*2014/11/20 09:51:17.76 *IOS HEADER VERSION 1.10 2011/10/26 2011/10/26 *FILE START TIME : UTC 1991/04/22 21:45:00.000 NUMBER OF RECORDS : 28 DATA DESCRIPTION : Bottle:Wire FILE TYPE : ASCII NUMBER OF CHANNELS : 17 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ------------------------------- --------- -------------- -------------- 1 Sample_Number n/a 2 Depth metres 0 5748 3 Temperature:Reversing 'deg C' 1.5 17.48 4 Salinity:Bottle ppt 34.12 34.819 5 Oxygen:Dissolved mL/L 0.93 5.98 6 Oxygen:Dissolved umol/kg 40.9 260.4 7 Phosphate umol/L 0.8E-01 3.05 8 Nitrate_plus_Nitrite umol/L 0.7 43.4 9 Silicate umol/L 2.3 160.3 10 Calcium:Total mmol/kg 10.067 10.296 11 Chlorophyll:Extracted mg/m^3 0.285 0.539 12 pH:NBS n/a 7.575 8.201 13 pH:SWS n/a 7.438 8.063 14 Carbon:Dissolved:Inorganic umol/kg 1984.8 2374.8 15 Alkalinity:Total:Colorimetric umol/kg 2273 2419 16 Alkalinity:Total umol/kg 2258 2471 17 Flag:Alkalinity:Total n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 ' ' ' ' 6 NQ C ' ' 2 -99 ' ' 7 F R4 1 3 -99 ' ' 7 F R4 2 4 -99 ' ' 8 F R4 3 5 -99 ' ' 7 F R4 2 6 -99 ' ' 7 F R4 1 7 -99 ' ' 7 F R4 2 8 -99 ' ' 6 F R4 1 9 -99 ' ' 6 F R4 1 10 -99 ' ' 8 F R4 3 11 -99 ' ' 8 F R4 3 12 -99 ' ' 8 F R4 3 13 -99 ' ' 8 F R4 3 14 -99 ' ' 7 F R4 1 15 -99 ' ' 7 F R4 1 16 -99 ' ' 7 F R4 1 17 ' ' ' ' 2 NQ C ' ' $END $REMARKS Input data file used: ./inpoc-1991-9117-gems91-av91-010b.dat04i Flag channels initialized with zeros. Non-zero values have the following significance: -------------------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (Flag 'b' also reported as ' ') 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). -------------------------------------------------------------------------------------- References: http://www.pacificinfo.ru/en/db/poi/?show=cruise&id=116 http://www.olympus.net/ISPSO/JointAssembly97/abstracts/ip5.html (IP5i) http://pubs.usgs.gov/publications/1997-06/informal.shtml Report available only through USGS, Information Services OF 94-0230 Data and results from R/V A. Vinogradov cruises 91-AV19 $END *ADMINISTRATION MISSION : 1991-17 AGENCY : POI,IOS PROJECT : COCC 9103, POI AV19 SCIENTIST : Bychkov A./ Wong C.S. PLATFORM : Ak. A. Vinogradov $REMARKS This is OSAP Cruise 1991-17 (IOS) Previously COCC Cruise 9103 (C.S.Wong) and Russian Cruise AV19 (POI) aka Cruise Gems91 (C.S.Wong) Chief Scientist for IOS: C.S.Wong (not aboard) Chief Scientist for POI: A.Bychkov Technicians (IOS): Ron Bellegay - sample log sheets, deck log sheets, ... Keith Johnson - DOC,DIC supplies, equipment, analysis Wendy Richardson - Alkalinity supplies, equipment, analysis also some assistance with Nutrient analysis Glenn Smith - pCO2 supplies, equipment, analysis Tim Soutar - Sediment traps, Satnav/GPS Frank Whitney - Nutrient supplies, equipment - Chlorophyll supplies, equipment - Oxygen kit and supplies - POC supplies - sample DOC, Primary Productivity, POC, Chla on Leg4 Valerie Forsland - analyze DIC, pCO2 Janet Barwell-Clarke - analyze nutrients - filter samples for POC, Primary Productivity, Chla $END *LOCATION GEOGRAPHIC AREA : NW