*2004/05/21 11:09:45.43 *IOS HEADER VERSION 1.4 2002/12/04 2002/12/04 *FILE START TIME : UTC 1994/10/24 09:07:00.000 NUMBER OF RECORDS : 23 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD FILE TYPE : ASCII NUMBER OF CHANNELS : 24 $TABLE: CHANNELS ! No Name Units Minimum Maximum ! -- --------------------------------- ---------------- -------------- -------------- 1 Sample_Number n/a 2062 2084 2 Bottle_Number n/a 3 Pressure dbar 37.2 5305.4 4 Temperature 'deg C (IPTS68)' 1.3033 28.8175 5 Salinity PSS-78 34.055 34.7011 6 Flag:Salinity ' ' 7 Salinity:Bottle PSS-78 34.068 34.703 8 Flag:Salinity:Bottle ' ' 9 Oxygen:Dissolved umol/kg 18.1 200.2 10 Flag:Oxygen:Dissolved ' ' 11 Silicate umol/kg 1.9 153 12 Flag:Silicate ' ' 13 Nitrate umol/kg 0 42.9 14 Flag:Nitrate ' ' 15 Nitrite umol/kg 0 0.7E-01 16 Flag:Nitrite ' ' 17 Phosphate umol/kg 0.16 3.15 18 Flag:Phosphate ' ' 19 Chlorofluorocarbon_11 pmol/kg 0 1.64 20 Flag:Chlorofluorocarbon_11 ' ' 21 Chlorofluorocarbon_12 pmol/kg 0 1.17 22 Flag:Chlorofluorocarbon_12 ' ' 23 Carbon:Dissolved:Inorganic umol/kg 1901.8 2348.6 24 Flag:Carbon:Dissolved:Inorganic ' ' $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places ! -- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 NQ C ' ' 3 -99 ' ' 7 F R4 1 4 -99 ' ' 9 F R4 4 5 -99 ' ' 9 F R4 4 6 -99 ' ' 2 NQ C ' ' 7 -99 ' ' 9 F R4 4 8 -99 ' ' 2 NQ C ' ' 9 -99 ' ' 6 F R4 1 10 -99 ' ' 2 NQ C ' ' 11 -99 ' ' 6 F R4 1 12 -99 ' ' 2 NQ C ' ' 13 -99 ' ' 6 F R4 1 14 -99 ' ' 2 NQ C ' ' 15 -99 ' ' 7 F R4 2 16 -99 ' ' 2 NQ C ' ' 17 -99 ' ' 7 F R4 2 18 -99 ' ' 2 NQ C ' ' 19 -99 ' ' 8 F R4 3 20 -99 ' ' 2 NQ C ' ' 21 -99 ' ' 8 F R4 3 22 -99 ' ' 2 NQ C ' ' 23 -99 ' ' 7 F R4 1 24 -99 ' ' 2 NQ C ' ' $END $REMARKS Input data file used: ./woce-9403-p15n-legs-14.sum02a Data quality is expressed with the following flags: ----------------------------------------------------------------------------- a = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). b = Acceptable measurement (Flag 'b' also reported as ' ') c = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). d = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). e = Not reported (lost sample; unredeemably bad measurement). f = Mean of replicate measurements. g = Manual chromatographic peak measurement. h = Irregular digital chromatographic peak integration. i = Sample not drawn for this measurement from this bottle (not normally used). ----------------------------------------------------------------------------- Data in these files was downloaded from the web site below, Mar 05 2003 Downloaded files were reformated and merged into single ascii file. Several errors in the WOCE sum and hyd files were found - WHPO interpolation of cast events were incorrect especially "BO"ttom of - corrections of sample #'s for Stn # - addition of data for Saanich Inlet station - numerous corrections, additions made to Alkalinity and associated DQ fla - and a few corrections wrt DIC and associated DQ flags WOCE data quality flags (QUALT2) were used when available, else QUALT1 DQ Warning: For Alkalinity (& DIC) data it was noticed that reporting techicians made overly generous use of DQ flag 'i' (ie WOCE DQ flag '9'), instead of using DQ flags ('a','e') (ie