.9 135.4 3.30 -99.00 0 -99.00 0 51 1000.6 3.2138 60.1 0.008 16.7 34.3572 6 0.320 -99.0000 14.3 0.39 45.1 132.0 3.29 -99.00 0 -99.00 0 49 1251.1 2.6837 60.2 0.008 21.4 34.4364 4 0.440 34.4372 19.7 0.50 44.9 149.1 3.27 -99.00 0 -99.00 0 48 1501.0 2.3228 60.2 0.008 32.9 34.5048 3 0.700 34.5065 31.4 0.76 44.6 161.0 3.22 -99.00 0 -99.00 0 47 1749.4 2.0765 60.3 0.006 49.3 34.5536 2 1.100 34.5545 49.1 1.14 43.5 166.0 3.15 -99.00 0 -99.00 0 46 2001.0 1.8696 60.2 0.005 67.9 34.5945 1 1.610 34.5955 72.0 1.56 42.2 170.1 3.07 -99.00 0 -99.00 0