*2014/11/20 09:51:21.12 *IOS HEADER VERSION 1.10 2011/10/26 2011/10/26 *FILE START TIME : UTC 1992/08/16 21:17:00.000 NUMBER OF RECORDS : 21 DATA DESCRIPTION : Bottle:Wire FILE TYPE : ASCII NUMBER OF CHANNELS : 17 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ------------------------------- --------- -------------- -------------- 1 Sample_Number n/a 2 Depth metres 0 2018 3 Temperature:Reversing 'deg C' 1.36 4.37 4 Salinity:Bottle ppt 32.944 34.553 5 Phosphate umol/L 1.53 3.06 6 Nitrate_plus_Nitrite umol/L 17.3 42.9 7 Silicate umol/L 34.4 171.3 8 Calcium:Total mmol/kg 9.705 10.222 9 Carbon:Dissolved:Organic umol/L 110 167 10 Chlorophyll:Extracted mg/m^3 0.151 1.589 11 pH:NBS n/a 7.55 7.884 12 pH:SWS n/a 7.399 7.734 13 Oxygen:Isotope:18 /mille -0.8544 -0.435E-01 14 Carbon:Dissolved:Inorganic umol/kg 2103 2364.7 15 Alkalinity:Total:Colorimetric umol/kg 2248 2414 16 Alkalinity:Total umol/kg 2221 2375 17 Flag:Alkalinity:Total n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 ' ' ' ' 6 NQ C ' ' 2 -99 ' ' 7 F R4 1 3 -99 ' ' 7 F R4 2 4 -99 ' ' 8 F R4 3 5 -99 ' ' 7 F R4 2 6 -99 ' ' 6 F R4 1 7 -99 ' ' 6 F R4 1 8 -99 ' ' 8 F R4 3 9 -99 ' ' 6 F R4 1 10 -99 ' ' 8 F R4 3 11 -99 ' ' 8 F R4 3 12 -99 ' ' 8 F R4 3 13 -99 ' ' 9 F R4 4 14 -99 ' ' 7 F R4 1 15 -99 ' ' 7 F R4 1 16 -99 ' ' 7 F R4 1 17 ' ' ' ' 2 NQ C ' ' $END $REMARKS Input data file used: ./inpoc-1992-9209-gems92-av23-03.dat06c Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (Flag 'b' also reported as ' ') 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- References: http://www.pacificinfo.ru/en/db/poi/?show=cruise&id=119 http://www.olympus.net/IAPSO/JointAssembly97/abstracts/ip5.html (IP5i) $END *ADMINISTRATION MISSION : 1992-09 AGENCY : POI,IOS PROJECT : COCC 9203, POI AV23 SCIENTIST : Bychkov A./ Wong C.S. PLATFORM : Ak. A. Vinogradov $REMARKS This is OSAP Cruise 1992-09 (IOS) Previously COCC Cruise 9203 (C.S.Wong) and Russian Cruise AV23 (POI) aka Cruise Gems92 (C.S.Wong) Chief Scientist for IOS: C.S.Wong (not aboard) Chief Scientist for POI: A.Bychkov Technicians (IOS): (from Cruise Plan & Field Notes) Ron Bellegay - (Party Chief) sample log sheets, deck log sheets, .. - FDSTAR deployments, Sediment trap recoveries, water Keith Johnson - DOC,DIC,TAlk,13-C,14-C,18-O supplies, equipment, - TCO2 analysis by coulometry Wendy Richardson - Freon supplies, equipment, analysis Janet Barwell-Clarke - Nutrient analysis, - Chlorophyll analysis, - Sediment traps, FDSTAR Magnus Eek - DOC analysis Technicians (POI): (from Field Notes) Gala - TCO2 (assisting Keith J.) Pavel - pCO2 - Freons (assisting Wendy R.) Ruslan - pH - Freons (assisting Wendy R.) Vika - Nutr (assisting Janet B-C.) Ludmilla - DOC (assisting Magnus E.) Yuri - Chla, POC filtration Nadia - Oxygen (2 methods: ROC & Winkler) Tamara - Talk (POI method) Andre - Talk (IOS method) Oleg - Sediment traps (assisting Ron & Janet) $END *LOCATION GEOGRAPHIC AREA : NW Pacific STATION : HS03 EVENT NUMBER : 3 LATITUDE : 46 31.10000 N ! (deg min) LONGITUDE : 151 35.50000 E ! (deg min) $REMARKS This was a joint Canada-Russia expedition aboard the Russian ship R/V R/V Akademik A. Vinogradov during August 1992, in the NW Pacific ocean. This cruise retraced Leg4 of the 1991 Cruise AV19 aboard Vinogradov. $END *INSTRUMENT TYPE : Bottle MODEL : Niskin (10 litre) $REMARKS See details wrt various instruments in COMMENTS section $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- chem_cast_gems_1992_01.F 1.1 2004/04/28 14:28:39 21 21 CLEAN 4.6.1 2004/04/28 14:23:39 21 21 HDREDIT2 2.0 2004/05/07 09:38:42 ? ? SORT 3.4.1 2004/05/07 09:44:53 21 21 REMOVECH 6.0 2004/05/07 09:46:48 21 21 CHGUNITS 1.4 2004/05/07 09:54:10 21 21 CLEAN 4.6.1 2004/05/07 09:54:54 21 21 