*2021/03/03 09:39:55.87 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2020/08/20 19:29:06.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 16 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 6AE280E4 NUMBER OF CHANNELS : 28 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- -------------------------------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 385 400 2 Bottle_Number n/a 1 16 3 Bottle:Firing_Sequence n/a 1 16 4 Pressure:CTD dbar 2.6 400.9 5 Temperature:CTD deg_C_(ITS90) 4.1771 13.7851 6 Salinity:CTD PSS-78 32.2812 33.964 7 Sigma-t:CTD kg/m^3 24.1572 26.9695 8 Transmissivity:CTD:650 %/m 52.3 59.8 9 Transmissivity:CTD:530 %/m 80.7 95.2 10 Oxygen:Dissolved:CTD:Volume ml/l 1.32 7.05 11 Oxygen:Dissolved:CTD:Mass µmol/kg 57.2 306.8 12 Fluorescence:CTD:Seapoint mg/m^3 0.8E-01 1.609 13 PAR:CTD µE/m^2/sec 0 823.1 14 Nitrate_plus_Nitrite:Bottle µmol/l 8.6 41.7 15 Flag:Nitrate_plus_Nitrite:Bottle n/a 16 Phosphate:Bottle µmol/l 0.736 2.843 17 Flag:Phosphate:Bottle n/a 18 Silicate:Bottle µmol/l 12.97 83.69 19 Flag:Silicate:Bottle n/a 20 Chlorophyll:Extracted:Bottle mg/m^3 0.1 0.46 21 Flag:Chlorophyll:Extracted:Bottle n/a 22 Phaeo-Pigment:Extracted:Bottle mg/m^3 0.2E-01 0.17 23 Dimethyl_Sulphide:Bottle nmol/l 0 3.6 24 Flag:Dimethyl_Sulphide:Bottle n/a 25 Dimethylsulfoniopropionate_Dissolved:Bottle nmol/l -99 -99 26 Flag:Dimethylsulfoniopropionate_Dissolved:Bottle n/a 27 Dimethylsulfoniopropionate_Total:Bottle nmol/l -99 -99 28 Flag:Dimethylsulfoniopropionate_Total:Bottle n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 3 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 9 F ' ' 4 7 -99 ' ' 9 F R4 4 8 -99 ' ' 6 F ' ' 1 9 -99 ' ' 6 F ' ' 1 10 -99 ' ' 7 F ' ' 2 11 -99 ' ' 6 F ' ' 1 12 -99 ' ' 8 F ' ' 3 13 -99 ' ' 7 F ' ' 1 14 -99 ' ' 6 F R4 1 15 0 ' ' 3 NQ C ' ' 16 -99 ' ' 8 F R4 3 17 0 ' ' 3 NQ C ' ' 18 -99 ' ' 7 F R4 2 19 0 ' ' 3 NQ C ' ' 20 -99 ' ' 7 F R4 2 21 0 ' ' 3 NQ C ' ' 22 -99 ' ' 7 F R4 2 23 -99 ' ' 7 F R4 2 24 0 ' ' 3 NQ C ' ' 25 -99 ' ' 7 F R4 2 26 0 ' ' 3 NQ C ' ' 27 -99 ' ' 7 F R4 2 28 0 ' ' 3 NQ C ' ' $END *ADMINISTRATION MISSION : 2020-008 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : P26 EVENT NUMBER : 77 LATITUDE : 49 59.97000 N ! (deg min) LONGITUDE : 144 59.96000 W ! (deg min) WATER DEPTH : 4250 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0443 LOCATION : Mid-ship ! custom item *COMMENTS Samples Number 385, 386, 387, 393, 395, 398, 400: DMSP-D:Bottle and DMSP-T:Bottle - samples compromised due to fridge failing while in storage. Analysis methods: ----------------- Salinity samples were collected in 200 ml type ll glass bottles with disposable nylon inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer standardized with IAPSO standard seawater 26 - 39 days after collection. For details on duplicate analysis see file 2020-008_SAL.pdf. Oxygen samples were analyzed at sea using an automated Winkler titration system (Metrohm Dosimat model 876 and a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details on duplicate analysis see file 2020-008_OXY.pdf. Nutrient samples were collected in plastic tubes. One set of samples was collected and immediately quick frozen in aluminum blocks stored in -20 freezer. Another set of samples from 400 dbar and deeper (to be used for silicate analysis) was collected and stored at 4C in the dark. All samples were returned to IOS for analysis using an Astoria analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For precision and duplicate analysis see file 2020-008_NUT.pdf. Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed at IOS ~5 weeks after the cruise. When duplicate samples were collected the average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). Flags and comments apply to chlorophyll values only. No flags or comments are assigned for Phaeopigment values. Precision Statement: Excluding degraded samples, chlorophyll values ranged from 0.04-34.88 µg/l in 119 samples. Average %CV for this cruise was 2.9% with 2 out of 24 duplicate pairs having a CV > 10% and 0 duplicate pairs having a CV > 30%. Our average dataset %CV is 3.80% for 2013 - 2018 so the overall quality of this dataset is good. For details on duplicates see file 2020-008_CHL.pdf. DMS samples were collected in 250 ml ground glass stoppered bottles and stored in a fridge, in the dark and removed one at a time before analysis. A sample was loaded onto the stripper and purged with UHP Nitrogen for 10 minutes at ~100 ml/min. The DMS was extracted from the water and absorbed on to a Tenax TA trap kept at -80C. The trap was subsequently desorbed at 100C (with a Dewar containing boiling water) onto a Chromosil 330 column which eluted onto a Flame Photometric Detector (FPD). All samples were run as soon as possible after being collected. The minimum detectable level for DMS is 0.10 nmol/l, so “0” values should be interpreted as < 0.1 nmol/l. DMS data are limited to 2 significant figures. Unless otherwise indicated the % relative difference between duplicates is < 20%. For more details see file 2020-008_DMS_report.pdf and for duplicate analysis see 2020-008_DMS.pdf. DMSP-D: Approximately 50-75 ml of seawater were allowed to flow directly from the Niskin into a filtration funnel containing a 0.7 µm GF/F filter. The first 3.5 ml were collected in a polypropylene tube (15 ml) containing 50 µl of a 50% sulphuric acid solution. DMSP-T: 3.5 ml of seawater were collected directly from the Niskin into a polypropylene tube (15 ml) containing 50 µl of a 50% sulphuric acid solution. DMSP-D and DMSP-T: Samples were stored in the dark at 4 degrees C for a minimum of 24 hours. They were hydrolized and analyzed later at the Institute of Ocean Sciences. The minimum detectable level is 0.1 nmol/l, so “0” values should be interpreted as < 0.1 nmol/l. DMSP data are limited to 2 significant figures. Unless otherwise indicated the % relative difference between duplicates is < 20%. NOTE: all DMSP data for this cruise were lost due to a freezer compressor failure at IOS. References: 1. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. Data Processing Notes: ---------------------- Transmissivity, Fluorescence and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. There were 2 WetLabs CStar transmissometers in use during this cruise: Transmissometer:CTD:650 refers to sensor #1185DR (650nm - red) Transmissometer:CTD:530 refers to sensor #1883DG (530nm - green) For comparison with other Institute of Ocean Sciences cruises, note that the transmissometer wavelength is 650 nm unless otherwise stated. NOTE: While the Fluorescence:CTD data are expressed in concentration units, they do not always compare well to extracted chlorophyll samples, particularly for casts far from shore. It is recommended that users check extracted chlorophyll values where available. The CTD fluorometer used for casts 0001 to 0050 produced steadily higher dark values after cast 0015 and compared poorly with extracted chlorophyll so those data were removed. From cast 0052 onwards a different fluorometer was used and performed well. For details on the processing see the report: 2020-008-proc.pdf. $REMARKS Quality flags have the following significance: ---------------------------------------------------------------------------------- 0 = Acceptable measurement with no header comment. 