*2014/11/20 09:51:24.78 *IOS HEADER VERSION 1.10 2011/10/26 2011/10/26 *FILE START TIME : UTC 1993/04/09 19:48:00.000 NUMBER OF RECORDS : 23 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD FILE TYPE : ASCII NUMBER OF CHANNELS : 30 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- --------------------------------- ---------------- -------------- -------------- 1 Sample_Number n/a 93 115 2 Bottle_Number n/a 1 23 3 Pressure decibar 10.5 3002.2 4 Temperature 'deg C (IPTS68)' 1.401 8.396 5 Salinity PSS-78 32.892 34.6812 6 Flag:Salinity n/a 7 Salinity:Bottle PSS-78 32.8864 34.6644 8 Flag:Salinity:Bottle n/a 9 Oxygen:Dissolved umol/kg 20.6 309.3 10 Flag:Oxygen:Dissolved n/a 11 Silicate umol/L 17.4 166.5 12 Flag:Silicate n/a 13 Nitrate umol/L 10 44.3 14 Flag:Nitrate n/a 15 Nitrite umol/L 0 0.32 16 Flag:Nitrite n/a 17 Phosphate umol/L 2.44 3.21 18 Flag:Phosphate n/a 19 Chlorofluorocarbon_11 pmol/kg 0 5.604 20 Flag:Chlorofluorocarbon_11 n/a 21 Chlorofluorocarbon_12 pmol/kg 0 2.67 22 Flag:Chlorofluorocarbon_12 n/a 23 Carbon:Dissolved:Inorganic umol/kg 2026.7 2378.2 24 Flag:Carbon:Dissolved:Inorganic n/a 25 Alkalinity:Total umol/kg 2242.8 2418.1 26 Flag:Alkalinity:Total n/a 27 pH:SWS n/a 7.476 8.058 28 Flag:pH:SWS n/a 29 Oxygen:Isotope:18 /mille -0.72 -0.3E-01 30 Flag:Oxygen:Isotope:18 n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 7 F R4 1 4 -99 ' ' 9 F R4 4 5 -99 ' ' 9 F R4 4 6 ' ' ' ' 2 NQ C ' ' 7 -99 ' ' 9 F R4 4 8 ' ' ' ' 2 NQ C ' ' 9 -99 ' ' 6 F R4 1 10 ' ' ' ' 2 NQ C ' ' 11 -99 ' ' 6 F R4 1 12 ' ' ' ' 2 NQ C ' ' 13 -99 ' ' 6 F R4 1 14 ' ' ' ' 2 NQ C ' ' 15 -99 ' ' 7 F R4 2 16 ' ' ' ' 2 NQ C ' ' 17 -99 ' ' 7 F R4 2 18 ' ' ' ' 2 NQ C ' ' 19 -99 ' ' 8 F R4 3 20 ' ' ' ' 2 NQ C ' ' 21 -99 ' ' 8 F R4 3 22 ' ' ' ' 2 NQ C ' ' 23 -99 ' ' 7 F R4 1 24 ' ' ' ' 2 NQ C ' ' 25 -99 ' ' 7 F R4 1 26 ' ' ' ' 2 NQ C ' ' 27 -99 ' ' 9 F R4 4 28 ' ' ' ' 2 NQ C ' ' 29 -99 ' ' 7 F R4 2 30 ' ' ' ' 2 NQ C ' ' $END $REMARKS This file converted from OSAP file. Input data file used: ./osap-che-btl-1993-9316-p01w-01.dat03 This was a Joint Russian (POI) and Canadian (IOS) Cruise Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- Data in these files was downloaded from the web site below, Feb 21 2003 Downloaded files were reformated and merged into single ascii file and WOCE data quality flags (QUALT2) translated into OSAP data quality flag equivalents before export to IOS Header format. References: http://whpo.ucsd.edu/data/onetime/pacific/p01/p01w/p01wsu.txt http://whpo.ucsd.edu/data/onetime/pacific/p01/p01w/p01why.txt $END *ADMINISTRATION MISSION : 1993-16 AGENCY : POI, IOS PROJECT : WOCE P1W SCIENTIST : Bychkov A./ Whitney F. PLATFORM : Ak Nesmeyanov $REMARKS This is OSAP cruise 1993-16 (previously 9316) This is WOCE cruise P1W $END *LOCATION GEOGRAPHIC AREA : Sea of Okhotsk STATION : 5 EVENT NUMBER : 5 LATITUDE : 45 59.88000 N ! (deg min) LONGITUDE : 152 11.82000 E ! (deg min) WATER DEPTH : 3070 $REMARKS The Nesmeyanov sailed from Vladivostok to the beginning of Line P1W near Bussol Strait in the Kuril Islands. A complete section was sampled from this