*2014/11/20 09:51:22.01 *IOS HEADER VERSION 1.10 2011/10/26 2011/10/26 *FILE START TIME : UTC 1992/08/30 01:17:00.000 NUMBER OF RECORDS : 25 DATA DESCRIPTION : Bottle:Wire FILE TYPE : ASCII NUMBER OF CHANNELS : 20 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ------------------------------- --------- -------------- -------------- 1 Depth metres 0 4474 2 Sample_Number n/a 3 Temperature:Reversing 'deg C' 1.54 10.36 4 Salinity:Bottle ppt 32.769 34.68 5 Oxygen:Dissolved umol/kg 19.5 324.4 6 Nitrate_plus_Nitrite umol/L 13.3 45.1 7 Silicate umol/L 21.6 174.7 8 Calcium:Total mmol/kg 9.672 10.261 9 Carbon:Dissolved:Organic umol/L 74 128 10 pH:NBS n/a 7.452 8.028 11 pH:SWS n/a 7.301 7.878 12 Carbon:Dissolved:Inorganic umol/kg 2018.5 2385.5 13 Alkalinity:Total:Colorimetric umol/kg 2212 2423 14 Alkalinity:Total umol/kg 2218 2420 15 Flag:Alkalinity:Total n/a 16 Oxygen:Dissolved mL/L 0.45 7.46 17 Chlorofluorocarbon_11 pmol/kg 0.45E-01 6.155 18 Flag:Chlorofluorocarbon_11 n/a 19 Chlorofluorocarbon_12 pmol/kg 0.86E-01 2.894 20 Flag:Chlorofluorocarbon_12 n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 7 F R4 1 2 0 ' ' 6 NQ C ' ' 3 -99 ' ' 7 F R4 2 4 -99 ' ' 8 F R4 3 5 -99 ' ' 7 F R4 1 6 -99 ' ' 6 F R4 1 7 -99 ' ' 6 F R4 1 8 -99 ' ' 8 F R4 3 9 -99 ' ' 6 F R4 1 10 -99 ' ' 8 F R4 3 11 -99 ' ' 8 F R4 3 12 -99 ' ' 7 F R4 1 13 -99 ' ' 7 F R4 1 14 -99 ' ' 7 F R4 1 15 0 ' ' 2 NQ C ' ' 16 -99 ' ' 7 F ' ' 2 17 -99 ' ' ' ' F8.3 R4 ' ' 18 0 ' ' 2 NQ C ' ' 19 -99 ' ' ' ' F8.3 R4 ' ' 20 0 ' ' 2 NQ C ' ' $END $REMARKS Input data file used: ./inpoc-1992-9209-gems92-av23-03.dat06c Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (Flag 'b' also reported as ' ') 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- References: http://www.pacificinfo.ru/en/db/poi/?show=cruise&id=119 http://www.olympus.net/IAPSO/JointAssembly97/abstracts/ip5.html (IP5i) $END *ADMINISTRATION MISSION : 1992-09 AGENCY : POI,IOS PROJECT : COCC 9203, POI AV23 SCIENTIST : Bychkov A./ Wong C.S. PLATFORM : Ak. A. Vinogradov $REMARKS This is OSAP Cruise 1992-09 (IOS) Previously COCC Cruise 9203 (C.S.Wong) and Russian Cruise AV23 (POI) aka Cruise Gems92 (C.S.Wong) Chief Scientist for IOS: C.S.Wong (not aboard) Chief Scientist for POI: A.Bychkov Technicians (IOS): (from Cruise Plan & Field Notes) Ron Bellegay - (Party Chief) sample log sheets, deck log sheets, .. - FDSTAR deployments, Sediment trap recoveries, water Keith Johnson - DOC,DIC,TAlk,13-C,14-C,18-O supplies, equipment, - TCO2 analysis by coulometry Wendy Richardson - Freon supplies, equipment, analysis Janet Barwell-Clarke - Nutrient analysis, - Chlorophyll analysis, - Sediment traps, FDSTAR Magnus Eek - DOC analysis Technicians (POI): (from Field Notes) Gala - TCO2 (assisting Keith J.) Pavel - pCO2 - Freons (assisting Wendy R.) Ruslan - pH - Freons (assisting Wendy R.) Vika - Nutr (assisting Janet B-C.) Ludmilla - DOC (assisting Magnus E.) Yuri - Chla, POC filtration Nadia - Oxygen (2 methods: ROC & Winkler) Tamara - Talk (POI method) Andre - Talk (IOS method) Oleg - Sediment traps (assisting Ron & Janet) $END *LOCATION GEOGRAPHIC AREA : NW Pacific STATION : HS22 EVENT NUMBER : 20 LATITUDE : 51 24.00000 N ! (deg min) LONGITUDE : 165 16.50000 E ! (deg min) $REMARKS This was a joint Canada-Russia expedition aboard the Russian ship R/V R/V Akademik A. Vinogradov during August 1992, in the NW Pacific ocean. This cruise retraced