CHANGE_FLAGS 1.0 2013/07/16 11:45:02 21 21 CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 14:36:23 21 21 CHANGE_FLAGS 2.0 2014/11/20 09:51:21 21 21 $END $REMARKS CLEAN functions: - Reset #RECS, MIN & MAX values in header. - Set header Start and End times from the data. *FAILED* -The following SORT parameters were used. Sorted by channel: Depth -No channels were removed. CHANGE units: CLEAN functions: $END *COMMENTS C Contents: C Bottle Cast (Niskin Bottles) observations for water chemistry C C Sample collection methods: C Collection device was C 10L PVC Niskin bottles (Canada) data as follows C and a Guildline CTD probe (Russia) see POI for data C http://www.pacificinfo.ru/en/db/poi/?show=cruise&id=119 C Depth C - corrected using reversing thermometer info C Sea Water Temp C - reversing thermometers C Salinity (CTD) C - Guildline AutoSal 8400 C Salinity (Bottle) C - Samples collected in glass bottles from Niskin Samplers C Oxygen:Dissolved C - Samples collected in glass bottles from Niskin Samplers C Phosphate C - Samples collected in 2 glass 16 x 12.5 mm test tubes. C Test tubes were twice rinsed with sample, then filled 2/3 and C stored at 4 C until analyzed. The samples were usually analyzed C within 12 hours of collection C Nitrate_plus_Nitrite C - Samples collected in 2 polystyrene 16 x 12.5 mm test tubes. C Test tubes were twice rinsed with sample, then filled 2/3 and C stored at 4 C until analyzed. The samples were usually analyzed C within 12 hours of collection C Silicate C - Samples collected in 2 polystyrene 16 x 12.5 mm test tubes. C Test tubes were twice rinsed with sample, then filled 2/3 and C stored at 4 C until analyzed. The samples were usually analyzed C within 12 hours of collection C Calcium:Total C - no information C Carbon:Dissolved:Organic C - glass ampoules, no further information C Chlorophyll:Extracted C - Samples drawn from 10L Niskin bottles into clean, volume calibrated C polyethylene bottles. The samples were filtered onto 24 mm diameter C Whatman GF/F filer (0.7 um nominal pore size) with vacuum pump C < 100 mm Hg. C ph:NBS C - no information C pH:SWS C - no information C Carbon:Isotope:13 C - Samples drawn from 10L Niskin bottles into 250ml glass bottles, C fixed with 200uL of saturated H2Cl2 solution - used ground glass C stoppers greased with Aprizon M and secured with tape/band. C Oxygen:Isotope:18 C - Samples drawn from 10L Niskin bottles into 30ml polyethylene C terephthalate copolyester bottles filled to base of neck, secured C with screw cap. No preservative. Samples allowed to come to C room temperature and screw caps tightened. Stored at room temp C until analyzed. C Carbon:Dissolved:Inorganic C - Samples collected in glass bottles from Niskin Samplers. C Mercuric Chloride added. C Alkalinity:Total:Colorimetric C - no information C Alkalinity:Total:Potentiometric C - Samples collected in glass bottles from Niskin Samplers. C Mercuric Chloride added. C C Sample analysis methods: C Depth C - computed from protected and unprotected thermometer readings C Sea Water Temp C - protected reversing thermometers C Salinity (Bottle) C - analyzed onboard with a Guildline Model 8400 Autosal C Oxygen:Dissolved C - IOS Oxygen was done by MicroWinkler method of Carpenter (1965) C with a starch end-point titration. C Phosphate C - A 3 channel Technicon Autoanalyzer II was used to measure Phosphate c Soluble orthophosphate was determined by C .. by Technicon Industrial Methods No.155-71). C Nitrate_plus_Nitrite C - A 3 channel Technicon Autoanalyzer II was used to measure Nitrate* C Soluble Nitrate was determined by C .. by Technicon Industrial Methods No.158-71W (revised Aug 1979) C .. and is a modification of procedure by Armstrong