*2014/11/20 09:51:21.55 *IOS HEADER VERSION 1.10 2011/10/26 2011/10/26 *FILE START TIME : UTC 1992/08/22 12:11:00.000 NUMBER OF RECORDS : 27 DATA DESCRIPTION : Bottle:Wire FILE TYPE : ASCII NUMBER OF CHANNELS : 17 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ------------------------------- --------- -------------- -------------- 1 Sample_Number n/a 2 Depth metres 0 3551 3 Temperature:Reversing 'deg C' 1.48 12.92 4 Salinity:Bottle ppt 33.075 34.671 5 Oxygen:Dissolved umol/kg 36 286.5 6 Nitrate_plus_Nitrite umol/L 8.9 44.1 7 Silicate umol/L 17.5 166.4 8 Calcium:Total mmol/kg 9.767 10.24 9 Carbon:Dissolved:Organic umol/L 76 138 10 Chlorophyll:Extracted mg/m^3 0.41E-01 1.651 11 pH:NBS n/a 7.497 8.062 12 pH:SWS n/a 7.347 7.912 13 Carbon:Dissolved:Inorganic umol/kg 2001.7 2381.8 14 Alkalinity:Total:Colorimetric umol/kg 2187 2423 15 Alkalinity:Total umol/kg 2201.5 2399.5 16 Flag:Alkalinity:Total n/a 17 Oxygen:Dissolved mL/L 0.83 6.59 $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 ' ' ' ' 6 NQ C ' ' 2 -99 ' ' 7 F R4 1 3 -99 ' ' 7 F R4 2 4 -99 ' ' 8 F R4 3 5 -99 ' ' 7 F R4 1 6 -99 ' ' 6 F R4 1 7 -99 ' ' 6 F R4 1 8 -99 ' ' 8 F R4 3 9 -99 ' ' 6 F R4 1 10 -99 ' ' 8 F R4 3 11 -99 ' ' 8 F R4 3 12 -99 ' ' 8 F R4 3 13 -99 ' ' 7 F R4 1 14 -99 ' ' 7 F R4 1 15 -99 ' ' 7 F R4 1 16 ' ' ' ' 2 NQ C ' ' 17 -99 ' ' 7 F ' ' 2 $END $REMARKS Input data file used: ./inpoc-1992-9209-gems92-av23-03.dat06c Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (Flag 'b' also reported as ' ') 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- References: http://www.pacificinfo.ru/en/db/poi/?show=cruise&id=119 http://www.olympus.net/IAPSO/JointAssembly97/abstracts/ip5.html (IP5i) $END *ADMINISTRATION MISSION : 1992-09 AGENCY : POI,IOS PROJECT : COCC 9203, POI AV23 SCIENTIST : Bychkov A./ Wong C.S. PLATFORM : Ak. A. Vinogradov $REMARKS This is OSAP Cruise 1992-09 (IOS) Previously COCC Cruise 9203 (C.S.Wong) and Russian Cruise AV23 (POI) aka Cruise Gems92 (C.S.Wong) Chief Scientist for IOS: C.S.Wong (not aboard) Chief Scientist for POI: A.Bychkov Technicians (IOS): (from Cruise Plan & Field Notes) Ron Bellegay - (Party Chief) sample log sheets, deck log sheets, .. - FDSTAR deployments, Sediment trap recoveries, water Keith Johnson - DOC,DIC,TAlk,13-C,14-C,18-O supplies, equipment, - TCO2 analysis by coulometry Wendy Richardson - Freon supplies, equipment, analysis Janet Barwell-Clarke - Nutrient analysis, - Chlorophyll analysis, - Sediment traps, FDSTAR Magnus Eek - DOC analysis Technicians (POI): (from Field Notes) Gala - TCO2 (assisting Keith J.) Pavel - pCO2 - Freons (assisting Wendy R.) Ruslan - pH - Freons (assisting Wendy R.) Vika - Nutr (assisting Janet B-C.) Ludmilla - DOC (assisting Magnus E.) Yuri - Chla, POC filtration Nadia - Oxygen (2 methods: ROC & Winkler) Tamara - Talk (POI method) Andre - Talk (IOS method) Oleg - Sediment traps (assisting Ron & Janet) $END *LOCATION GEOGRAPHIC AREA : NW Pacific STATION : HS16 EVENT NUMBER : 12 LATITUDE : 44 59.80000 N ! (deg min) LONGITUDE : 175 1.10000 E ! (deg min) $REMARKS This was a joint Canada-Russia expedition aboard