*2014/11/20 09:51:18.20 *IOS HEADER VERSION 1.10 2011/10/26 2011/10/26 *FILE START TIME : UTC 1991/05/14 01:05:00.000 NUMBER OF RECORDS : 42 DATA DESCRIPTION : Bottle:Wire FILE TYPE : ASCII NUMBER OF CHANNELS : 18 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ------------------------------- --------- -------------- -------------- 1 Sample_Number n/a 2 Depth metres 0 4058 3 Temperature:Reversing 'deg C' 1.48 26.52 4 Salinity:Bottle ppt 34.237 35.022 5 Oxygen:Dissolved mL/L 0.83 4.81 6 Oxygen:Dissolved umol/kg 35.1 205.2 7 Phosphate umol/L 0.6E-01 3.11 8 Nitrate_plus_Nitrite umol/L 0 43.4 9 Silicate umol/L 1.3 155.9 10 Calcium:Total mmol/kg 10.018 10.247 11 Carbon:Dissolved:Organic umol/L 61 140 12 Chlorophyll:Extracted mg/m^3 0.25E-01 0.11 13 pH:NBS n/a 7.561 8.264 14 pH:SWS n/a 7.452 8.155 15 Carbon:Dissolved:Inorganic umol/kg 1913.5 2349.2 16 Alkalinity:Total:Colorimetric umol/kg 2259 2442 17 Alkalinity:Total umol/kg 2254 2426 18 Flag:Alkalinity:Total n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 ' ' ' ' 6 NQ C ' ' 2 -99 ' ' 7 F R4 1 3 -99 ' ' 7 F R4 2 4 -99 ' ' 8 F R4 3 5 -99 ' ' 7 F R4 2 6 -99 ' ' 7 F R4 1 7 -99 ' ' 7 F R4 2 8 -99 ' ' 6 F R4 1 9 -99 ' ' 6 F R4 1 10 -99 ' ' 8 F R4 3 11 -99 ' ' 6 F R4 1 12 -99 ' ' 8 F R4 3 13 -99 ' ' 8 F R4 3 14 -99 ' ' 8 F R4 3 15 -99 ' ' 7 F R4 1 16 -99 ' ' 7 F R4 1 17 -99 ' ' 7 F R4 1 18 ' ' ' ' 2 NQ C ' ' $END $REMARKS Input data file used: ./inpoc-1991-9117-gems91-av91-010b.dat04i Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (Flag 'b' also reported as ' ') 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- References: http://www.pacificinfo.ru/en/db/poi/?show=cruise&id=116 http://www.olympus.net/ISPSO/JointAssembly97/abstracts/ip5.html (IP5i) http://pubs.usgs.gov/publications/1997-06/informal.shtml Report available only through USGS, Information Services OF 94-0230 Data and results from R/V A. Vinogradov cruises 91-AV19 $END *ADMINISTRATION MISSION : 1991-17 AGENCY : POI,IOS PROJECT : COCC 9103, POI AV19 SCIENTIST : Bychkov A./ Wong C.S. PLATFORM : Ak. A. Vinogradov $REMARKS This is OSAP Cruise 1991-17 (IOS) Previously COCC Cruise 9103 (C.S.Wong) and Russian Cruise AV19 (POI) aka Cruise Gems91 (C.S.Wong) Chief Scientist for IOS: C.S.Wong (not aboard) Chief Scientist for POI: A.Bychkov Technicians (IOS): Ron Bellegay - sample log sheets, deck log sheets, ... Keith Johnson - DOC,DIC supplies, equipment, analysis Wendy Richardson - Alkalinity supplies, equipment, analysis also some assistance with Nutrient analysis Glenn Smith - pCO2 supplies, equipment, analysis Tim Soutar - Sediment traps, Satnav/GPS Frank Whitney - Nutrient supplies, equipment - Chlorophyll supplies, equipment - Oxygen kit and supplies - POC supplies - sample DOC, Primary Productivity, POC, Chla on Leg4 Valerie Forsland - analyze DIC, pCO2 Janet Barwell-Clarke - analyze nutrients - filter samples for POC, Primary Productivity, Chla $END *LOCATION GEOGRAPHIC AREA : NW Pacific STATION : HS14 EVENT NUMBER : 10 LATITUDE : 16 33.00000 N ! (deg min) LONGITUDE : 168 27.40000 W ! (deg min) $REMARKS This was a joint Canada-Russia expedition aboard the Russian ship R/V R/V Akademik A. Vinogradov during April-May 1991, in the NW Pacific ocean. Leg1 = Vladivostok to Hawaii Leg3 = Hawaii to Taiwan Leg4 = Vladivostok to Vladivostok via Bering Sea $END *INSTRUMENT TYPE : Bottle MODEL : Niskin (10 litre) $REMARKS