Leg4 of the 1991 Cruise AV19 aboard Vinogradov. $END *INSTRUMENT TYPE : Bottle MODEL : Niskin (10 litre) $REMARKS See details wrt various instruments in COMMENTS section $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- chem_cast_gems_1992_01.F 1.1 2004/04/28 14:28:49 25 25 CLEAN 4.6.1 2004/04/28 14:24:14 25 25 HDREDIT2 2.0 2004/05/07 09:38:43 ? ? SORT 3.4.1 2004/05/07 09:44:54 25 25 REMOVECH 6.0 2004/05/07 09:46:49 25 25 CHGUNITS 1.4 2004/05/07 09:54:11 25 25 CLEAN 4.6.1 2004/05/07 09:54:55 25 25 MERGE 3.4 2012/11/23 14:07:38 25 25 HDREDIT2 2.5.1 2012/11/23 14:21:00 ? ? CHANGE_FLAGS 1.0 2013/07/16 11:45:03 25 25 CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 14:36:23 25 25 CHANGE_FLAGS 2.0 2014/11/20 09:51:22 25 25 $END $REMARKS CLEAN functions: - Reset #RECS, MIN & MAX values in header. - Set header Start and End times from the data. *FAILED* -The following SORT parameters were used. Sorted by channel: Depth -The following CHANNEL(S) were removed from file. CHANGE units: CLEAN functions: -The following MERGE parameters were used: 2012/11/23 14:07:38 2012/11/23 14:07:38 2012/11/23 14:07: Merge Channel: Depth Merge Scheme Used: Add Secondary to Primary Overlap Scheme Used: Keep Secondary Primary Channels to Include: ALL Secondary Channels to Include: Chlorofluorocarbon_11, Flag:Chlorofluorocarbon_11, Chlorofluorocarbon_12, Flag:Chlorofluorocarbon_12 Primary file : P:\John Pages Archive\1992-09\1992-09-0020.bot Secondary file: P:\John Pages Archive\1992-09\1992-09-0020.ios -HEADER EDITS: 2012/11/23 14:21:00 Applied edit header: O:\Data Processing\Header Comments\Work\Freons_no_corrections.txt $END *COMMENTS C Contents: C Bottle Cast (Niskin Bottles) observations for water chemistry C C Sample collection methods: C Collection device was C 10L PVC Niskin bottles (Canada) data as follows C and a Guildline CTD probe (Russia) see POI for data C http://www.pacificinfo.ru/en/db/poi/?show=cruise&id=119 C Depth C - corrected using reversing thermometer info C Sea Water Temp C - reversing thermometers C Salinity (CTD) C - Guildline AutoSal 8400 C Salinity (Bottle) C - Samples collected in glass bottles from Niskin Samplers C Oxygen:Dissolved C - Samples collected in glass bottles from Niskin Samplers C Phosphate C - Samples collected in 2 glass 16 x 12.5 mm test tubes. C Test tubes were twice rinsed with sample, then filled 2/3 and C stored at 4 C until analyzed. The samples were usually analyzed C within 12 hours of collection C Nitrate_plus_Nitrite C - Samples collected in 2 polystyrene 16 x 12.5 mm test tubes. C Test tubes were twice rinsed with sample, then filled 2/3 and C stored at 4 C until analyzed. The samples were usually analyzed C within 12 hours of collection C Silicate C - Samples collected in 2 polystyrene 16 x 12.5 mm test tubes. C Test tubes were twice rinsed with sample, then filled 2/3 and C stored at 4 C until analyzed. The samples were usually analyzed C within 12 hours of collection C Calcium:Total C - no information C Carbon:Dissolved:Organic C - glass ampoules, no further information C Chlorophyll:Extracted C - Samples drawn from 10L Niskin bottles into clean, volume calibrated C polyethylene bottles. The samples were filtered onto 24 mm diameter C Whatman GF/F filer (0.7 um nominal pore size) with vacuum pump C < 100 mm Hg. C ph:NBS C - no information C pH:SWS C - no information C Carbon:Isotope:13 C - Samples drawn from 10L Niskin bottles into 250ml glass bottles, C fixed with 200uL of saturated H2Cl2 solution - used ground glass C stoppers greased with Aprizon M and secured with tape/band. C Oxygen:Isotope:18 C - Samples drawn from 10L Niskin bottles into 30ml polyethylene C terephthalate copolyester bottles filled to base of neck, secured C with screw cap. No preservative. Samples allowed to come to C room temperature and screw caps tightened. Stored at room temp C until analyzed. C Carbon:Dissolved:Inorganic C - Samples collected in glass bottles from Niskin Samplers. C Mercuric Chloride added. C Alkalinity:Total:Colorimetric C - no information C Alkalinity:Total:Potentiometric C - Samples collected in glass bottles from Niskin Samplers. C Mercuric Chloride added. C C Sample analysis methods: C Depth C - computed from protected and unprotected thermometer readings C Sea Water Temp C - protected reversing thermometers C Salinity (Bottle) C - analyzed onboard with a Guildline Model 8400 Autosal C Oxygen:Dissolved C - IOS Oxygen was done by MicroWinkler method of Carpenter (1965) C with a starch end-point titration. C Phosphate C - A 3 channel Technicon Autoanalyzer II was used to measure Phosphate c Soluble orthophosphate was determined by C .. by Technicon Industrial Methods No.155-71). C Nitrate_plus_Nitrite C - A 3 channel Technicon Autoanalyzer II was used to measure Nitrate* C Soluble Nitrate was determined by C .. by Technicon Industrial Methods No.158-71W (revised Aug 1979) C .. and is a modification of procedure by Armstrong et al. (1967). C Silicate C - A 3 channel Technicon Autoanalyzer II was used to measure Nitrate* C Dissolved Silica was determined by C .. by Technicon Industrial Methods No.186-72W, C .. essentially that of Armstrong et al (1967). C C Nutrient Sample Analysis - more info - see separate Word Document C Calcium:Total C - potentiometric titration C Carbon:Dissolved:Organic C - spectrophotometric measurements C Chlorophyll:Extracted C - After filtering, the sample was analyzed immediately or frozen for C later analysis. When freezing, the folded filter was placed in a C cone made from a paper filter (eg Whatmon #1, 9mm diameter), C labelled, then placed in a large plastic jar with silica desiccant. C The flourometer was calibrated with a spectrophotometer using C 'fucus sp.' extracted in 90% acetone. C ph:NBS C - pH on NBS Scale, "pH was determined by glass (OP-0718P) and C calomel (OP-0830P) electrodes of 'Radelkis' firm. C The digital precision pH-meter 'Radelkis' (OP-208/1) was used. C Measurements werecarried out at 24 +/- 0.1C at once after hydrocast. C Electrodes were standardized in NBS-scale by phosphate buffer C (GOST 8,135-74) ph(25)=6.86 - Russian commercial standard. C pH:SWS C - pH on Sea Water Scale, "pH was determined by glass (OP-0718P) and C calomel (OP-0830P) electrodes of 'Radelkis' firm. C The digital precision pH-meter 'Radelkis' (OP-208/1) was used. C Measurements werecarried out at 24 +/- 0.1C at once after hydrocast. C Electrodes were standardized in SWS-scale by TRIS buffer prepared C according to the prescription of Table 6 (Millero,1986) C Refs: C 1. Millero F.J. (1986) C The pH of Estuarine Water C Limnol. Oceaogr. V31, N4, pp839-847 C 2. UNESCO technical paper in marine science (1987) V5, 21p C 3. Hansson I. (1973) C A new set of acidity constants for carbonic acid and boric acid