et al. (1967). C Silicate C - A 3 channel Technicon Autoanalyzer II was used to measure Nitrate* C Dissolved Silica was determined by C .. by Technicon Industrial Methods No.186-72W, C .. essentially that of Armstrong et al (1967). C C Nutrient Sample Analysis - more info - see separate Word Document C Calcium:Total C - potentiometric titration C Carbon:Dissolved:Organic C - spectrophotometric measurements C Chlorophyll:Extracted C - After filtering, the sample was analyzed immediately or frozen for C later analysis. When freezing, the folded filter was placed in a C cone made from a paper filter (eg Whatmon #1, 9mm diameter), C labelled, then placed in a large plastic jar with silica desiccant. C The flourometer was calibrated with a spectrophotometer using C 'fucus sp.' extracted in 90% acetone. C ph:NBS C - pH on NBS Scale, "pH was determined by glass (OP-0718P) and C calomel (OP-0830P) electrodes of 'Radelkis' firm. C The digital precision pH-meter 'Radelkis' (OP-208/1) was used. C Measurements werecarried out at 24 +/- 0.1C at once after hydrocast. C Electrodes were standardized in NBS-scale by phosphate buffer C (GOST 8,135-74) ph(25)=6.86 - Russian commercial standard. C pH:SWS C - pH on Sea Water Scale, "pH was determined by glass (OP-0718P) and C calomel (OP-0830P) electrodes of 'Radelkis' firm. C The digital precision pH-meter 'Radelkis' (OP-208/1) was used. C Measurements werecarried out at 24 +/- 0.1C at once after hydrocast. C Electrodes were standardized in SWS-scale by TRIS buffer prepared C according to the prescription of Table 6 (Millero,1986) C Refs: C 1. Millero F.J. (1986) C The pH of Estuarine Water C Limnol. Oceaogr. V31, N4, pp839-847 C 2. UNESCO technical paper in marine science (1987) V5, 21p C 3. Hansson I. (1973) C A new set of acidity constants for carbonic acid and boric acid C in seawater. C Deep-Sea Res., V20, N5, pp461-478 C 4. Letter (undated) from Pavel Ya.Tishchenko (POI) C to Frank Whitney (IOS) detailing analysis procedure for pH. C 5. Wong C.S., A. Andreev, A. Bychkov, F. Whitney, P. Tischenko C The linear relations between carbonate parameters, nutrients, C and temperature in the North-West Pacific sea surface layer C published ??, year ?? C Carbon:Isotope:13 C - CO2 extracted from seawater by NIWA Automated DIC Extraction system, C as per NIWA Seawater Line Manual (cryogenic vaccum removal). C C-13 samples analyzed by Nuclide Mass Spectrometer Procedure C (Forsland, 1994). C (technician = Valerie Forsland) C Oxygen:Isotope:18 C - CO2 extracted from seawater by reservoir equilibrator apparatus. C (D. MacDonald 1993). C Analyzed by Nuclide Mass Spectrometer Procedure (Forsland, 1994). C Carbon:Dissolved:Inorganic C - SOMMA-I Coulometer (Johnson et al., 1985,1987) C The accuracy was not less than 0.07 - 0.08%. C Alkalinity:Total:Colorimetric C - determined by POI using Bruevich's Method (1944), C which consists of direct colorimetric titration by HCl acid in an C open system. A mixed indicator (methylene blue and methylene red) C is used to visually determine the equivalence point (color changes C from geen to light pink). The titration is carried out under a C continuous flow of CO2 free air (or nitrogen gas). C The equivalence point is reached at approximately pH 5.4 - 5.5 . C The precision of the method is about 0.2% . C Alkalinity:Total:Potentiometric C - determined by IOS using potentiometric titration in a closed cell. C IOS Alkalinity Vol,Emf data acquired from Metrohm 636 Titroprocessor C using PC program 'GTITR215.BAS'. C IOS Alkalinity was computed using PC program 'TALKY123.BAS' C Duplicate samples are averaged - see flag "f" C C REFERENCES: C Carpenter, J.H. 1965 C The Chesapeake Bay Inst technique for Winkler Dissolved Oxygen Method. C Limnol. Oceanogr. 