point, into the Sea of Okhotsk, ending near the town of Okhotsk in the NW corner of the sea. $END *INSTRUMENT TYPE : Guildline CTD MODEL : 8737 $REMARKS See details wrt various instruments in COMMENTS section $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- chem_cast_woce_9316_05.F 1.0 2003/03/07 15:21:11 23 23 HDREDIT2 2.0 2004/04/23 17:08:06 ? ? SORT 3.4.1 2004/04/23 17:09:03 23 23 CLEAN 4.6.1 2004/04/23 17:09:21 23 23 HDREDIT2 2.0 2004/05/05 14:52:43 ? ? HDREDIT2 2.0 2004/05/18 11:45:08 ? ? CHGUNITS 2.1 2004/05/25 10:47:57 23 23 CLEAN 4.6.2 2004/05/25 10:59:37 23 23 HDREDIT2 2.1 2004/05/28 09:23:36 ? ? CHANGE_FLAGS 1.0 2013/07/16 11:45:06 23 23 CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 14:41:29 23 23 CHANGE_FLAGS 2.0 2014/11/20 09:51:24 23 23 $END $REMARKS -The following SORT parameters were used. Sorted by channel: Pressure Pressure channel sorted according to values in sort channel CLEAN functions: - Reset #RECS, MIN & MAX values in header. - Delete Empty Channels: 0 deleted. -CHANGE units: 'Nitrate' changed from umol/kg to umol/L 'Silicate' changed from umol/kg to umol/L 'Phosphate' changed from umol/kg to umol/L 'Nitrite' changed from umol/kg to umol/L Lab temperature used for density calculation: 22.0 CLEAN functions: - Reset #RECS, MIN & MAX values in header. $END *COMMENTS C Contents: C Bottle Cast (Rosette) observations for water chemistry C Date and Time are taken from Bottom of Cast (BO) C Latitude and Longitude determined by GPS C C This was a Joint Russian (POI) and Canadian (IOS) Cruise C C Water Property Data includes: C CTD Pressure C CTD Sea Water Temp C CTD Salinity (+ data quality flag) C Bottle Salinity (+ data quality flag) C Oxygen:Dissolved (+ data quality flag) C Silicate (SiO4) (+ data quality flag) C Nitrate (NO3) (+ data quality flag) C Nitrite (NO2) (+ data quality flag) C Phosphate (PO4) (+ data quality flag) C CFC-11 (aka Freon-11) (+ data quality flag) C CFC-12 (aka Freon-12) (+ data quality flag) C Dissolved Inorganic Carbon (DIC) (aka TCO2) (+ data quality flag) C Total Alkalinity (+ data quality flag) C pH (acidity) (+ data quality flag) C Delta O18 (O18/O16 Isotope Ratio) (+ data quality flag) C C Sample collection methods: C Collection device was General Oceanics Rosette C with 24 10L Niskin bottles C and a Guildline 8737 CTD C Pressure C - Guildline 8737 CTD C Sea Water Temp (CTD) C - Guildline 8737 CTD C Salinity (CTD) C - Guildline 8737 CTD on 24 bottle General Oceanics Rosette C (10 L Niskin samplers) C Salinity (Bottle) C - Samples collected in glass bottles from Niskin Samplers C Oxygen:Dissolved C - Samples collected in glass bottles from Niskin Samplers C Silicate C - Samples collected in polystyrene tubes (16 x 125 mm) from Niskin btl C - Samples refrigerated between 0 and 20 hr before being analyzed. C Nitrate C - Samples collected in polystyrene tubes (16 x 125 mm) from Niskin btl C - Samples refrigerated between 0 and 20 hr before being analyzed. C Nitrite C - Samples collected in polystyrene tubes (16 x 125 mm) from Niskin btl C - Samples refrigerated between 0 and 20 hr before being