*2004/05/21 11:09:50.09 *IOS HEADER VERSION 1.4 2002/12/04 2002/12/04 *FILE START TIME : UTC 1994/10/24 21:02:00.000 NUMBER OF RECORDS : 23 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD FILE TYPE : ASCII NUMBER OF CHANNELS : 26 $TABLE: CHANNELS ! No Name Units Minimum Maximum ! -- ------------------------------------- ---------------- -------------- -------------- 1 Sample_Number n/a 2108 2130 2 Bottle_Number n/a 3 Pressure dbar 10.2 5083.9 4 Temperature 'deg C (IPTS68)' 1.2936 29.3378 5 Salinity PSS-78 34.0501 34.8768 6 Flag:Salinity ' ' 7 Salinity:Bottle PSS-78 34.057 34.845 8 Flag:Salinity:Bottle ' ' 9 Oxygen:Dissolved umol/kg 20.9 206.3 10 Flag:Oxygen:Dissolved ' ' 11 Silicate umol/kg 1.4 153.2 12 Flag:Silicate ' ' 13 Nitrate umol/kg 0 42.5 14 Flag:Nitrate ' ' 15 Nitrite umol/kg 0 1.44 16 Flag:Nitrite ' ' 17 Phosphate umol/kg 0.12 3.11 18 Flag:Phosphate ' ' 19 Chlorofluorocarbon_11 pmol/kg 0 2.64 20 Flag:Chlorofluorocarbon_11 ' ' 21 Chlorofluorocarbon_12 pmol/kg 0 1.34 22 Flag:Chlorofluorocarbon_12 ' ' 23 Carbon:Dissolved:Inorganic umol/kg 1897.4 2351.1 24 Flag:Carbon:Dissolved:Inorganic ' ' 25 Alkalinity:Total:CRM:Corrected umol/kg 2128 2442.5 26 Flag:Alkalinity:Total:CRM:Corrected ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places ! -- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 NQ C ' ' 3 -99 ' ' 7 F R4 1 4 -99 ' ' 9 F R4 4 5 -99 ' ' 9 F R4 4 6 -99 ' ' 2 NQ C ' ' 7 -99 ' ' 9 F R4 4 8 -99 ' ' 2 NQ C ' ' 9 -99 ' ' 6 F R4 1 10 -99 ' ' 2 NQ C ' ' 11 -99 ' ' 6 F R4 1 12 -99 ' ' 2 NQ C ' ' 13 -99 ' ' 6 F R4 1 14 -99 ' ' 2 NQ C ' ' 15 -99 ' ' 7 F R4 2 16 -99 ' ' 2 NQ C ' ' 17 -99 ' ' 7 F R4 2 18 -99 ' ' 2 NQ C ' ' 19 -99 ' ' 8 F R4 3 20 -99 ' ' 2 NQ C ' ' 21 -99 ' ' 8 F R4 3 22 -99 ' ' 2 NQ C ' ' 23 -99 ' ' 7 F R4 1 24 -99 ' ' 2 NQ C ' ' 25 -99 ' ' 7 F R4 1 26 -99 ' ' 2 NQ C ' ' $END $REMARKS Input data file used: ./woce-9403-p15n-legs-14.sum02a Data quality is expressed with the following flags: ----------------------------------------------------------------------------- a = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). b = Acceptable measurement (Flag 'b' also reported as ' ') c = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). d = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). e = Not reported (lost sample; unredeemably bad measurement). f = Mean of replicate measurements. g = Manual chromatographic peak measurement. h = Irregular digital chromatographic peak integration. i = Sample not drawn for this measurement from this bottle (not normally used). ----------------------------------------------------------------------------- Data in these files was downloaded from the web site below, Mar 05 2003 Downloaded files were reformated and merged into single ascii file. Several errors in the WOCE sum and hyd files were found - WHPO interpolation of cast events were incorrect especially "BO"ttom of - corrections of sample #'s for Stn # - addition of data for Saanich Inlet station - numerous corrections, additions made to Alkalinity and associated DQ fla - and a few corrections wrt DIC and associated DQ flags WOCE data quality flags (QUALT2) were used when available, else QUALT1 DQ Warning: For Alkalinity (& DIC) data it was noticed that reporting techicians made overly generous use of DQ flag 'i' (ie WOCE