*2014/11/20 09:51:17.81 *IOS HEADER VERSION 1.10 2011/10/26 2011/10/26 *FILE START TIME : UTC 1991/04/24 08:00:00.000 NUMBER OF RECORDS : 39 DATA DESCRIPTION : Bottle:Wire FILE TYPE : ASCII NUMBER OF CHANNELS : 18 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ------------------------------- --------- -------------- -------------- 1 Sample_Number n/a 2 Depth metres 0 4106 3 Temperature:Reversing 'deg C' 1.51 17.46 4 Salinity:Bottle ppt 32.963 34.799 5 Oxygen:Dissolved mL/L 1.11 5.92 6 Oxygen:Dissolved umol/kg 48.7 257.5 7 Phosphate umol/L 0.13 3.13 8 Nitrate_plus_Nitrite umol/L 1.2 44 9 Silicate umol/L 2.4 160.7 10 Calcium:Total mmol/kg 9.99 10.257 11 Carbon:Dissolved:Organic umol/L 73 168 12 Chlorophyll:Extracted mg/m^3 0.78E-01 0.342 13 pH:NBS n/a 7.583 8.21 14 pH:SWS n/a 7.442 8.069 15 Carbon:Dissolved:Inorganic umol/kg 1988.1 2366 16 Alkalinity:Total:Colorimetric umol/kg 2271 2415 17 Alkalinity:Total umol/kg 2245 2411 18 Flag:Alkalinity:Total n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 ' ' ' ' 6 NQ C ' ' 2 -99 ' ' 7 F R4 1 3 -99 ' ' 7 F R4 2 4 -99 ' ' 8 F R4 3 5 -99 ' ' 7 F R4 2 6 -99 ' ' 7 F R4 1 7 -99 ' ' 7 F R4 2 8 -99 ' ' 6 F R4 1 9 -99 ' ' 6 F R4 1 10 -99 ' ' 8 F R4 3 11 -99 ' ' 6 F R4 1 12 -99 ' ' 8 F R4 3 13 -99 ' ' 8 F R4 3 14 -99 ' ' 8 F R4 3 15 -99 ' ' 7 F R4 1 16 -99 ' ' 7 F R4 1 17 -99 ' ' 7 F R4 1 18 ' ' ' ' 2 NQ C ' ' $END $REMARKS Input data file used: ./inpoc-1991-9117-gems91-av91-010b.dat04i Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (Flag 'b' also reported as ' ') 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- References: http://www.pacificinfo.ru/en/db/poi/?show=cruise&id=116 http://www.olympus.net/ISPSO/JointAssembly97/abstracts/ip5.html (IP5i) http://pubs.usgs.gov/publications/1997-06/informal.shtml Report available only through USGS, Information Services OF 94-0230 Data and results from R/V A. Vinogradov cruises 91-AV19 $END *ADMINISTRATION MISSION : 1991-17 AGENCY : POI,IOS PROJECT : COCC 9103, POI AV19 SCIENTIST : Bychkov A./ Wong C.S. PLATFORM : Ak. A. Vinogradov $REMARKS This is OSAP Cruise 1991-17 (IOS) Previously COCC Cruise 9103 (C.S.Wong) and Russian Cruise AV19 (POI) aka Cruise Gems91 (C.S.Wong) Chief Scientist for IOS: C.S.Wong (not aboard) Chief Scientist for POI: A.Bychkov Technicians (IOS): Ron Bellegay - sample log sheets, deck log sheets, ... Keith Johnson - DOC,DIC supplies, equipment, analysis Wendy Richardson - Alkalinity supplies, equipment, analysis also some assistance with Nutrient analysis Glenn Smith - pCO2 supplies, equipment, analysis Tim Soutar - Sediment traps, Satnav/GPS Frank Whitney - Nutrient supplies, equipment - Chlorophyll supplies, equipment - Oxygen kit and supplies - POC supplies - sample DOC, Primary Productivity, POC, Chla on Leg4 Valerie Forsland - analyze DIC, pCO2 Janet Barwell-Clarke - analyze nutrients - filter samples for POC, Primary Productivity, Chla $END *LOCATION GEOGRAPHIC AREA : NW Pacific STATION : HS05 EVENT NUMBER : 3 LATITUDE : 34 57.80000 N ! (deg min) LONGITUDE : 155 2.30000 E ! (deg min) $REMARKS This was a joint Canada-Russia expedition aboard the Russian ship R/V R/V Akademik A. Vinogradov during April-May 1991, in the NW Pacific ocean. Leg1 = Vladivostok to Hawaii Leg3 = Hawaii to Taiwan Leg4 = Vladivostok to Vladivostok via Bering Sea $END *INSTRUMENT TYPE : Bottle MODEL : Niskin (10 litre) $REMARKS See details wrt various instruments in COMMENTS section $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- chem_cast_gems_1991_01.F 1.3 2004/05/05 16:23:18 39 39 CLEAN 4.6.1 2004/05/05 16:18:34 39 39 HDREDIT2 2.0 2004/05/06 11:03:51 ? ? CLEAN 4.6.1 2004/05/06 11:28:01 39 39 SORT 3.4.1 2004/06/02 11:35:39 39 39 CHANGE_FLAGS 1.0 2013/07/16 11:44:59 39 39 CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 14:31:19 39 39 CHANGE_FLAGS 2.0 2014/11/20 09:51:17 39 39 $END $REMARKS CLEAN functions: - Reset #RECS, MIN & MAX values in header. - Set header Start and End times from the data. *FAILED* CLEAN functions: - Reset #RECS, MIN & MAX values in header. - Delete Empty Channels: 0 deleted. -The following SORT parameters were used. Sorted by channel: Depth Pressure channel sorted according to values in sort channel $END *COMMENTS C Contents: C Bottle Cast (Niskin Bottles) observations for water chemistry C C Sample collection methods: C Collection device was C 10L PVC Niskin bottles (Canada) data as follows C and a Guildline CTD probe (Russia) see POI for data C http://www.pacificinfo.ru/en/db/poi/?show=cruise&id=116 C Depth C - corrected using reversing thermometer info C Sea Water Temp C - reversing thermometers C Salinity (CTD) C - Guildline AutoSal 8400 C Salinity (Bottle) C - Samples collected in glass bottles from Niskin Samplers C Oxygen:Dissolved C - no information C Phosphate C - Samples collected in 2 glass 16 x 12.5 mm test tubes. C Test tubes were twice rinsed with sample, then filled 2/3 and C stored at 4 C until analyzed. The samples were usually analyzed C within 12 hours of collection C Nitrate_plus_Nitrite C - Samples collected in 2 polystyrene 16 x 12.5 mm test tubes. C Test tubes were twice rinsed with sample, then filled 2/3 and C stored at 4 C until analyzed. The samples were usually analyzed C within 12 hours of collection C Silicate C - Samples collected in 2 polystyrene 16 x 12.5 mm test tubes. C Test tubes were twice rinsed with sample, then filled 2/3 and C stored at 4 C until analyzed. The samples were usually analyzed C within 12 hours of collection C Calcium:Total C - no information C Carbon:Dissolved:Organic C - glass ampoules, no further information C Chlorophyll:Extracted C - Samples drawn from 10L Niskin bottles into clean, volume calibrated C polyethylene bottles. The samples were filtered onto 24 mm diameter C Whatman GF/F filer (0.7 um nominal pore size) with vacuum pump C < 100 mm Hg. C ph:NBS C - no information C pH:SWS C - no information C Carbon:Isotope:13 C - Samples drawn from 10L Niskin bottles into 250ml glass bottles, C fixed with 200uL of saturated H2Cl2 solution - used ground glass C stoppers greased with Aprizon M and secured with tape/band. C Carbon:Dissolved:Inorganic C - no information C Alkalinity:Total:Colorimetric C - no information C Alkalinity:Total:Potentiometric C - no information C C Sample analysis methods: C Depth C - computed from protected and unprotected thermometer readings C Sea Water Temp C - protected reversing thermometers C Salinity (Bottle) C - analyzed onboard with a Guildline Model 8400 Autosal C Oxygen:Dissolved C - Oxygen for legs 1 & 3 were done by Russian method which C has no blank correction. C Oxygen for leg 4 was done by