analyzed. C Phosphate C - Samples collected in polystyrene tubes (16 x 125 mm) from Niskin btl C - Samples refrigerated between 0 and 20 hr before being analyzed. C CFC-11 C - Samples drawn in 100 ml glass syringes from Niskin Samplers C CFC-12 C - Samples drawn in 100 ml glass syringes from Niskin Samplers C Dissolved Inorganic Carbon (DIC) (aka TCO2) C - Samples collected in glass bottles from Niskin Samplers C Water was dispensed through Tygon tubing to bottom of sample bottles. C The bottles allowed to overflow at least 50% of the bottle volume. C Water poured off to create air head space approx 1% of bottle volume. C Add 200 uL saturated mercuric chloride solution per 250 mL of sample C TCO2 samples collected in 250 mL GS bottles. C Stoppers greased when taped in place. C All samples were stored at 4 deg C onboard ship and at IOS. C Total Alkalinity C - Samples collected in glass bottles from Niskin Samplers C (as descr by Dickson and Goyet (1991)) C Samples either analyzed immediately or C treated with 50 ul of mercuric chloride. C Alkalinity samples were collected in 500 mL screw cap bottles. C Caps were taped to prevent loosening. C All samples were stored at 4 deg C onboard ship and at IOS. C pH C - Water collected according to recommentations for oxygen C (Culberson, 1991), and measurements conducted immediately after C sampling. C Delta O18 (ie O18/O16 Isotope Ratio in seawater) C - Samples collected in 30 or 60 ml polyethylene bottles. C When possible samples were refrigerated (onboard and at IOS) C C Sample analysis methods: C Pressure C - Guildline 8737 CTD C - (CTD readings checked by digital pressure sensor) C Sea Water Temp C - Guildline 8737 CTD C (CTD readings checked by two pairs of reversing digital thermometers) C Salinity (CTD) C - Guildline 8737 CTD C (CTD readings standardized by bottle samples/Guildline 8410 Portasal) C Salinity (Bottle) C - analyzed onboard with a Guildline Model 8410 Portasal C The Portasal was standardized daily with IAPSO standard sea water. C Oxygen:Dissolved C - automated titration system (Brinkman Dosimat) using micro-Winkler C method (Carpenter, 1965) detected iodine end-point colorimetrically. C Standards prepared as outlined in WOCE Report 73/91. C Silicate C - analyzed using Technicon procedures C Nitrate C - analyzed using Technicon procedures C Nitrite C - analyzed using Technicon procedures C Phosphate C - analyzed using Technicon procedures C CFC-11 C - analyzed using Gas Chromatography, following procedure of Bullister C and Weiss (1987). All CFC equipment kept on aft deck of ship. C Make-shift laboratory was set up in a shipping container on aft deck. C Nesmeyanov was badly contaminated with CFC's with air concentrations C 2 to 4 times that of clean air (especially for CFC-12) C CFC-12 C - analyzed using Gas Chromatography, following procedure of Bullister C and Weiss (1987). All CFC equipment kept on aft deck of ship. C Make-shift laboratory was set up in a shipping container on aft deck. C Nesmeyanov was badly contaminated with CFC's with air concentrations C 2 to 4 times that of clean air (especially for CFC-12) C Dissolved Inorganic Carbon (DIC) C - by Coulometer (Coulometric Somma 5011) at IOS. C Total Alkalinity C - by Potentiometric Titration C Some samples analyzed immediately onboard. C Some samples shipped to IOS for analysis. C 25ml open cell (Methods ... 