DQ flag '9'), instead of using DQ flags ('a','e') (ie WOCE DQ flags ('1','5'). References: http://whpo.ucsd.edu/data/onetime/pacific/p15/p15n/p15na/ http://whpo.ucsd.edu/data/onetime/pacific/p15/p15n/p15nb/ $END *ADMINISTRATION MISSION : 1994-03 AGENCY : IOS PROJECT : WOCE P15N, PR6, PRS1 SCIENTIST : H.Freeland (Leg2) PLATFORM : John P. Tully $REMARKS This is OSAP cruise 1994-03 (previously 9403) This includes WOCE cruise PR6, PRS1, P15N $END *LOCATION GEOGRAPHIC AREA : 'IOS to Dutch Harbour, to Honolulu, to Pago Pago, to' CONTINUED : ' IOS' STATION : W094 EVENT NUMBER : 110 LATITUDE : 8 59.71000 N ! (deg min) LONGITUDE : 168 45.25000 W ! (deg min) $REMARKS This is WOCE Cast # 3 On Sept 6, the Tully sailed west from the mouth of the Juan de Fuca Strait, along Line PR6. After completing 4 stations en route to Station PRS1, the vessel sailed for Dutch Harbour, Alaska, where it refueled. Section P15N (leg 1) started near Dutch Harbour continuing south along 165W. At 24N, the ship gradually shifted west, to coincide with a previous NOAA section, and the planned route of P15S. Most of the scientific crew were changed in Honolulu after 35 days at sea. Section P15N (leg 2) continued on from 20:30'N, following a course that moved gradually westward to 168:45'W at 10N. The ship remained on this longitude through the equator, then began a second southwestward course at 8:30'S that took the ship to 170W x 10S. At 15S, Leg2 ended and the vessel sailed to American Samoa. $END *INSTRUMENT TYPE : Guildline CTD MODEL : 8737, 8705 $REMARKS See details wrt various instruments in COMMENTS section $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- chem_cast_woce_9403_02.F 1.0 2003/04/16 11:32:22 23 23 HDREDIT2 1.9 2004/04/13 13:33:42 ? ? REMOVECH 6.0 2004/04/28 11:14:13 23 23 CLEAN 4.6.1 2004/04/28 11:15:44 23 23 HDREDIT2 2.0 2004/05/21 11:09:50 ? ? $END $REMARKS -The following CHANNEL(S) were removed from file. Alkalinity:Total:uncorrected Flag:Alkalinity:Total:uncorrected Alkalinity:Total:CRM:adjustment Flag:Alkalinity:Total:CRM:adjustment CLEAN functions: - Reset #RECS, MIN & MAX values in header. - Change Pad Value to -99 in All Channels. - Delete Empty Channels: 0 deleted. - Set channel name post-colon letters to upper case. - Remove Sea-Bird comments from the header. $END *COMMENTS C Contents: C Bottle Cast (Rosette) observations for water chemistry C Date and Time are taken from BEginning of Rosette Niskin Bottle UP Cast C Latitude and Longitude determined by GPS C C Sample collection methods: C Collection device was General Oceanics Rosette C with 24 10L Niskin bottles C and a Guildline 8737 CTD C Pressure C - Guildline 8737 CTD on 23 bottle Rosette (primary sampling system) C - Guildline 8705 CTD on 11 bottle Rosette (for shallow casts) C Sea Water Temp (CTD) C - Guildline 8737 CTD on 23 bottle Rosette (primary sampling system) C - Guildline 8705 CTD on 11 bottle Rosette (for shallow casts) C Salinity (CTD) C - Guildline 8737 CTD on 23 bottle Rosette (primary sampling system) C - Guildline 8705 CTD on 11 bottle Rosette (for shallow casts) C (10 L Niskin samplers) C Salinity (Bottle) C - Samples collected in glass bottles from Niskin Samplers C Oxygen:Dissolved C - Samples were drawn through either amber rubber or Tygon tubing into C 125 ml iodine flasks. The