*2014/11/20 09:53:01.89 *IOS HEADER VERSION 1.10 2011/10/26 2011/10/26 *FILE START TIME : UTC 2001/06/05 06:02:25.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 22 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII NUMBER OF CHANNELS : 21 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- --------------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 245 266 2 Pressure decibar 2.6 2001.2 3 Temperature:Primary 'deg C (ITS90)' 1.918 9.1503 4 Salinity:T0:C0 PSS-78 32.3957 34.5896 5 Fluorescence:URU:Seapoint mg/m^3 -0.26E-01 1.569 6 Transmissivity %/metre 33.5 60.1 7 Bottle_Number n/a 1 22 8 Oxygen:Dissolved mL/L 0.278 6.887 9 Salinity:Bottle PSS-78 32.4009 34.59 10 Oxygen:Dissolved:SBE umol/kg 18.8 312.3 11 Oxygen:Dissolved umol/kg 12.4 307.5 12 Nitrate_plus_Nitrite umol/L 5.6 44.9 13 Phosphate umol/L 0.81 3.24 14 Silicate umol/L 10.9 173.4 15 Oxygen:Dissolved:SBE mL/L 0.39 7.13 16 Carbon:Dissolved:Inorganic umol/kg 1990.19 1990.19 17 Flag:Carbon:Dissolved:Inorganic n/a 18 Alkalinity:Total umol/kg 2183.29 2183.29 19 Flag:Alkalinity:Total n/a 20 pH n/a 8.1029 8.1029 21 Flag:pH n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 7 F ' ' 1 3 -99 ' ' 9 F ' ' 4 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 8 F ' ' 3 6 -99 ' ' 7 F ' ' 1 7 -99 ' ' 3 I I 0 8 -99 ' ' 8 F ' ' 3 9 -99 ' ' 9 F R4 4 10 -99 ' ' 6 F ' ' 1 11 -99 ' ' 6 F ' ' 1 12 -99 ' ' 6 F R4 1 13 -99 ' ' 7 F R4 2 14 -99 ' ' 6 F R4 1 15 -99 ' ' 7 F ' ' 2 16 -99 ' ' ' ' F8.2 R4 ' ' 17 -99 ' ' 3 NQ C ' ' 18 -99 ' ' ' ' F8.2 R4 ' ' 19 -99 ' ' 3 NQ C ' ' 20 -99 ' ' ' ' F9.4 R4 ' ' 21 -99 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2001-08 AGENCY : IOS, Ocean Science and Productivity, Sidney, BC COUNTRY : Canada PROJECT : Line P SCIENTIST : Whitney F. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : NORTH EAST PACIFIC STATION : ED12 EVENT NUMBER : 75 LATITUDE : 51 14.98000 N ! (deg min) LONGITUDE : 132 30.03000 W ! (deg min) WATER DEPTH : 2778 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0443 $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------- -------------- ---------- temperature ' ' primary conductivity ' ' primary pressure ' ' 63507 temperature ' ' secondary conductivity ' ' secondary Seapoint ' ' ' ' transmissometer ' ' 333DR irradiance ' ' 4615 Oxygen ' ' SBE $END $REMARKS SOFTWARE VERSION SEASAVE WIN32 V1.21 Comments from secondary file: D:\data\2001-08\21080075.cln ---------------------------------------------------------- Dissolved oxygen concentration determined using an automated titration system consisting of a Brinkman dosimat (model 665) and a PC 900 Colorimeter. $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 1.8 2001/06/14 22:31:42 2662 2662 DESPIKE 2.1 2001/06/14 22:34:34 2662 2662 DESPIKE 2.1 2001/06/19 12:26:46 2662 2662 BINAVE 4.0.1 2001/06/19 12:27:57 2662 22 MERGE 2.6.1 2001/06/20 09:04:52 22 22 MERGE 2.6.1 2001/06/20 11:01:51 22 22 CHANGE_UNITS 1.0 2001/06/20 22:58:27 22 22 CHANGE_UNITS 1.0 2001/06/20 23:00:42 22 22 MERGE 2.6.1 