*2014/11/20 09:52:35.95 *IOS HEADER VERSION 1.10 2011/10/26 2011/10/26 *FILE START TIME : UTC 1999/06/13 16:56:00.000 NUMBER OF RECORDS : 22 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII NUMBER OF CHANNELS : 21 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- -------------------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 574 595 2 Pressure decibar 1.4 4282.1 3 Temperature:Secondary 'deg C (ITS90)' 1.5006 6.9979 4 Salinity:T1:C1 PSS-78 32.8397 34.6812 5 Transmissivity %/metre 48.1 76.4 6 Bottle_Number n/a 1 22 7 Salinity:Bottle PSS-78 32.8442 34.681 8 Oxygen:Dissolved mL/L 0.415 7.26 9 Phosphate umol/L 1.23 3.18 10 Nitrate_plus_Nitrite umol/L 13.2 45.4 11 Silicate umol/L 18.7 172.6 12 Chlorophyll:Extracted mg/m^3 0.8E-01 0.27 13 Alkalinity:Total:Potentiometric umol/kg 2200.3 2438.2 14 Flag:Alkalinity:Total:Potentiometric n/a 15 Carbon:Dissolved:Inorganic umol/kg 2043.9 2389.7 16 Flag:Carbon:Dissolved:Inorganic n/a 17 Dimethyl_Sulphide nmol/L 0 2.32 18 Chlorofluorocarbon_11 pmol/kg 0 5.17 19 Flag:Chlorofluorocarbon_11 n/a 20 Chlorofluorocarbon_12 pmol/kg 0 2.67 21 Flag:Chlorofluorocarbon_12 n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 7 F ' ' 1 3 -99 ' ' 9 F ' ' 4 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 6 F ' ' 1 6 -99 ' ' 3 I I 0 7 -99 ' ' 9 F ' ' 4 8 -99 ' ' 8 F ' ' 3 9 -99 ' ' 7 F R4 2 10 -99 ' ' 6 F R4 1 11 -99 ' ' 6 F R4 1 12 -99 ' ' 7 F R4 2 13 -999 ' ' ' ' F7.1 R4 ' ' 14 0 ' ' 3 NQ C ' ' 15 -999 ' ' ' ' F7.1 R4 ' ' 16 0 ' ' 3 NQ C ' ' 17 -99 ' ' ' ' F7.2 R4 ' ' 18 -99 ' ' ' ' F7.2 R4 ' ' 19 0 ' ' 2 NQ C ' ' 20 -99 ' ' ' ' F7.2 R4 ' ' 21 0 ' ' 2 NQ C ' ' $END $REMARKS Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- Comments from secondary file: d:\data\1999\9910\99100034.oxy -------------------------------------------------------------------------------------- Raw data in file 9910 VI03 = 10.02 ! Volume of iodate standard (cm**3) NI03 = .0101285 ! Normality of iodate standard VREG = 2.0 ! Volume of sample displaced by reagents (cm**3) DOREG = 0.0017 ! Absolute amount of O2 added with reagents (ml) UFLAG = 0 ! 0|-1, -1 indicates DO_mass is valid $END *ADMINISTRATION MISSION : 1999-10 AGENCY : IOS, Ocean Science and Productivity, Sidney, BC COUNTRY : Canada PROJECT : Line P SCIENTIST : Perkin R. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : Line P, P1E STATION : P26 EVENT NUMBER : 34 LATITUDE : 49 59.78000 N ! (deg min) LONGITUDE : 145 1.78000 W ! (deg min) WATER DEPTH : 4247 *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- SPRD2IS 2.1 1999/06/30 11:43:03 0 22 MERGE 2.3 1999/10/08 12:18:13 22 22 REMOVECH 5.0 2001/04/03 14:43:18 22 22 MERGE 2.6.1 2001/04/04 11:28:40 22 22 CALIB 10.0 2001/04/04 13:01:48 22 22 CALIB 10.0 2001/04/25 09:34:55 22 22 HDREDIT2 1.2 2001/12/24 11:42:07 ? ? HDREDIT2 1.6 2003/04/25 13:36:13 ? ? CLEAN 4.2 2003/04/25 13:40:42 22 22 MERGE 2.8 2003/04/25 14:46:43 22 22 HDREDIT2 1.6 2003/04/25 15:16:32 ? ? SORT 3.4.1 2004/04/14 08:35:59 22 22 REMOVECH 8.1.1 2012/02/16 11:03:01 22 22 MERGE 3.4 2012/02/16 11:04:23 22 22 HDREDIT2 2.5.1 2012/02/16 11:13:26 ? ? SORT 3.6 2013/06/25 14:35:40 22 22 MERGE 3.5 2013/06/25 16:05:55 22 22 SORT 3.6 2013/06/25 16:07:35 22 22 HDREDIT2 2.6 2013/06/26 11:38:27 ? ? SORT 3.6 2013/06/28 13:42:43 22 22 MERGE 3.5 2013/06/28 13:44:07 22 22 SORT 3.6 2013/06/28 13:47:36 22 22 HDREDIT2 2.6 2013/06/28 13:51:27 ? ? CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:17:56 22 22 CHANGE_FLAGS 2.0 2014/11/20 09:52:35 22 22 $END $REMARKS -The following MERGE parameters were used: Merge Channel: Sample_Number Merge Scheme Used: Interweave Records from Both Files Overlap