flasks were allowed to overflow twice C their volume before being stoppered then unstoppered, fixed with C manganous and iodide reagents (Carpenter, 1965), restoppered, then C shaken thoroughly. Sample temperatures were measured before initial C stoppering to within 0.5C. To avoid outgassing during analysis, C samples were initially all refrigerated at 4C for 1 to 24 hours C before analysis. C see cruise report for details wrt Stn dependent air contamination. C Silicate C - Samples collected in 50 ml polystyrene tubes from Niskin bottles C - Samples refrigerated for a maximum of 12 hours (rosette) or C 30 hr (USW) before analysis. C Nitrate C - Samples collected in 50 ml polystyrene tubes from Niskin bottles C - Samples refrigerated for a maximum of 12 hours (rosette) or C 30 hr (USW) before analysis. C Nitrite C - Samples collected in 50 ml polystyrene tubes from Niskin bottles C - Samples refrigerated for a maximum of 12 hours (rosette) or C 30 hr (USW) before analysis. C Phosphate C - Samples collected in 50 ml polystyrene tubes from Niskin bottles C - Samples refrigerated for a maximum of 12 hours (rosette) or C 30 hr (USW) before analysis. C CFC-11 C - Samples were drawn into 100 ml glass syringes that were thoroughly C rinsed in a continuous stream of sample. C CFC samplers checked each Niskin bottle for leaking by pushing in C the sample spigot before opening the air vent. C CFC-12 C - Samples were drawn into 100 ml glass syringes that were thoroughly C rinsed in a continuous stream of sample. C CFC samplers checked each Niskin bottle for leaking by pushing in C the sample spigot before opening the air vent. C Dissolved Inorganic Carbon (DIC) (aka TCO2) C - Samples collected in 250 ml glass bottles, fixed with 200 ul of C saturated HgCL2 solution, and cool stored until analyzed. C Total Alkalinity C - Samples collected in 250 ml glass bottles, fixed with 200 ul of C saturated HgCL2 solution, and cool stored until analyzed. C C Sample analysis methods: C Pressure C - Guildline 8737 CTD on 23 bottle Rosette (primary sampling system) C - Guildline 8705 CTD on 11 bottle Rosette (for shallow casts) C Sea Water Temp C - Guildline 8737 CTD on 23 bottle Rosette (primary sampling system) C - Guildline 8705 CTD on 11 bottle Rosette (for shallow casts) C Salinity (CTD) C - Guildline 8737 CTD on 23 bottle Rosette (primary sampling system) C - Guildline 8705 CTD on 11 bottle Rosette (for shallow casts) C Salinity (Bottle) C - analyzed onboard with a Guildline Model 8410 Portasal C The Portasal was standardized daily with IAPSO standard sea water C Batch P125. C Oxygen:Dissolved C - automated titration system (Brinkman Dosimat) using micro-Winkler C method (Carpenter, 1965) detected iodine end-point colorimetrically. C Silicate C - analyzed using Technicon Analyzer C Concentrated standards were prepared from oven dried (80C) reagents C shortly before sailing on Leg1 and again in Honolulu. Working C standards were made every 1 to 2 days by diluting 1 to 6 ml of C various stock solutions to 250 ml with 3.2% NaCl (w/v in double run C Milli-Q water). C - Silicate standards were compared to Sagami standards. C - Nutrient lab temperatures were recorded hourly during analysis. C Nitrate C - analyzed using Technicon Analyzer C Concentrated standards were prepared