C in seawater. C Deep-Sea Res., V20, N5, pp461-478 C 4. Letter (undated) from Pavel Ya.Tishchenko (POI) C to Frank Whitney (IOS) detailing analysis procedure for pH. C 5. Wong C.S., A. Andreev, A. Bychkov, F. Whitney, P. Tischenko C The linear relations between carbonate parameters, nutrients, C and temperature in the North-West Pacific sea surface layer C published ??, year ?? C Carbon:Isotope:13 C - CO2 extracted from seawater by NIWA Automated DIC Extraction system, C as per NIWA Seawater Line Manual (cryogenic vaccum removal). C C-13 samples analyzed by Nuclide Mass Spectrometer Procedure C (Forsland, 1994). C (technician = Valerie Forsland) C Oxygen:Isotope:18 C - CO2 extracted from seawater by reservoir equilibrator apparatus. C (D. MacDonald 1993). C Analyzed by Nuclide Mass Spectrometer Procedure (Forsland, 1994). C Carbon:Dissolved:Inorganic C - SOMMA-I Coulometer (Johnson et al., 1985,1987) C The accuracy was not less than 0.07 - 0.08%. C Alkalinity:Total:Colorimetric C - determined by POI using Bruevich's Method (1944), C which consists of direct colorimetric titration by HCl acid in an C open system. A mixed indicator (methylene blue and methylene red) C is used to visually determine the equivalence point (color changes C from geen to light pink). The titration is carried out under a C continuous flow of CO2 free air (or nitrogen gas). C The equivalence point is reached at approximately pH 5.4 - 5.5 . C The precision of the method is about 0.2% . C Alkalinity:Total:Potentiometric C - determined by IOS using potentiometric titration in a closed cell. C IOS Alkalinity Vol,Emf data acquired from Metrohm 636 Titroprocessor C using PC program 'GTITR215.BAS'. C IOS Alkalinity was computed using PC program 'TALKY123.BAS' C Duplicate samples are averaged - see flag "f" C C REFERENCES: C Carpenter, J.H. 1965 C The Chesapeake Bay Inst technique for Winkler Dissolved Oxygen Method. C Limnol. Oceanogr. 10: 141-143 C WOCE Report No. 73/91, 1991. C A comparison of methods for the determination of dissolved oxygen in C seawater. C WHPO Publication 91-2. Unpublished manuscript. C Analysis of Total Alkalinity using two methods: direct titration in C opened system. C (Bruevich) and potentiometric titration in closed system (Edmond) C by Galina Pavlova (POI), Wendy Richardson (IOS), W.Keith Johnson (IOS) C April 1993 C Comparison of three methods of determination of total alkalinity in C seawater. IOS internal paper (no author or date) C http://sam.ucsd.edu/onr_jes/talley/revelle_report.html C (some description of Bruevich Method) C Determination alkalinity of small volumes of seawater by direct titration. C In: Instruction of chemical investigation of seawater. C Bruevich C.V., 1944, Glavsevmorput, M.-L., 83p. C Alkalinity - According To C "Methods Of Hydrochemical Investigations Of The Ocean", C Moscow, Science, 1978. Method Of Bruevich. C Barwell-Clarke J., F. Whitney (1996) C Nutrient Methods and Analysis CFC-11 and CFC-12 were analyzed using Gas Chromatography, following procedure of Bullister and Weiss (1987). In their current form, they not meet the relaxed WOCE standard for CFC's. Therefore the CFC qulaity flags have been given a value of'3'(questionable). The results are in raw form with no corrections applied as stated in the report. For CFC methods refer to the "Centre for Ocean Climate Chemistry Freon Data Report" located in the cruise .DOC directory. . !