*2014/11/20 09:51:18.03 *IOS HEADER VERSION 1.10 2011/10/26 2011/10/26 *FILE START TIME : UTC 1991/04/30 01:05:00.000 NUMBER OF RECORDS : 39 DATA DESCRIPTION : Bottle:Wire FILE TYPE : ASCII NUMBER OF CHANNELS : 18 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ------------------------------- --------- -------------- -------------- 1 Sample_Number n/a 2 Depth metres 0 4599 3 Temperature:Reversing 'deg C' 1.46 23.06 4 Salinity:Bottle ppt 34.04 35.332 5 Oxygen:Dissolved mL/L 0.83 5.41 6 Oxygen:Dissolved umol/kg 36 236.1 7 Phosphate umol/L 0.2E-01 3.18 8 Nitrate_plus_Nitrite umol/L 0 44.3 9 Silicate umol/L 1.5 161.1 10 Calcium:Total mmol/kg 10.007 10.375 11 Carbon:Dissolved:Organic umol/L 79 144 12 Chlorophyll:Extracted mg/m^3 0.61E-01 0.342 13 pH:NBS n/a 7.542 8.25 14 pH:SWS n/a 7.398 8.116 15 Carbon:Dissolved:Inorganic umol/kg 1983.5 2372.7 16 Alkalinity:Total:Colorimetric umol/kg 2259 2419 17 Alkalinity:Total umol/kg 2268 2428 18 Flag:Alkalinity:Total n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 ' ' ' ' 6 NQ C ' ' 2 -99 ' ' 7 F R4 1 3 -99 ' ' 7 F R4 2 4 -99 ' ' 8 F R4 3 5 -99 ' ' 7 F R4 2 6 -99 ' ' 7 F R4 1 7 -99 ' ' 7 F R4 2 8 -99 ' ' 6 F R4 1 9 -99 ' ' 6 F R4 1 10 -99 ' ' 8 F R4 3 11 -99 ' ' 6 F R4 1 12 -99 ' ' 8 F R4 3 13 -99 ' ' 8 F R4 3 14 -99 ' ' 8 F R4 3 15 -99 ' ' 7 F R4 1 16 -99 ' ' 7 F R4 1 17 -99 ' ' 7 F R4 1 18 ' ' ' ' 2 NQ C ' ' $END $REMARKS Input data file used: ./inpoc-1991-9117-gems91-av91-010b.dat04i Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (Flag 'b' also reported as ' ') 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- References: http://www.pacificinfo.ru/en/db/poi/?show=cruise&id=116 http://www.olympus.net/ISPSO/JointAssembly97/abstracts/ip5.html (IP5i) http://pubs.usgs.gov/publications/1997-06/informal.shtml Report available only through USGS, Information Services OF 94-0230 Data and results from R/V A. Vinogradov cruises 91-AV19 $END *ADMINISTRATION MISSION : 1991-17 AGENCY : POI,IOS PROJECT : COCC 9103, POI AV19 SCIENTIST : Bychkov A./ Wong C.S. PLATFORM : Ak. A. Vinogradov $REMARKS This is OSAP Cruise 1991-17 (IOS) Previously COCC Cruise 9103 (C.S.Wong) and Russian Cruise AV19 (POI) aka Cruise Gems91 (C.S.Wong) Chief Scientist for IOS: C.S.Wong (not aboard) Chief Scientist for POI: A.Bychkov Technicians (IOS): Ron Bellegay - sample log sheets, deck log sheets, ... Keith Johnson - DOC,DIC supplies, equipment, analysis Wendy Richardson - Alkalinity supplies, equipment, analysis also some assistance with Nutrient analysis Glenn Smith - pCO2 supplies, equipment, analysis Tim Soutar - Sediment traps, Satnav/GPS Frank Whitney - Nutrient supplies, equipment - Chlorophyll supplies, equipment - Oxygen kit and supplies - POC supplies - sample DOC, Primary Productivity, POC, Chla on Leg4 Valerie Forsland - analyze DIC, pCO2 Janet Barwell-Clarke - analyze nutrients - filter samples for POC, Primary Productivity, Chla $END *LOCATION GEOGRAPHIC AREA : NW Pacific STATION : HS10 EVENT NUMBER : 7 LATITUDE : 27 46.50000 N ! (deg min) LONGITUDE : 174 59.40000 E ! (deg min) $REMARKS This was a joint Canada-Russia expedition aboard the Russian ship R/V R/V Akademik A. Vinogradov during April-May 1991, in the NW Pacific ocean. Leg1 = Vladivostok to Hawaii Leg3 = Hawaii to Taiwan Leg4 = Vladivostok to Vladivostok via Bering Sea $END *INSTRUMENT TYPE : Bottle MODEL : Niskin (10 litre) $REMARKS See details wrt various instruments in COMMENTS section $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- chem_cast_gems_1991_01.F 1.3 2004/05/05 16:23:19 39 39 CLEAN 4.6.1 2004/05/05 16:18:42 39 39 HDREDIT2 2.0 2004/05/06 11:03:51 ? ? CLEAN 4.6.1 2004/05/06 11:28:01 39 39 SORT 3.4.1 2004/06/02 11:35:53 39 39 CHANGE_FLAGS 1.0 2013/07/16 11:44:59 39 39 CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 14:31:19 39 39 CHANGE_FLAGS 2.0 2014/11/20 09:51:18 39 39 $END $REMARKS CLEAN functions: - Reset #RECS, MIN & MAX values in header. - Set header Start and End times from the data. *FAILED* CLEAN functions: - Reset #RECS, MIN & MAX values in header. - Delete Empty Channels: 0 deleted. -The following SORT parameters were used. Sorted by channel: Depth Pressure channel sorted according to values in sort channel $END *COMMENTS C Contents: C Bottle Cast (Niskin Bottles) observations for water chemistry C C Sample collection methods: C Collection device was C 10L PVC Niskin bottles (Canada) data as follows C and a Guildline CTD probe (Russia) see POI for data C http://www.pacificinfo.ru/en/db/poi/?show=cruise&id=116 C Depth C - corrected using reversing thermometer info C Sea Water Temp C - reversing thermometers C Salinity (CTD) C - Guildline AutoSal 8400 C Salinity (Bottle) C - Samples collected in glass bottles from Niskin Samplers C Oxygen:Dissolved C - no information C Phosphate C - Samples collected in 2 glass 16 x 12.5 mm test tubes. C Test tubes were twice rinsed with sample, then filled 2/3 and C stored at 4 C until analyzed. The samples were usually analyzed C within 12 hours of collection C Nitrate_plus_Nitrite C - Samples collected in 2 polystyrene 16 x 12.5 mm test tubes. C Test tubes were twice rinsed with sample, then filled 2/3 and C stored at 4 C until analyzed. The samples were usually analyzed C within 12 hours of collection C Silicate C - Samples collected in 2 polystyrene 16 x 12.5 mm test tubes. C Test tubes were twice rinsed with sample, then filled 2/3 and C stored at 4 C until analyzed. The samples were usually analyzed C within 12 hours of collection C Calcium:Total C - no information C Carbon:Dissolved:Organic C - glass ampoules, no further information C Chlorophyll:Extracted C - Samples drawn from 10L Niskin bottles into clean, volume calibrated C polyethylene bottles. The samples were filtered onto 24 mm diameter C Whatman GF/F filer (0.7 um nominal pore size) with vacuum pump C < 100 mm Hg. C ph:NBS C - no information C pH:SWS C - no information C Carbon:Isotope:13 C - Samples drawn from 10L Niskin bottles into 250ml glass bottles, C fixed with 200uL of saturated H2Cl2 solution - used ground glass C stoppers greased with Aprizon M and secured with tape/band. C Carbon:Dissolved:Inorganic C - no information C Alkalinity:Total:Colorimetric C - no information C Alkalinity:Total:Potentiometric C - no information C C Sample analysis methods: C Depth C - computed from protected and unprotected thermometer readings C Sea Water Temp C - protected reversing thermometers C Salinity (Bottle) C - analyzed onboard with a Guildline Model 8400 Autosal C Oxygen:Dissolved C - Oxygen for legs 1 & 3 were done by Russian method which C has no blank correction. C Oxygen for leg 4 was