*2014/11/20 09:51:18.09 *IOS HEADER VERSION 1.10 2011/10/26 2011/10/26 *FILE START TIME : UTC 1991/05/01 19:15:00.000 NUMBER OF RECORDS : 28 DATA DESCRIPTION : Bottle:Wire FILE TYPE : ASCII NUMBER OF CHANNELS : 18 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ------------------------------- --------- -------------- -------------- 1 Sample_Number n/a 2 Depth metres 0 5105 3 Temperature:Reversing 'deg C' 1.44 23.85 4 Salinity:Bottle ppt 34.081 35.385 5 Oxygen:Dissolved mL/L 0.9 5.04 6 Oxygen:Dissolved umol/kg 38.9 219.7 7 Phosphate umol/L 0.3E-01 3.24 8 Nitrate_plus_Nitrite umol/L 0 43.5 9 Silicate umol/L 1.2 156.3 10 Calcium:Total mmol/kg 10.033 10.384 11 Carbon:Dissolved:Organic umol/L 158 191 12 Chlorophyll:Extracted mg/m^3 0.59E-01 0.162 13 pH:NBS n/a 7.566 8.254 14 pH:SWS n/a 7.426 8.114 15 Carbon:Dissolved:Inorganic umol/kg 1981 2360.8 16 Alkalinity:Total:Colorimetric umol/kg 2263 2422 17 Alkalinity:Total umol/kg 2260 2426 18 Flag:Alkalinity:Total n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 ' ' ' ' 6 NQ C ' ' 2 -99 ' ' 7 F R4 1 3 -99 ' ' 7 F R4 2 4 -99 ' ' 8 F R4 3 5 -99 ' ' 7 F R4 2 6 -99 ' ' 7 F R4 1 7 -99 ' ' 7 F R4 2 8 -99 ' ' 6 F R4 1 9 -99 ' ' 6 F R4 1 10 -99 ' ' 8 F R4 3 11 -99 ' ' 6 F R4 1 12 -99 ' ' 8 F R4 3 13 -99 ' ' 8 F R4 3 14 -99 ' ' 8 F R4 3 15 -99 ' ' 7 F R4 1 16 -99 ' ' 7 F R4 1 17 -99 ' ' 7 F R4 1 18 ' ' ' ' 2 NQ C ' ' $END $REMARKS Input data file used: ./inpoc-1991-9117-gems91-av91-010b.dat04i Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (Flag 'b' also reported as ' ') 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- References: http://www.pacificinfo.ru/en/db/poi/?show=cruise&id=116 http://www.olympus.net/ISPSO/JointAssembly97/abstracts/ip5.html (IP5i) http://pubs.usgs.gov/publications/1997-06/informal.shtml Report available only through USGS, Information Services OF 94-0230 Data and results from R/V A. Vinogradov cruises 91-AV19 $END *ADMINISTRATION MISSION : 1991-17 AGENCY : POI,IOS PROJECT : COCC 9103, POI AV19 SCIENTIST : Bychkov A./ Wong C.S. PLATFORM : Ak. A. Vinogradov $REMARKS This is OSAP Cruise 1991-17 (IOS) Previously COCC Cruise 9103 (C.S.Wong) and Russian Cruise AV19 (POI) aka Cruise Gems91 (C.S.Wong) Chief Scientist for IOS: C.S.Wong (not aboard) Chief Scientist for POI: A.Bychkov Technicians (IOS): Ron Bellegay - sample log sheets, deck log sheets, ... Keith Johnson - DOC,DIC supplies, equipment, analysis Wendy Richardson - Alkalinity supplies, equipment, analysis also some assistance with Nutrient analysis Glenn Smith - pCO2 supplies, equipment, analysis Tim Soutar - Sediment traps, Satnav/GPS Frank Whitney - Nutrient supplies, equipment - Chlorophyll supplies, equipment - Oxygen kit and supplies - POC supplies - sample DOC, Primary Productivity, POC, Chla on Leg4 Valerie Forsland - analyze DIC, pCO2 Janet Barwell-Clarke - analyze nutrients - filter samples for POC, Primary Productivity, Chla $END *LOCATION GEOGRAPHIC AREA : NW Pacific STATION : HS11 EVENT NUMBER : 8 LATITUDE : 25 18.10000 N ! (deg min) LONGITUDE : 179 59.80000 W ! (deg min) $REMARKS This