IOS MicroWinkler (Carpenter) method C (with blank correction). => ~+0.5 ml/L bias on Russian oxygen data. C Phosphate C - A 3 channel Technicon Autoanalyzer II was used to measure Phosphate c Soluble orthophosphate was determined by C .. by Technicon Industrial Methods No.155-71). C Nitrate_plus_Nitrite C - A 3 channel Technicon Autoanalyzer II was used to measure Nitrate* C Soluble Nitrate was determined by C .. by Technicon Industrial Methods No.158-71W (revised Aug 1979) C .. and is a modification of procedure by Armstrong et al. (1967). C Silicate C - A 3 channel Technicon Autoanalyzer II was used to measure Nitrate* C Dissolved Silica was determined by C .. by Technicon Industrial Methods No.186-72W, C .. essentially that of Armstrong et al (1967). C C Nutrient Sample Analysis - more info - see separate Word Document C Calcium:Total C - potentiometric titration C Carbon:Dissolved:Organic C - spectrophotometric measurements C Chlorophyll:Extracted C - After filtering, the sample was analyzed immediately or frozen for C later analysis. When freezing, the folded filter was placed in a C cone made from a paper filter (eg Whatmon #1, 9mm diameter), C labelled, then placed in a large plastic jar with silica desiccant. C The flourometer was calibrated with a spectrophotometer using C 'fucus sp.' extracted in 90% acetone. C ph:NBS C - pH on NBS Scale, "pH was determined by glass (OP-0718P) and C calomel (OP-0830P) electrodes of 'Radelkis' firm. C The digital precision pH-meter 'Radelkis' (OP-208/1) was used. C Measurements werecarried out at 24 +/- 0.1C at once after hydrocast. C Electrodes were standardized in NBS-scale by phosphate buffer C (GOST 8,135-74) ph(25)=6.86 - Russian commercial standard. C pH:SWS C - pH on Sea Water Scale, "pH was determined by glass (OP-0718P) and C calomel (OP-0830P) electrodes of 'Radelkis' firm. C The digital precision pH-meter 'Radelkis' (OP-208/1) was used. C Measurements werecarried out at 24 +/- 0.1C at once after hydrocast. C Electrodes were standardized in SWS-scale by TRIS buffer prepared C according to the prescription of Table 6 (Millero,1986) C Refs: C 1. Millero F.J. (1986) C The pH of Estuarine Water C Limnol. Oceaogr. V31, N4, pp839-847 C 2. UNESCO technical paper in marine science (1987) V5, 21p C 3. Hansson I. (1973) C A new set of acidity constants for carbonic acid and boric acid C in seawater. C Deep-Sea Res., V20, N5, pp461-478 C 4. Letter (undated) from Pavel Ya.Tishchenko (POI) C to Frank Whitney (IOS) detailing analysis procedure for pH. C Carbon:Isotope:13 C - CO2 extracted from seawater by NIWA Automated DIC Extraction system, C as per NIWA Seawater Line Manual (cryogenic vaccum removal). C C-13 samples analyzed by Nuclide Mass Spectrometer Procedure C (Forsland, 1994). C C-13 samples were measured wrt to our Working Tank (aluminum) C whose concentration was determined wrt NBS standard tank. C (technician = Valerie Forsland) C Carbon:Dissolved:Inorganic C - SOMMA-I Coulometer (Stns HS01,...,HS11 analyzed aboard ship) C Alkalinity:Total:Colorimetric C - determined by POI using Bruevich's Method (1944), C which consists of direct colorimetric titration by HCl acid in an C open system. A mixed indicator (methylene blue and methylene red) C is used to visually determine the equivalence point (color changes C