done by IOS MicroWinkler (Carpenter) method C (with blank correction). => ~+0.5 ml/L bias on Russian oxygen data. C Phosphate C - A 3 channel Technicon Autoanalyzer II was used to measure Phosphate c Soluble orthophosphate was determined by C .. by Technicon Industrial Methods No.155-71). C Nitrate_plus_Nitrite C - A 3 channel Technicon Autoanalyzer II was used to measure Nitrate* C Soluble Nitrate was determined by C .. by Technicon Industrial Methods No.158-71W (revised Aug 1979) C .. and is a modification of procedure by Armstrong et al. (1967). C Silicate C - A 3 channel Technicon Autoanalyzer II was used to measure Nitrate* C Dissolved Silica was determined by C .. by Technicon Industrial Methods No.186-72W, C .. essentially that of Armstrong et al (1967). C C Nutrient Sample Analysis - more info - see separate Word Document C Calcium:Total C - potentiometric titration C Carbon:Dissolved:Organic C - spectrophotometric measurements C Chlorophyll:Extracted C - After filtering, the sample was analyzed immediately or frozen for C later analysis. When freezing, the folded filter was placed in a C cone made from a paper filter (eg Whatmon #1, 9mm diameter), C labelled, then placed in a large plastic jar with silica desiccant. C The flourometer was calibrated with a spectrophotometer using C 'fucus sp.' extracted in 90% acetone. C ph:NBS C - pH on NBS Scale, "pH was determined by glass (OP-0718P) and C calomel (OP-0830P) electrodes of 'Radelkis' firm. C The digital precision pH-meter 'Radelkis' (OP-208/1) was used. C Measurements werecarried out at 24 +/- 0.1C at once after hydrocast. C Electrodes were standardized in NBS-scale by phosphate buffer C (GOST 8,135-74) ph(25)=6.86 - Russian commercial standard. C pH:SWS C - pH on Sea Water Scale, "pH was determined by glass (OP-0718P) and C calomel (OP-0830P) electrodes of 'Radelkis' firm. C The digital precision pH-meter 'Radelkis' (OP-208/1) was used. C Measurements werecarried out at 24 +/- 0.1C at once after hydrocast. C Electrodes were standardized in SWS-scale by TRIS buffer prepared C according to the prescription of Table 6 (Millero,1986) C Refs: C 1. Millero F.J. (1986) C The pH of Estuarine Water C Limnol. Oceaogr. V31, N4, pp839-847 C 2. UNESCO technical paper in marine science (1987) V5, 21p C 3. Hansson I. (1973) C A new set of acidity constants for carbonic acid and boric acid C in seawater. C Deep-Sea Res., V20, N5, pp461-478 C 4. Letter (undated) from Pavel Ya.Tishchenko (POI) C to Frank Whitney (IOS) detailing analysis procedure for pH. C Carbon:Isotope:13 C - CO2 extracted from seawater by NIWA Automated DIC Extraction system, C as per NIWA Seawater Line Manual (cryogenic vaccum removal). C C-13 samples analyzed by Nuclide Mass Spectrometer Procedure C (Forsland, 1994). C C-13 samples were measured wrt to our Working Tank (aluminum) C whose concentration was determined wrt NBS standard tank. C (technician = Valerie Forsland) C Carbon:Dissolved:Inorganic C - SOMMA-I Coulometer (Stns HS01,...,HS11 analyzed aboard ship) C Alkalinity:Total:Colorimetric C - determined by POI using Bruevich's Method (1944), C which consists of direct colorimetric titration by HCl acid in an C open system. A mixed indicator (methylene blue and methylene red) C is used to visually determine the equivalence point (color changes