2001/08/09 12:37:36 22 22 CALIB 10.0 2001/08/27 15:30:55 22 22 REMOVECH 6.0 2001/08/27 16:46:02 22 22 REMOVECH 6.0 2001/08/27 16:50:49 22 22 REORDER 1.1 2001/08/28 08:55:53 ? ? HDREDIT2 1.1 2001/10/25 13:53:55 ? ? REMOVECH 6.0 2002/03/18 14:18:10 22 22 CHGUNITS 1.3 2002/03/18 14:19:56 22 22 CHGUNITS 1.3 2002/03/18 14:21:21 22 22 HDREDIT2 1.3 2002/03/18 14:29:30 ? ? CALIB 10.2 2002/03/18 16:07:01 22 22 HDREDIT2 1.51 2003/04/16 19:03:55 ? ? CLEAN 4.2 2003/04/16 19:07:24 22 22 REVERSE 2.0 2004/01/02 10:14:38 22 22 SORT 3.4.1 2004/04/23 11:41:54 22 22 SORT 3.5 2005/07/29 15:47:38 22 22 MERGE 3.3 2005/07/29 15:48:11 22 22 SORT 3.5 2005/07/29 15:53:08 22 22 HDREDIT2 2.5 2005/07/29 15:54:37 ? ? CLEAN 4.8 2005/11/04 14:39:23 22 22 CHANGE_FLAGS 1.0 2013/07/16 11:46:38 22 22 CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:23:08 22 22 $END $REMARKS -The following DESPIKE parameters were used: DESPIKE TABLE CHANNEL FIT OVER- MIN MAX MIN MAX SPIKE WIDTH LAP VALUE VALUE STDDEV STDDEV TOL. -------------------- ----- ----- ------- ------- ------- ------- ----- Pressure 55 5 0.00 4500.00 0.10000 999.000 3.00 Temperature:Primary 55 5 1.00 17.00 0.00100 999.000 3.00 Temperature:Secondar 55 5 1.00 17.00 0.00100 999.000 3.00 Salinity:T0:C0 55 5 20.00 35.00 0.00100 999.000 3.00 Salinity:T1:C1 55 5 20.00 35.00 0.00100 999.000 3.00 -The following DESPIKE parameters were used: DESPIKE TABLE CHANNEL FIT OVER- MIN MAX MIN MAX SPIKE WIDTH LAP VALUE VALUE STDDEV STDDEV TOL. -------------------- ----- ----- ------- ------- ------- ------- ----- Chl_fluorescence:Sea 55 5 0.00 15.00 0.01000 999.000 3.00 Transmissivity 55 5 5.00 95.00 0.01000 999.000 3.00 Oxygen:dissolved:mas 55 5 0.00 400.00 0.01000 999.000 3.00 Oxygen:dissolved:vol 55 5 0.00 10.00 0.01000 999.000 3.00 -The following BINAVE parameters were used: Bin channel = Bottle_Number Averaging interval = 1.0 Minimum bin value = 0.000 Bin value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: Pressure, Temperature:Primary, Salinity:T0:C0, Chl_fluorescence:Seapoint, Transmissivity, Irradiance_PAR, Oxygen:dissolved:volume, Bottle_Number Secondary Channels to Include: Dissolved_Oxygen:volume Primary file : D:\data\2001-08\21080075.sam Secondary file: D:\data\2001-08\21080075.cln Comments from secondary file: D:\data\2001-08\21080075.cln ---------------------------------------------------------- C.H. Culbertson's paper on Dissolved Oxygen in the 'Woce Hydrographic Program Operations and Methods - July 1991' CLEAN functions: - Reset #RECS, MIN & MAX values in header. -The following MERGE parameters were used: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: Pressure, Temperature:Primary, Salinity:T0:C0, Chl_fluorescence:Seapoint, Transmissivity, Irradiance_PAR, Oxygen:SBE:volume, Bottle_Number, Dissolved_Oxygen:volume Secondary Channels to Include: Salinity:Bottle Primary file : D:\data\2001-08\21080075.tab Secondary file: D:\data\2001-08\21080075.sal CHANGE units: - Units changed from ml/l to umol/l CHANGE units: - Units changed