Pacific STATION : HS03 EVENT NUMBER : 2 LATITUDE : 36 50.90000 N ! (deg min) LONGITUDE : 149 59.40000 E ! (deg min) $REMARKS This was a joint Canada-Russia expedition aboard the Russian ship R/V R/V Akademik A. Vinogradov during April-May 1991, in the NW Pacific ocean. Leg1 = Vladivostok to Hawaii Leg3 = Hawaii to Taiwan Leg4 = Vladivostok to Vladivostok via Bering Sea $END *INSTRUMENT TYPE : Bottle MODEL : Niskin (10 litre) $REMARKS See details wrt various instruments in COMMENTS section $END *HISTORY $TABLE: PROGRAMS ! Name Vers Date Time Recs In Recs Out ! ------------------------ ------ ---------- -------- --------- --------- chem_cast_gems_1991_01.F 1.3 2004/05/05 16:23:18 28 28 CLEAN 4.6.1 2004/05/05 16:18:32 28 28 HDREDIT2 2.0 2004/05/06 11:03:51 ? ? CLEAN 4.6.1 2004/05/06 11:28:01 28 28 SORT 3.4.1 2004/06/02 11:35:37 28 28 CHANGE_FLAGS 1.0 2013/07/29 14:27:03 28 28 CHANGE_CTD_CHANNEL_NAMES 1.0 2013/12/16 14:31:19 28 28 CHANGE_FLAGS 2.0 2014/11/20 09:51:17 28 28 $END $REMARKS CLEAN functions: - Reset #RECS, MIN & MAX values in header. - Set header Start and End times from the data. *FAILED* CLEAN functions: - Reset #RECS, MIN & MAX values in header. - Delete Empty Channels: 0 deleted. -The following SORT parameters were used. Sorted by channel: Depth Pressure channel sorted according to values in sort channel $END *COMMENTS C Contents: C Bottle Cast (Niskin Bottles) observations for water chemistry C C Sample collection methods: C Collection device was C 10L PVC Niskin bottles (Canada) data as follows C and a Guildline CTD probe (Russia) see POI for data C http://www.pacificinfo.ru/en/db/poi/?show=cruise&id=116 C Depth C - corrected using reversing thermometer info C Sea Water Temp C - reversing thermometers C Salinity (CTD) C - Guildline AutoSal 8400 C Salinity (Bottle) C - Samples collected in glass bottles from Niskin Samplers C Oxygen:Dissolved C - no information C Phosphate C - Samples collected in 2 glass 16 x 12.5 mm test tubes. C Test tubes were twice rinsed with sample, then filled 2/3 and C stored at 4 C until analyzed. The samples were usually analyzed C within 12 hours of collection C Nitrate_plus_Nitrite C - Samples collected in 2 polystyrene 16 x 12.5 mm test tubes. C Test tubes were twice rinsed with sample, then filled 2/3 and C stored at 4 C until analyzed. The samples were usually analyzed C within 12 hours of collection C Silicate C - Samples collected in 2 polystyrene 16 x 12.5 mm test tubes. C Test tubes were twice rinsed with sample, then filled 2/3 and C stored at 4 C until analyzed. The samples were usually analyzed C within 12 hours of collection C Calcium:Total C - no information C Carbon:Dissolved:Organic C - glass ampoules, no further information C Chlorophyll:Extracted C - Samples drawn from 10L Niskin bottles into clean, volume calibrated C polyethylene bottles. The samples were filtered onto 24 mm diameter C Whatman GF/F filer (0.7 um nominal pore size) with vacuum pump C < 100 mm Hg. C ph:NBS C - no information C pH:SWS C - no information C Carbon:Isotope:13 C - Samples drawn from 10L