was a joint Canada-Russia expedition aboard the Russian ship R/V R/V Akademik A. Vinogradov during April-May 1991, in the NW Pacific ocean. Leg1 = Vladivostok to Hawaii Leg3 = Hawaii to Taiwan Leg4 = Vladivostok to Vladivostok via Bering Sea $END *INSTRUMENT TYPE : Bottle MODEL : Niskin (10 litre) $REMARKS See details wrt various instruments in COMMENTS section $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- chem_cast_gems_1991_01.F 1.3 2004/05/05 16:23:19 28 28 CLEAN 4.6.1 2004/05/05 16:18:44 28 28 HDREDIT2 2.0 2004/05/06 11:03:52 ? ? CLEAN 4.6.1 2004/05/06 11:28:01 28 28 SORT 3.4.1 2004/06/02 11:35:55 28 28 CHANGE_FLAGS 1.0 2013/07/29 14:27:03 28 28 CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 14:31:19 28 28 CHANGE_FLAGS 2.0 2014/11/20 09:51:18 28 28 $END $REMARKS CLEAN functions: - Reset #RECS, MIN & MAX values in header. - Set header Start and End times from the data. *FAILED* CLEAN functions: - Reset #RECS, MIN & MAX values in header. - Delete Empty Channels: 0 deleted. -The following SORT parameters were used. Sorted by channel: Depth Pressure channel sorted according to values in sort channel $END *COMMENTS C Contents: C Bottle Cast (Niskin Bottles) observations for water chemistry C C Sample collection methods: C Collection device was C 10L PVC Niskin bottles (Canada) data as follows C and a Guildline CTD probe (Russia) see POI for data C http://www.pacificinfo.ru/en/db/poi/?show=cruise&id=116 C Depth C - corrected using reversing thermometer info C Sea Water Temp C - reversing thermometers C Salinity (CTD) C - Guildline AutoSal 8400 C Salinity (Bottle) C - Samples collected in glass bottles from Niskin Samplers C Oxygen:Dissolved C - no information C Phosphate C - Samples collected in 2 glass 16 x 12.5 mm test tubes. C Test tubes were twice rinsed with sample, then filled 2/3 and C stored at 4 C until analyzed. The samples were usually analyzed C within 12 hours of collection C Nitrate_plus_Nitrite C - Samples collected in 2 polystyrene 16 x 12.5 mm test tubes. C Test tubes were twice rinsed with sample, then filled 2/3 and C stored at 4 C until analyzed. The samples were usually analyzed C within 12 hours of collection C Silicate C - Samples collected in 2 polystyrene 16 x 12.5 mm test tubes. C Test tubes were twice rinsed with sample, then filled 2/3 and C stored at 4 C until analyzed. The samples were usually analyzed C within 12 hours of collection C Calcium:Total C - no information C Carbon:Dissolved:Organic C - glass ampoules, no further information C Chlorophyll:Extracted C - Samples drawn from 10L Niskin bottles into clean, volume calibrated C polyethylene bottles. The samples were filtered onto 24 mm diameter C Whatman GF/F filer (0.7 um nominal pore size) with vacuum pump C < 100 mm Hg. C ph:NBS C - no information C pH:SWS C - no information C Carbon:Isotope:13 C - Samples drawn from 10L Niskin bottles into 250ml glass bottles, C fixed with 200uL of saturated H2Cl2 solution - used ground glass C stoppers greased with Aprizon M and secured with tape/band. C Carbon:Dissolved:Inorganic C - no