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable measurement with header comment. 3 = Questionable measurement (probably good). 4 = Poor measurement (probably bad). 5 = Measurement not reported (bad). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample was planned for this measurement from this bottle but was not collected. ----------------------------------------------------------------------------------- $END !-1-- 2- 3- --4--- ---5---- ---6---- ---7---- --8-- --9-- --10-- --11- ---12-- --13-- --14- 15 ---16-- 17 --18-- 19 --20-- 21 --22-- --23-- 24 --25-- 26 --27-- 28 !Samp Bo Bo Pressu Temperat Salinity Sigma-t: Trans Trans Oxygen Oxyge Fluores PAR: Nitra Fl Phospha Fl Silica Fl Chloro Fl Phaeo- Dimeth Fl Dimeth Fl Dimeth Fl !le_ tt tt re:CTD ure:CTD :CTD CTD missi missi :Disso n:Dis cence: CTD te_pl ag te: ag te: ag phyll: ag Pigmen yl_ ag ylsulf ag ylsulf ag !Numb ~u ~u vity: vity: lved: solve CTD: ~Nitr ~o Bottle ~o Bottle ~o Extrac ~o t:Extr Sulphi ~o ~_Diss ~o ~nate_ ~o !er mb en CTD: CTD: CTD: d:CTD Seapoin ite:B tt tt tt ted: tt acted: de: tt olved: tt Total: tt ! er ce 650 530 Volume :Mass t ottle le le le Bottle le Bottle Bottle le Bottle le Bottle le !---- -- -- ------ -------- -------- -------- ----- ----- ------ ----- ------- ------ ----- -- ------- -- ------ -- ------ -- ------ ------ -- ------ -- ------ -- *END OF HEADER 400 16 16 2.6 13.7766 32.2813 24.1589 54.0 84.5 6.08 264.8 0.196 823.1 8.7 0 0.819 0 14.81 0 0.21 0 0.03 2.30 0 -99.00 1 -99.00 1 399 15 15 5.3 13.7841 32.2814 24.1574 54.1 84.7 6.07 264.4 0.187 643.7 8.7 0 0.738 0 14.83 0 0.22 0 0.02 -99.00 0 -99.00 0 -99.00 0 398 14 14 5.4 13.7851 32.2814 24.1572 54.2 84.7 6.07 264.6 0.191 592.0 8.7 0 0.736 0 14.80 0 -99.00 0 -99.00 2.40 0 -99.00 1 -99.00 1 397 13 13 10.8 13.7796 32.2814 24.1583 54.1 84.5 6.07 264.4 0.275 313.9 8.7 0 0.838 0 14.78 0 0.22 0 0.03 2.40 0 -99.00 0 -99.00 0 396 12 12 15.4 13.7198 32.2812 24.1703 54.1 84.5 6.08 265.2 0.302 265.8 8.7 0 0.761 0 14.89 0 0.21 0 0.05 2.50 0 -99.00 0 -99.00 0 395 11 11 20.9 13.5269 32.2839 24.2113 52.3 80.7 6.15 268.0 0.471 180.7 8.8 0 0.794 0 15.47 0 0.32 6 0.09 3.60 6 -99.00 1 -99.00 1 394 10 10 25.9 13.5045 32.2834 24.2154 52.8 81.5 6.14 267.6 0.589 136.7 8.8 0 0.921 0 15.47 0 0.31 0 0.10 3.40 0 -99.00 0 -99.00 0 393 9 9 30.1 12.3009 32.3064 24.4676 54.5 85.2 6.40 278.8 0.570 132.5 8.6 0 0.928 0 13.04 0 0.30 0 0.08 1.30 0 -99.00 1 -99.00 1 392 8 8 40.3 9.5505 32.3956 25.0183 53.3 82.7 6.88 299.7 0.950 66.3 9.7 0 0.995 0 12.97 0 0.42 6 0.13 0.92 0 -99.00 0 -99.00 0 391 7 7 50.3 7.1108 32.4791 25.4444 53.6 82.6 7.05 306.8 1.609 28.2 12.4 0 1.159 0 15.74 0 0.46 0 0.17 0.79 0 -99.00 0 -99.00 0 390 6 6 61.1 6.3215 32.5130 25.5738 57.0 89.3 6.94 302.0 0.762 11.7 14.2 0 1.263 0 18.31 0 0.30 0 0.13 -99.00 0 -99.00 0 -99.00 0 389 5 5 75.8 5.9225 32.5338 25.6395 58.2 91.9 6.95 302.4 0.476 4.8 15.5 0 1.326 0 20.57 0 0.22 0 0.13 0.31 0 -99.00 0 -99.00 0 388 4 4 100.8 5.3764 32.5911 25.7492 59.2 94.0 6.87 299.1 0.236 1.2 17.5 0 1.447 0 24.56 0 0.10 0 0.06 0.19 0 -99.00 0 -99.00 0 387 3 3 150.6 5.3655 33.4680 26.4445 59.3 94.1 4.54 197.6 0.109 0.1 26.8 6 1.910 6 40.28 6 -99.00 0 -99.00 0.00 0 -99.00 1 -99.00 1 386 2 2 200.4 4.7874 33.7140 26.7054 59.2 94.1 3.21 139.4 0.087 0.0 33.4 0 2.303 0 56.67 0 -99.00 0 -99.00 0.00 0 -99.00 1 -99.00 1 385 1 1 400.9 4.1771 33.9640 26.9695 59.8 95.2 1.32 57.2 0.080 0.0 41.7 0 2.843 0 83.69 0 -99.00 0 -99.00 0.00 0 -99.00 1 -99.00 1