Niskin bottles into 250ml glass bottles, C fixed with 200uL of saturated H2Cl2 solution - used ground glass C stoppers greased with Aprizon M and secured with tape/band. C Carbon:Dissolved:Inorganic C - no information C Alkalinity:Total:Colorimetric C - no information C Alkalinity:Total:Potentiometric C - no information C C Sample analysis methods: C Depth C - computed from protected and unprotected thermometer readings C Sea Water Temp C - protected reversing thermometers C Salinity (Bottle) C - analyzed onboard with a Guildline Model 8400 Autosal C Oxygen:Dissolved C - Oxygen for legs 1 & 3 were done by Russian method which C has no blank correction. C Oxygen for leg 4 was done by IOS MicroWinkler (Carpenter) method C (with blank correction). => ~+0.5 ml/L bias on Russian oxygen data. C Phosphate C - A 3 channel Technicon Autoanalyzer II was used to measure Phosphate c Soluble orthophosphate was determined by C .. by Technicon Industrial Methods No.155-71). C Nitrate_plus_Nitrite C - A 3 channel Technicon Autoanalyzer II was used to measure Nitrate* C Soluble Nitrate was determined by C .. by Technicon Industrial Methods No.158-71W (revised Aug 1979) C .. and is a modification of procedure by Armstrong et al. (1967). C Silicate C - A 3 channel Technicon Autoanalyzer II was used to measure Nitrate* C Dissolved Silica was determined by C .. by Technicon Industrial Methods No.186-72W, C .. essentially that of Armstrong et al (1967). C C Nutrient Sample Analysis - more info - see separate Word Document C Calcium:Total C - potentiometric titration C Carbon:Dissolved:Organic C - spectrophotometric measurements C Chlorophyll:Extracted C - After filtering, the sample was analyzed immediately or frozen for C later analysis. When freezing, the folded filter was placed in a C cone made from a paper filter (eg Whatmon #1, 9mm diameter), C labelled, then placed in a large plastic jar with silica desiccant. C The flourometer was calibrated with a spectrophotometer using C 'fucus sp.' extracted in 90% acetone. C ph:NBS C - pH on NBS Scale, "pH was determined by glass (OP-0718P) and C calomel (OP-0830P) electrodes of 'Radelkis' firm. C The digital precision pH-meter 'Radelkis' (OP-208/1) was used. C Measurements werecarried out at 24 +/- 0.1C at once after hydrocast. C Electrodes were standardized in NBS-scale by phosphate buffer C (GOST 8,135-74) ph(25)=6.86 - Russian commercial standard. C pH:SWS C - pH on Sea Water Scale, "pH was determined by glass (OP-0718P) and C calomel (OP-0830P) electrodes of 'Radelkis' firm. C The digital precision pH-meter 'Radelkis' (OP-208/1) was used. C Measurements werecarried out at 24 +/- 0.1C at once after hydrocast. C Electrodes were standardized in SWS-scale by TRIS buffer prepared C according to the prescription of Table 6 (Millero,1986) C Refs: C 1. Millero F.J. (1986) C The pH of Estuarine Water C Limnol. Oceaogr. V31, N4, pp839-847 C 2. UNESCO technical paper in marine science (1987) V5, 21p C 3. Hansson I. (1973) C A new set of acidity constants for carbonic acid and boric acid C in seawater. C Deep-Sea