Scheme Used: Keep Primary Primary Channels to Include: Pressure, Temperature:primary, Temperature:secondar, Salinity:T0:C0, Salinity:T1:C1, Transmissivity, Irradiance_PAR, CHL_FLUORESCENCE, Bottle_Number, Salinity:Bottle Secondary Channels to Include: Dissolved_Oxygen:vol, Flask_Number Primary file : d:\data\1999\9910\99100034.ios Secondary file: d:\data\1999\9910\99100034.oxy Comments from secondary file: d:\data\1999\9910\99100034.oxy ------------------------------------------------------------ C.H. Culbertson's paper on Dissolved Oxygen in the 'Woce Hydrographic Program Operations and Methods - July 1991' OxyRedo fixes DO_mass and DO_volumne when incorrect values for VIO3, NIO3, blank, or standard had been entered. -The following CALIB parameters were used: Calibration type = C Pressure offset = 0.0 Calibration file = D:\DATA\1999\9910\OXYCOR -The following CHANNEL(S) were removed from file. TEMPERATURE:PRIMARY SALINITY:T0:C0 IRRADIANCE_PAR CHL_FLUORESCENCE Flask_Number -The following MERGE parameters were used: Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: Pressure, TEMPERATURE:SECONDAR, SALINITY:T1:C1, TRANSMISSIVITY, Bottle_Number, SALINITY:BOTTLE, Dissolved_Oxygen:volume Secondary Channels to Include: Phosphate, Nitrate, Silicate, Chlorophyll Primary file : e:\data\1999\9910\99100034.tab Secondary file: e:\data\1999\9910\99100034.nut -The following CALIB parameters were used: Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = e:\data\1999\9910\ctd_cal.txt Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 5 TRANSMISSIVITY % 10 0.0000000E+00 0.1035000E+01 -The following CALIB parameters were used: Calibration type = Calculate Mode: HEAD - calibration specs from header only. Transmissivity converted to %/metre WARNING: No calibration done on file L:\CTD\1999\1999-10\99100034.clc CLEAN functions: - Reset #RECS, MIN & MAX values in header. - Change Pad Value to -99 in All Channels. - Delete Empty Channels: 0 deleted. - Set channel name post-colon letters to upper case. - Remove Sea-Bird comments from the header. -The following MERGE parameters were used: Merge Channel: Sample_Number Merge Scheme Used: Interweave Records from Both Files Overlap Scheme Used: Keep Primary Primary Channels to Include: ALL Secondary Channels to Include: Alkalinity:Total, Flag:Alkalinity:Total, Carbon:Dissolved:Inorganic, Flag:Carbon:Dissolved:Inorganic Primary file : H:\STNPCHEM\process\1999\1999-10\bottle\99100034.cln Secondary file: H:\STNPCHEM\process\1999\1999-10\bottle\99100034.srt Comments from secondary file: H:\STNPCHEM\process\1999\1999-10\bottle\99100034.srt ---------------------------------------------------- -The following SORT parameters were used. Sorted by channel: Sample_Number Pressure channel sorted according to values in sort channel -The following SORT parameters were used. Sorted by channel: Pressure Pressure channel sorted according to values in sort channel -REMOVECH 2012/02/16 11:03:01 4 channels removed. -The following MERGE parameters were used: 2012/02/16 11:04:23 Merge Channel: Pressure Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Average Primary Channels to Include: ALL Secondary Channels to Include: Alkalinity:Total:Potentiometric, Flag:Alkalinity:Total:Potentiometric, Carbon:Dissolved:Inorganic, Flag:Carbon:Dissolved:Inorganic Primary file : P:\John Pages Archive\1999-10\1999-10-0034.rem Secondary file: P:\John Pages Archive\1999-10\1999-10-0034.ios -HEADER EDITS: 2012/02/16 11:13:26 Applied edit header: O:\Data Processing\Header Comments\Work\Quality_Flags_numeric.txt -SORT parameters: 2013/06/25 14:35:40 Sorted in ascending order of channel