--1--- --2-- --3--- ---4--- --5--- --6-- --7-- ---8--- --9-- ---10-- ---11-- --12-- --13-- --14-- - --16-- ---17-- - ---19-- - !Depth Sampl Temper Salinit Oxygen Nitra Silic Calcium Carbo pH:NBS pH:SWS Carbon Alkali Alkali F Oxygen Chlorof F Chlorof F ! e_ ature: y: : te_ ate :Total n:Dis :Disso nity: nity: l : luoroca l luoroca l ! Numbe Revers Bottle Dissol plus_ solve lved: Total: Total ~ Dissol rbon_11 ~ rbon_12 ~ ! r ing ved Nitri d:Org Inorga Colori a ved 1 1 ! te anic nic metric l 1 2 !------ ----- ------ ------- ------ ----- ----- ------- ----- ------- ------- ------ ------ ------ - ------ ------- - ------- - *END OF HEADER 0.0 2201 10.36 32.769 286.8 13.3 21.6 9.672 128.0 8.028 7.878 2018.5 2212.0 2218.0 0 6.59 4.397 3 2.468 3 50.0 2204 2.67 33.051 324.4 23.3 28.5 9.759 93.0 7.857 7.707 2102.8 2223.0 2231.0 0 7.46 6.155 3 2.894 3 100.0 2206 2.47 33.265 284.4 31.4 55.8 9.825 103.0 7.741 7.590 2157.7 2247.0 2240.0 6 6.54 -99.000 0 -99.000 0 150.0 2208 2.42 33.385 244.5 33.8 64.7 9.855 93.0 7.727 7.577 2186.0 2259.0 2257.0 6 5.62 4.364 3 2.153 3 200.0 2209 3.94 33.658 121.7 38.9 80.9 9.943 84.0 7.568 7.418 2252.9 2272.0 2270.5 6 2.80 2.495 3 1.340 3 300.0 2210 3.85 33.861 62.3 42.5 92.6 9.997 97.0 7.477 7.327 2299.8 2295.0 2290.0 6 1.43 1.545 3 0.859 3 400.0 2211 3.79 33.986 34.1 44.7 102.3 10.038 -99.0 7.453 7.303 2324.4 2311.0 2311.0 0 0.78 0.874 3 0.534 3 492.0 2212 3.65 34.077 25.3 45.1 112.0 10.067 92.0 7.452 7.301 2336.5 2319.0 2305.0 6 0.58 0.569 3 0.497 3 599.0 2213 3.51 34.160 20.4 45.1 120.5 10.102 -99.0 7.453 7.303 2348.1 2333.0 2330.0 6 0.47 0.302 3 0.238 3 700.0 2214 3.30 34.224 20.4 45.1 129.3 10.117 79.0 7.470 7.320 2356.4 2347.0 2341.5 6 0.47 -99.000 0 -99.000 0 795.0 2215 3.18 34.274 19.5 45.1 134.7 10.126 -99.0 7.474 7.323 2363.9 2357.0 2352.5 6 0.45 0.189 3 0.265 3 997.0 2216 2.90 34.357 19.5 44.7 146.1 10.146 85.0 7.479 7.328 2373.9 2373.0 2357.0 0 0.45 0.118 3 0.259 3 1199.0 2217 2.60 34.423 24.3 45.0 155.3 10.181 -99.0 7.497 7.347 2382.8 2382.0 2371.5 6 0.56 0.107 3 0.244 3 1392.0 2218 2.34 34.477 30.2 44.6 161.9 10.193 87.0 7.501 7.350 2385.5 2394.0 2379.0 0 0.70 0.075 3 0.167 3 1591.0 2219 2.24 34.523 39.9 44.0 167.6 10.209 -99.0 7.526 7.376 2384.2 2401.0 2388.0 0 0.92 0.062 3 0.166 3 1790.0 2220 2.06 34.554 50.6 43.1 170.3 10.234 -99.0 7.556 7.406 2381.7 2404.0 2397.0 6 1.16 -99.000 0 -99.000 0 1989.0 2221 1.95 34.587 64.2 42.4 174.7 10.236 79.0 7.573 7.423 2377.5 2413.0 2396.0 0 1.48 0.045 3 0.177 3 2237.0 2222 1.81 34.610 79.8 41.2 171.6 10.256 -99.0 7.599 7.448 2364.0 2418.0 2406.0 0 1.84 0.062 3 0.116 3 2486.0 2223 1.70 34.627 92.4 40.5 172.2 10.251 -99.0 7.617 7.467 2359.2 2418.0 2401.5 6 2.13 -99.000 0 -99.000 0 2734.0 2224 1.64 34.641 106.1 39.7 166.7 10.258 -99.0 7.648 7.497 2350.8 2420.0 2389.0 0 2.44 0.048 3 0.086 3 2982.0 2225 1.60 34.654 117.7 39.0 163.5 10.261 74.0 7.661 7.511 2343.3 2422.0 2420.0 6 2.71 0.051 3 0.133 3 3231.0 2226 1.57 34.660 126.5 38.2 161.0 10.261 -99.0 7.683 7.533 2338.0 2423.0 2417.5 6 2.91 -99.000 0 -99.000 0 3479.0 2227 1.54 34.668 -99.0 37.7 158.4 10.254 -99.0 7.692 7.541 2333.3 2423.0 2418.0 0 -99.00 -99.000 0 -99.000 0 3976.0 2228 1.54 34.678 144.0 37.3 155.3 10.253 77.0 7.710 7.560 2326.0 2421.0 2409.5 6 3.32 -99.000 0 -99.000 0 4474.0 2229 1.56 34.680 150.8 36.6 153.8 10.256 99.0 7.714 7.563 2319.9 2421.0 2414.0 0 3.47 -99.000 0 -99.000 0