See details wrt various instruments in COMMENTS section $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- chem_cast_gems_1991_01.F 1.3 2004/05/05 16:23:19 42 42 CLEAN 4.6.1 2004/05/05 16:18:48 42 42 HDREDIT2 2.0 2004/05/06 11:03:52 ? ? CLEAN 4.6.1 2004/05/06 11:28:02 42 42 SORT 3.4.1 2004/06/02 11:35:59 42 42 CHANGE_FLAGS 1.0 2013/07/16 11:44:59 42 42 CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 14:31:19 42 42 CHANGE_FLAGS 2.0 2014/11/20 09:51:18 42 42 $END $REMARKS CLEAN functions: - Reset #RECS, MIN & MAX values in header. - Set header Start and End times from the data. *FAILED* CLEAN functions: - Reset #RECS, MIN & MAX values in header. - Delete Empty Channels: 0 deleted. -The following SORT parameters were used. Sorted by channel: Depth Pressure channel sorted according to values in sort channel $END *COMMENTS C Contents: C Bottle Cast (Niskin Bottles) observations for water chemistry C C Sample collection methods: C Collection device was C 10L PVC Niskin bottles (Canada) data as follows C and a Guildline CTD probe (Russia) see POI for data C http://www.pacificinfo.ru/en/db/poi/?show=cruise&id=116 C Depth C - corrected using reversing thermometer info C Sea Water Temp C - reversing thermometers C Salinity (CTD) C - Guildline AutoSal 8400 C Salinity (Bottle) C - Samples collected in glass bottles from Niskin Samplers C Oxygen:Dissolved C - no information C Phosphate C - Samples collected in 2 glass 16 x 12.5 mm test tubes. C Test tubes were twice rinsed with sample, then filled 2/3 and C stored at 4 C until analyzed. The samples were usually analyzed C within 12 hours of collection C Nitrate_plus_Nitrite C - Samples collected in 2 polystyrene 16 x 12.5 mm test tubes. C Test tubes were twice rinsed with sample, then filled 2/3 and C stored at 4 C until analyzed. The samples were usually analyzed C within 12 hours of collection C Silicate C - Samples collected in 2 polystyrene 16 x 12.5 mm test tubes. C Test tubes were twice rinsed with sample, then filled 2/3 and C stored at 4 C until analyzed. The samples were usually analyzed C within 12 hours of collection C Calcium:Total C - no information C Carbon:Dissolved:Organic C - glass ampoules, no further information C Chlorophyll:Extracted C - Samples drawn from 10L Niskin bottles into clean, volume calibrated C polyethylene bottles. The samples were filtered onto 24 mm diameter C Whatman GF/F filer (0.7 um nominal pore size) with vacuum pump C < 100 mm Hg. C ph:NBS C - no information C pH:SWS C - no information C Carbon:Isotope:13 C - Samples drawn from 10L Niskin bottles into 250ml glass bottles, C fixed with 200uL of saturated H2Cl2 solution - used ground glass C stoppers greased with Aprizon M and secured with tape/band. C Carbon:Dissolved:Inorganic C - no information C Alkalinity:Total:Colorimetric C - no information C Alkalinity:Total:Potentiometric C - no information C C Sample analysis methods: C Depth C - computed from protected and unprotected thermometer readings C Sea Water Temp C - protected reversing thermometers C Salinity (Bottle) C - analyzed onboard with a Guildline Model 8400 Autosal C Oxygen:Dissolved C - Oxygen for legs 1 & 3 were done by Russian method which C has no blank correction. C Oxygen for leg 4 was done by IOS MicroWinkler (Carpenter) method C (with blank correction). => ~+0.5 ml/L bias on Russian oxygen data. C Phosphate