*2014/02/03 16:35:34.29 *IOS HEADER VERSION 1.10 2011/10/26 2011/10/26 *FILE START TIME : UTC 1997/06/05 02:18:00.000 NUMBER OF RECORDS : 14 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII NUMBER OF CHANNELS : 13 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- --------------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 17 30 2 Pressure decibar 1.1 1318.5 3 Temperature 'deg C (ITS90)' 3.0738 13.4653 4 Oxygen:Dissolved umol/kg 10.2 282.2 5 Oxygen:Dissolved mL/L 0.235 6.468 6 Salinity:Bottle PSS-78 31.4663 34.4488 7 Phosphate umol/L 0.41 3.33 8 Nitrate_plus_Nitrite umol/L 0.8 44.9 9 Silicate umol/L 6.4 145 10 Carbon:Dissolved:Inorganic umol/kg 1979.2 2365.7 11 Flag:Carbon:Dissolved:Inorganic n/a 12 Carbon:Dissolved:Organic umol/L 54 117.8 13 Nitrogen:Dissolved:Organic umol/L 2.9 5.5 $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 7 F ' ' 1 3 -99 ' ' 9 F ' ' 4 4 -99 ' ' 6 F ' ' 1 5 -99 ' ' 8 F ' ' 3 6 -99 ' ' 9 F ' ' 4 7 -99 ' ' 7 F ' ' 2 8 -99 ' ' 6 F ' ' 1 9 -99 ' ' 6 F ' ' 1 10 -999 ' ' ' ' F7.1 R4 ' ' 11 0 ' ' 3 NQ C ' ' 12 -99 ' ' ' ' F7.1 R4 ' ' 13 -99 ' ' ' ' F7.1 R4 ' ' $END $REMARKS Data quality is expressed with the following flags ------------------------------------------------------------------------------ 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). ------------------------------------------------------------------------------ Raw data in file 97110010 VI03 = 10.03 ! Volume of iodate standard (cm**3) NI03 = .01012923 ! Normalitity of iodate standard VREG = 2.0 ! Volume of sample displaced by reagents (cm**3) DOREG = 0.0017 ! Absolute amount of O2 added with reagents (ml) UFLAG = -1 ! 0|-1, -1 indicates DO_mass is valid $END *ADMINISTRATION MISSION : 1997-11 AGENCY : IOS, Ocean Science and Productivity, Sidney, B.C. COUNTRY : Canada PROJECT : Line P, JGOFS SCIENTIST : Boyd P. PLATFORM : John P. Tully *LOCATION STATION : MP04 EVENT NUMBER : 10 LATITUDE : 48 39.46000 N ! (deg min) LONGITUDE : 126 38.46000 W ! (deg min) WATER DEPTH : 1305 *INSTRUMENT TYPE : Bottle MODEL : Niskin 10 Litre $REMARKS Dissolved oxygen concentration determined using an automated titration system consisting of a Brinkman Dosimat (model 665) and a PC 900 Colorimeter. $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- AutoOxy.bas 2.1 1997/06/05 18:22:56 ' ' 14 MERGE 1.0 1997/06/07 21:28:01 14 14 REMOVECH 3.0 1997/06/16 18:49:11 14 14 CLEAN 2.2 1997/06/16 18:57:50 14 14 MERGE 1.0 1998/03/02 13:11:21 14 14 REMOVECH 4.0 2000/05/26 08:34:37 14 14 REMOVECH 4.0 2000/06/05 14:11:18 14 14 HDREDIT2 1.6 2003/04/30 16:50:13 ? ? CLEAN 4.2 2003/04/30 16:50:21 14 14 SORT 3.4.1 2004/04/13 16:56:15 14 14 CALIB 11.7 2011/07/15 17:19:40 14 14 MERGE 3.4 2012/02/13 14:18:00 14 14 CLEAN 5.0.4 2012/02/13 14:25:04 14 14 HDREDIT2 2.5.1 2012/02/13 14:25:57 ? ? SORT 3.6 2013/06/14 14:35:14 14 14 MERGE 3.5 2013/06/14 14:36:30 14 14 SORT 3.6 2013/06/14 14:37:15 14 14 HDREDIT2 2.6 2013/06/14 14:37:39 ? ? CLEAN 5.1 2013/06/14 14:38:06 14 14 CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 15:12:07 14 14 REMOVECH 8.2 2014/02/03 16:35:34 14 14 $END $REMARKS C.H. Culbertson's paper on Dissolved Oxygen in the 'Woce Hydrographic Program Operations and Methods - July 1991' -The following MERGE parameters were used: Primary File Extension: oxy Secondary File Extension: sal Merge Channel: Sample_no Merge Scheme Used: Interweave Records from Both Files Overlap Scheme Used: Keep Primary Primary Channels to