from ml/l to umol/l -The following MERGE parameters were used: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: Pressure, Temperature:Primary, Salinity:T0:C0, Chl_fluorescence:Seapoint, Transmissivity, Irradiance_PAR, Oxygen:SBE:volume, Bottle_Number, Oxygen:Dissolved:volume, Salinity:Bottle, Oxygen:SBE:mass, Oxygen:Dissolved:mass Secondary Channels to Include: nitrate, phosphate, silicate, chlorophyll Primary file : D:\DATA\2001\2001-08\21080075.hyd Secondary file: D:\DATA\2001\2001-08\21080075.nut -The following CALIB parameters were used: Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = 2108_COR.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 4 Salinity:T0:C0 PSS-78 10 -0.2300000E-02 0.1000000E+01 5 Chl_fluorescence:Seapoint ug/l 10 -0.5500000E-01 0.1000000E+01 -The following CHANNEL(S) were removed from file. Irradiance_PAR -No channels were removed. -The following CHANNEL(S) were removed from file. Oxygen:SBE:volume CHANGE units: - Units changed from umol/l to umol/kg CHANGE units: - Units changed from umol/kg to ml/l -The following CALIB parameters were used: Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = M:\Data\oxy\2108\2108oxy.CCF Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 10 Oxygen:SBE:mass umol/kg 10 0.4979300E+01 0.1040000E+01 16 Oxygen:SBE:volume ml/l 10 0.6670000E-01 0.1040000E+01 CLEAN functions: - Reset #RECS, MIN & MAX values in header. - Change Pad Value to -99 in All Channels. - Delete Empty Channels: 1 deleted. - Set channel name post-colon letters to upper case. - Remove Sea-Bird comments from the header. -The following SORT parameters were used. Sorted by channel: Pressure Pressure channel sorted according to values in sort channel -SORT parameters: 2005/07/29 15:47:38 Sorted in descending order of channel Sample_Number -The following MERGE parameters were used: 2005/07/29 15:48:10 2005/07/29 15:48:10 2005/07/29 15:48: Merge Channel: Sample_Number Merge Scheme Used: Interweave Records from Both Files Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Carbon:Dissolved:Inorganic, Flag:Carbon:Dissolved:Inorganic, Alkalinity:Total, Flag:Alkalinity:Total, pH, Flag:pH Primary file : H:\Data Processing\Carbon\Haida\2001-08\2001-08-0075.srtche Secondary file: H:\Data Processing\Carbon\Haida\2001-08\2001-08-0075.ios -SORT parameters: 2005/07/29 15:53:08 Sorted in ascending order of channel Pressure -HEADER EDITS: 2005/07/29 15:54:37 Applied edit header: H:\Data Processing\Carbon\Haida\2001-08\DIC_ALK_pH.txt -CLEAN functions: 2005/11/04 14:39:11 20 Reset #RECS, MIN & MAX values in header. Change Pad Value to -99 in All Channels. Delete Empty Channels: 0 deleted. $END *COMMENTS Comments from secondary file: D:\data\2001-08\21080075.cln ---------------------------------------------------------- SAMPLE 265 FOR OXYGEN, NO STIR BAR. DATA DELETED. The SBE Oxygen data should be considered to be within +/- 5%. Collection method: ------------------ A rosette, holding 24 ten-litre water samplers, with a CTD was used. Analysis