the Russian ship R/V R/V Akademik A. Vinogradov during August 1992, in the NW Pacific ocean. This cruise retraced Leg4 of the 1991 Cruise AV19 aboard Vinogradov. $END *INSTRUMENT TYPE : Bottle MODEL : Niskin (10 litre) $REMARKS See details wrt various instruments in COMMENTS section $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- chem_cast_gems_1992_01.F 1.1 2004/04/28 14:28:44 27 27 CLEAN 4.6.1 2004/04/28 14:23:58 27 27 HDREDIT2 2.0 2004/05/07 09:38:42 ? ? SORT 3.4.1 2004/05/07 09:44:54 27 27 REMOVECH 6.0 2004/05/07 09:46:49 27 27 CHGUNITS 1.4 2004/05/07 09:54:11 27 27 CLEAN 4.6.1 2004/05/07 09:54:55 27 27 CHANGE_FLAGS 1.0 2013/07/16 11:45:02 27 27 CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 14:36:23 27 27 CHANGE_FLAGS 2.0 2014/11/20 09:51:21 27 27 $END $REMARKS CLEAN functions: - Reset #RECS, MIN & MAX values in header. - Set header Start and End times from the data. *FAILED* -The following SORT parameters were used. Sorted by channel: Depth -The following CHANNEL(S) were removed from file. CHANGE units: CLEAN functions: $END *COMMENTS C Contents: C Bottle Cast (Niskin Bottles) observations for water chemistry C C Sample collection methods: C Collection device was C 10L PVC Niskin bottles (Canada) data as follows C and a Guildline CTD probe (Russia) see POI for data C http://www.pacificinfo.ru/en/db/poi/?show=cruise&id=119 C Depth C - corrected using reversing thermometer info C Sea Water Temp C - reversing thermometers C Salinity (CTD) C - Guildline AutoSal 8400 C Salinity (Bottle) C - Samples collected in glass bottles from Niskin Samplers C Oxygen:Dissolved C - Samples collected in glass bottles from Niskin Samplers C Phosphate C - Samples collected in 2 glass 16 x 12.5 mm test tubes. C Test tubes were twice rinsed with sample, then filled 2/3 and C stored at 4 C until analyzed. The samples were usually analyzed C within 12 hours of collection C Nitrate_plus_Nitrite C - Samples collected in 2 polystyrene 16 x 12.5 mm test tubes. C Test tubes were twice rinsed with sample, then filled 2/3 and C stored at 4 C until analyzed. The samples were usually analyzed C within 12 hours of collection C Silicate C - Samples collected in 2 polystyrene 16 x 12.5 mm test tubes. C Test tubes were twice rinsed with sample, then filled 2/3 and C stored at 4 C until analyzed. The samples were usually analyzed C within 12 hours of collection C Calcium:Total C - no information C Carbon:Dissolved:Organic C - glass ampoules, no further information C Chlorophyll:Extracted C - Samples drawn from 10L Niskin bottles into clean, volume calibrated C polyethylene bottles. The samples were filtered onto 24 mm diameter C Whatman GF/F filer (0.7 um nominal pore size) with vacuum pump C < 100 mm Hg. C ph:NBS C - no information C pH:SWS C - no information C Carbon:Isotope:13 C - Samples drawn from 10L Niskin bottles into 250ml glass bottles, C fixed with 200uL of saturated H2Cl2 solution - used ground glass C stoppers greased with Aprizon M and secured with tape/band. C Oxygen:Isotope:18 C - Samples drawn from 10L Niskin bottles into 30ml polyethylene C terephthalate