*2014/11/20 09:52:59.93 *IOS HEADER VERSION 1.10 2011/10/26 2011/10/26 *FILE START TIME : UTC 2001/02/16 12:49:45.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 18 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII NUMBER OF CHANNELS : 21 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- -------------------------------------- --------------- -------------- -------------- 1 Pressure decibar 1.4 2001.2 2 Sample_Number n/a 135 152 3 Temperature:Primary 'deg C (ITS90)' 1.9164 5.3644 4 Salinity:T0:C0 PSS-78 32.6771 34.5869 5 Transmissivity %/metre 47.7 54.4 6 Fluorescence:URU:Seapoint mg/m^3 -0.7E-01 0.492 7 Bottle_Number n/a 1 18 8 Salinity:Bottle PSS-78 32.6791 34.5881 9 Oxygen:Dissolved mL/L 0.4 7.24 10 Phosphate umol/L 1.44 3.26 11 Nitrate_plus_Nitrite umol/L 15.5 45.8 12 Silicate umol/L 22.7 171.8 13 pH n/a 7.5095 8.0318 14 Carbon:Particulate:Total umol/L 0.4 3.38 15 Flag:Carbon:Particulate:Total n/a 16 Nitrogen:Particulate:Total umol/L 0.43E-01 0.543 17 Flag:Nitrogen:Particulate:Total n/a 18 Alkalinity:Total:Potentiometric umol/kg 2160.5 2411.9 19 Flag:Alkalinity:Total:Potentiometric n/a 20 Carbon:Dissolved:Inorganic umol/kg 2053.9 2389.7 21 Flag:Carbon:Dissolved:Inorganic n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 7 F ' ' 1 2 -99 ' ' 5 I I 0 3 -99 ' ' 9 F ' ' 4 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 7 F ' ' 1 6 -99 ' ' 8 F ' ' 3 7 -99 ' ' 3 I I 0 8 -99 ' ' 9 F R4 4 9 -99 ' ' 8 F ' ' 3 10 -99 ' ' 7 F R4 2 11 -99 ' ' 6 F R4 1 12 -99 ' ' 6 F R4 1 13 -99 ' ' ' ' F9.4 R4 ' ' 14 -99 ' ' ' ' F7.2 R4 ' ' 15 0 ' ' 3 NQ C ' ' 16 -99 ' ' ' ' F8.3 R4 ' ' 17 0 ' ' 3 NQ C ' ' 18 -999 ' ' ' ' F7.1 R4 ' ' 19 0 ' ' 3 NQ C ' ' 20 -999 ' ' ' ' F7.1 R4 ' ' 21 0 ' ' 3 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- $END *ADMINISTRATION MISSION : 2001-06 AGENCY : IOS, Ocean Science and Productivity, Sidney, BC COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : Line P, N.E. Pacific STATION : EDOUT EVENT NUMBER : 39 LATITUDE : 53 48.00000 N ! (deg min) LONGITUDE : 139 30.03000 W ! (deg min) WATER DEPTH : 3503 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : $TABLE: SENSORS ! Name Abs Depth Serial No ! ----------------- -------------- ---------- temperature ' ' primary conductivity ' ' primary pressure ' ' 75636 temperature ' ' secondary conductivity ' ' secondary Seapoint ' ' ' ' transmissometer ' ' 333DR userpoly ' ' 180339 userpoly ' ' 180293 $END $REMARKS SOFTWARE VERSION SEASAVE WIN32 V1.19 Comments from secondary file: D:\DATA\2001\2001-06\21060039.dox --------------------------------------------------------------- Dissolved oxygen concentration determined using an automated titration system consisting of a Brinkman dosimat (model 665) and a PC 900 Colorimeter. $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SBE_IOS 1.8 2001/03/14 12:58:50 1746 1746 DESPIKE 2.1 2001/03/14 12:59:32 1746 1746 BINAVE 4.0.1 2001/03/14 13:01:29 1746 18 MERGE 2.6.1 2001/10/23 15:05:59 18 18 MERGE 2.6.1 2001/10/23 15:13:39 18 18 MERGE 2.6.1 