methods: ----------------- Salinity samples are collected in glass bottles and analyzed on Guildline model 8410 Portasal Salinometers which are standardized with IAPSO standard seawater. Oxygen samples are analyzed on an automated Winkler titration system following the procedures of Carpenter (1965). A Brinkmann model 665 Dosimat and model PC910 Colorimeter is controlled by Visual-Basic program to titrate the oxygen samples. Nutrient samples are analyzed fresh on board using a Technicon AAII auto- analyzer following methods described in Barwell-Clarke and Whitney (1996). Chlorophyll samples are collected in duplicate in calibrated polycarbonate bottles (~330ml), then filtered onto 25mm MFS GF/75 filters at <70mmHg vacuum. The filters are placed in glass scintillation vials and immediately frozen at -20ºC until analysis. The chlorophyll is extracted in 10 ml of 90% acetone for 24h at -20ºC, then brought to room temperature and the extract is decanted and measured using a Turner Designs 10-AU-005-CE fluorometer, which has been calibrated with solutions of commercially prepared chlorophyll. References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. J. Barwell-Clarke and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. Dissolved inorganic carbon (DIC) and total alkalinity (Alk) samples were collected in 500 mL glass bottles, according to the DOE Handbook of Methods (1994), poisoned with 100 microL of saturated HgCl2, and kept at 4 C during transport back to shore for analysis at the Institute of Ocean Sciences. Total dissolved inorganic carbon was determined by coulometric titration with photometric detection using a SOMMA (Johnson et al., 1985; 1987), and Alk was determined by potentiometric titration in an open cell with 0.1 M HCl (Dickson et al., 2003; Haraldsson et al., 1997). The accuracy was assured by calibrating against Certified Reference Materials, CRM’s (DOE, 1994; Dickson 2001; Dickson et al., 2003), supplied by Andrew Dickson (Scripps Institution of Oceanography, San Diego, USA) and analyzed once a day. The measured and certified values of the CRMs differed by 0.7-1.1 µmol kg-1 for DIC and between 0.9 and 2.4 µmol kg-1 for AT. DIC analytical precision: 0.66 umol/kg. Alk analytical precision: 2.4 ueq/kg. pH samples were collected directly into 5-cm quartz cells and analyzed spectrophotometrically (Clayton and Byrne, 1993) using an Ocean Optics spectrophotometer within 2 hours of collection. Values given corrected to in situ T & P. Analytical precision: 0.0069 *CALIBRATION $TABLE: CORRECTED CHANNELS !Name Units Fmla Pad Coefficients !--------------------------- --------- ---- ------ ------------ Salinity:T0:C0 PSS-78 10 -9.9 () (-0.23E-02 1) Chl_fluorescence:Seapoint ug/l 10 -9.9 () (-0.55E-01 1) Oxygen:SBE:mass umol/kg 10 -9.9 () (4.9793 1.04) Oxygen:SBE:volume ml/l 10 -9.9 () (0.667E-01 1.04) $END !