copolyester bottles filled to base of neck, secured C with screw cap. No preservative. Samples allowed to come to C room temperature and screw caps tightened. Stored at room temp C until analyzed. C Carbon:Dissolved:Inorganic C - Samples collected in glass bottles from Niskin Samplers. C Mercuric Chloride added. C Alkalinity:Total:Colorimetric C - no information C Alkalinity:Total:Potentiometric C - Samples collected in glass bottles from Niskin Samplers. C Mercuric Chloride added. C C Sample analysis methods: C Depth C - computed from protected and unprotected thermometer readings C Sea Water Temp C - protected reversing thermometers C Salinity (Bottle) C - analyzed onboard with a Guildline Model 8400 Autosal C Oxygen:Dissolved C - IOS Oxygen was done by MicroWinkler method of Carpenter (1965) C with a starch end-point titration. C Phosphate C - A 3 channel Technicon Autoanalyzer II was used to measure Phosphate c Soluble orthophosphate was determined by C .. by Technicon Industrial Methods No.155-71). C Nitrate_plus_Nitrite C - A 3 channel Technicon Autoanalyzer II was used to measure Nitrate* C Soluble Nitrate was determined by C .. by Technicon Industrial Methods No.158-71W (revised Aug 1979) C .. and is a modification of procedure by Armstrong et al. (1967). C Silicate C - A 3 channel Technicon Autoanalyzer II was used to measure Nitrate* C Dissolved Silica was determined by C .. by Technicon Industrial Methods No.186-72W, C .. essentially that of Armstrong et al (1967). C C Nutrient Sample Analysis - more info - see separate Word Document C Calcium:Total C - potentiometric titration C Carbon:Dissolved:Organic C - spectrophotometric measurements C Chlorophyll:Extracted C - After filtering, the sample was analyzed immediately or frozen for C later analysis. When freezing, the folded filter was placed in a C cone made from a paper filter (eg Whatmon #1, 9mm diameter), C labelled, then placed in a large plastic jar with silica desiccant. C The flourometer was calibrated with a spectrophotometer using C 'fucus sp.' extracted in 90% acetone. C ph:NBS C - pH on NBS Scale, "pH was determined by glass (OP-0718P) and C calomel (OP-0830P) electrodes of 'Radelkis' firm. C The digital precision pH-meter 'Radelkis' (OP-208/1) was used. C Measurements werecarried out at 24 +/- 0.1C at once after hydrocast. C Electrodes were standardized in NBS-scale by phosphate buffer C (GOST 8,135-74) ph(25)=6.86 - Russian commercial standard. C pH:SWS C - pH on Sea Water Scale, "pH was determined by glass (OP-0718P) and C calomel (OP-0830P) electrodes of 'Radelkis' firm. C The digital precision pH-meter 'Radelkis' (OP-208/1) was used. C Measurements werecarried out at 24 +/- 0.1C at once after hydrocast. C Electrodes were standardized in SWS-scale by TRIS buffer prepared C according to the prescription of Table 6 (Millero,1986) C Refs: C 1. Millero F.J. (1986) C The pH of Estuarine Water C Limnol. Oceaogr. V31, N4, pp839-847 C 2. UNESCO technical paper in marine science (1987) V5, 21p C 3. Hansson I. (1973) C A new set of acidity constants for carbonic acid and boric