Res., V20, N5, pp461-478 C 4. Letter (undated) from Pavel Ya.Tishchenko (POI) C to Frank Whitney (IOS) detailing analysis procedure for pH. C Carbon:Isotope:13 C - CO2 extracted from seawater by NIWA Automated DIC Extraction system, C as per NIWA Seawater Line Manual (cryogenic vaccum removal). C C-13 samples analyzed by Nuclide Mass Spectrometer Procedure C (Forsland, 1994). C C-13 samples were measured wrt to our Working Tank (aluminum) C whose concentration was determined wrt NBS standard tank. C (technician = Valerie Forsland) C Carbon:Dissolved:Inorganic C - SOMMA-I Coulometer (Stns HS01,...,HS11 analyzed aboard ship) C Alkalinity:Total:Colorimetric C - determined by POI using Bruevich's Method (1944), C which consists of direct colorimetric titration by HCl acid in an C open system. A mixed indicator (methylene blue and methylene red) C is used to visually determine the equivalence point (color changes C from geen to light pink). The titration is carried out under a C continuous flow of CO2 free air (or nitrogen gas). C The equivalence point is reached at approximately pH 5.4 - 5.5 . C The precision of the method is about 0.2% . C Alkalinity:Total:Potentiometric C - determined by IOS using potentiometric titration in a closed cell. C IOS Alkalinity Vol,Emf data acquired from Metrohm 636 Titroprocessor C using PC program 'GTITR211.BAS'. C IOS Alkalinity was computed using PC program 'TALKY117.BAS' C Some IOS Alkalinity values were recomputed due to an Acid concentrati C recalibration on approx May 10 1991. C The original Acid Normality of 0.2506 (mol/L) was replaced by C 0.2524 (mol/L). The final corrected values are used here. C Duplicate samples are averaged - see flag "f" C C Note: POI also took CTD samples - not included here C C REFERENCES: C Carpenter, J.H. 1965 C The Chesapeake Bay Inst technique for Winkler Dissolved Oxygen Method. C Limnol. Oceanogr. 10: 141-143 C WOCE Report No. 73/91, 1991. C A comparison of methods for the determination of dissolved oxygen in C seawater. C WHPO Publication 91-2. Unpublished manuscript. C Analysis of Total Alkalinity using two methods: direct titration in C opened system. C (Bruevich) and potentiometric titration in closed system (Edmond) C by Galina Pavlova (POI), Wendy Richardson (IOS), W.Keith Johnson (IOS) C April 1993 C Comparison of three methods of determination of total alkalinity in C seawater. IOS internal paper (no author or date) C http://sam.ucsd.edu/onr_jes/talley/revelle_report.html C (some description of Bruevich Method) C Determination alkalinity of small volumes of seawater by direct titration. C In: Instruction of chemical investigation of seawater. C Bruevich C.V., 1944, Glavsevmorput, M.-L., 83p. C Alkalinity - According To C "Methods Of Hydrochemical Investigations Of The Ocean", C Moscow, Science, 1978. Method Of Bruevich. C !--1-- --2--- --3--- ---4--- --5--- --6--- --7--- --8-- --9-- ---10-- ---11-- ---12-- ---13-- --14-- --15-- --16-- - !Sampl Depth Temper Salinit Oxygen Oxygen Phosph Nitra Silic Calcium Chlorop pH:NBS pH:SWS Carbon Alkali Alkali F !e_ ature: y: : : ate te_ ate :Total hyll: :Disso nity: nity: l !Numbe Revers Bottle Dissol Dissol plus_ Extract lved: Total: Total ~ !r ing ved ved Nitri ed Inorga Colori a ! te nic metric l !