WOCE DQ flags ('1','5'). References: http://whpo.ucsd.edu/data/onetime/pacific/p15/p15n/p15na/ http://whpo.ucsd.edu/data/onetime/pacific/p15/p15n/p15nb/ $END *ADMINISTRATION MISSION : 1994-03 AGENCY : IOS PROJECT : WOCE P15N, PR6, PRS1 SCIENTIST : H.Freeland (Leg2) PLATFORM : John P. Tully $REMARKS This is OSAP cruise 1994-03 (previously 9403) This includes WOCE cruise PR6, PRS1, P15N $END *LOCATION GEOGRAPHIC AREA : 'IOS to Dutch Harbour, to Honolulu, to Pago Pago, to' CONTINUED : ' IOS' STATION : W092 EVENT NUMBER : 108 LATITUDE : 10 0.97000 N ! (deg min) LONGITUDE : 168 44.84000 W ! (deg min) $REMARKS This is WOCE Cast # 3 On Sept 6, the Tully sailed west from the mouth of the Juan de Fuca Strait, along Line PR6. After completing 4 stations en route to Station PRS1, the vessel sailed for Dutch Harbour, Alaska, where it refueled. Section P15N (leg 1) started near Dutch Harbour continuing south along 165W. At 24N, the ship gradually shifted west, to coincide with a previous NOAA section, and the planned route of P15S. Most of the scientific crew were changed in Honolulu after 35 days at sea. Section P15N (leg 2) continued on from 20:30'N, following a course that moved gradually westward to 168:45'W at 10N. The ship remained on this longitude through the equator, then began a second southwestward course at 8:30'S that took the ship to 170W x 10S. At 15S, Leg2 ended and the vessel sailed to American Samoa. $END *INSTRUMENT TYPE : Guildline CTD MODEL : 8737, 8705 $REMARKS See details wrt various instruments in COMMENTS section $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- chem_cast_woce_9403_02.F 1.0 2003/04/16 11:32:22 23 23 HDREDIT2 1.9 2004/04/13 13:33:42 ? ? REMOVECH 6.0 2004/04/28 11:14:12 23 23 CLEAN 4.6.1 2004/04/28 11:15:44 23 23 HDREDIT2 2.0 2004/05/21 11:09:45 ? ? $END $REMARKS -The following CHANNEL(S) were removed from file. Alkalinity:Total:uncorrected Flag:Alkalinity:Total:uncorrected CLEAN functions: - Reset #RECS, MIN & MAX values in header. - Change Pad Value to -99 in All Channels. - Delete Empty Channels: 0 deleted. - Set channel name post-colon letters to upper case. - Remove Sea-Bird comments from the header. $END *COMMENTS C Contents: C Bottle Cast (Rosette) observations for water chemistry C Date and Time are taken from BEginning of Rosette Niskin Bottle UP Cast C Latitude and Longitude determined by GPS C C Sample collection methods: C Collection device was General Oceanics Rosette C with 24 10L Niskin bottles C and a Guildline 8737 CTD C Pressure C - Guildline 8737 CTD on 23 bottle Rosette (primary sampling system) C - Guildline 8705 CTD on 11 bottle Rosette (for shallow casts) C Sea Water Temp (CTD) C - Guildline 8737 CTD on 23 bottle Rosette (primary sampling system) C - Guildline 8705 CTD on 11 bottle Rosette (for shallow casts) C Salinity (CTD) C - Guildline 8737 CTD on 23 bottle Rosette (primary sampling system) C - Guildline 8705 CTD on 11 bottle Rosette (for shallow casts) C (10 L Niskin samplers) C Salinity (Bottle) C - Samples collected in glass bottles from Niskin Samplers C Oxygen:Dissolved C - Samples were drawn through either amber rubber or Tygon tubing into C 125 ml iodine flasks. The flasks were allowed to overflow twice