C - A 3 channel Technicon Autoanalyzer II was used to measure Phosphate c Soluble orthophosphate was determined by C .. by Technicon Industrial Methods No.155-71). C Nitrate_plus_Nitrite C - A 3 channel Technicon Autoanalyzer II was used to measure Nitrate* C Soluble Nitrate was determined by C .. by Technicon Industrial Methods No.158-71W (revised Aug 1979) C .. and is a modification of procedure by Armstrong et al. (1967). C Silicate C - A 3 channel Technicon Autoanalyzer II was used to measure Nitrate* C Dissolved Silica was determined by C .. by Technicon Industrial Methods No.186-72W, C .. essentially that of Armstrong et al (1967). C C Nutrient Sample Analysis - more info - see separate Word Document C Calcium:Total C - potentiometric titration C Carbon:Dissolved:Organic C - spectrophotometric measurements C Chlorophyll:Extracted C - After filtering, the sample was analyzed immediately or frozen for C later analysis. When freezing, the folded filter was placed in a C cone made from a paper filter (eg Whatmon #1, 9mm diameter), C labelled, then placed in a large plastic jar with silica desiccant. C The flourometer was calibrated with a spectrophotometer using C 'fucus sp.' extracted in 90% acetone. C ph:NBS C - pH on NBS Scale, "pH was determined by glass (OP-0718P) and C calomel (OP-0830P) electrodes of 'Radelkis' firm. C The digital precision pH-meter 'Radelkis' (OP-208/1) was used. C Measurements werecarried out at 24 +/- 0.1C at once after hydrocast. C Electrodes were standardized in NBS-scale by phosphate buffer C (GOST 8,135-74) ph(25)=6.86 - Russian commercial standard. C pH:SWS C - pH on Sea Water Scale, "pH was determined by glass (OP-0718P) and C calomel (OP-0830P) electrodes of 'Radelkis' firm. C The digital precision pH-meter 'Radelkis' (OP-208/1) was used. C Measurements werecarried out at 24 +/- 0.1C at once after hydrocast. C Electrodes were standardized in SWS-scale by TRIS buffer prepared C according to the prescription of Table 6 (Millero,1986) C Refs: C 1. Millero F.J. (1986) C The pH of Estuarine Water C Limnol. Oceaogr. V31, N4, pp839-847 C 2. UNESCO technical paper in marine science (1987) V5, 21p C 3. Hansson I. (1973) C A new set of acidity constants for carbonic acid and boric acid C in seawater. C Deep-Sea Res., V20, N5, pp461-478 C 4. Letter (undated) from Pavel Ya.Tishchenko (POI) C to Frank Whitney (IOS) detailing analysis procedure for pH. C Carbon:Isotope:13 C - CO2 extracted from seawater by NIWA Automated DIC Extraction system, C as per NIWA Seawater Line Manual (cryogenic vaccum removal). C C-13 samples analyzed by Nuclide Mass Spectrometer Procedure C (Forsland, 1994). C C-13 samples were measured wrt to our Working Tank (aluminum) C whose concentration was determined wrt NBS standard tank. C (technician = Valerie Forsland) C Carbon:Dissolved:Inorganic C - SOMMA-I Coulometer (Stns HS01,...,HS11 analyzed aboard ship) C Alkalinity:Total:Colorimetric C - determined by POI using Bruevich's Method (1944), C which consists of direct colorimetric titration by HCl acid in an C open system. A mixed indicator (methylene blue and methylene red) C is used to visually determine the equivalence point (color changes C from geen to light pink). The titration is carried out under a C continuous flow of CO2 free air (or nitrogen gas). C The equivalence point is reached at approximately pH 5.4 - 5.5 . C The precision of the method is about 0.2% . C Alkalinity:Total:Potentiometric C - determined by IOS using potentiometric titration in a closed cell. C IOS Alkalinity Vol,Emf data acquired from Metrohm 636 Titroprocessor C using PC program 'GTITR211.BAS'. C IOS Alkalinity was computed using PC program 'TALKY117.BAS' C Some IOS Alkalinity values were recomputed due to an Acid concentrati C recalibration on approx May 10 1991. C The original Acid Normality of 0.2506 (mol/L) was replaced by C 0.2524 (mol/L). The final corrected values are used here. C Duplicate samples are averaged - see flag "f" C C Note: POI also took CTD samples - not included here C C REFERENCES: C Carpenter, J.H. 1965 C The Chesapeake Bay Inst technique for Winkler Dissolved Oxygen Method. C Limnol. Oceanogr. 10: 141-143 C WOCE Report No. 73/91, 1991. C A comparison of methods for the determination of dissolved oxygen in C seawater. C WHPO Publication 91-2. Unpublished manuscript. C Analysis of Total Alkalinity using two methods: direct titration in C opened system. C (Bruevich) and potentiometric titration in closed system (Edmond) C by Galina Pavlova (POI), Wendy Richardson (IOS), W.Keith Johnson (IOS) C April 1993 C Comparison of three methods of determination of total alkalinity in C seawater. IOS internal paper (no author or date) C http://sam.ucsd.edu/onr_jes/talley/revelle_report.html C (some description of Bruevich Method) C Determination alkalinity of small volumes of seawater by direct titration. C In: Instruction of chemical investigation of seawater. C Bruevich C.V., 1944, Glavsevmorput, M.-L., 83p. C Alkalinity - According To C "Methods Of Hydrochemical Investigations Of The Ocean", C Moscow, Science, 1978. Method Of Bruevich. C !--1-- --2--- --3--- ---4--- --5--- --6--- --7--- --8-- --9-- ---10-- --11- ---12-- ---13-- ---14-- --15-- --16-- --17-- - !Sampl Depth Temper Salinit Oxygen Oxygen Phosph Nitra Silic Calcium Carbo Chlorop pH:NBS pH:SWS Carbon Alkali Alkali F !e_ ature: y: : : ate te_ ate :Total n:Dis hyll: :Disso nity: nity: l !Numbe Revers Bottle Dissol Dissol plus_ solve Extract lved: Total: Total ~ !r ing ved ved Nitri d:Org ed Inorga Colori a ! te anic nic metric l !----- ------ ------ ------- ------ ------ ------ ----- ----- ------- ----- ------- ------- ------- ------ ------ ------ - *END OF HEADER 7523 0.0 26.52 34.380 4.65 198.6 0.10 0.0 1.6 10.104 -99.0 0.025 8.239 8.130 1914.0 2259.0 2256.0 0 7524 11.0 26.50 34.385 4.63 197.6 0.10 0.0 1.6 10.105 -99.0 0.056 8.250 8.141 1913.5 2259.0 2265.0 0 7525 22.0 26.46 34.390 4.65 198.5 0.10 0.0 1.5 10.090 -99.0 0.047 8.256 8.147 1914.8 2261.0 2254.0 0 25.0 26.37 34.348 -99.00 -99.0 -99.00 -99.0 -99.0 -99.000 122.0 -99.000 -99.000 -99.000 -99.0 -99.0 -99.0 5 7526 34.0 26.49 34.401 4.63 197.6 0.10 0.0 1.3 10.086 -99.0 0.050 8.257 8.148 1915.1 2267.0 2254.0 0 50.0 26.34 34.348 -99.00 -99.0 -99.00 -99.0 -99.0 -99.000 92.0 -99.000 -99.000 -99.000 -99.0 -99.0 -99.0 5 7527 53.0 26.45 34.406 4.68 199.5 0.10 0.0 1.5 10.084 -99.0 0.050 8.264 8.155 1915.3 2261.0 2260.0 0 7528 79.0 25.61 34.811 4.76 203.3 0.08 0.0 1.5 10.202 -99.0 0.091 8.247 8.138 1942.7 2291.0 2283.0 6 100.0 24.88 34.649 -99.00 -99.0 -99.00 -99.0 -99.0 -99.000 140.0 -99.000 -99.000 -99.000 -99.0 -99.0 -99.0 5 7529 107.0 24.63 35.022 4.81 205.2 0.06 0.0 1.7 10.247 -99.0 0.110 8.242 8.133 1957.7 2300.0 2302.0 0 7530 131.0 23.02 