-1-- --2--- ---3---- ---4---- ---5--- --6--- 7- ---8--- ---9---- --10- --11- --12- --13-- --14- --15-- ---16-- 17 ---18-- 19 ---20--- 21 !Samp Pressu Temperat Salinity Fluores Transm Bo Oxygen: Salinity Oxyge Oxyge Nitra Phosph Silic Oxygen Carbon: Fl Alkalin Fl pH Fl !le_ re ure: :T0:C0 cence: issivi tt Dissolv :Bottle n: n: te_ ate ate : Dissolv ag ity: ag ag !Numb Primary URU: ty ~u ed Disso Disso plus_ Dissol ed: ~g Total ~T : !er Seapoin mb lved: lved Nitri ved: Inorgan an ot pH ! t er SBE te SBE ic ic al !---- ------ -------- -------- ------- ------ -- ------- -------- ----- ----- ----- ------ ----- ------ ------- -- ------- -- -------- -- *END OF HEADER 266 2.6 9.1503 32.3957 1.238 33.5 22 6.840 -99.0000 311.2 305.4 5.6 0.81 10.9 7.10 -99.00 0 -99.00 0 -99.0000 0 265 11.4 9.1503 32.3977 1.217 51.0 21 -99.000 32.4009 311.7 -99.0 5.6 0.81 10.9 7.11 1990.19 6 2183.29 6 8.1029 6 264 26.1 8.9582 32.4036 1.569 50.9 20 6.887 -99.0000 312.3 307.5 5.6 0.82 11.1 7.13 -99.00 0 -99.00 0 -99.0000 0 263 50.8 8.0950 32.4746 0.683 56.7 19 6.609 -99.0000 299.9 295.0 8.6 1.02 13.7 6.84 -99.00 0 -99.00 0 -99.0000 0 262 75.6 7.3018 33.0552 0.027 59.5 18 4.676 -99.0000 213.4 208.8 20.9 1.70 29.8 4.85 -99.00 0 -99.00 0 -99.0000 0 261 101.4 7.1569 33.5150 -0.026 59.3 17 3.540 -99.0000 162.4 158.0 26.5 2.01 38.1 3.69 -99.00 0 -99.00 0 -99.0000 0 260 124.0 7.1383 33.7668 -0.016 59.4 16 2.833 -99.0000 132.2 126.5 29.8 2.20 43.8 2.99 -99.00 0 -99.00 0 -99.0000 0 259 149.5 6.9747 33.8916 -0.007 59.3 15 2.444 -99.0000 114.1 109.1 32.2 2.33 48.6 2.57 -99.00 0 -99.00 0 -99.0000 0 258 175.0 6.6968 33.9280 -0.007 59.3 14 2.391 -99.0000 111.7 106.7 32.7 2.37 51.6 2.52 -99.00 0 -99.00 0 -99.0000 0 257 201.4 6.4169 33.9494 -0.008 59.3 13 2.105 -99.0000 98.6 94.0 34.5 2.48 56.4 2.22 -99.00 0 -99.00 0 -99.0000 0 256 251.6 5.8582 33.9600 -0.004 59.4 12 1.891 -99.0000 89.8 84.4 36.4 2.62 63.3 2.02 -99.00 0 -99.00 0 -99.0000 0 255 300.4 5.4235 33.9625 -0.001 59.5 11 1.768 -99.0000 83.8 78.9 37.7 2.68 69.4 1.88 -99.00 0 -99.00 0 -99.0000 0 254 401.5 4.7045 34.0092 -0.002 59.8 10 1.260 -99.0000 61.7 56.2 40.5 2.88 84.1 1.37 -99.00 0 -99.00 0 -99.0000 0 253 501.1 4.3693 34.0980 -0.001 59.9 9 0.734 -99.0000 37.9 32.8 42.8 3.06 97.1 0.83 -99.00 0 -99.00 0 -99.0000 0 252 601.2 4.2219 34.1632 0.004 59.9 8 0.470 -99.0000 27.1 21.0 43.3 3.14 105.0 0.58 -99.00 0 -99.00 0 -99.0000 0 251 798.4 3.7297 34.2873 0.006 59.9 7 0.316 -99.0000 19.0 14.1 44.3 3.22 123.0 0.39 -99.00 0 -99.00 0 -99.0000 0 250 798.5 3.7294 34.2872 0.005 59.9 6 0.294 -99.0000 19.0 13.1 44.2 3.22 123.0 0.39 -99.00 0 -99.00 0 -99.0000 0 249 998.3 3.2371 34.3609 0.006 60.0 5 0.278 -99.0000 18.8 12.4 44.9 3.24 139.0 0.39 -99.00 0 -99.00 0 -99.0000 0 248 1248.0 2.7439 34.4409 0.004 60.0 4 0.386 34.4411 23.0 17.2 44.6 3.22 154.0 0.48 -99.00 0 -99.00 0 -99.0000 0 247 1501.3 2.3600 34.5059 0.003 60.0 3 0.629 34.5070 34.0 28.1 44.5 3.18 165.0 0.73 -99.00 0 -99.00 0 -99.0000 0 246 1750.9 2.0951 34.5548 0.002 60.1 2 1.006 34.5593 49.8 44.9 43.5 3.08 171.0 1.10 -99.00 0 -99.00 0 -99.0000 0 245 2001.2 1.9180 34.5896 0.000 60.1 1 1.400 34.5900 65.8 62.5 42.8 3.01 173.4 1.47 -99.00 0 -99.00 0 -99.0000 0