Include: Sample_no,pressure,Temperature:sample,Salinity:CTD,Dissolved_oxygen:mas,Dissolv Secondary Channels to Include: Sample_no,Salinity:bottle -The following CHANNEL(S) were removed from file. Temperature:Sample CLEAN functions performed: - Reset #RECS, MIN & MAX values in header. -The following MERGE parameters were used: Primary File Extension: cln Secondary File Extension: srt Merge Channel: Sample_number Merge Scheme Used: Interpolate Secondary onto Primary Overlap Scheme Used: Keep Primary Primary Channels to Include: Sample_number,pressure,Temperature:CTD,Salinity:CTD,Dissolved_oxygen:mas,Dissol Secondary Channels to Include: Sample_number,Phosphate,Nitrate,Silicate,Ammonia,Chlorophyll -The following CHANNEL(S) were removed from file. Ammonia -The following CHANNEL(S) were removed from file. Chlorophyll CLEAN functions: - Reset #RECS, MIN & MAX values in header. - Change Pad Value to -99 in All Channels. - Delete Empty Channels: 0 deleted. - Set channel name post-colon letters to upper case. - Remove Sea-Bird comments from the header. -The following SORT parameters were used. Sorted by channel: Pressure Pressure channel sorted according to values in sort channel -CALIB parameters: 2011/07/15 17:19:40 Calibration type = Correct Mode: ONLY - calibration specs from Cal File only. Calibration file = L:\Cruise_Data\1997\1997-11\BOTTLE\9711COMP July 2011.CTR Calibrations applied: Ch Name Units Fmla Coefficents -- ----------------------------- --------- --- ----------------------------- 4 Salinity PSU 11 -0.2270516E-01 0.9697408E-06 Pressure -The following MERGE parameters were used: 2012/02/13 14:18:00 Merge Channel: Pressure Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Average Primary Channels to Include: ALL Secondary Channels to Include: Alkalinity:Total:Potentiometric, Flag:Alkalinity:Total:Potentiometric, Carbon:Dissolved:Inorganic, Flag:Carbon:Dissolved:Inorganic Primary file : P:\John Pages Archive\1997-11\1997-11-0010.che Secondary file: P:\John Pages Archive\1997-11\1997-11-0010.ios -CLEAN functions: 2012/02/13 14:25:04 Reset #RECS, MIN & MAX values in header. Delete Empty Channels: 2 deleted. -HEADER EDITS: 2012/02/13 14:25:57 Applied edit header: O:\Data Processing\Header Comments\Work\DIC & Alkalinity 1994-03 to 1999-01.tx -SORT parameters: 2013/06/14 14:35:14 Sorted in ascending order of channel Sample_Number -The following MERGE parameters were used: 2013/06/14 14:36:30 Merge Channel: Sample_Number Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Secondary Primary Channels to Include: ALL Secondary Channels to Include: Carbon:Dissolved:Organic, Nitrogen:Dissolved:Organic, Dimethyl_Sulphide Primary file : P:\John Pages Archive\1997-11\DMS, DOC, DON\1997-11-0010.srt_che Secondary file: P:\John Pages Archive\1997-11\DMS, DOC, DON\1997-11-0010.srt_ios Comments from secondary file: P:\John Pages Archive\1997-11\DMS, DOC, DON\1997-11-0010.srt_ios ---------------------------------------------------------------- -SORT parameters: 2013/06/14 14:35:39 Sorted in ascending order of channel Sample_Number -SORT parameters: 2013/06/14 14:37:15 Sorted in ascending order of channel Pressure -HEADER EDITS: 2013/06/14 14:37:39 Applied edit header: P:\John Pages Archive\DMS_Methods.txt -CLEAN functions: 2013/06/14 14:38:06 20 Reset #RECS, MIN & MAX values in header. Delete Empty Channels: 1 deleted. -REMOVECH 2014/02/03 16:35:34 The following CHANNEL(S) were removed: Salinity [PSS-78] $END *COMMENTS Rosette touched bottom. Oxygen sample #20, air bubble, poor end-point. Collection method: ------------------ A rosette, holding 24 ten-litre water samplers, with a CTD was used. Analysis methods: ----------------- Salinity samples are collected in glass bottles and analyzed on Guildline model 8410 Portasal Salinometers which are standardized with IAPSO standard seawater. Oxygen samples are analyzed on an automated Winkler titration system following the procedures of Carpenter (1965). A Brinkmann model 665 Dosimat and model PC910 Colorimeter is controlled by Visual-Basic program to titrate the oxygen samples. Nutrient samples are analyzed fresh on board using a Technicon AAII auto- analyzer following methods described in Barwell-Clarke and Whitney (1996). Chlorophyll was extracted with 90% acetone and analyzed fluorimetrically. Dissolved inorganic carbon (DIC) was determined using coulometric analysis. Total Alkalinity was determined by Potentiometric Titrations using the Millero Closed Cell, Non-Linear Method. All total alkalinity data prior to and including cruise 1999-01 are of poor quality and should be used with caution. Data have been re-quality controlled and flagged, but even data flagged as good contain unknown accuracy errors. Users should consult the PACIFICA corrected values at CDIAC for estimates of these errors. . For DMS methods see file "Method 1996 to 1999 for Dimethylsulfide Analysis.doc" in directory \\OSD_Data_Archive\Cruise_Data\Documents\Analysis Reference Papers\. . References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. J. Barwell-Clarke and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 3. Minkley, B.G., and F.A. Whitney. 2001. Summary of Hydrographic/CTD Observations Made Along Line P and at Station P: 1991-1999. Canadian Data Report of Hydrography and Ocean Sciences 156: 45 pp. *CALIBRATION $TABLE: CORRECTED CHANNELS ! Name Units Fmla Pad Coefficients ! ---------- ----- ---- ------ ------------ Salinity PSU 11 -999 (Pressure) (-0.2270516E-01 0.9697408E-06) $END !-1-- --2--- ---3---- --4-- ---5--- ---6---- --7--- --8-- --9-- --10-- 11 --12-- --13-- !Samp Pressu Temperat Oxyge Oxygen: Salinity Phosph Nitra Silic Carbon Fl Carbon Nitrog !le_ re ure n: Dissolv :Bottle ate te_ ate :Disso ag : en: !Numb Disso ed plus_ lved: ~g Dissol Dissol !er lved Nitri Inorga an ved:Or ved:Or ! te nic ic ganic ganic !---- ------ -------- ----- ------- -------- ------ ----- ----- ------ -- ------ ------ *END OF HEADER 30 1.1 13.4653 282.2 6.468 31.4663 0.41 0.8 6.4 2215.3 2 106.9 5.1 29 24.0 11.1661 263.1 6.035 31.7965 0.83 5.6 12.2 1979.2 2 117.8 5.5 28 48.2 8.6471 204.0 4.683 32.3119 1.58 18.1 26.4 2069.8 2 93.8 5.3 27 78.4 8.1983 194.9 4.474 32.8546 1.62 19.3 24.6 2095.1 2 70.7 4.6 26 98.6 8.1015 161.3 3.705 33.3258 1.87 23.7 27.7 2136.7 2 60.9 4.9 25 148.9 7.3689 114.6 2.633 33.8174 2.28 30.7 39.7 2197.0 2 63.0 4.2 24 202.1 6.8636 107.6 2.473 33.9032 2.36 31.9 45.1 -999.0 9 75.8 5.1 23 300.4 6.0405 88.9 2.045 33.9528 2.57 35.6 57.0 2239.2 2 54.0 2.9 22 399.7 5.5833 53.6 1.233 34.0239 2.85 39.2 70.2 2311.0 2 68.3 4.6 21 599.8 4.7767 22.4 0.515 34.1474 3.17 42.8 92.5 2318.5 2 66.8 3.4 20 803.0 4.2479 14.3 0.329 34.2713 3.28 44.0 110.1 2343.9 2 -99.0 -99.0 19 1000.8 3.7128 10.2 0.235 34.3724 3.33 44.5 126.0 2365.7 2 -99.0 -99.0 18 1200.2 3.2512 14.0 0.322 34.4276 3.30 44.7 139.3 -999.0 9 -99.0 -99.0 17 1318.5 3.0738 16.9 0.389 34.4488 3.29 44.9 145.0 -999.0 9 -99.0 -99.0