*2014/11/20 09:51:21.05 *IOS HEADER VERSION 1.10 2011/10/26 2011/10/26 *FILE START TIME : UTC 1992/08/16 12:06:00.000 NUMBER OF RECORDS : 25 DATA DESCRIPTION : Bottle:Wire FILE TYPE : ASCII NUMBER OF CHANNELS : 19 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ------------------------------- --------- -------------- -------------- 1 Sample_Number n/a 2 Depth metres 0 2992 3 Temperature:Reversing 'deg C' 1.3 4.75 4 Salinity:Bottle ppt 32.923 34.604 5 Oxygen:Dissolved umol/kg 51.6 301.2 6 Phosphate umol/L 1.5 3.13 7 Nitrate_plus_Nitrite umol/L 16.3 43 8 Silicate umol/L 31.3 175 9 Calcium:Total mmol/kg 9.679 10.244 10 Carbon:Dissolved:Organic umol/L 104 254 11 Chlorophyll:Extracted mg/m^3 0.85E-01 1.524 12 pH:NBS n/a 7.533 7.898 13 pH:SWS n/a 7.382 7.748 14 Oxygen:Isotope:18 /mille -0.7784 -0.3104 15 Carbon:Dissolved:Inorganic umol/kg 2093.8 2367.3 16 Alkalinity:Total:Colorimetric umol/kg 2200 2428 17 Alkalinity:Total umol/kg 2215.5 2385 18 Flag:Alkalinity:Total n/a 19 Oxygen:Dissolved mL/L 1.19 6.92 $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 ' ' ' ' 6 NQ C ' ' 2 -99 ' ' 7 F R4 1 3 -99 ' ' 7 F R4 2 4 -99 ' ' 8 F R4 3 5 -99 ' ' 7 F R4 1 6 -99 ' ' 7 F R4 2 7 -99 ' ' 6 F R4 1 8 -99 ' ' 6 F R4 1 9 -99 ' ' 8 F R4 3 10 -99 ' ' 6 F R4 1 11 -99 ' ' 8 F R4 3 12 -99 ' ' 8 F R4 3 13 -99 ' ' 8 F R4 3 14 -99 ' ' 9 F R4 4 15 -99 ' ' 7 F R4 1 16 -99 ' ' 7 F R4 1 17 -99 ' ' 7 F R4 1 18 ' ' ' ' 2 NQ C ' ' 19 -99 ' ' 7 F ' ' 2 $END $REMARKS Input data file used: ./inpoc-1992-9209-gems92-av23-03.dat06c Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (Flag 'b' also reported as ' ') 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- References: http://www.pacificinfo.ru/en/db/poi/?show=cruise&id=119 http://www.olympus.net/IAPSO/JointAssembly97/abstracts/ip5.html (IP5i) $END *ADMINISTRATION MISSION : 1992-09 AGENCY : POI,IOS PROJECT : COCC 9203, POI AV23 SCIENTIST : Bychkov A./ Wong C.S. PLATFORM : Ak. A. Vinogradov $REMARKS This is OSAP Cruise 1992-09 (IOS) Previously COCC Cruise 9203 (C.S.Wong) and Russian Cruise AV23 (POI) aka Cruise Gems92 (C.S.Wong) Chief Scientist for IOS: C.S.Wong (not aboard) Chief Scientist for POI: A.Bychkov Technicians (IOS): (from Cruise Plan & Field Notes) Ron Bellegay - (Party Chief) sample log sheets, deck log sheets, .. - FDSTAR deployments, Sediment trap recoveries, water Keith Johnson - DOC,DIC,TAlk,13-C,14-C,18-O supplies, equipment, - TCO2 analysis by coulometry Wendy Richardson - Freon supplies, equipment, analysis Janet Barwell-Clarke - Nutrient analysis, - Chlorophyll analysis, - Sediment traps, FDSTAR Magnus Eek - DOC analysis Technicians (POI): (from Field Notes) Gala - TCO2 (assisting Keith J.) Pavel - pCO2 - Freons (assisting Wendy R.) Ruslan - pH - Freons (assisting Wendy R.) Vika - Nutr (assisting Janet B-C.) Ludmilla - DOC (assisting Magnus E.) Yuri - Chla, POC filtration Nadia - Oxygen (2 methods: ROC & Winkler) Tamara - Talk (POI method) Andre - Talk (IOS method) Oleg - Sediment traps (assisting Ron & Janet) $END *LOCATION GEOGRAPHIC AREA : NW Pacific STATION : HS02 EVENT NUMBER : 2 LATITUDE : 46 58.40000 N ! (deg min) LONGITUDE : 150 58.20000 E ! (deg