----- ------ ------ ------- ------ ------ ------ ----- ----- ------- ------- ------- ------- ------ ------ ------ - *END OF HEADER 7128 0.0 17.48 34.818 5.47 238.0 0.08 0.7 2.3 10.180 0.413 8.193 8.051 1984.8 2273.0 2260.0 0 7129 13.0 17.46 34.819 5.45 237.0 0.09 0.7 2.4 10.194 0.453 8.196 8.054 1985.3 2290.0 2258.0 0 7130 26.0 17.44 34.818 5.98 260.4 0.08 0.7 2.4 10.203 0.539 8.196 8.056 1985.1 2281.0 2268.0 0 7131 39.0 17.44 34.816 -99.00 -99.0 0.08 0.8 2.4 10.196 0.516 8.192 8.053 1986.0 2281.0 2278.0 0 7132 65.0 17.44 34.815 5.40 235.1 0.08 0.8 2.4 10.188 0.476 8.198 8.059 1986.3 2285.0 2289.0 0 7133 93.0 17.43 34.814 5.36 233.1 0.08 0.8 2.4 10.199 0.420 8.201 8.063 1987.6 2285.0 2278.0 0 7134 121.0 17.29 34.813 5.25 228.2 0.09 1.0 2.5 10.204 0.285 8.201 8.063 1988.8 2281.0 2280.0 0 7135 150.0 17.14 34.812 5.26 229.2 0.18 2.7 3.4 10.203 -99.000 8.180 8.044 1996.9 2281.0 2300.0 0 7136 188.0 17.07 34.807 5.27 229.2 0.18 2.7 3.4 10.199 -99.000 8.182 8.046 1997.0 2281.0 2271.0 0 7137 233.0 16.95 34.801 5.39 235.0 0.21 2.7 3.4 10.220 -99.000 8.183 8.048 1999.1 2284.0 2289.0 0 7138 280.0 16.81 34.801 5.22 227.2 0.21 3.1 3.8 10.213 -99.000 8.177 8.043 2003.0 2284.0 2295.0 0 7139 326.0 15.99 34.700 4.55 197.9 0.52 7.3 7.7 10.227 -99.000 8.104 7.970 2035.9 2280.0 2284.0 0 7140 429.0 13.69 34.533 4.28 186.2 0.86 12.1 15.8 10.150 -99.000 8.027 7.894 2073.9 2290.0 2277.0 0 7141 533.0 10.34 34.306 4.01 174.4 1.38 18.8 30.1 10.108 -99.000 7.925 7.792 2126.4 2277.0 2290.0 0 7145 594.0 8.52 34.239 3.72 161.7 1.78 23.8 42.6 10.073 -99.000 7.889 7.753 2163.5 2279.0 2278.0 0 7142 639.0 7.50 34.175 3.43 149.0 1.96 26.4 51.8 10.088 -99.000 7.802 7.671 2187.1 2296.0 2293.0 0 7143 737.0 5.76 34.134 2.69 116.9 2.41 32.7 73.8 10.067 -99.000 7.706 7.567 2239.8 2316.0 2303.0 0 7144 840.0 4.68 34.172 1.99 86.7 2.69 37.5 94.4 10.087 -99.000 7.643 7.512 2283.8 2337.0 2330.0 0 7146 849.0 4.61 34.120 2.32 101.3 2.70 37.2 90.4 10.091 -99.000 7.661 7.524 2275.6 2321.0 2316.0 0 7147 1135.0 3.24 34.374 0.93 40.9 3.05 43.1 134.0 10.150 -99.000 7.575 7.438 2350.3 2357.0 2370.0 0 7148 1722.0 2.29 34.538 1.40 61.3 3.05 43.4 158.4 10.223 -99.000 7.604 7.467 2374.8 2402.0 2397.0 0 7149 2315.0 1.81 34.619 1.37 59.4 2.89 41.2 160.3 10.278 -99.000 7.668 7.531 2357.7 2419.0 2421.0 0 7150 2886.0 1.60 34.657 2.86 124.5 2.76 39.7 156.5 10.296 -99.000 7.712 7.575 2342.6 2406.0 2412.0 0 7151 3427.0 1.53 34.672 3.10 134.3 2.67 38.6 154.1 10.293 -99.000 7.737 7.601 2332.7 2412.0 2412.0 0 7152 4046.0 1.50 34.682 3.50 151.8 2.60 38.1 150.5 10.280 -99.000 7.754 7.617 2324.9 2413.0 2410.0 0 7153 4643.0 1.50 34.689 3.68 159.6 2.56 37.0 148.5 10.279 -99.000 7.771 7.634 2319.2 2410.0 2418.0 0 7154 5193.0 1.52 34.693 3.80 165.4 2.51 37.1 145.4 10.272 -99.000 7.911 7.636 2315.0 2408.0 2471.0 0 7155 5748.0 1.54 34.692 -99.00 -99.0 2.51 36.4 142.1 10.265 -99.000 7.781 7.644 2311.6 2401.0 2442.0 0