Sample_Number -The following MERGE parameters were used: 2013/06/25 16:05:55 Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Secondary Primary Channels to Include: ALL Secondary Channels to Include: Dimethyl_Sulphide Primary file : P:\John Pages Archive\1999-10\DMS\1999-10-0034.srt_che Secondary file: P:\John Pages Archive\1999-10\DMS\1999-10-0034.srt_ios Comments from secondary file: P:\John Pages Archive\1999-10\DMS\1999-10-0034.srt_ios ------------------------------------------------------ -SORT parameters: 2013/06/25 16:05:47 Sorted in ascending order of channel Sample_Number -SORT parameters: 2013/06/25 16:07:35 Sorted in ascending order of channel Pressure -HEADER EDITS: 2013/06/26 11:38:27 Applied edit header: P:\John Pages Archive\DMS_Methods post 1999.txt -SORT parameters: 2013/06/28 13:42:43 Sorted in ascending order of channel Sample_Number -The following MERGE parameters were used: 2013/06/28 13:44:07 Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Secondary Primary Channels to Include: ALL Secondary Channels to Include: Chlorofluorocarbon_11, Flag:Chlorofluorocarbon_11, Chlorofluorocarbon_12, Flag:Chlorofluorocarbon_12, Chlorofluorocarbon_113, Flag:Chlorofluorocarbon_113, Carbontetrachloride, Flag:Carbontetrachloride Primary file : P:\John Pages Archive\1999-10\CFC\1999-10-0034.srt_che Secondary file: P:\John Pages Archive\1999-10\CFC\1999-10-0034.ios -SORT parameters: 2013/06/28 13:47:36 Sorted in ascending order of channel Pressure -HEADER EDITS: 2013/06/28 13:51:27 Applied edit header: O:\Data Processing\Header Comments\Work\Freons 1999.txt $END *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------------- ----- ---- ------ ------------ TRANSMISSIVITY % 10 -99 () (0 1.035) $END *INSTRUMENT TYPE : Bottle MODEL : Niskin 10 Litre $REMARKS Comments from secondary file: d:\data\1999\9910\99100034.oxy ------------------------------------------------------------ Dissolved oxygen concentration determined using an automated titration system consisting of a Brinkman Dosimat (model 665) and a PC 900 Colorimeter. $END *COMMENTS Collection method: ------------------ A rosette, holding 24 ten-litre water samplers, with a CTD was used. Analysis methods: ----------------- Salinity samples are collected in glass bottles and analyzed on Guildline model 8410 Portasal Salinometers which are standardized with IAPSO standard seawater. Oxygen samples are analyzed on an automated Winkler titration system following the procedures of Carpenter (1965). A Brinkmann model 665 Dosimat and model PC910 Colorimeter is controlled by Visual-Basic program to titrate the oxygen samples. Nutrient samples are analyzed fresh on board using a Technicon AAII auto- analyzer following methods described in Barwell-Clarke and Whitney (1996). Chlorophyll was extracted with 90% acetone and analyzed fluorimetrically. For DMS methods see file "Method post 1999 for Dimethylsulfide Analysis.docx" in directory \\OSD_Data_Archive\Cruise_Data\Documents\Analysis Reference Papers\. . CFC-11 and CFC-12, in their current form, do not meet the relaxed WOCE standard for CFC's. Therefore the CFC qulaity flags have been given a value of'3'(questionable). For CFC methods refer to the "Ocean Science and Productivity Division Line P cruises 9829, 9901 and 9910 CFC Data Report" located in the cruise .DOC directory. . References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. J. Barwell-Clarke and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 3. Minkley, B.G., and F.A. Whitney. 