min) $REMARKS This was a joint Canada-Russia expedition aboard the Russian ship R/V R/V Akademik A. Vinogradov during August 1992, in the NW Pacific ocean. This cruise retraced Leg4 of the 1991 Cruise AV19 aboard Vinogradov. $END *INSTRUMENT TYPE : Bottle MODEL : Niskin (10 litre) $REMARKS See details wrt various instruments in COMMENTS section $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- chem_cast_gems_1992_01.F 1.1 2004/04/28 14:28:39 25 25 CLEAN 4.6.1 2004/04/28 14:23:37 25 25 HDREDIT2 2.0 2004/05/07 09:38:41 ? ? SORT 3.4.1 2004/05/07 09:44:53 25 25 REMOVECH 6.0 2004/05/07 09:46:48 25 25 CHGUNITS 1.4 2004/05/07 09:54:10 25 25 CLEAN 4.6.1 2004/05/07 09:54:54 25 25 CHANGE_FLAGS 1.0 2013/07/16 11:45:03 25 25 CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 14:36:22 25 25 CHANGE_FLAGS 2.0 2014/11/20 09:51:21 25 25 $END $REMARKS CLEAN functions: - Reset #RECS, MIN & MAX values in header. - Set header Start and End times from the data. *FAILED* -The following SORT parameters were used. Sorted by channel: Depth -The following CHANNEL(S) were removed from file. CHANGE units: CLEAN functions: $END *COMMENTS C Contents: C Bottle Cast (Niskin Bottles) observations for water chemistry C C Sample collection methods: C Collection device was C 10L PVC Niskin bottles (Canada) data as follows C and a Guildline CTD probe (Russia) see POI for data C http://www.pacificinfo.ru/en/db/poi/?show=cruise&id=119 C Depth C - corrected using reversing thermometer info C Sea Water Temp C - reversing thermometers C Salinity (CTD) C - Guildline AutoSal 8400 C Salinity (Bottle) C - Samples collected in glass bottles from Niskin Samplers C Oxygen:Dissolved C - Samples collected in glass bottles from Niskin Samplers C Phosphate C - Samples collected in 2 glass 16 x 12.5 mm test tubes. C Test tubes were twice rinsed with sample, then filled 2/3 and C stored at 4 C until analyzed. The samples were usually analyzed C within 12 hours of collection C Nitrate_plus_Nitrite C - Samples collected in 2 polystyrene 16 x 12.5 mm test tubes. C Test tubes were twice rinsed with sample, then filled 2/3 and C stored at 4 C until analyzed. The samples were usually analyzed C within 12 hours of collection C Silicate C - Samples collected in 2 polystyrene 16 x 12.5 mm test tubes. C Test tubes were twice rinsed with sample, then filled 2/3 and C stored at 4 C until analyzed. The samples were usually analyzed C within 12 hours of collection C Calcium:Total C - no information C Carbon:Dissolved:Organic C - glass ampoules, no further information C Chlorophyll:Extracted C - Samples drawn from 10L Niskin bottles into clean, volume calibrated C polyethylene bottles. The samples were filtered onto 24 mm diameter C Whatman GF/F filer (0.7 um nominal pore size) with vacuum pump C < 100 mm Hg. C ph:NBS C - no information C pH:SWS C - no information C Carbon:Isotope:13 C - Samples drawn from 10L Niskin bottles into 250ml glass bottles, C fixed with 200uL of saturated H2Cl2 solution - used ground glass C stoppers greased with Aprizon M and secured with tape/band. C Oxygen:Isotope:18 C - Samples drawn from 10L Niskin bottles into 30ml polyethylene C