2001/10/23 15:44:10 18 18 CALIB 10.0 2001/10/23 15:53:01 18 18 REORDER 1.1 2001/10/24 08:36:10 ? ? HEADEDIT 1.1 2001/10/24 16:35:55 ' ' ' ' HDREDIT2 1.2 2001/12/24 11:36:38 ? ? MERGE 2.8 2003/02/24 10:54:46 18 18 HDREDIT2 1.51 2003/04/17 14:03:25 ? ? CLEAN 4.2 2003/04/17 14:04:06 18 18 REVERSE 2.0 2003/12/31 13:41:27 18 18 REMOVECH 7.0 2005/08/16 11:30:54 18 18 MERGE 3.3 2005/08/16 11:34:08 18 18 HDREDIT2 2.5 2005/08/16 11:44:28 ? ? REMOVECH 8.1.1 2012/02/20 09:28:13 18 18 MERGE 3.4 2012/02/20 09:28:24 18 18 HDREDIT2 2.5.1 2012/02/20 09:38:44 ? ? CHANGE_FLAGS 1.0 2013/07/16 11:46:36 18 18 CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:22:56 18 18 CHANGE_FLAGS 2.0 2014/11/20 09:52:59 18 18 $END $REMARKS -The following DESPIKE parameters were used: DESPIKE TABLE CHANNEL FIT OVER- MIN MAX MIN MAX SPIKE WIDTH LAP VALUE VALUE STDDEV STDDEV TOL. -------------------- ----- ----- ------- ------- ------- ------- ----- Pressure 55 5 0.00 4500.00 0.10000 999.000 3.00 Temperature:Primary 55 5 1.00 25.00 0.00100 999.000 3.00 Temperature:Secondar 55 5 1.00 25.00 0.00100 999.000 3.00 Salinity:T0:C0 55 5 2.00 35.00 0.00100 999.000 3.00 Salinity:T1:C1 55 5 2.00 35.00 0.00100 999.000 3.00 -The following BINAVE parameters were used: Bin channel = Sample_Number Averaging interval = 1.0 Minimum bin value = 0.000 Bin value was used Interpolated values were NOT used for empty bins Channel 'NUMBER_OF_BIN_RECORDS' was added to file. -The following MERGE parameters were used: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: Pressure, Temperature:Primary, Temperature:Secondary, Salinity:T0:C0, Salinity:T1:C1, Transmissivity, Chl_fluorescence:Seapoint, Irradiance (PAR), Bottle_Number Secondary Channels to Include: Salinity:Bottle Primary file : D:\DATA\2001\2001-06\21060039.avt Secondary file: D:\DATA\2001\2001-06\21060039.sal -The following MERGE parameters were used: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: Pressure, Temperature:Primary, Salinity:T0:C0, Transmissivity, Chl_fluorescence:Seapoint, Irradiance (PAR), Bottle_Number, Salinity:Bottle Secondary Channels to Include: Dissolved_Oxygen:volume Primary file : D:\DATA\2001\2001-06\21060039.tab Secondary file: D:\DATA\2001\2001-06\21060039.dox Comments from secondary file: D:\DATA\2001\2001-06\21060039.dox --------------------------------------------------------------- C.H. Culbertson's paper on Dissolved Oxygen in the 'Woce Hydrographic Program Operations and Methods - July 1991' -The following OXYCALC parameters were used Blank = 0.005 Sodium Thiosulfate concentration = 0.718 Volume of iodate standard (cm**3) = 10.02 Enter Normalitity of iodate standard = 0.01012960 -The following MERGE parameters were used: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: Pressure, Temperature:Primary, Salinity:T0:C0, Transmissivity, Chl_fluorescence:Seapoint, Bottle_Number, Salinity:Bottle, Dissolved_Oxygen:volume Secondary Channels to Include: PO4, NO3, SiO4 Primary file : D:\DATA\2001\2001-06\21060039.tab Secondary file: D:\DATA\2001\2001-06\21060039.nut -The following CALIB parameters were used: Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = D:\DATA\2001\2001-06\2106rcal.ccf Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 4 Salinity:T0:C0 PSS-78 10 -0.1100000E-02 0.1000000E+01 6 Chl_fluorescence:Seapoint ug/l 10 -0.7000000E-01 0.1000000E+01 -The following MERGE parameters were used: Merge Channel: Sample_Number Merge Scheme Used: Interweave Records from Both Files Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Alkalinity:Total, Alkalinity:Total:Flag, Carbon:Dissolved:Inorganic, Carbon:Dissolved:Inorganic:Flag Primary file : C:\temp\carbon\21060039.che Secondary file: C:\temp\carbon\21060039.srt Comments from secondary file: C:\temp\carbon\21060039.srt --------------------------------------------------------- -The following SORT parameters were used. Sorted by channel: Sample_Number Pressure channel sorted according to values in sort channel CLEAN functions: - Reset #RECS, MIN & MAX values in header. - Change Pad Value to -99 in All Channels. - Delete Empty Channels: 0 deleted. - Set channel name post-colon letters to upper case. - Remove Sea-Bird comments from the header. -REMOVECH 2005/08/16 11:30:54 The following CHANNEL(S) were removed: Alkalinity:Total [umol/kg] Flag:Alkalinity:Total Carbon:Dissolved:Inorganic [umol/kg] Flag:Carbon:Dissolved:Inorganic -The following MERGE parameters were used: 2005/08/16 11:34:08 Merge Channel: Sample_Number Merge Scheme Used: Interweave Records from Both Files Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Carbon:Dissolved:Inorganic, Flag:Carbon:Dissolved:Inorganic, Alkalinity:Total, Flag:Alkalinity:Total, pH, Carbon:Particulate:Total, Flag:Carbon:Particulate:Total, Nitrogen:Particulate:Total, Flag:Nitrogen:Particulate:Total Primary file : H:\Data Processing\Carbon\Haida\2001-06\2001-06-0039.rem Secondary file: H:\Data Processing\Carbon\Haida\2001-06\2001-06-0039.ios -HEADER EDITS: 2005/08/16 11:44:28 Applied edit header: H:\Data Processing\Carbon\Haida\2001-06\DIC_ALK_pH_PC_PN.txt -REMOVECH 2012/02/20 09:28:13 4 channels removed. -The following MERGE parameters were used: 2012/02/20 09:28:24 2012/02/20 09:28:24 Merge Channel: Pressure Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Average Primary Channels to Include: ALL Secondary Channels to Include: Alkalinity:Total:Potentiometric, Flag:Alkalinity:Total:Potentiometric, Carbon:Dissolved:Inorganic, Flag:Carbon:Dissolved:Inorganic Primary file : P:\John Pages Archive\2001-06\2001-06-0039.rem Secondary file: P:\John Pages Archive\2001-06\2001-06-0039.ios -HEADER EDITS: 2012/02/20 09:38:44 Applied edit header: O:\Data Processing\Header Comments\Work\Quality_Flags_Alpha_numeric.txt $END *COMMENTS Collection method: ------------------ A rosette, holding 24 ten-litre water samplers, with a CTD was used. Analysis methods: ----------------- Salinity samples are collected in glass bottles and analyzed on Guildline model 8410 Portasal Salinometers which are standardized with