2001. Summary of Hydrographic/CTD Observations Made Along Line P and at Station P: 1991-1999. Canadian Data Report of Hydrography and Ocean Sciences 156: 45 pp. Dissolved inorganic carbon (DIC) and total alkalinity (TA) were collected together in the same 250 or 500 mL glass bottles closed with greased ground glass stoppers and sealed with elastic clamps. Samples were stored in the dark at 4 degrees C until analysis ashore. DIC was analyzed using a SOMMA coulometric titration of CO2 purged from the sample after acidification. TA was determined by potentiometric acid titration with endpoints determined using modified gran plots. For more details see the metadata associated with this particular data set. !-1-- --2--- ---3---- ---4---- --5-- 6- ---7---- ---8--- --9--- --10- --11- --12-- --13-- 14 --15-- 16 --17-- --18-- - --20-- - !Samp Pressu Temperat Salinity Trans Bo Salinity Oxygen: Phosph Nitra Silic Chloro Alkali Fl Carbon Fl Dimeth Chloro F Chloro F !le_ re ure: :T1:C1 missi tt :Bottle Dissolv ate te_ ate phyll: nity:T ag :Disso ag yl_ fluoro l fluoro l !Numb Secondar vity ~u ed plus_ Extrac ~al:Po ~e lved: ~g Sulphi carbon ~ carbon ~ !er y mb Nitri ted tentio tr Inorga an de _11 1 _12 1 ! er te metric ic nic ic 1 2 !---- ------ -------- -------- ----- -- -------- ------- ------ ----- ----- ------ ------ -- ------ -- ------ ------ - ------ - *END OF HEADER 595 1.4 6.9979 32.8397 48.1 22 32.8442 7.134 1.23 13.2 18.7 0.27 2204.9 2 2043.9 2 2.32 4.99 3 2.52 3 594 48.6 6.3535 32.8644 68.6 21 32.8658 7.260 1.25 13.5 19.0 0.27 2200.3 2 2051.1 2 1.64 5.00 3 2.60 3 593 74.5 5.5286 32.9223 72.0 20 32.9144 7.249 1.34 14.9 21.1 0.25 2212.9 2 2062.1 2 0.63 5.17 3 2.67 3 592 102.8 5.2280 32.9659 74.5 19 32.9666 7.042 1.44 16.2 22.3 0.08 2215.6 2 2070.8 2 0.00 4.92 3 2.58 3 591 151.2 5.9855 33.8446 74.8 18 33.8466 3.784 2.08 29.3 45.7 -99.00 2272.3 2 2185.8 2 0.00 3.41 3 1.70 3 590 202.4 5.0839 33.8342 74.2 17 33.8364 3.178 2.39 33.4 58.8 -99.00 2277.0 2 2220.0 2 0.00 2.93 3 1.42 3 589 302.5 4.2818 33.8952 74.8 16 33.8958 2.045 2.75 39.2 77.1 -99.00 2293.7 2 2269.7 2 0.00 2.09 3 1.03 3 588 402.5 4.3092 34.0285 75.5 15 34.0292 1.163 2.97 42.7 89.7 -99.00 2314.1 2 2304.5 2 0.00 0.94 3 0.48 3 587 602.4 3.7567 34.1702 75.5 14 34.1708 0.761 3.07 43.7 110.8 -99.00 2364.3 2 2327.6 2 -99.00 0.36 3 0.20 3 586 801.6 3.3094 34.2849 75.8 13 34.2842 0.471 3.14 44.6 129.1 -99.00 2375.0 2 2359.7 2 -99.00 0.08 3 0.04 3 585 1000.8 2.9711 34.3621 75.8 12 34.3621 0.415 3.17 45.4 141.7 -99.00 2384.3 2 2371.8 2 -99.00 0.03 3 0.00 3 584 1237.9 2.6015 34.4428 75.8 11 34.4436 0.494 3.18 45.3 154.2 -99.00 2401.0 2 2382.7 2 -99.00 0.00 3 0.00 3 583 1503.9 2.3183 34.5023 76.1 10 34.5028 0.658 3.14 45.1 164.9 -99.00 2405.5 2 2389.7 2 -99.00 0.00 3 0.00 3 582 1752.2 2.1036 34.5477 76.1 9 34.5490 0.992 3.07 44.0 167.9 -99.00 2410.1 2 2388.1 2 -99.00 0.00 3 0.00 3 581 2000.6 1.9265 34.5839 76.4 8 34.5854 1.385 3.00 43.4 170.9 -99.00 2421.3 2 2383.1 2 -99.00 0.00 3 0.00 3 580 2254.0 1.8140 34.6070 76.4 7 34.6098 1.686 2.95 42.2 172.2 -99.00 2427.3 2 2373.8 2 -99.00 -99.00 0 -99.00 0 579 2502.1 1.7064 34.6277 76.4 6 34.6290 2.044 2.87 41.5 172.6 -99.00 2431.0 2 2365.5 2 -99.00 -99.00 0 -99.00 0 578 2754.7 1.6276 34.6432 76.4 5 34.6438 2.350 2.80 40.3 171.3 -99.00 2434.1 2 2354.4 2 -99.00 -99.00 0 -99.00 0 577 2999.0 1.5781 34.6536 76.4 4 34.6549 2.556 2.76 39.5 170.0 -99.00 2435.6 2 2350.8 2 -99.00 -99.00 0 -99.00 0 576 3496.7 1.5105 34.6698 76.4 3 34.6696 2.973 2.68 38.3 169.0 -99.00 2437.4 2 2342.1 2 -99.00 -99.00 0 -99.00 0 575 3995.8 1.5006 34.6781 76.4 2 34.6795 3.217 2.62 38.0 169.8 -99.00 2438.2 2 2333.9 2 -99.00 0.00 3 0.00 3 574 4282.1 1.5141 34.6812 76.1 1 34.6810 3.275 2.60 37.4 169.6 -99.00 2430.9 2 2340.9 2 -99.00 0.00 3 0.00 3