from geen to light pink). The titration is carried out under a C continuous flow of CO2 free air (or nitrogen gas). C The equivalence point is reached at approximately pH 5.4 - 5.5 . C The precision of the method is about 0.2% . C Alkalinity:Total:Potentiometric C - determined by IOS using potentiometric titration in a closed cell. C IOS Alkalinity Vol,Emf data acquired from Metrohm 636 Titroprocessor C using PC program 'GTITR211.BAS'. C IOS Alkalinity was computed using PC program 'TALKY117.BAS' C Some IOS Alkalinity values were recomputed due to an Acid concentrati C recalibration on approx May 10 1991. C The original Acid Normality of 0.2506 (mol/L) was replaced by C 0.2524 (mol/L). The final corrected values are used here. C Duplicate samples are averaged - see flag "f" C C Note: POI also took CTD samples - not included here C C REFERENCES: C Carpenter, J.H. 1965 C The Chesapeake Bay Inst technique for Winkler Dissolved Oxygen Method. C Limnol. Oceanogr. 10: 141-143 C WOCE Report No. 73/91, 1991. C A comparison of methods for the determination of dissolved oxygen in C seawater. C WHPO Publication 91-2. Unpublished manuscript. C Analysis of Total Alkalinity using two methods: direct titration in C opened system. C (Bruevich) and potentiometric titration in closed system (Edmond) C by Galina Pavlova (POI), Wendy Richardson (IOS), W.Keith Johnson (IOS) C April 1993 C Comparison of three methods of determination of total alkalinity in C seawater. IOS internal paper (no author or date) C http://sam.ucsd.edu/onr_jes/talley/revelle_report.html C (some description of Bruevich Method) C Determination alkalinity of small volumes of seawater by direct titration. C In: Instruction of chemical investigation of seawater. C Bruevich C.V., 1944, Glavsevmorput, M.-L., 83p. C Alkalinity - According To C "Methods Of Hydrochemical Investigations Of The Ocean", C Moscow, Science, 1978. Method Of Bruevich. C !--1-- --2--- --3--- ---4--- --5--- --6--- --7--- --8-- --9-- ---10-- --11- ---12-- ---13-- ---14-- --15-- --16-- --17-- - !Sampl Depth Temper Salinit Oxygen Oxygen Phosph Nitra Silic Calcium Carbo Chlorop pH:NBS pH:SWS Carbon Alkali Alkali F !e_ ature: y: : : ate te_ ate :Total n:Dis hyll: :Disso nity: nity: l !Numbe Revers Bottle Dissol Dissol plus_ solve Extract lved: Total: Total ~ !r ing ved ved Nitri d:Org ed Inorga Colori a ! te anic nic metric l !----- ------ ------ ------- ------ ------ ------ ----- ----- ------- ----- ------- ------- ------- ------ ------ ------ - *END OF HEADER 7156 0.0 17.42 34.796 5.36 233.1 0.13 1.2 2.4 10.201 -99.0 0.313 8.197 8.055 1988.1 2278.0 2256.0 0 7157 12.0 17.43 32.963 5.06 220.7 0.13 1.2 2.4 10.217 -99.0 0.328 8.200 8.059 1989.9 2276.0 2251.0 0 7158 23.0 17.44 34.793 5.39 235.1 0.13 1.2 2.4 -99.000 -99.0 0.318 8.204 8.062 1988.8 2280.0 2251.0 0 25.0 17.44 34.772 -99.00 -99.0 -99.00 -99.0 -99.0 -99.000 103.0 -99.000 -99.000 -99.000 -99.0 -99.0 -99.0 5 7159 35.0 17.46 34.799 5.42 236.0 0.13 1.2 2.4 10.210 -99.0 0.316 8.210 8.054 1989.2 2274.0 2252.0 0 50.0 17.44 34.759 -99.00 -99.0 -99.00 -99.0 -99.0 -99.000 91.0 -99.000 -99.000 -99.000 -99.0 -99.0 -99.0 5 7160 56.0 17.44 34.799 5.35 233.1 0.13 1.2 2.4 10.214 -99.0 0.342 8.195 8.069 1989.0 2274.0 2248.0 0 75.0 17.44 34.782 -99.00 -99.0 -99.00 -99.0 -99.0 -99.000 107.0 -99.000 -99.000 -99.000 -99.0 -99.0 -99.0 5 7161 84.0 17.43 34.795 5.39 235.1 0.13 1.2 2.4 10.215 -99.0 0.338 8.195 8.054 1989.0 2276.0 2258.0 0 100.0 17.24 34.791 -99.00 -99.0 -99.00 -99.0 -99.0 -99.000 102.0 -99.000 -99.000 -99.000 -99.0 -99.0 -99.0 5 7162 111.0 17.11 34.787 5.92 257.5 0.15 1.3 2.4 10.199 -99.0 0.290 8.188 8.047 1990.6 2274.0 2249.0 0 7163 138.0 17.00 34.783 5.26 229.2 0.27 2.6 3.1 10.216 -99.0 0.078 8.182 8.040 1997.9 2276.0 2253.0 0 7164 165.0 16.86 34.782 5.25 228.2 0.25 2.9 3.5 10.183 -99.0 -99.000 8.175 8.033 2000.9 2280.0 2257.0 0 7165 218.0 16.58 34.777 5.27 229.2 0.27 3.2 3.6 10.191 -99.0 -99.000 8.170 8.028 2002.7 2285.0 2260.0 0 262.0 16.51 34.781 -99.00 -99.0 -99.00 -99.0 -99.0 -99.000 86.0 -99.000 -99.000 -99.000 -99.0 -99.0 -99.0 5 7166 266.0 16.50 34.769 5.21 227.2 0.30 3.6 3.8 10.163 -99.0 -99.000 8.167 8.026 2005.4 2277.0 2260.0 0 7167 318.0 16.06 34.709 4.77 207.7 0.47 3.2 6.3 10.170 -99.0 -99.000 8.134 7.993 2026.3 2279.0 2255.0 0 410.0 13.75 34.442 -99.00 -99.0 -99.00 -99.0 -99.0 -99.000 84.0 -99.000 -99.000 -99.000 -99.0 -99.0 -99.0 5 7168 419.0 12.90 34.445 4.89 212.5 0.82 11.0 14.6 10.132 -99.0 -99.000 8.056 7.915 2063.6 2271.0 2254.0 0 457.0 11.12 34.314 -99.00 -99.0 -99.00 -99.0 -99.0 -99.000 85.0 -99.000 -99.000 -99.000 -99.0 -99.0 -99.0 5 7169 519.0 10.60 34.310 4.07 177.3 1.35 18.4 27.2 10.094 -99.0 -99.000 7.947 7.805 2118.8 2277.0 2245.0 0 7170 618.0 8.40 34.177 3.77 163.7 1.75 24.0 41.8 10.035 -99.0 -99.000 7.864 7.722 2161.6 2285.0 2257.0 0 692.0 6.49 34.045 -99.00 -99.0 -99.00 -99.0 -99.0 -99.000 73.0 -99.000 -99.000 -99.000 -99.0 -99.0 -99.0 5 7171 718.0 5.54 33.956 3.64 158.7 2.24 30.3 60.6 9.990 -99.0 -99.000 7.762 7.621 2205.9 2288.0 2276.0 0 7172 807.0 4.78 34.061 2.42 105.2 2.64 36.3 81.8 10.026 -99.0 -99.000 7.673 7.531 2257.8 2304.0 2296.0 0 7173 994.0 4.07 34.256 1.49 65.2 2.94 41.1 110.9 10.126 -99.0 -99.000 7.605 7.464 2317.7 2337.0 2328.0 0 1013.0 3.98 34.256 -99.00 -99.0 -99.00 -99.0 -99.0 -99.000 135.0 -99.000 -99.000 -99.000 -99.0 -99.0 -99.0 5 7174 1170.0 3.28 34.355 1.11 48.7 3.10 43.1 131.5 10.203 -99.0 -99.000 7.583 7.442 2346.0 2361.0 2344.0 0 7175 1483.0 2.65 34.472 1.11 48.7 3.13 44.0 149.4 10.197 -99.0 -99.000 7.592 7.450 2364.7 2386.0 2378.0 0 1502.0 2.63 34.472 -99.00 -99.0 -99.00 -99.0 -99.0 -99.000 78.0 -99.000 -99.000 -99.000 -99.0 -99.0 -99.0 5 7181 2088.0 -99.00 34.593 1.74 -99.0 -99.00 -99.0 -99.0 10.211 -99.0 -99.000 7.642 7.502 2366.0 2404.0 -99.0 5 7176 2118.0 1.98 34.599 1.91 82.7 2.97 42.2 160.7 10.216 -99.0 -99.000 7.730 7.590 2363.7 2408.0 2402.0 0 7182? 2410.0 -99.00 34.628 2.28 -99.0 -99.00 -99.0 -99.0 10.189 -99.0 -99.000 7.688 7.548 2355.5 2404.0 -99.0 5 2568.0 1.75 34.585 -99.00 -99.0 -99.00 -99.0 -99.0 -99.000 80.0 -99.000 -99.000 -99.000 -99.0 -99.0 -99.0 5 7177 2614.0 1.69 34.644 2.58 111.9 2.84 40.4 159.8 10.206 -99.0 -99.000 7.715 7.575 2347.2 2412.0 2399.0 0 3051.0 1.58 34.646 -99.00 -99.0 -99.00 -99.0 -99.0 -99.000 168.0 -99.000 -99.000 -99.000 -99.0 -99.0 -99.0 5 7178 3110.0 1.56 34.667 3.03 131.4 2.74 39.0 155.3 10.222 -99.0 -99.000 7.732 7.592 2335.3 2415.0 2374.0 0 7179 3612.0 1.51 34.679 3.32 144.0 2.67 37.9 152.5 10.235 -99.0 -99.000 7.757 7.617 2327.2 2415.0 2411.0 0 7180 4106.0 1.52 34.704 4.54 197.5 2.62 37.2 149.8 10.257 -99.0 -99.000 7.773 7.633 2320.5 2415.0 2411.0 0