IAPSO standard seawater. Oxygen samples are analyzed on an automated Winkler titration system following the procedures of Carpenter (1965). A Brinkmann model 665 Dosimat and model PC910 Colorimeter is controlled by Visual-Basic program to titrate the oxygen samples. Nutrient samples are analyzed fresh on board using a Technicon AAII auto- analyzer following methods described in Barwell-Clarke and Whitney (1996). Chlorophyll samples are collected in duplicate in calibrated polycarbonate bottles (~330ml), then filtered onto 25mm MFS GF/75 filters at <70mmHg vacuum. The filters are placed in glass scintillation vials and immediately frozen at -20ºC until analysis. The chlorophyll is extracted in 10 ml of 90% acetone for 24h at -20ºC, then brought to room temperature and the extract is decanted and measured using a Turner Designs 10-AU-005-CE fluorometer, which has been calibrated with solutions of commercially prepared chlorophyll. References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. J. Barwell-Clarke and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. Comments from secondary file: H:\Data Processing\Carbon\Haida\2001-06\2001-06-0039.ios -------------------------------------------------------- Sample_Number 149.: DIC Alk & pH inconsistent Sample_Number 144.: pH inconsistent w/DIC & Alk Sample_Number 142.: pH inconsistent w/DIC & Alk Dissolved inorganic carbon (DIC) and total alkalinity (Alk) samples were collected in 500 mL glass bottles, according to the DOE Handbook of Methods (1994), poisoned with 100 microL of saturated HgCl2, and kept at 4 C during transport back to shore for analysis at the Institute of Ocean Sciences. Total dissolved inorganic carbon was determined by coulometric titration with photometric detection using a SOMMA (Johnson et al., 1985; 1987), and Alk was determined by potentiometric titration in an open cell with 0.1 M HCl (Dickson et al., 2003; Haraldsson et al., 1997). The accuracy was assured by calibrating against Certified Reference Materials, CRM’s (DOE, 1994; Dickson 2001; Dickson et al., 2003), supplied by Andrew Dickson (Scripps Institution of Oceanography, San Diego, USA) and analyzed once a day. The measured and certified values of the CRMs differed by 0.7-1.1 µmol kg-1 for DIC and between 0.9 and 2.4 µmol kg-1 for AT. DIC analytical precision: 0.7 umol/kg. Alk analytical precision: 2.0 ueq/kg. pH samples were collected directly into 5-cm quartz cells and analyzed spectrophotometrically (Clayton and Byrne, 1993) using an Ocean Optics spectrophotometer within 2 hours of collection. Values given corrected to in situ T & P. Analytical precision: 0.007 Total particulate carbon (PC) and nitrogen (PN) samples were collected into 5 L polyethylene carboys, and 1-2 L volumes were filtered under vacuum through precombusted (4 hours at 450 °C) Whatman (GF75, 25 mm) filters within 12 hours of sampling (Knap et al., 1996). The filter was then analyzed on a Control Equipment Corporation (CEC) 440 Elemental Analyzer standardized with acetanilide PC analytical precision: 0.72 umol C/kg PN analytical precision: 0.84 umol N/kg *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! --------------------------- -------- ---- ------ ------------ Salinity:T0:C0 PSS-78 10 -9.99 () (-0.11E-02 1) Chl_fluorescence:Seapoint ug/l 10 -9.9 () (-0.7E-01 1) $END !