terephthalate copolyester bottles filled to base of neck, secured C with screw cap. No preservative. Samples allowed to come to C room temperature and screw caps tightened. Stored at room temp C until analyzed. C Carbon:Dissolved:Inorganic C - Samples collected in glass bottles from Niskin Samplers. C Mercuric Chloride added. C Alkalinity:Total:Colorimetric C - no information C Alkalinity:Total:Potentiometric C - Samples collected in glass bottles from Niskin Samplers. C Mercuric Chloride added. C C Sample analysis methods: C Depth C - computed from protected and unprotected thermometer readings C Sea Water Temp C - protected reversing thermometers C Salinity (Bottle) C - analyzed onboard with a Guildline Model 8400 Autosal C Oxygen:Dissolved C - IOS Oxygen was done by MicroWinkler method of Carpenter (1965) C with a starch end-point titration. C Phosphate C - A 3 channel Technicon Autoanalyzer II was used to measure Phosphate c Soluble orthophosphate was determined by C .. by Technicon Industrial Methods No.155-71). C Nitrate_plus_Nitrite C - A 3 channel Technicon Autoanalyzer II was used to measure Nitrate* C Soluble Nitrate was determined by C .. by Technicon Industrial Methods No.158-71W (revised Aug 1979) C .. and is a modification of procedure by Armstrong et al. (1967). C Silicate C - A 3 channel Technicon Autoanalyzer II was used to measure Nitrate* C Dissolved Silica was determined by C .. by Technicon Industrial Methods No.186-72W, C .. essentially that of Armstrong et al (1967). C C Nutrient Sample Analysis - more info - see separate Word Document C Calcium:Total C - potentiometric titration C Carbon:Dissolved:Organic C - spectrophotometric measurements C Chlorophyll:Extracted C - After filtering, the sample was analyzed immediately or frozen for C later analysis. When freezing, the folded filter was placed in a C cone made from a paper filter (eg Whatmon #1, 9mm diameter), C labelled, then placed in a large plastic jar with silica desiccant. C The flourometer was calibrated with a spectrophotometer using C 'fucus sp.' extracted in 90% acetone. C ph:NBS C - pH on NBS Scale, "pH was determined by glass (OP-0718P) and C calomel (OP-0830P) electrodes of 'Radelkis' firm. C The digital precision pH-meter 'Radelkis' (OP-208/1) was used. C Measurements werecarried out at 24 +/- 0.1C at once after hydrocast. C Electrodes were standardized in NBS-scale by phosphate buffer C (GOST 8,135-74) ph(25)=6.86 - Russian commercial standard. C pH:SWS C - pH on Sea Water Scale, "pH was determined by glass (OP-0718P) and C calomel (OP-0830P) electrodes of 'Radelkis' firm. C The digital precision pH-meter 'Radelkis' (OP-208/1) was used. C Measurements werecarried out at 24 +/- 0.1C at once after hydrocast. C Electrodes were standardized in SWS-scale by TRIS buffer prepared C according to the prescription of Table 6 (Millero,1986) C Refs: C 1. Millero F.J. (1986) C The pH of Estuarine Water C Limnol. Oceaogr. V31, N4, pp839-847 C 2. UNESCO technical paper in marine science (1987) V5, 21p C 3. Hansson I. (1973) C A new set of acidity constants for carbonic acid and boric acid C in seawater. C Deep-Sea Res., V20, N5, pp461-478 