10: 141-143 C WOCE Report No. 73/91, 1991. C A comparison of methods for the determination of dissolved oxygen in C seawater. C WHPO Publication 91-2. Unpublished manuscript. C Analysis of Total Alkalinity using two methods: direct titration in C opened system. C (Bruevich) and potentiometric titration in closed system (Edmond) C by Galina Pavlova (POI), Wendy Richardson (IOS), W.Keith Johnson (IOS) C April 1993 C Comparison of three methods of determination of total alkalinity in C seawater. IOS internal paper (no author or date) C http://sam.ucsd.edu/onr_jes/talley/revelle_report.html C (some description of Bruevich Method) C Determination alkalinity of small volumes of seawater by direct titration. C In: Instruction of chemical investigation of seawater. C Bruevich C.V., 1944, Glavsevmorput, M.-L., 83p. C Alkalinity - According To C "Methods Of Hydrochemical Investigations Of The Ocean", C Moscow, Science, 1978. Method Of Bruevich. C Barwell-Clarke J., F. Whitney (1996) C Nutrient Methods and Analysis !--1-- --2--- --3--- ---4--- --5--- --6-- --7-- ---8--- --9-- ---10-- ---11-- ---12-- ---13--- --14-- --15-- --16-- - !Sampl Depth Temper Salinit Phosph Nitra Silic Calcium Carbo Chlorop pH:NBS pH:SWS Oxygen: Carbon Alkali Alkali F !e_ ature: y: ate te_ ate :Total n:Dis hyll: Isotope: :Disso nity: nity: l !Numbe Revers Bottle plus_ solve Extract 18 lved: Total: Total ~ !r ing Nitri d:Org ed Inorga Colori a ! te anic nic metric l !----- ------ ------ ------- ------ ----- ----- ------- ----- ------- ------- ------- -------- ------ ------ ------ - *END OF HEADER 301 0.0 4.37 32.944 1.53 17.3 34.4 9.715 138.0 1.394 7.884 7.734 -0.8051 2103.0 2248.0 2221.0 0 302 10.0 4.14 32.964 1.55 17.9 35.3 9.705 -99.0 1.589 7.876 7.726 -0.8544 2108.8 2252.0 -99.0 5 303 25.0 3.45 33.041 1.69 19.7 40.5 9.737 -99.0 1.374 7.846 7.695 -0.6645 2125.2 2254.0 -99.0 5 304 50.0 2.88 33.127 1.83 22.0 44.8 9.764 144.0 1.087 7.812 7.661 -0.7240 2140.1 2260.0 2227.5 6 305 75.0 2.34 33.202 1.94 24.2 49.8 9.774 -99.0 0.616 7.778 7.628 -0.6173 2155.2 2262.0 -99.0 5 306 100.0 2.01 33.237 2.03 25.2 52.6 9.813 156.0 0.310 7.753 7.602 -0.6696 2168.4 2266.0 2234.0 0 307 126.0 1.69 33.291 2.13 27.1 56.9 9.832 -99.0 0.221 7.731 7.580 -0.5711 2179.6 2268.0 -99.0 5 308 152.0 1.66 33.293 2.14 27.3 56.5 9.802 167.0 0.151 7.724 7.573 -0.5372 2181.1 2268.0 2233.0 0 309 201.0 1.59 33.297 2.14 27.8 57.2 9.825 134.0 -99.000 7.758 7.607 -0.5362 2185.3 2270.0 2235.0 6 310 302.0 1.43 33.353 2.23 28.8 61.1 9.837 132.0 -99.000 7.707 7.557 -0.6511 2192.6 2278.0 2241.0 0 311 403.0 1.43 33.449 2.40 31.7 70.3 9.866 -99.0 -99.000 7.660 7.509 -0.5526 2213.9 2282.0 2245.0 0 312 504.0 1.36 33.560 2.55 33.9 80.3 9.915 133.0 -99.000 7.619 7.469 -0.4366 2236.9 2288.0 2258.0 0 313 605.0 1.80 33.848 2.78 37.6 108.9 9.985 -99.0 -99.000 7.572 7.421 -0.3648 2285.5 2324.0 2285.0 0 314 706.0 2.02 33.968 2.83 38.8 119.8 10.032 146.0 -99.000 7.565 7.415 -0.2642 2307.1 2340.0 2302.0 6 315 807.0 2.02 34.039 2.90 39.7 127.5 10.061 -99.0 -99.000 7.556 7.406 -0.3463 2314.1 2354.0 2314.0 0 316 1009.0 2.11 34.233 2.98 41.3 145.2 10.117 110.0 -99.000 7.558 7.408 -0.1615 2339.8 2373.0 2334.0 0 317 1210.0 2.15 34.348 3.01 41.9 157.5 10.167 -99.0 -99.000 7.550 7.399 -0.1728 2358.2 2389.0 2350.0 0 318 1412.0 2.09 34.443 3.05 42.4 163.7 10.185 117.0 -99.000 7.563 7.413 -0.2611 2360.5 2402.0 2363.0 0 319 1615.0 2.07 34.487 3.06 42.9 166.7 10.222 -99.0 -99.000 7.572 7.421 -0.0435 2364.0 2410.0 2366.5 6 320 1817.0 2.01 34.514 3.06 42.7 168.6 10.217 -99.0 -99.000 7.592 7.442 -0.1348 2364.7 2409.0 2375.0 0 321 2018.0 1.93 34.553 3.01 42.3 171.3 10.218 120.0 -99.000 7.597 7.447 -0.1605 2363.9 2414.0 2372.0 0