C their volume before being stoppered then unstoppered, fixed with C manganous and iodide reagents (Carpenter, 1965), restoppered, then C shaken thoroughly. Sample temperatures were measured before initial C stoppering to within 0.5C. To avoid outgassing during analysis, C samples were initially all refrigerated at 4C for 1 to 24 hours C before analysis. C see cruise report for details wrt Stn dependent air contamination. C Silicate C - Samples collected in 50 ml polystyrene tubes from Niskin bottles C - Samples refrigerated for a maximum of 12 hours (rosette) or C 30 hr (USW) before analysis. C Nitrate C - Samples collected in 50 ml polystyrene tubes from Niskin bottles C - Samples refrigerated for a maximum of 12 hours (rosette) or C 30 hr (USW) before analysis. C Nitrite C - Samples collected in 50 ml polystyrene tubes from Niskin bottles C - Samples refrigerated for a maximum of 12 hours (rosette) or C 30 hr (USW) before analysis. C Phosphate C - Samples collected in 50 ml polystyrene tubes from Niskin bottles C - Samples refrigerated for a maximum of 12 hours (rosette) or C 30 hr (USW) before analysis. C CFC-11 C - Samples were drawn into 100 ml glass syringes that were thoroughly C rinsed in a continuous stream of sample. C CFC samplers checked each Niskin bottle for leaking by pushing in C the sample spigot before opening the air vent. C CFC-12 C - Samples were drawn into 100 ml glass syringes that were thoroughly C rinsed in a continuous stream of sample. C CFC samplers checked each Niskin bottle for leaking by pushing in C the sample spigot before opening the air vent. C Dissolved Inorganic Carbon (DIC) (aka TCO2) C - Samples collected in 250 ml glass bottles, fixed with 200 ul of C saturated HgCL2 solution, and cool stored until analyzed. C Total Alkalinity C - Samples collected in 250 ml glass bottles, fixed with 200 ul of C saturated HgCL2 solution, and cool stored until analyzed. C C Sample analysis methods: C Pressure C - Guildline 8737 CTD on 23 bottle Rosette (primary sampling system) C - Guildline 8705 CTD on 11 bottle Rosette (for shallow casts) C Sea Water Temp C - Guildline 8737 CTD on 23 bottle Rosette (primary sampling system) C - Guildline 8705 CTD on 11 bottle Rosette (for shallow casts) C Salinity (CTD) C - Guildline 8737 CTD on 23 bottle Rosette (primary sampling system) C - Guildline 8705 CTD on 11 bottle Rosette (for shallow casts) C Salinity (Bottle) C - analyzed onboard with a Guildline Model 8410 Portasal C The Portasal was standardized daily with IAPSO standard sea water C Batch P125. C Oxygen:Dissolved C - automated titration system (Brinkman Dosimat) using micro-Winkler C method (Carpenter, 1965) detected iodine end-point colorimetrically. C Silicate C - analyzed using Technicon Analyzer C Concentrated standards were prepared from oven dried (80C) reagents C shortly before sailing on Leg1 and again in Honolulu. Working C standards were made every 1 to 2 days by diluting 1 to 6 ml of C various stock solutions to 250 ml with 3.2% NaCl (w/v in double run C Milli-Q water). C - Silicate standards were compared to Sagami standards. C - Nutrient lab temperatures were recorded hourly during analysis. C Nitrate C - analyzed using Technicon Analyzer