C 4. Letter (undated) from Pavel Ya.Tishchenko (POI) C to Frank Whitney (IOS) detailing analysis procedure for pH. C 5. Wong C.S., A. Andreev, A. Bychkov, F. Whitney, P. Tischenko C The linear relations between carbonate parameters, nutrients, C and temperature in the North-West Pacific sea surface layer C published ??, year ?? C Carbon:Isotope:13 C - CO2 extracted from seawater by NIWA Automated DIC Extraction system, C as per NIWA Seawater Line Manual (cryogenic vaccum removal). C C-13 samples analyzed by Nuclide Mass Spectrometer Procedure C (Forsland, 1994). C (technician = Valerie Forsland) C Oxygen:Isotope:18 C - CO2 extracted from seawater by reservoir equilibrator apparatus. C (D. MacDonald 1993). C Analyzed by Nuclide Mass Spectrometer Procedure (Forsland, 1994). C Carbon:Dissolved:Inorganic C - SOMMA-I Coulometer (Johnson et al., 1985,1987) C The accuracy was not less than 0.07 - 0.08%. C Alkalinity:Total:Colorimetric C - determined by POI using Bruevich's Method (1944), C which consists of direct colorimetric titration by HCl acid in an C open system. A mixed indicator (methylene blue and methylene red) C is used to visually determine the equivalence point (color changes C from geen to light pink). The titration is carried out under a C continuous flow of CO2 free air (or nitrogen gas). C The equivalence point is reached at approximately pH 5.4 - 5.5 . C The precision of the method is about 0.2% . C Alkalinity:Total:Potentiometric C - determined by IOS using potentiometric titration in a closed cell. C IOS Alkalinity Vol,Emf data acquired from Metrohm 636 Titroprocessor C using PC program 'GTITR215.BAS'. C IOS Alkalinity was computed using PC program 'TALKY123.BAS' C Duplicate samples are averaged - see flag "f" C C REFERENCES: C Carpenter, J.H. 1965 C The Chesapeake Bay Inst technique for Winkler Dissolved Oxygen Method. C Limnol. Oceanogr. 10: 141-143 C WOCE Report No. 73/91, 1991. C A comparison of methods for the determination of dissolved oxygen in C seawater. C WHPO Publication 91-2. Unpublished manuscript. C Analysis of Total Alkalinity using two methods: direct titration in C opened system. C (Bruevich) and potentiometric titration in closed system (Edmond) C by Galina Pavlova (POI), Wendy Richardson (IOS), W.Keith Johnson (IOS) C April 1993 C Comparison of three methods of determination of total alkalinity in C seawater. IOS internal paper (no author or date) C http://sam.ucsd.edu/onr_jes/talley/revelle_report.html C (some description of Bruevich Method) C Determination alkalinity of small volumes of seawater by direct titration. C In: Instruction of chemical investigation of seawater. C Bruevich C.V., 1944, Glavsevmorput, M.-L., 83p. C Alkalinity - According To C "Methods Of Hydrochemical Investigations Of The Ocean", C Moscow, Science, 1978. Method Of Bruevich. C Barwell-Clarke J., F. Whitney (1996) C Nutrient Methods and Analysis !--1-- --2--- --3--- ---4--- --5--- --6--- --7-- --8-- ---9--- --10- ---11-- ---12-- ---13-- ---14--- --15-- --16-- --17-- - --19-- !Sampl Depth Temper Salinit Oxygen Phosph Nitra Silic Calcium Carbo Chlorop pH:NBS pH:SWS Oxygen: Carbon Alkali Alkali F Oxygen !e_ ature: y: : ate te_ ate :Total n:Dis hyll: Isotope: :Disso nity: nity: l : !Numbe Revers Bottle Dissol plus_ solve Extract 18 lved: Total: Total ~ Dissol !r ing ved Nitri d:Org ed Inorga Colori a ved ! te anic nic metric l !