information C Alkalinity:Total:Colorimetric C - no information C Alkalinity:Total:Potentiometric C - no information C C Sample analysis methods: C Depth C - computed from protected and unprotected thermometer readings C Sea Water Temp C - protected reversing thermometers C Salinity (Bottle) C - analyzed onboard with a Guildline Model 8400 Autosal C Oxygen:Dissolved C - Oxygen for legs 1 & 3 were done by Russian method which C has no blank correction. C Oxygen for leg 4 was done by IOS MicroWinkler (Carpenter) method C (with blank correction). => ~+0.5 ml/L bias on Russian oxygen data. C Phosphate C - A 3 channel Technicon Autoanalyzer II was used to measure Phosphate c Soluble orthophosphate was determined by C .. by Technicon Industrial Methods No.155-71). C Nitrate_plus_Nitrite C - A 3 channel Technicon Autoanalyzer II was used to measure Nitrate* C Soluble Nitrate was determined by C .. by Technicon Industrial Methods No.158-71W (revised Aug 1979) C .. and is a modification of procedure by Armstrong et al. (1967). C Silicate C - A 3 channel Technicon Autoanalyzer II was used to measure Nitrate* C Dissolved Silica was determined by C .. by Technicon Industrial Methods No.186-72W, C .. essentially that of Armstrong et al (1967). C C Nutrient Sample Analysis - more info - see separate Word Document C Calcium:Total C - potentiometric titration C Carbon:Dissolved:Organic C - spectrophotometric measurements C Chlorophyll:Extracted C - After filtering, the sample was analyzed immediately or frozen for C later analysis. When freezing, the folded filter was placed in a C cone made from a paper filter (eg Whatmon #1, 9mm diameter), C labelled, then placed in a large plastic jar with silica desiccant. C The flourometer was calibrated with a spectrophotometer using C 'fucus sp.' extracted in 90% acetone. C ph:NBS C - pH on NBS Scale, "pH was determined by glass (OP-0718P) and C calomel (OP-0830P) electrodes of 'Radelkis' firm. C The digital precision pH-meter 'Radelkis' (OP-208/1) was used. C Measurements werecarried out at 24 +/- 0.1C at once after hydrocast. C Electrodes were standardized in NBS-scale by phosphate buffer C (GOST 8,135-74) ph(25)=6.86 - Russian commercial standard. C pH:SWS C - pH on Sea Water Scale, "pH was determined by glass (OP-0718P) and C calomel (OP-0830P) electrodes of 'Radelkis' firm. C The digital precision pH-meter 'Radelkis' (OP-208/1) was used. C Measurements werecarried out at 24 +/- 0.1C at once after hydrocast. C Electrodes were standardized in SWS-scale by TRIS buffer prepared C according to the prescription of Table 6 (Millero,1986) C Refs: C 1. Millero F.J. (1986) C The pH of Estuarine Water C Limnol. Oceaogr. V31, N4, pp839-847 C 2. UNESCO technical paper in marine science (1987) V5, 21p C 3. Hansson I. (1973) C A new set of acidity constants for carbonic acid and boric acid C in seawater. C Deep-Sea Res., V20, N5, pp461-478 C 4. Letter (undated) from Pavel Ya.Tishchenko (POI) C to Frank Whitney (IOS) detailing analysis procedure for pH. C Carbon:Isotope:13 C - CO2 extracted from seawater by NIWA