from oven dried (80C) reagents C shortly before sailing on Leg1 and again in Honolulu. Working C standards were made every 1 to 2 days by diluting 1 to 6 ml of C various stock solutions to 250 ml with 3.2% NaCl (w/v in double run C Milli-Q water). C - Nitrate standards were compared to Sagami standards. C - Nutrient lab temperatures were recorded hourly during analysis. C - Crystals developed in nitrate line from Station W123 onwards. C Nitrite C - analyzed using Technicon Analyzer C Concentrated standards were prepared from oven dried (80C) reagents C shortly before sailing on Leg1 and again in Honolulu. Working C standards were made every 1 to 2 days by diluting 1 to 6 ml of C various stock solutions to 250 ml with 3.2% NaCl (w/v in double run C Milli-Q water). C - Nitrite standards were compared to Sagami standards. C - Nutrient lab temperatures were recorded hourly during analysis. C Phosphate C - analyzed using Technicon Analyzer C Concentrated standards were prepared from oven dried (80C) reagents C shortly before sailing on Leg1 and again in Honolulu. Working C standards were made every 1 to 2 days by diluting 1 to 6 ml of C various stock solutions to 250 ml with 3.2% NaCl (w/v in double run C Milli-Q water). C - Nutrient lab temperatures were recorded hourly during analysis. C - Phosphate samples were occasionally contaminated during 2nd half of C leg 1. C CFC-11 C - analyzed using Gas Chromatography, following procedure of Bullister C and Weiss (1987). HP GC failed on leg1 and replaced with 2nd HP GC C on leg2. See cruise report for details on Limit of Detection. C CFC-12 C - analyzed using Gas Chromatography, following procedure of Bullister C and Weiss (1987). HP GC failed on leg1 and replaced with 2nd HP GC C on leg2. See cruise report for details on Limit of Detection. C Dissolved Inorganic Carbon (DIC) C - by Coulometer (Coulometric Somma 5011) at IOS, using method outlined C in DOE (1994). C Total Alkalinity C - by Potentiometric Titration, following the method of DOE (1994) C Alkalinity was determined using a temperature stable (25C) closed C titration cell, a Metrohm 665 Dosimat, a Metrohm 649 stir apparatus, C and an Orion model 720A pH meter. Software by D.M.Campbell. C About 1/2 of samples from Leg1 were analyzed on Leg1, the other 1/2 C being analyzed on Leg2. C - Problems abounded with method, etc, etc for Alkalinity. C for more information, see 'Data Assessment..." report by J.Page C Data quality flags have been downgraded here, from previous values. C - CRM values for Cell#2 were averaged before Cell repair => ave adj C CRM values for Cell#2 were averaged after Cell repair => ave adj C CRM values for Cell#1 were too few to compute average adjustment. C C REFERENCES: C Bullister, J.L. and Weiss, R.F. (1988) C Determination of CC13F and CC12F2 in seawater and air. C Deep-Sea Research, Vol 35, 839-853. C Carpenter, J.H. 1965 C The Chesapeake Bay Inst technique for the Winkler Dissolved Oxygen Meth C Limnol. Oceanogr. 10: 141-143 C DOE. 1994. C Handbook of methods of the analysis of the various parameters of the C carbon dioxide systen in sea water: version 2 C Dickson, A.G., Goyet, C., eds. ORNL/CDIAC-74. C Koroleff, F. and K. Grasshoff. 