C Concentrated standards were prepared from oven dried (80C) reagents C shortly before sailing on Leg1 and again in Honolulu. Working C standards were made every 1 to 2 days by diluting 1 to 6 ml of C various stock solutions to 250 ml with 3.2% NaCl (w/v in double run C Milli-Q water). C - Nitrate standards were compared to Sagami standards. C - Nutrient lab temperatures were recorded hourly during analysis. C - Crystals developed in nitrate line from Station W123 onwards. C Nitrite C - analyzed using Technicon Analyzer C Concentrated standards were prepared from oven dried (80C) reagents C shortly before sailing on Leg1 and again in Honolulu. Working C standards were made every 1 to 2 days by diluting 1 to 6 ml of C various stock solutions to 250 ml with 3.2% NaCl (w/v in double run C Milli-Q water). C - Nitrite standards were compared to Sagami standards. C - Nutrient lab temperatures were recorded hourly during analysis. C Phosphate C - analyzed using Technicon Analyzer C Concentrated standards were prepared from oven dried (80C) reagents C shortly before sailing on Leg1 and again in Honolulu. Working C standards were made every 1 to 2 days by diluting 1 to 6 ml of C various stock solutions to 250 ml with 3.2% NaCl (w/v in double run C Milli-Q water). C - Nutrient lab temperatures were recorded hourly during analysis. C - Phosphate samples were occasionally contaminated during 2nd half of C leg 1. C CFC-11 C - analyzed using Gas Chromatography, following procedure of Bullister C and Weiss (1987). HP GC failed on leg1 and replaced with 2nd HP GC C on leg2. See cruise report for details on Limit of Detection. C CFC-12 C - analyzed using Gas Chromatography, following procedure of Bullister C and Weiss (1987). HP GC failed on leg1 and replaced with 2nd HP GC C on leg2. See cruise report for details on Limit of Detection. C Dissolved Inorganic Carbon (DIC) C - by Coulometer (Coulometric Somma 5011) at IOS, using method outlined C in DOE (1994). C Total Alkalinity C - by Potentiometric Titration, following the method of DOE (1994) C Alkalinity was determined using a temperature stable (25C) closed C titration cell, a Metrohm 665 Dosimat, a Metrohm 649 stir apparatus, C and an Orion model 720A pH meter. Software by D.M.Campbell. C About 1/2 of samples from Leg1 were analyzed on Leg1, the other 1/2 C being analyzed on Leg2. C - Problems abounded with method, etc, etc for Alkalinity. C for more information, see 'Data Assessment..." report by J.Page C Data quality flags have been downgraded here, from previous values. C - CRM values for Cell#2 were averaged before Cell repair => ave adj C CRM values for Cell#2 were averaged after Cell repair => ave adj C CRM values for Cell#1 were too few to compute average adjustment. C C REFERENCES: C Bullister, J.L. and Weiss, R.F. (1988) C Determination of CC13F and CC12F2 in seawater and air. C Deep-Sea Research, Vol 35, 839-853. C Carpenter, J.H. 1965 C The Chesapeake Bay Inst technique for the Winkler Dissolved Oxygen Meth C Limnol. Oceanogr. 10: 141-143 C DOE. 1994. C Handbook of methods of the analysis of the various parameters of the C carbon dioxide systen in sea water: version 2 C Dickson, A.G., Goyet, C., eds. ORNL/CDIAC-74. C Koroleff, F. and K. Grasshoff. 