acid C in seawater. C Deep-Sea Res., V20, N5, pp461-478 C 4. Letter (undated) from Pavel Ya.Tishchenko (POI) C to Frank Whitney (IOS) detailing analysis procedure for pH. C 5. Wong C.S., A. Andreev, A. Bychkov, F. Whitney, P. Tischenko C The linear relations between carbonate parameters, nutrients, C and temperature in the North-West Pacific sea surface layer C published ??, year ?? C Carbon:Isotope:13 C - CO2 extracted from seawater by NIWA Automated DIC Extraction system, C as per NIWA Seawater Line Manual (cryogenic vaccum removal). C C-13 samples analyzed by Nuclide Mass Spectrometer Procedure C (Forsland, 1994). C (technician = Valerie Forsland) C Oxygen:Isotope:18 C - CO2 extracted from seawater by reservoir equilibrator apparatus. C (D. MacDonald 1993). C Analyzed by Nuclide Mass Spectrometer Procedure (Forsland, 1994). C Carbon:Dissolved:Inorganic C - SOMMA-I Coulometer (Johnson et al., 1985,1987) C The accuracy was not less than 0.07 - 0.08%. C Alkalinity:Total:Colorimetric C - determined by POI using Bruevich's Method (1944), C which consists of direct colorimetric titration by HCl acid in an C open system. A mixed indicator (methylene blue and methylene red) C is used to visually determine the equivalence point (color changes C from geen to light pink). The titration is carried out under a C continuous flow of CO2 free air (or nitrogen gas). C The equivalence point is reached at approximately pH 5.4 - 5.5 . C The precision of the method is about 0.2% . C Alkalinity:Total:Potentiometric C - determined by IOS using potentiometric titration in a closed cell. C IOS Alkalinity Vol,Emf data acquired from Metrohm 636 Titroprocessor C using PC program 'GTITR215.BAS'. C IOS Alkalinity was computed using PC program 'TALKY123.BAS' C Duplicate samples are averaged - see flag "f" C C REFERENCES: C Carpenter, J.H. 1965 C The Chesapeake Bay Inst technique for Winkler Dissolved Oxygen Method. C Limnol. Oceanogr. 10: 141-143 C WOCE Report No. 73/91, 1991. C A comparison of methods for the determination of dissolved oxygen in C seawater. C WHPO Publication 91-2. Unpublished manuscript. C Analysis of Total Alkalinity using two methods: direct titration in C opened system. C (Bruevich) and potentiometric titration in closed system (Edmond) C by Galina Pavlova (POI), Wendy Richardson (IOS), W.Keith Johnson (IOS) C April 1993 C Comparison of three methods of determination of total alkalinity in C seawater. IOS internal paper (no author or date) C http://sam.ucsd.edu/onr_jes/talley/revelle_report.html C (some description of Bruevich Method) C Determination alkalinity of small volumes of seawater by direct titration. C In: Instruction of chemical investigation of seawater. C Bruevich C.V., 1944, Glavsevmorput, M.-L., 83p. C Alkalinity - According To C "Methods Of Hydrochemical Investigations Of The Ocean", C Moscow, Science, 1978. Method Of Bruevich. C Barwell-Clarke J., F. Whitney (1996) C Nutrient Methods and Analysis !