1978) using 0.02N HCl C Acid standardized daily with soln of Na2CO3 dissolved in deionized C water free of CO2. C Concentrations converted from volume units to mass units using C seawater density calc at temp of analysis (Millero & Poisson, 1981) C pH C - analyzed by direct potentiometry (Bates, 1973). C analysis done at 25 +/- 0.1 dec C with glass (OP-0718) and C calomel (OP-0830P) electrodes manufactured by Radelkis Co (Hungary) C Tris-seawater prepared using (Millero, 1986) as stnd before/after C each set. pH value of this buffer and Nernst slope of electrode C pair were controlled with Russian NBS commerical standards: C 6.86 (phosphate buffer) and 4.01 (phtalate buffer). C Delta O18 (ie O18/O16 Isotope Ratio in seawater) C - analysis by equilibrating 5 ml of sample with CO2 of known isotopic C composition. Samples were equilibrated for 15 hr at 20 deg C before C the gas was passed through a moisture trap, then fed into a Nuclide C Radio Mass Spectrometer. The O18/O16 isotope ratios are expressed C relative to the V-SMOW standard as Del O18. C Procedure described in (Paton, 1994). C C Bates, R.G., 1973. Determinatation of pH, theory and practice. C Wiley, N.Y., 368 pp C Bullister, J.L. and Weiss, R.F. (1987) C Determination of CC13F and CC12F2 in seawater and air. C Deep-Sea Research, Vol 25, No 5, 839-853. C Carpenter, J.H. 1965 C The Chesapeake Bay Inst technique for the Winkler Dissolved Oxygen Method. C Limnol. Oceanogr. 10: 141-143 C Culberson, C.H., 1991 Dissolved Oxygen. C WOCE Operations Manual. WHP Operations and Methods. WOCE Rpt 69/91: 1-15. C Dickson, A.G., Goyet, C., 1991. C Handbook of Methods for the Analysis of the Various Parameters of the C Carbon Dioxide System in Seawater. C DOE Publ., 89-7A, Version 1.0 C Millero, F.J., 1986. The pH of estuarine waters. C Limnol. Oceanogr. 31:839-847 C Millero, F.J., Poisson, A., 1981. C International one atmosphere equation of state for seawater. C Deep-Sea Res., 28:625-629 pp C Paton, D.W., Abehennah, W. Grieve and R.W. MacDonald, 1994 C Oxygen isotope data from water and ice cores from the Beaufort Sea. C Sept 1990, May 1991 and September 1991. C NOGAP B.6, Canadian Data Report of Hydrography and Ocean Sciences. No 134 C C !-1-- -2-- --3--- ---4---- ---5---- 6 ---7---- 8 --9-- - --11- - --13- - --15-- - --17-- - ---19-- - ---21-- - --23-- - --25-- - ---27--- - --29-- - !Samp Bott Pressu Temperat Salinity F Salinity F Oxyge F Silic F Nitra F Nitrit F Phosph F Chlorof F Chlorof F Carbon F Alkali F pH:SWS F Oxygen F !le_ le_ re ure l :Bottle l n: l ate l te l e l ate l luoroca l luoroca l :Disso l nity: l l : l !Numb Numb ~ ~ Disso ~ ~ ~ ~ ~ rbon_11 ~ rbon_12 ~ lved: ~ Total ~ ~ Isotop ~ !er er t l lved e t t t t 1 1 Inorga i a W e:18 1 ! y e d e e e e 1 2 nic c l S 8 !