1983. C Determination of nutients. in Methods of Seawater Analysis. C eds K. Grasshoff, M. Ehrhardt, K. Kremling. C Page, J. 2003 C Data Assessment for Total Alkalinity by Millero Closed Cell Method C For the 1994 Climate Chem Cruise 9403 / WOCE P15N Line. C (draft copy for internal use) C Weiss, R.F. C Freon Lab Manual. Unpublished manuscript C Scripps Inst of Oceanography, San Diego, California, USA. C WOCE Report No. 73/91, 1991. C A comparison of methods for the determination of dissolved oxygen in se C WHPO Publication 91-2. Unpublished manuscript. C !-1-- -2-- --3--- ---4---- ---5---- 6 ---7---- 8 --9-- 10--11- 12--13- 14--15-- 16--17-- 18---19-- 20---21-- 22--23-- 2 !Samp Bott Pressu Temperat Salinity F Salinity F Oxyge F Silic F Nitra F Nitrit F Phosph F Chlorof F Chlorof F Carbon F !le_ le_ re ure l :Bottle l n: l ate l te l e l ate l luoroca l luoroca l :Disso l !Numb Numb ~ ~ Disso ~ ~ ~ ~ ~ rbon_11 ~ rbon_12 ~ lved: ~ !er er t l lved e t t t t 1 1 Inorga i ! y e d e e e e 1 2 nic c !---- ---- ------ -------- -------- - -------- - ----- - ----- - ----- - ------ - ------ - ------- - ------- - ------ - *END OF HEADER 2084 23 37.2 28.8175 34.0550 34.0680 200.2 1.9 0.0 0.00 0.16 1.430 c 1.170 c 1901.8 2083 22 119.4 14.4380 34.5397 34.5410 100.1 15.5 18.5 0.07 1.52 1.640 c 0.800 c 2144.0 2082 21 204.5 10.7363 34.6421 34.6560 22.5 31.7 33.5 0.01 2.46 0.250 c 0.220 c 2236.9 2081 20 301.1 9.8192 34.6687 34.6660 18.1 35.7 36.0 0.02 2.61 0.000 c 0.000 c 2254.8 2080 19 403.4 8.9064 34.6225 34.6240 18.4 41.7 36.7 0.03 2.77 0.000 c 0.000 c 2268.2 2079 18 603.2 6.8913 34.5402 34.5400 20.6 60.0 39.8 0.03 3.03 0.000 c 0.000 c 2295.2 2078 17 799.7 5.4219 34.5338 34.5320 30.3 80.2 42.9 0.02 3.14 0.000 c 0.000 c 2315.7 2077 16 1000.1 4.4863 34.5520 34.5530 47.2 96.7 42.7 0.03 3.15 -99.000 i -99.000 i 2327.9 2076 15 1250.6 3.5417 34.5833 34.5810 62.1 115.9 42.6 0.03 3.08 -99.000 i -99.000 i 2342.4 2075 14 1498.3 2.8561 34.6055 34.6050 86.3 130.0 40.7 0.03 2.91 -99.000 i -99.000 i 2340.7 2074 13 1750.8 2.3963 34.6270 34.6260 96.6 140.6 40.1 0.03 2.85 -99.000 i -99.000 i 2346.7 2073 12 2000.9 2.1298 34.6422 34.6410 104.2 145.2 39.9 0.02 2.84 -99.000 i -99.000 i 2344.2 2072 11 2250.9 1.9565 34.6541 34.6500 109.2 150.4 39.4 0.04 2.79 -99.000 i -99.000 i 2346.0 2071 10 2500.3 1.8642 34.6621 34.6610 -99.0 d 151.4 39.1 0.02 2.75 -99.000 i -99.000 i 2348.6 2070 9 2749.0 1.7649 34.6681 34.6680 122.3 152.7 38.5 0.04 2.71 -99.000 i -99.000 i 2346.8 2069 8 3000.2 1.6799 34.6728 34.6730 129.0 153.0 38.2 0.03 2.66 -99.000 i -99.000 i 2344.5 2068 7 3250.9 1.6001 34.6773 34.6770 135.9 151.8 37.5 0.02 2.66 -99.000 i -99.000 i 2303.1 d 2067 6 3502.8 1.5314 34.6811 34.6810 143.1 150.4 37.0 0.02 2.58 -99.000 i -99.000 i 2323.8 2066 5 3999.7 1.3906 34.6903 34.6900 162.3 144.2 36.0 0.04 2.48 -99.000 i -99.000 i 2309.6 2065 4 4501.3 1.3033 34.6978 34.6990 179.2 134.2 34.6 0.04 2.39 -99.000 i -99.000 i 2291.3 2064 3 4998.4 1.3139 34.7011 34.7020 186.7 129.8 34.2 0.04 2.35 -99.000 i -99.000 i 2283.5 2063 2 5305.4 1.3468 34.7009 34.7030 187.4 129.5 34.1 0.02 2.34 -99.000 i -99.000 i -99.0 i 2062 1 5305.4 1.3468 34.7009 34.7020 187.5 129.5 34.1 0.03 2.34 0.000 c 0.000 c 2238.9