--1-- --2--- --3--- ---4--- --5--- --6-- --7-- ---8--- --9-- ---10-- ---11-- ---12-- --13-- --14-- --15-- - --17-- !Sampl Depth Temper Salinit Oxygen Nitra Silic Calcium Carbo Chlorop pH:NBS pH:SWS Carbon Alkali Alkali F Oxygen !e_ ature: y: : te_ ate :Total n:Dis hyll: :Disso nity: nity: l : !Numbe Revers Bottle Dissol plus_ solve Extract lved: Total: Total ~ Dissol !r ing ved Nitri d:Org ed Inorga Colori a ved ! te anic nic metric l !----- ------ ------ ------- ------ ----- ----- ------- ----- ------- ------- ------- ------ ------ ------ - ------ *END OF HEADER 1601 0.0 12.88 33.078 274.2 8.9 18.0 9.767 110.0 1.524 8.062 7.912 2001.7 2187.0 2201.5 6 6.30 1602 10.0 12.92 33.075 275.1 9.0 17.5 -99.000 -99.0 1.651 -99.000 -99.000 -99.0 -99.0 -99.0 5 6.32 1603 25.0 12.89 33.077 274.2 9.0 17.7 -99.000 -99.0 1.598 -99.000 -99.000 -99.0 -99.0 -99.0 5 6.30 1604 50.0 9.15 33.830 286.5 11.1 17.5 9.931 111.0 0.519 7.976 7.825 2064.1 2254.0 2222.0 0 6.59 1605 75.0 8.90 33.937 273.8 12.8 17.9 -99.000 -99.0 0.231 -99.000 -99.000 -99.0 -99.0 -99.0 5 6.29 1606 100.0 7.77 33.913 266.0 15.9 21.9 9.947 105.0 0.115 7.928 7.778 2095.0 2269.0 2239.0 0 6.12 1607 124.0 7.30 33.905 259.1 16.9 24.7 -99.000 -99.0 0.062 -99.000 -99.000 -99.0 -99.0 -99.0 5 5.96 1608 143.0 6.67 33.829 261.1 18.0 26.9 9.926 138.0 0.041 7.886 7.736 2108.9 2265.0 2231.0 6 6.00 1609 191.0 5.48 33.746 239.6 22.2 35.8 9.943 87.0 -99.000 7.824 7.673 2137.2 2260.0 2234.0 0 5.51 1610 286.0 4.44 33.825 153.9 32.2 64.3 9.952 109.0 -99.000 7.658 7.508 2221.6 2283.0 2265.0 0 3.54 1611 382.0 4.16 33.957 109.1 36.0 79.6 9.984 -99.0 -99.000 7.590 7.440 2258.8 2302.0 2283.0 0 2.51 1612 478.0 3.61 34.005 68.2 41.1 98.5 10.026 110.0 -99.000 7.511 7.360 2303.1 2317.0 2287.0 6 1.57 1613 573.0 3.53 34.132 51.6 41.5 109.8 10.057 -99.0 -99.000 7.509 7.359 2321.3 2339.0 2317.0 0 1.19 1614 750.0 3.41 34.267 40.9 43.0 126.0 10.103 90.0 -99.000 7.521 7.371 2341.8 2357.0 2327.0 0 0.94 1615 864.0 3.17 34.317 37.0 43.0 132.5 10.113 -99.0 -99.000 7.499 7.349 2350.7 2368.0 2333.0 6 0.85 1616 1063.0 2.78 34.388 37.0 43.2 144.9 10.138 87.0 -99.000 7.497 7.347 2376.1 2380.0 2352.0 0 0.85 1617 1263.0 2.59 34.452 36.0 44.1 153.4 10.163 -99.0 -99.000 7.509 7.359 2375.2 2391.0 2371.0 0 0.83 1618 1461.0 2.39 34.498 38.0 43.8 160.2 10.189 76.0 -99.000 7.518 7.367 2381.8 2389.0 2386.5 6 0.87 1619 1660.0 2.18 34.531 48.7 43.0 164.2 10.189 -99.0 -99.000 7.534 7.384 2377.0 2395.0 2378.0 6 1.12 1620 1860.0 2.03 34.588 60.3 43.1 166.1 10.194 -99.0 -99.000 7.562 7.411 2375.8 2407.0 2381.0 0 1.39 1621 2058.0 1.89 34.588 73.0 41.5 165.0 10.202 84.0 -99.000 7.592 7.442 2369.9 2411.0 2395.0 0 1.68 1622 2307.0 1.78 34.615 87.6 41.1 166.4 10.217 -99.0 -99.000 7.611 7.460 2363.3 2412.0 2385.0 0 2.02 1623 2556.0 1.71 34.634 104.1 40.1 164.2 10.240 -99.0 -99.000 7.636 7.486 2354.2 2419.0 2393.0 0 2.40 1624 2805.0 1.64 34.647 114.8 39.6 163.1 10.229 -99.0 -99.000 7.660 7.509 2347.1 2420.0 2391.0 0 2.64 1625 3054.0 1.55 34.657 124.5 38.7 161.0 10.240 85.0 -99.000 7.673 7.523 2342.7 2420.0 2391.0 0 2.87 1626 3302.0 1.51 34.667 134.3 37.9 158.0 10.231 -99.0 -99.000 7.682 7.531 2336.8 2420.0 2399.5 6 3.09 1627 3551.0 1.48 34.671 141.1 36.7 155.6 10.239 -99.0 -99.000 7.704 7.553 2333.9 2423.0 2392.0 0 3.25