Automated DIC Extraction system, C as per NIWA Seawater Line Manual (cryogenic vaccum removal). C C-13 samples analyzed by Nuclide Mass Spectrometer Procedure C (Forsland, 1994). C C-13 samples were measured wrt to our Working Tank (aluminum) C whose concentration was determined wrt NBS standard tank. C (technician = Valerie Forsland) C Carbon:Dissolved:Inorganic C - SOMMA-I Coulometer (Stns HS01,...,HS11 analyzed aboard ship) C Alkalinity:Total:Colorimetric C - determined by POI using Bruevich's Method (1944), C which consists of direct colorimetric titration by HCl acid in an C open system. A mixed indicator (methylene blue and methylene red) C is used to visually determine the equivalence point (color changes C from geen to light pink). The titration is carried out under a C continuous flow of CO2 free air (or nitrogen gas). C The equivalence point is reached at approximately pH 5.4 - 5.5 . C The precision of the method is about 0.2% . C Alkalinity:Total:Potentiometric C - determined by IOS using potentiometric titration in a closed cell. C IOS Alkalinity Vol,Emf data acquired from Metrohm 636 Titroprocessor C using PC program 'GTITR211.BAS'. C IOS Alkalinity was computed using PC program 'TALKY117.BAS' C Some IOS Alkalinity values were recomputed due to an Acid concentrati C recalibration on approx May 10 1991. C The original Acid Normality of 0.2506 (mol/L) was replaced by C 0.2524 (mol/L). The final corrected values are used here. C Duplicate samples are averaged - see flag "f" C C Note: POI also took CTD samples - not included here C C REFERENCES: C Carpenter, J.H. 1965 C The Chesapeake Bay Inst technique for Winkler Dissolved Oxygen Method. C Limnol. Oceanogr. 10: 141-143 C WOCE Report No. 73/91, 1991. C A comparison of methods for the determination of dissolved oxygen in C seawater. C WHPO Publication 91-2. Unpublished manuscript. C Analysis of Total Alkalinity using two methods: direct titration in C opened system. C (Bruevich) and potentiometric titration in closed system (Edmond) C by Galina Pavlova (POI), Wendy Richardson (IOS), W.Keith Johnson (IOS) C April 1993 C Comparison of three methods of determination of total alkalinity in C seawater. IOS internal paper (no author or date) C http://sam.ucsd.edu/onr_jes/talley/revelle_report.html C (some description of Bruevich Method) C Determination alkalinity of small volumes of seawater by direct titration. C In: Instruction of chemical investigation of seawater. C Bruevich C.V., 1944, Glavsevmorput, M.-L., 83p. C Alkalinity - According To C "Methods Of Hydrochemical Investigations Of The Ocean", C Moscow, Science, 1978. Method Of Bruevich. C !--1-- --2--- --3--- ---4--- --5--- --6--- --7--- --8-- --9-- ---10-- --11- ---12-- ---13-- ---14-- --15-- --16-- --17-- - !Sampl Depth Temper Salinit Oxygen Oxygen Phosph Nitra Silic Calcium Carbo Chlorop pH:NBS pH:SWS Carbon Alkali Alkali F !e_ ature: y: : : ate te_ ate :Total n:Dis hyll: :Disso nity: nity: l !Numbe Revers Bottle Dissol Dissol plus_ solve Extract lved: Total: Total ~ !r ing ved ved Nitri d:Org ed Inorga Colori a ! te anic nic metric l !