---- ---- ------ -------- -------- - -------- - ----- - ----- - ----- - ------ - ------ - ------- - ------- - ------ - ------ - -------- - ------ - *END OF HEADER 93 23 10.5 8.3960 32.8920 0 32.8864 0 309.3 0 17.4 0 10.0 0 0.21 0 -99.00 9 5.078 3 2.289 3 2026.7 0 2242.8 0 8.0580 0 -0.71 0 94 22 48.9 3.3260 33.1433 0 33.1368 0 298.1 0 43.1 0 23.3 0 0.32 0 -99.00 9 5.588 3 2.670 3 2127.1 0 2251.8 0 7.8480 0 -0.72 0 95 21 99.3 1.9970 33.2529 0 33.2376 0 285.7 0 54.7 0 28.3 0 0.10 0 -99.00 9 5.604 3 2.629 3 2158.0 0 2254.6 0 7.7700 0 -0.59 0 96 20 150.4 1.4010 33.3118 0 33.2991 0 267.8 0 61.5 0 30.8 0 -99.00 9 2.44 0 5.272 3 2.602 3 2171.9 0 2262.3 0 7.7260 0 -0.56 0 97 19 199.3 3.0920 33.6742 0 33.6566 0 119.9 0 85.4 0 39.4 0 -99.00 9 2.94 0 2.809 3 1.356 3 2264.7 0 2279.3 0 7.5440 0 -0.46 0 98 18 299.4 3.3420 33.8837 0 33.8708 0 59.6 0 99.5 0 42.5 0 -99.00 9 3.17 0 1.617 3 0.811 3 2310.0 0 2298.8 0 7.5030 0 -0.28 0 99 17 399.2 3.3570 34.0611 0 34.0495 0 33.1 0 -99.0 0 -99.0 0 -99.00 9 3.21 0 0.860 3 0.288 3 2335.6 0 2320.2 0 7.4760 0 -0.32 0 100 16 598.8 3.1910 34.2049 0 34.1930 0 23.9 0 130.1 0 43.7 0 -99.00 9 3.21 0 0.359 3 0.110 3 2358.0 0 2348.2 0 7.4780 0 -0.26 0 101 15 799.4 2.9490 34.3235 0 34.3114 0 20.6 0 143.3 0 44.3 0 -99.00 9 3.21 0 0.116 3 0.000 3 2364.9 0 2374.4 0 7.5100 0 -0.12 0 102 14 998.9 2.5690 34.3991 0 34.3856 0 31.9 0 -99.0 9 -99.0 9 -99.00 9 -99.00 9 0.111 3 0.000 3 2371.2 0 2379.9 0 7.5250 0 -0.23 0 103 13 999.7 2.5680 34.3989 0 34.3865 0 30.6 0 154.6 0 42.9 0 -99.00 9 3.17 0 0.118 3 0.000 3 2370.6 0 2380.8 0 7.5250 0 -0.11 0 104 12 1200.2 2.1910 34.4553 0 34.4415 0 52.8 0 162.5 0 42.1 0 -99.00 9 3.09 0 0.168 3 0.006 3 2367.9 0 2385.8 0 7.5500 0 -0.10 0 105 11 1400.4 2.1250 34.5002 0 34.4874 0 55.7 0 164.6 0 41.9 0 -99.00 9 3.08 0 0.088 3 0.001 3 2378.2 0 2397.4 0 7.5710 0 -0.19 0 106 10 1599.2 2.0160 34.5328 0 34.5186 0 64.6 0 166.5 0 41.5 0 -99.00 9 3.02 0 -99.000 9 -99.000 9 2368.9 0 2402.2 0 7.5860 0 -0.21 0 107 9 1800.8 1.9140 34.5669 0 34.5526 0 76.5 0 166.5 0 40.5 0 -99.00 9 2.97 0 -99.000 9 -99.000 9 2363.2 0 2407.1 0 7.6180 0 -0.14 0 108 8 2001.1 1.8660 34.5840 0 34.5714 0 82.1 0 166.5 0 40.4 0 0.00 0 2.95 0 0.007 3 0.002 3 2362.8 0 2411.0 0 7.6180 0 -0.29 0 109 7 2199.2 1.8000 34.6242 0 34.6099 0 89.8 0 166.3 0 39.8 0 0.00 0 2.97 0 -99.000 9 -99.000 9 2357.6 0 2412.1 0 7.6420 0 -0.12 0 110 6 2399.3 1.6930 34.6451 0 34.6305 0 103.5 0 164.6 0 39.4 0 0.00 0 2.90 0 -99.000 9 -99.000 9 2352.3 0 2417.0 0 7.6550 0 -0.21 0 111 5 2599.9 1.6230 34.6582 0 34.6428 0 113.4 0 162.2 0 37.9 0 0.00 0 2.86 0 -99.000 9 -99.000 9 2343.9 0 2417.0 0 7.6760 0 -0.03 0 112 4 2800.9 1.5510 34.6708 0 34.6544 0 124.5 0 160.1 0 38.1 0 0.00 0 2.81 0 -99.000 9 -99.000 9 2341.0 0 2417.0 0 7.6980 0 -0.11 0 115 1 3000.5 1.4970 34.6812 0 34.6622 0 134.1 0 162.9 0 37.7 0 0.00 0 2.77 0 0.000 3 0.056 3 2334.1 0 2418.1 0 7.7160 0 -0.12 0 114 2 3001.2 1.4960 34.6805 0 34.6632 0 134.3 0 158.9 0 37.2 0 0.00 0 2.75 0 -99.000 9 -99.000 9 2333.4 0 2418.1 0 7.7080 0 -0.08 0 113 3 3002.2 1.4960 34.6809 0 34.6644 0 133.0 0 158.2 0 37.6 0 0.00 0 2.75 0 -99.000 9 -99.000 9 2336.0 0 2418.1 0 7.7090 0 -0.16 0