C from geen to light pink). The titration is carried out under a C continuous flow of CO2 free air (or nitrogen gas). C The equivalence point is reached at approximately pH 5.4 - 5.5 . C The precision of the method is about 0.2% . C Alkalinity:Total:Potentiometric C - determined by IOS using potentiometric titration in a closed cell. C IOS Alkalinity Vol,Emf data acquired from Metrohm 636 Titroprocessor C using PC program 'GTITR211.BAS'. C IOS Alkalinity was computed using PC program 'TALKY117.BAS' C Some IOS Alkalinity values were recomputed due to an Acid concentrati C recalibration on approx May 10 1991. C The original Acid Normality of 0.2506 (mol/L) was replaced by C 0.2524 (mol/L). The final corrected values are used here. C Duplicate samples are averaged - see flag "f" C C Note: POI also took CTD samples - not included here C C REFERENCES: C Carpenter, J.H. 1965 C The Chesapeake Bay Inst technique for Winkler Dissolved Oxygen Method. C Limnol. Oceanogr. 10: 141-143 C WOCE Report No. 73/91, 1991. C A comparison of methods for the determination of dissolved oxygen in C seawater. C WHPO Publication 91-2. Unpublished manuscript. C Analysis of Total Alkalinity using two methods: direct titration in C opened system. C (Bruevich) and potentiometric titration in closed system (Edmond) C by Galina Pavlova (POI), Wendy Richardson (IOS), W.Keith Johnson (IOS) C April 1993 C Comparison of three methods of determination of total alkalinity in C seawater. IOS internal paper (no author or date) C http://sam.ucsd.edu/onr_jes/talley/revelle_report.html C (some description of Bruevich Method) C Determination alkalinity of small volumes of seawater by direct titration. C In: Instruction of chemical investigation of seawater. C Bruevich C.V., 1944, Glavsevmorput, M.-L., 83p. C Alkalinity - According To C "Methods Of Hydrochemical Investigations Of The Ocean", C Moscow, Science, 1978. Method Of Bruevich. C !--1-- --2--- --3--- ---4--- --5--- --6--- --7--- --8-- --9-- ---10-- --11- ---12-- ---13-- ---14-- --15-- --16-- --17-- - !Sampl Depth Temper Salinit Oxygen Oxygen Phosph Nitra Silic Calcium Carbo Chlorop pH:NBS pH:SWS Carbon Alkali Alkali F !e_ ature: y: : : ate te_ ate :Total n:Dis hyll: :Disso nity: nity: l !Numbe Revers Bottle Dissol Dissol plus_ solve Extract lved: Total: Total ~ !r ing ved ved Nitri d:Org ed Inorga Colori a ! te anic nic metric l !----- ------ ------ ------- ------ ------ ------ ----- ----- ------- ----- ------- ------- ------- ------ ------ ------ - *END OF HEADER 7268 0.0 23.06 35.327 5.00 217.7 0.04 0.0 1.5 10.375 -99.0 0.063 8.241 8.108 1985.0 2309.0 2301.0 0 7269 10.0 22.67 35.328 4.94 215.8 0.03 0.0 1.9 10.352 -99.0 0.061 8.250 8.116 1984.3 2312.0 2310.0 0 7270 20.0 22.67 35.328 5.03 219.7 0.02 0.0 1.5 10.359 -99.0 0.083 8.246 8.111 1985.1 2316.0 2297.0 0 25.0 22.63 35.332 -99.00 -99.0 -99.00 -99.0 -99.0 -99.000 140.0 -99.000 -99.000 -99.000 -99.0 -99.0 -99.0 5 7271 30.0 22.59 35.319 4.99 217.7 0.02 0.0 2.5 10.350 -99.0 0.095 8.236 8.101 1984.8 2313.0 2312.0 0 7272 49.0 19.80 34.982 5.41 236.1 0.04 0.0 2.5 10.280 -99.0 0.083 8.217 8.081 1983.5 2292.0 2283.0 0 50.0 19.75 34.996 -99.00 -99.0 -99.00 -99.0 -99.0 -99.000 127.0 -99.000 -99.000 -99.000 -99.0 -99.0 -99.0 5 7273 74.0 18.55 34.898 5.40 235.1 0.05 0.0 2.2 10.241 -99.0 0.193 8.203 