----- ------ ------ ------- ------ ------ ------ ----- ----- ------- ----- ------- ------- ------- ------ ------ ------ - *END OF HEADER 7295 0.0 23.85 35.385 4.88 212.9 0.03 0.0 1.2 10.367 -99.0 0.059 8.235 8.095 1982.9 2314.0 2329.0 0 7296 10.0 23.71 35.384 4.85 211.9 0.03 0.0 1.2 10.384 178.0 0.063 8.240 8.100 1983.5 2317.0 2324.0 0 7297 20.0 23.23 35.353 4.96 215.8 0.03 0.0 1.5 10.369 -99.0 0.063 8.243 8.103 1981.7 2320.0 2317.0 0 7298 30.0 23.09 35.353 4.97 216.8 0.04 0.0 1.6 10.355 -99.0 0.083 8.254 8.114 1982.0 2322.0 2320.0 0 7299 50.0 22.94 35.347 5.03 219.7 0.04 0.0 1.6 10.374 -99.0 0.067 8.247 8.107 1981.0 2321.0 2319.0 0 7300 75.0 22.40 35.310 5.01 218.7 0.03 0.0 1.6 10.359 191.0 0.120 8.248 8.108 1981.4 2318.0 2316.0 0 7501 100.0 21.65 35.296 4.98 216.7 0.04 0.0 1.6 10.362 -99.0 0.162 8.233 8.093 1989.1 2314.0 2313.0 0 7502 126.0 21.22 35.290 4.94 215.7 0.05 0.1 1.6 10.357 -99.0 -99.000 8.221 8.081 1995.7 2314.0 2310.0 0 7503 151.0 21.04 35.290 4.96 215.7 0.07 0.3 1.6 10.384 -99.0 -99.000 8.216 8.076 1996.5 2314.0 2325.0 0 7504 177.0 20.72 35.268 4.96 215.7 0.06 0.3 1.6 10.369 -99.0 -99.000 8.215 8.075 1998.6 2316.0 2309.0 0 7505 204.0 20.08 35.188 4.86 211.7 0.12 0.8 2.1 10.312 -99.0 -99.000 8.198 8.058 2004.9 2306.0 2305.0 0 7506 258.0 18.54 34.993 5.04 219.5 0.16 1.2 2.6 10.284 -99.0 -99.000 8.176 8.036 2006.8 2294.0 2290.0 0 7507 310.0 16.55 34.763 4.79 208.7 0.38 4.4 4.7 10.234 -99.0 -99.000 8.115 7.975 2028.0 2280.0 2276.0 0 7508 414.0 12.46 34.338 4.44 193.0 0.94 12.3 12.4 10.068 -99.0 -99.000 7.986 7.846 2078.7 2263.0 2260.0 0 7509 519.0 9.92 34.197 4.45 193.9 1.31 17.7 21.5 10.045 -99.0 -99.000 7.912 7.772 2110.4 2272.0 2260.0 0 7510 624.0 7.64 34.092 3.46 150.0 1.93 26.5 40.6 10.033 158.0 -99.000 7.780 7.640 2175.3 2277.0 2278.0 0 7511 726.0 5.62 34.081 2.51 109.1 2.49 34.1 65.3 10.036 -99.0 -99.000 7.665 7.525 2234.4 2290.0 2293.0 0 7512 800.0 4.87 34.136 1.68 73.0 2.85 38.8 87.3 10.058 -99.0 -99.000 7.640 7.500 2281.4 2320.0 2309.0 0 7513 1002.0 3.85 34.329 0.90 38.9 3.24 43.2 116.0 10.113 -99.0 -99.000 7.566 7.426 2339.2 2360.0 2351.0 0 7514 1204.0 3.37 34.471 1.14 49.6 3.15 43.5 131.2 10.175 -99.0 -99.000 7.576 7.436 2351.0 2377.0 2377.0 0 7515 1510.0 2.52 34.552 1.52 66.2 3.06 42.7 146.5 10.200 -99.0 -99.000 7.603 7.463 2360.8 2399.0 2400.0 0 7516 2016.0 1.96 34.622 2.92 126.5 2.93 40.9 154.2 10.223 -99.0 -99.000 7.660 7.520 2352.4 2412.0 2416.0 0 7517 2529.0 1.66 34.652 2.75 119.7 2.79 40.0 156.3 10.238 -99.0 -99.000 7.692 7.552 2345.4 2422.0 2418.0 0 7518 3036.0 1.54 34.671 3.06 133.3 2.70 38.3 155.1 10.242 -99.0 -99.000 7.713 7.573 2335.6 2415.0 2423.0 0 7519 3543.0 1.50 34.681 3.15 137.2 2.63 37.6 151.9 10.256 -99.0 -99.000 7.730 7.590 2323.9 2416.0 2426.0 0 7520 4063.0 1.46 34.689 3.61 156.7 2.59 36.9 148.3 10.243 -99.0 -99.000 7.743 7.603 2317.7 2414.0 2415.0 0 7521 4592.0 1.46 34.693 3.82 166.4 2.53 36.5 142.6 10.235 -99.0 -99.000 7.751 7.611 2309.4 2419.0 2416.0 0 7522 5105.0 1.44 34.699 3.96 172.2 2.48 35.5 136.8 10.253 -99.0 -99.000 7.758 7.618 2299.5 2405.0 2404.0 0