1983. C Determination of nutients. in Methods of Seawater Analysis. C eds K. Grasshoff, M. Ehrhardt, K. Kremling. C Page, J. 2003 C Data Assessment for Total Alkalinity by Millero Closed Cell Method C For the 1994 Climate Chem Cruise 9403 / WOCE P15N Line. C (draft copy for internal use) C Weiss, R.F. C Freon Lab Manual. Unpublished manuscript C Scripps Inst of Oceanography, San Diego, California, USA. C WOCE Report No. 73/91, 1991. C A comparison of methods for the determination of dissolved oxygen in se C WHPO Publication 91-2. Unpublished manuscript. C !-1-- -2-- --3--- ---4---- ---5---- 6 ---7---- 8 --9-- 10--11- 12--13- 14--15-- 16--17-- 18---19-- 20---21-- 22--23-- 24--25-- 2 !Samp Bott Pressu Temperat Salinity F Salinity F Oxyge F Silic F Nitra F Nitrit F Phosph F Chlorof F Chlorof F Carbon F Alkali F !le_ le_ re ure l :Bottle l n: l ate l te l e l ate l luoroca l luoroca l :Disso l nity:T l !Numb Numb ~ ~ Disso ~ ~ ~ ~ ~ rbon_11 ~ rbon_12 ~ lved: ~ otal:C ~ !er er t l lved e t t t t 1 1 Inorga i RM:Cor e ! y e d e e e e 1 2 nic c rected d !---- ---- ------ -------- -------- - -------- - ----- - ----- - ----- - ------ - ------ - ------- - ------- - ------ - ------ - *END OF HEADER 2130 23 10.2 29.3378 34.0501 34.0570 196.2 1.4 0.1 0.03 0.12 2.410 c 0.380 c 1897.4 2234.8 2129 22 48.4 29.0529 34.1479 34.3280 206.3 1.6 0.0 0.06 0.16 1.260 c 1.080 c 1932.2 2255.1 2128 21 73.4 19.4970 34.8768 34.8450 183.7 3.8 3.0 0.00 0.43 2.640 c 1.340 c 2050.9 2294.5 2127 20 189.2 11.1668 34.6361 34.6610 20.9 30.9 33.1 0.17 2.46 0.290 c 0.650 c 2243.8 2293.6 2126 19 299.7 9.7627 34.6680 34.6650 21.5 34.9 35.3 0.01 2.56 0.000 c 0.000 c 2255.9 2305.5 2125 18 299.9 9.7612 34.6679 34.6650 21.3 34.9 35.6 0.01 2.57 0.000 c 0.000 c 2252.9 2299.1 2124 17 401.4 8.9051 34.6282 34.6230 20.9 40.8 36.9 0.01 2.71 0.000 c 0.000 c 2264.9 2306.6 2123 16 400.5 8.9130 34.6278 34.6230 21.7 40.6 36.8 0.01 2.70 0.000 c 0.000 c 2264.1 2293.5 2122 15 601.1 6.8268 34.5413 34.5360 23.5 62.0 40.3 0.02 3.00 0.000 c 0.000 c 2294.8 2324.7 2121 14 800.4 5.5725 34.5341 34.5350 35.3 81.1 42.5 0.01 3.11 0.000 c 0.000 c 2319.5 2345.6 2120 13 997.7 4.4085 34.5591 34.5590 60.5 98.0 41.7 0.01 3.00 -99.000 i -99.000 i 2326.5 2366.7 2119 12 1247.6 3.4385 34.5858 34.5830 77.1 114.5 39.7 d 1.44 2.98 -99.000 i -99.000 i 2336.0 2387.2 2118 11 1495.8 2.8050 34.6098 34.6050 87.8 127.3 40.3 0.01 2.91 -99.000 i -99.000 i 2341.1 2401.6 2117 10 1750.3 2.4036 34.6279 34.6240 97.2 136.2 40.1 0.01 2.86 -99.000 i -99.000 i 2345.1 2408.9 2116 9 1999.3 2.1412 34.6424 34.6370 103.7 142.4 39.6 0.01 2.82 -99.000 i -99.000 i 2349.1 2417.8 2115 8 2246.9 1.9995 34.6541 34.6520 107.8 148.3 39.6 0.03 2.80 -99.000 i -99.000 i -99.0 i 2412.5 c 2114 7 2499.4 1.8870 34.6627 34.6620 114.3 149.8 38.8 0.02 2.74 -99.000 i -99.000 i 2351.1 -99.0 i 2113 6 2748.8 1.7602 34.6701 34.6680 121.4 153.2 38.7 0.03 2.71 -99.000 i -99.000 i 2347.5 2435.1 2112 5 2999.2 1.6466 34.6760 34.6740 130.0 152.2 38.0 0.04 2.66 -99.000 i -99.000 i 2344.4 2433.2 2111 4 3499.2 1.5130 34.6835 34.6830 146.3 148.3 36.9 0.03 2.57 -99.000 i -99.000 i 2329.5 2442.5 c 2110 3 3999.1 1.3995 34.6913 34.6910 162.5 141.9 35.8 0.02 2.49 -99.000 i -99.000 i 2315.0 2153.3 d 2109 2 4545.6 1.2936 34.6991 34.7000 181.9 131.7 34.5 0.03 2.41 -99.000 i -99.000 i 2293.8 2128.0 d 2108 1 5083.9 1.2948 34.7026 34.7040 188.8 128.3 33.9 0.06 2.35 0.000 c 0.000 c 2284.9 2272.1 c