----- ------ ------ ------- ------ ------ ----- ----- ------- ----- ------- ------- ------- -------- ------ ------ ------ - ------ *END OF HEADER 201 0.0 4.75 32.923 301.2 1.50 16.3 31.3 9.679 254.0 1.329 7.898 7.748 -0.7199 2093.8 2200.0 2215.5 6 6.92 202 10.0 4.66 32.931 301.1 1.57 16.5 31.3 9.720 -99.0 1.524 7.895 7.744 -0.6132 2098.8 2216.0 -99.0 5 6.92 203 25.0 3.75 33.091 280.6 1.86 20.8 42.7 9.737 -99.0 1.215 7.835 7.685 -0.6265 2132.2 2225.0 -99.0 5 6.45 204 50.0 2.43 33.277 250.4 2.18 26.3 56.6 9.794 155.0 0.575 7.754 7.604 -0.4192 2174.5 2246.0 2238.0 0 5.76 205 75.0 2.23 33.320 243.5 2.24 27.4 59.8 9.807 -99.0 0.404 7.736 7.585 -0.6152 2182.3 2244.0 -99.0 5 5.60 206 101.0 2.06 33.356 234.7 2.34 28.7 63.2 9.818 139.0 0.310 7.712 7.562 -0.4428 2192.6 2249.0 2242.0 0 5.40 207 126.0 1.82 33.378 230.8 2.38 29.3 64.8 9.841 -99.0 0.087 7.702 7.551 -0.7784 2195.9 2252.0 -99.0 5 5.31 208 152.0 1.30 33.367 236.7 2.37 30.0 62.5 9.826 112.0 0.085 7.693 7.543 -0.7322 2197.6 2250.0 2251.0 6 5.44 209 203.0 1.78 33.486 207.4 2.53 31.7 73.8 9.865 110.0 -99.000 7.661 7.511 -0.7055 2221.7 2280.0 2242.5 6 4.77 210 304.0 1.95 33.566 185.0 2.62 33.2 80.8 9.902 121.0 -99.000 7.634 7.484 -0.4284 2237.6 2289.0 2261.0 0 4.26 211 405.0 1.68 33.619 170.4 2.70 34.6 86.3 9.931 -99.0 -99.000 7.607 7.457 -0.4931 2251.8 2298.0 2265.0 0 3.92 212 507.0 1.84 33.693 153.9 2.75 35.6 93.2 9.940 109.0 -99.000 7.602 7.452 -0.3104 2264.7 2308.0 2269.0 6 3.54 213 608.0 1.97 33.829 123.7 2.85 37.8 107.2 10.000 -99.0 -99.000 7.568 7.418 -0.3853 2289.8 2320.0 2283.0 0 2.85 214 710.0 2.15 33.991 89.6 3.02 40.1 124.1 10.056 115.0 -99.000 7.533 7.382 -0.4263 2320.0 2342.0 2299.0 0 2.06 215 794.0 2.30 34.152 64.2 3.07 41.5 141.8 10.099 -99.0 -99.000 7.594 7.472 -99.0000 2343.5 2361.0 2325.0 0 1.48 216 994.0 2.28 34.281 53.5 3.12 42.6 153.0 10.142 116.0 -99.000 7.540 7.389 -99.0000 2358.9 2376.0 2334.5 6 1.23 217 1193.0 2.20 34.424 51.6 3.13 43.0 161.8 10.180 -99.0 -99.000 7.540 7.389 -99.0000 2364.0 2393.0 2354.0 0 1.19 218 1391.0 2.06 34.483 58.4 3.11 42.8 165.7 10.195 109.0 -99.000 7.558 7.408 -99.0000 2367.3 2403.0 2363.0 0 1.34 219 1590.0 2.01 34.515 65.2 3.10 42.5 167.6 10.209 -99.0 -99.000 7.577 7.426 -99.0000 2366.1 2410.0 -99.0 5 1.50 220 1789.0 1.95 34.538 65.2 3.09 42.2 169.4 10.229 -99.0 -99.000 7.585 7.435 -99.0000 2365.3 2414.0 2368.5 6 1.50 221 2003.0 1.95 34.560 76.9 3.07 42.0 171.5 10.231 104.0 -99.000 7.595 7.445 -99.0000 2365.6 2425.0 2375.0 0 1.77 222 2243.0 1.87 34.576 78.8 3.07 41.6 172.9 10.244 -99.0 -99.000 7.616 7.465 -99.0000 2360.9 2423.0 2379.0 0 1.81 223 2492.0 1.87 34.590 83.7 3.06 41.3 174.2 10.240 -99.0 -99.000 7.619 7.469 -99.0000 2359.6 2427.0 2379.0 0 1.93 224 2742.0 1.82 34.598 84.7 3.09 41.0 175.0 10.239 -99.0 -99.000 7.619 7.469 -99.0000 2359.6 2427.0 -99.0 5 1.95 225 2992.0 1.81 34.604 88.5 3.04 40.9 174.8 10.243 104.0 -99.000 7.621 7.470 -99.0000 2359.8 2428.0 2385.0 0 2.04