34.960 4.74 202.2 0.15 0.0 1.9 10.217 -99.0 -99.000 8.193 8.084 1989.3 2304.0 2300.0 0 7531 154.0 21.43 34.904 4.51 192.3 0.25 1.1 2.8 10.209 -99.0 -99.000 8.141 8.032 2016.0 2304.0 2301.0 0 7532 180.0 18.10 34.791 3.95 167.8 0.55 5.8 5.0 10.185 -99.0 -99.000 8.044 7.935 2056.3 2294.0 2285.0 6 7533 202.0 16.84 34.653 3.84 162.9 0.71 8.0 6.3 10.138 -99.0 -99.000 7.992 7.883 2071.8 2295.0 2283.0 0 250.0 12.00 34.312 -99.00 -99.0 -99.00 -99.0 -99.0 -99.000 65.0 -99.000 -99.000 -99.000 -99.0 -99.0 -99.0 5 7534 254.0 12.54 34.337 3.54 150.1 1.25 16.4 14.8 10.066 -99.0 -99.000 7.887 7.778 2110.3 2266.0 2264.0 0 300.0 10.40 34.299 -99.00 -99.0 -99.00 -99.0 -99.0 -99.000 64.0 -99.000 -99.000 -99.000 -99.0 -99.0 -99.0 5 7535 306.0 10.12 34.250 3.29 139.3 1.62 22.0 24.3 10.018 -99.0 -99.000 7.813 7.704 2146.1 2273.0 2268.0 0 7549? 374.0 8.77 34.237 2.82 119.8 1.85 25.1 29.9 10.058 -99.0 -99.000 7.737 7.644 2170.5 2442.0 -99.0 5 ? 394.0 8.37 34.237 -99.00 -99.0 -99.00 -99.0 -99.0 -99.000 -99.0 -99.000 -99.000 -99.000 -99.0 -99.0 -99.0 5 7536 410.0 8.06 34.349 1.54 65.3 2.55 34.0 45.0 10.068 -99.0 -99.000 7.620 7.511 2240.8 2300.0 2301.0 0 500.0 6.94 34.398 -99.00 -99.0 -99.00 -99.0 -99.0 -99.000 61.0 -99.000 -99.000 -99.000 -99.0 -99.0 -99.0 5 7537 511.0 6.80 34.474 0.88 37.0 2.92 39.4 57.8 10.128 -99.0 -99.000 7.579 7.470 2283.2 2324.0 2311.0 0 7538 586.0 6.44 34.499 0.83 35.1 3.01 40.7 63.7 10.130 -99.0 -99.000 7.569 7.460 2293.0 2325.0 2317.0 6 7539 670.0 5.89 34.508 1.06 44.8 3.07 42.0 70.6 10.152 -99.0 -99.000 7.571 7.462 2301.3 2337.0 2326.0 0 716.0 5.69 34.512 -99.00 -99.0 -99.00 -99.0 -99.0 -99.000 86.0 -99.000 -99.000 -99.000 -99.0 -99.0 -99.0 5 7540 775.0 5.44 34.518 1.03 43.8 3.07 42.8 78.1 10.159 -99.0 -99.000 7.561 7.452 2310.0 2353.0 2338.0 0 916.0 4.68 34.545 -99.00 -99.0 -99.00 -99.0 -99.0 -99.000 69.0 -99.000 -99.000 -99.000 -99.0 -99.0 -99.0 5 7541 1032.0 4.32 34.551 1.25 52.6 3.11 43.4 96.8 10.186 -99.0 -99.000 7.596 7.487 2327.3 2369.0 2358.0 0 7542 1096.0 4.04 34.563 1.33 56.5 3.10 43.2 101.5 10.187 -99.0 -99.000 7.581 7.472 2330.3 2377.0 2367.0 0 1115.0 3.98 34.555 -99.00 -99.0 -99.00 -99.0 -99.0 -99.000 127.0 -99.000 -99.000 -99.000 -99.0 -99.0 -99.0 5 7543 1413.0 3.06 34.596 1.77 74.9 3.02 42.4 122.7 10.197 -99.0 -99.000 7.615 7.506 2342.4 2398.0 2389.0 0 1432.0 3.01 34.604 -99.00 -99.0 -99.00 -99.0 -99.0 -99.000 122.0 -99.000 -99.000 -99.000 -99.0 -99.0 -99.0 5 7543* 1505.0 2.92 34.596 1.78 74.9 2.98 41.8 132.0 10.200 -99.0 -99.000 7.673 7.580 2344.4 2406.0 2387.0 0 7544 2002.0 2.22 34.636 2.90 122.6 2.89 40.8 147.2 10.205 -99.0 -99.000 7.642 7.550 2349.2 2420.0 2409.0 0 2346.0 1.98 34.645 -99.00 -99.0 -99.00 -99.0 -99.0 -99.000 86.0 -99.000 -99.000 -99.000 -99.0 -99.0 -99.0 5 2352.0 1.90 34.656 -99.00 -99.0 -99.00 -99.0 -99.0 -99.000 96.0 -99.000 -99.000 -99.000 -99.0 -99.0 -99.0 5 7545 2505.0 1.88 34.659 2.61 110.0 2.81 39.7 153.3 10.220 -99.0 -99.000 7.661 7.568 2346.0 2435.0 2412.0 0 7546 3002.0 1.62 34.677 2.97 125.5 2.71 38.7 155.9 10.225 -99.0 -99.000 7.696 7.604 2339.5 2435.0 2425.0 0 7547 3515.0 1.54 34.690 3.03 128.4 2.64 37.9 155.8 10.239 -99.0 -99.000 7.708 7.616 2331.7 2436.0 2426.0 0 7548 4038.0 1.48 34.696 3.55 149.8 2.58 37.0 150.7 10.225 -99.0 -99.000 7.715 7.622 2321.3 2428.0 2420.0 0 4058.0 1.48 34.696 -99.00 -99.0 -99.00 -99.0 -99.0 -99.000 125.0 -99.000 -99.000 -99.000 -99.0 -99.0 -99.0 5