--1--- -2-- ---3---- ---4---- --5--- ---6--- 7- ---8---- ---9--- --10-- --11- --12- ---13--- --14-- 15 ---16-- 17 --18-- 19 --20-- 21 !Pressu Samp Temperat Salinity Transm Fluores Bo Salinity Oxygen: Phosph Nitra Silic pH Carbon Fl Nitroge Fl Alkali Fl Carbon Fl !re le_ ure: :T0:C0 issivi cence: tt :Bottle Dissolv ate te_ ate : ag n: ag nity:T ag :Disso ag ! Numb Primary ty URU: ~u ed plus_ Partic ~T Particu ~T ~al:Po ~e lved: ~g ! er Seapoin mb Nitri ulate: ot late: ot tentio tr Inorga an ! t er te Total al Total al metric ic nic ic !------ ---- -------- -------- ------ ------- -- -------- ------- ------ ----- ----- -------- ------ -- ------- -- ------ -- ------ -- *END OF HEADER 1.4 152 5.3475 32.6773 47.7 0.468 18 32.6791 7.180 1.44 15.6 23.0 8.0259 -99.00 0 -99.000 0 2180.4 2 2057.8 2 9.8 151 5.3581 32.6772 51.5 0.492 17 -99.0000 7.150 1.44 15.6 22.8 8.0318 3.38 0 0.543 0 2187.3 2 2057.6 2 25.1 150 5.3584 32.6774 51.5 0.472 16 -99.0000 7.150 1.44 15.5 23.1 8.0270 -99.00 0 -99.000 0 2188.4 2 2055.6 2 49.6 149 5.3601 32.6771 51.5 -0.070 15 -99.0000 7.170 1.44 15.6 22.7 8.0291 2.83 0 0.446 0 2160.5 2 2053.9 2 75.2 148 5.3644 32.6781 51.5 -0.070 14 -99.0000 7.240 1.44 15.6 23.1 8.0271 -99.00 0 -99.000 0 2178.5 2 2058.3 2 99.6 147 4.5224 33.2290 53.6 -0.070 13 -99.0000 5.220 2.12 27.3 43.5 7.8536 1.38 0 0.249 0 2184.6 2 2149.1 2 149.3 146 4.5521 33.8075 53.6 -0.070 12 -99.0000 2.210 2.79 38.7 70.0 7.6232 -99.00 0 -99.000 0 2239.9 2 2261.2 2 200.9 145 4.2988 33.8923 53.7 -0.066 11 -99.0000 1.550 2.97 41.5 79.5 7.5588 0.70 6 0.132 6 2261.7 2 2288.7 2 299.1 144 4.1265 33.9792 54.1 -0.064 10 -99.0000 1.130 3.08 43.4 90.6 7.5275 0.72 0 0.105 0 2270.9 2 2307.1 2 399.9 143 3.8945 34.0719 54.3 -0.007 9 -99.0000 0.810 3.15 44.3 103.2 7.5298 -99.00 0 -99.000 0 2304.1 2 2325.2 2 601.0 142 3.5850 34.2204 54.4 -0.008 8 -99.0000 0.490 3.21 44.9 121.8 7.5323 0.40 0 0.043 0 2320.1 2 2352.3 2 800.4 141 3.1939 34.3236 54.3 -0.007 7 -99.0000 0.410 3.26 45.2 136.9 7.5095 -99.00 0 -99.000 0 2351.1 2 2366.6 2 999.9 140 2.8749 34.3916 54.3 -0.007 6 34.3915 0.400 3.26 45.4 148.2 7.5155 -99.00 0 -99.000 0 2360.1 2 2379.9 2 1249.9 139 2.5445 34.4567 54.3 -0.006 5 34.4574 0.500 3.24 45.8 156.4 7.5265 -99.00 0 -99.000 0 2378.2 2 2387.1 2 1500.0 138 2.2773 34.5101 54.4 -0.009 4 34.5105 0.760 3.18 45.8 164.5 7.5683 -99.00 0 -99.000 0 2391.5 2 2389.7 2 1751.4 137 2.0736 34.5545 54.4 -0.009 3 34.5548 1.070 3.13 44.5 170.5 7.5990 -99.00 0 -99.000 0 2394.8 3 2388.4 2 1751.8 136 2.0734 34.5545 54.4 -0.009 2 34.5539 1.070 3.12 44.1 169.6 7.5861 -99.00 0 -99.000 0 2400.0 3 2389.6 2 2001.2 135 1.9164 34.5869 54.4 -0.009 1 34.5881 1.430 3.07 43.6 171.8 7.6129 -99.00 0 -99.000 0 2411.9 2 2383.5 2