8.067 1986.8 2290.0 2287.0 0 75.0 18.52 34.936 -99.00 -99.0 -99.00 -99.0 -99.0 -99.000 135.0 -99.000 -99.000 -99.000 -99.0 -99.0 -99.0 5 100.0 17.87 34.875 -99.00 -99.0 -99.00 -99.0 -99.0 -99.000 144.0 -99.000 -99.000 -99.000 -99.0 -99.0 -99.0 5 7274 100.0 17.81 34.865 5.16 224.3 0.13 0.9 2.5 10.227 -99.0 0.342 8.186 8.048 1994.5 2286.0 2279.0 0 7275 125.0 17.46 34.820 5.09 221.4 0.18 2.0 2.9 10.215 -99.0 -99.000 8.171 8.033 2000.3 2286.0 2276.0 0 7276 151.0 17.08 34.776 4.93 214.6 0.27 3.3 3.3 10.224 -99.0 -99.000 8.152 8.013 2009.2 2278.0 2280.0 0 7277 177.0 16.51 34.754 4.89 212.6 0.38 4.4 4.2 10.223 -99.0 -99.000 8.134 7.994 2016.4 2278.0 2277.0 0 7278 201.0 16.24 34.724 4.81 209.7 0.40 5.2 5.0 10.181 -99.0 -99.000 8.075 7.977 2020.7 2285.0 2274.0 0 238.0 15.62 34.705 -99.00 -99.0 -99.00 -99.0 -99.0 -99.000 101.0 -99.000 -99.000 -99.000 -99.0 -99.0 -99.0 5 7279 250.0 15.43 34.647 4.69 203.8 0.55 7.3 6.9 10.155 -99.0 -99.000 8.092 7.952 2034.8 2276.0 2270.0 0 7280 299.0 14.34 34.563 4.64 201.8 0.96 13.2 16.1 10.155 -99.0 -99.000 8.062 7.922 2050.2 2272.0 2269.0 0 388.0 12.77 34.415 -99.00 -99.0 -99.00 -99.0 -99.0 -99.000 97.0 -99.000 -99.000 -99.000 -99.0 -99.0 -99.0 5 7281 394.0 11.94 34.384 4.66 202.7 0.96 13.2 15.6 10.109 -99.0 -99.000 7.999 7.857 2080.2 2272.0 2268.0 0 7282 495.0 9.22 34.178 4.52 196.8 1.39 18.9 26.1 10.047 -99.0 -99.000 7.912 7.770 2120.1 2259.0 2269.0 0 511.0 8.71 34.178 -99.00 -99.0 -99.00 -99.0 -99.0 -99.000 99.0 -99.000 -99.000 -99.000 -99.0 -99.0 -99.0 5 7283 565.0 7.01 34.041 3.91 170.5 1.88 25.4 42.2 10.007 -99.0 -99.000 7.806 7.663 2168.8 2277.0 2276.0 0 7284 680.0 5.44 34.040 2.81 121.7 2.44 33.2 67.2 10.023 -99.0 -99.000 7.675 7.531 2231.4 2297.0 2293.0 0 7285 786.0 4.56 34.124 1.84 79.8 2.82 39.0 90.3 10.061 -99.0 -99.000 7.606 7.462 2286.4 2315.0 2341.0 0 7286 990.0 3.63 34.295 0.97 41.9 3.14 43.5 120.7 10.142 -99.0 -99.000 7.542 7.398 2342.7 2350.0 2344.0 0 1009.0 3.58 34.300 -99.00 -99.0 -99.00 -99.0 -99.0 -99.000 95.0 -99.000 -99.000 -99.000 -99.0 -99.0 -99.0 5 7287 1171.0 3.18 34.430 0.83 36.0 3.18 44.3 136.3 10.162 -99.0 -99.000 7.544 7.399 2364.8 2376.0 2377.0 0 7288 1472.0 2.51 34.535 1.21 52.6 3.14 43.8 151.5 10.201 -99.0 -99.000 7.576 7.430 2372.7 2399.0 2396.0 0 1492.0 2.50 34.533 -99.00 -99.0 -99.00 -99.0 -99.0 -99.000 90.0 -99.000 -99.000 -99.000 -99.0 -99.0 -99.0 5 7289 2030.0 1.86 34.627 2.70 117.7 2.93 41.4 161.1 10.243 -99.0 -99.000 7.774 7.629 2361.3 2414.0 2412.0 0 7290 2561.0 1.64 34.660 2.70 117.7 2.78 39.7 158.4 10.268 -99.0 -99.000 7.693 7.548 2346.1 2414.0 2426.0 0 2615.0 1.61 34.662 -99.00 -99.0 -99.00 -99.0 -99.0 -99.000 101.0 -99.000 -99.000 -99.000 -99.0 -99.0 -99.0 5 7291 3050.0 1.55 34.677 3.14 136.2 2.70 38.2 154.4 10.259 -99.0 -99.000 7.717 7.572 2336.1 2419.0 2428.0 0 3116.0 1.50 34.673 -99.00 -99.0 -99.00 -99.0 -99.0 -99.000 105.0 -99.000 -99.000 -99.000 -99.0 -99.0 -99.0 5 7292 3576.0 1.47 34.687 3.18 138.2 2.63 37.6 150.8 10.278 -99.0 -99.000 7.735 7.590 2325.8 2416.0 2423.0 0 7293 4091.0 1.47 34.695 3.61 156.7 2.56 36.8 146.4 10.270 -99.0 -99.000 7.747 7.602 2315.0 2411.0 2428.0 0 4599.0 1.46 34.696 -99.00 -99.0 -99.00 -99.0 -99.0 -99.000 79.0 -99.000 -99.000 -99.000 -99.0 -99.0 -99.0 5 7294 4599.0 1.46 34.699 3.87 168.3 2.51 36.0 139.5 10.255 -99.0 -99.000 7.761 7.616 2305.4 2406.0 2417.0 0