*2021/04/22 15:09:27.05 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2020/02/13 01:34:47.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 24 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 143E2A09 NUMBER OF CHANNELS : 23 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 281 304 2 Bottle_Number n/a 1 24 3 Bottle:Firing_Sequence n/a 1 24 4 Pressure:CTD dbar 5.6 3684.6 5 Temperature:CTD deg_C_(ITS90) 1.5758 8.4304 6 Salinity:CTD PSS-78 32.31 34.6668 7 Sigma-t:CTD kg/m^3 25.1248 27.7629 8 Transmissivity:CTD:650 %/m 53.5 57.2 9 Transmissivity:CTD:530 %/m 88.8 96.7 10 Oxygen:Dissolved:CTD:Volume ml/l 0.26 6.62 11 Oxygen:Dissolved:CTD:Mass µmol/kg 11.3 288.4 12 Fluorescence:CTD:Seapoint mg/m^3 0.64E-01 0.861 13 Salinity:Bottle PSS-78 32.3087 34.6657 14 Flag:Salinity:Bottle n/a 15 Oxygen:Dissolved:Bottle:Volume ml/l 0.238 6.636 16 Oxygen:Dissolved:Bottle:Mass µmol/kg 10.3 289 17 Flag:Oxygen:Dissolved:Bottle n/a 18 Nitrate_plus_Nitrite:Bottle µmol/l 7.2 45 19 Flag:Nitrate_plus_Nitrite:Bottle n/a 20 Phosphate:Bottle µmol/l 0.907 3.301 21 Flag:Phosphate:Bottle n/a 22 Silicate:Bottle µmol/l 6.35 180.64 23 Flag:Silicate:Bottle n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 3 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 9 F ' ' 4 7 -99 ' ' 9 F R4 4 8 -99 ' ' 6 F ' ' 1 9 -99 ' ' 6 F ' ' 1 10 -99 ' ' 7 F ' ' 2 11 -99 ' ' 6 F ' ' 1 12 -99 ' ' 8 F ' ' 3 13 -99 ' ' 9 F R4 4 14 0 ' ' 3 NQ C ' ' 15 -99 ' ' 8 F R4 3 16 -99 ' ' 6 F ' ' 1 17 0 ' ' 3 NQ C ' ' 18 -99 ' ' 6 F R4 1 19 0 ' ' 3 NQ C ' ' 20 -99 ' ' 8 F R4 3 21 0 ' ' 3 NQ C ' ' 22 -99 ' ' 7 F R4 2 23 0 ' ' 3 NQ C ' ' $END *ADMINISTRATION MISSION : 2020-001 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : P16 EVENT NUMBER : 46 LATITUDE : 49 16.97000 N ! (deg min) LONGITUDE : 134 39.92000 W ! (deg min) WATER DEPTH : 3660 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 443 LOCATION : Mid-ship ! custom item *COMMENTS Sample Number 281: OXY:Bottle - two stir bars in sample. One was recovered using forceps. Sample Number 283: NIT:Bottle and PHOS:Bottle - frozen tube cracked and sample contaminated. Sample Number 284: SIL:Bottle - Chauvenet outlier in duplicate study. Samples Number 284 and 299: PHOS:Bottle - analysis error resulted in poor duplicate values, only one value available. Sample Number 289: SAL:Bottle - reported only one duplicate. The other duplicate value was an outlier when compared to the CTD salinity sensor. Sample Number 294: ALL: Niskin bottom cap was leaking. Sample Number 296: OXY:Bottle - sample over-titrated. Sample Number 304: SAL:Bottle - screw cap was nearly off. Insert was not seated properly. Analysis methods: ----------------- Salinity samples were collected in 200 ml type ll glass bottles with disposable nylon inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer standardized with IAPSO standard seawater 17 - 32 days after collection. For details on duplicate analysis see file 2020-001_SAL.pdf. Oxygen samples were analyzed at sea using an automated Winkler titration system (Metrohm Dosimat model 876 and a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details on duplicate analysis see file 2020-001_OXY.pdf. Nutrient samples were collected in plastic tubes. One set of samples was collected and immediately quick frozen in aluminum blocks stored in -20 freezer. Another set of samples from 400 dbar and deeper (to be used for silicate analysis) was collected and stored at 4C in the dark. All samples were returned to IOS for analysis using an Astoria analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For precision and duplicate analysis see file 2020-001_NUT.pdf. Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed at IOS ~1 to 7 weeks after the cruise, during the COVID-19 pandemic restriction. When duplicate samples were collected the average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). Flags and comments apply to chlorophyll values only. No flags or comments are assigned for Phaeopigment values. Precision Statement: Chlorophyll values ranged from 0.02-1.11 µg/l in 171 samples. Average %CV for this cruise was 2.24% with 0 out of 52 duplicate pairs having a CV > 10% and 0 duplicate pairs having a CV > 30%. Our average dataset %CV is 3.80% for 2013 - 2018 so the overall quality of this dataset is excellent. For details on duplicates see file 2020-001_CHL.pdf. DMS samples were collected in 250 ml ground glass stoppered bottles and stored in a fridge, in the dark and removed one at a time before analysis. A sample was loaded onto the stripper and purged with UHP Nitrogen for 10 minutes at ~100 ml/min. The DMS was extracted from the water and absorbed on to a Tenax TA trap kept at -80C. The trap was subsequently desorbed at 100C (with a Dewar containing boiling water) onto a Chromosil 330 column which eluted onto a Flame Photometric Detector (FPD). All samples were run as soon as possible after being collected. Many samples were run but had bad calibration and data were not logical. Many other samples were planned to be collected but were not due to the instrument problems. The minimum detectable level for DMS is 0.10 nmol/l, so “0” values should be interpreted as < 0.1 nmol/l. DMS data are limited to 2 significant figures. Unless otherwise indicated the % relative difference between duplicates is < 20%. For more details see file 2020-001_DMS_report.pdf and for duplicate analysis see 2020-001_DMS.pdf. DMSP-D: Approximately 50-75 ml of seawater were allowed to flow directly from the Niskin into a filtration funnel containing a 0.7 µm GF/F filter. The first 3.5 ml were collected in a polypropylene tube (15 ml) containing 50 µl of a 50% sulphuric acid solution. DMSP-T: 3.5 ml of seawater were collected directly from the Niskin into a polypropylene tube (15 ml) containing 50 µl of a 50% sulphuric acid solution. DMSP-D and DMSP-T: Samples were stored in the dark at 4 degrees C for a minimum of 24 hours. They were hydrolized and analyzed later at the Institute of Ocean Sciences. The minimum detectable level is 0.1 nmol/l, so “0” values should be interpreted as < 0.1 nmol/l. DMSP data are limited to 2 significant figures. Unless otherwise indicated the % relative difference between duplicates is < 20%. There were some detectable concentrations for DMSP-D & DMSP-T at 200m for this cruise. It is uncertain as to the validity of these "hits" because there are not enough historical data to support them, nor are there DMS data for this cruise due to instrument problems. For more details see file 2020-001_DMS_report.pdf and for duplicate analysis see 2020-001_DMSP.pdf. References: 1. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. Data Processing Notes: ---------------------- Transmissivity, Fluorescence and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. There were 2 WetLabs CStar transmissometers in use during this cruise: Transmissometer:CTD:530 refers to sensor #1883DG (530nm - green) Transmissometer:CTD:650 refers to sensor #1185DR (650nm - red) For comparison with other Institute of Ocean Sciences cruises, note that the transmissometer wavelength is 650 nm unless otherwise stated. NOTE: While the Fluorescence:CTD data are expressed in concentration units, they do not always compare well to extracted chlorophyll samples, particularly for casts far from shore. It is recommended that users check extracted chlorophyll values where available. For details on the processing see the report: 2020-001-proc.pdf. $REMARKS Quality flags have the following significance: ---------------------------------------------------------------------------------- 0 = Acceptable measurement with no header comment. 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable measurement with header comment. 3 = Questionable measurement (probably good). 4 = Poor measurement (probably bad). 5 = Measurement not reported (bad). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample was planned for this measurement from this bottle but was not collected. ----------------------------------------------------------------------------------- $END !-1-- 2- 3- --4--- ---5---- ---6---- ---7---- --8-- --9-- --10-- --11- ---12-- ---13--- 14 ---15-- --16- 17 --18- 19 ---20-- 21 --22-- 23 !Samp Bo Bo Pressu Temperat Salinity Sigma-t: Trans Trans Oxygen Oxyge Fluores Salinity Fl Oxygen: Oxyge Fl Nitra Fl Phospha Fl Silica Fl !le_ tt tt re:CTD ure:CTD :CTD CTD missi missi :Disso n:Dis cence: :Bottle ag Dissolv n:Dis ag te_pl ag te: ag te: ag !Numb ~u ~u vity: vity: lved: solve CTD: ~o ed: ~ed:B ~o ~Nitr ~o Bottle ~o Bottle ~o !er mb en CTD: CTD: CTD: d:CTD Seapoin tt Bottle: ottle tt ite:B tt tt tt ! er ce 650 530 Volume :Mass t le Volume :Mass le ottle le le le !---- -- -- ------ -------- -------- -------- ----- ----- ------ ----- ------- -------- -- ------- ----- -- ----- -- ------- -- ------ -- *END OF HEADER 304 24 24 5.6 8.4294 32.3102 25.1250 53.5 88.8 6.62 288.4 0.861 32.3087 4 6.628 288.7 0 7.2 0 0.907 0 6.35 0 303 23 23 9.5 8.4304 32.3101 25.1248 53.5 89.0 6.62 288.3 0.859 -99.0000 0 6.626 288.6 0 7.2 0 0.914 0 6.42 0 302 22 22 25.1 8.4291 32.3100 25.1249 53.5 88.8 6.62 288.1 0.851 -99.0000 0 6.636 289.0 6 7.2 0 0.907 0 6.38 0 301 21 21 50.1 8.4282 32.3125 25.1270 53.8 89.4 6.61 287.7 0.823 -99.0000 0 6.621 288.3 0 7.2 0 0.914 0 6.37 0 300 20 20 75.0 8.2879 32.3269 25.1590 54.9 91.7 6.53 284.3 0.542 -99.0000 0 6.566 285.9 0 7.9 0 0.956 0 7.16 0 299 19 19 100.6 7.8572 32.5744 25.4158 56.0 93.9 6.02 262.3 0.265 -99.0000 0 6.075 264.5 0 11.9 6 1.174 2 12.20 6 298 18 18 125.8 6.7293 33.0464 25.9419 56.3 94.9 5.41 235.6 0.117 -99.0000 0 5.483 238.6 0 18.9 0 1.548 0 22.84 0 297 17 17 150.8 6.3395 33.4441 26.3062 56.5 95.3 5.06 220.1 0.084 -99.0000 0 5.000 217.5 0 22.2 0 1.693 0 30.37 0 296 16 16 175.0 6.3982 33.6534 26.4638 56.6 95.3 4.66 202.6 0.075 -99.0000 0 4.684 203.7 2 23.7 0 1.741 0 34.92 0 295 15 15 200.2 6.4639 33.7919 26.5646 56.6 95.3 4.06 176.4 0.074 -99.0000 0 4.074 177.2 0 26.2 0 1.893 0 40.73 0 294 14 14 250.8 5.8349 33.8672 26.7039 56.7 95.6 3.00 130.4 0.074 -99.0000 0 3.003 130.6 36 32.0 2 2.301 2 54.67 2 293 13 13 300.7 5.3594 33.8742 26.7669 56.9 95.7 2.64 114.7 0.073 -99.0000 0 2.641 114.8 0 34.2 0 2.468 0 62.25 0 292 12 12 400.2 4.8646 33.9617 26.8932 57.0 95.9 1.48 64.3 0.073 -99.0000 0 1.472 64.0 0 39.7 0 2.850 0 78.92 0 291 11 11 600.5 4.2354 34.1592 27.1186 57.1 96.2 0.45 19.6 0.072 -99.0000 0 0.432 18.8 0 43.5 0 3.181 0 105.54 0 290 10 10 799.4 3.8368 34.2841 27.2591 57.0 96.0 0.26 11.3 0.073 -99.0000 0 0.238 10.3 0 44.4 0 3.279 0 121.22 0 289 9 9 999.9 3.3344 34.3734 27.3795 57.0 96.0 0.27 11.5 0.073 34.3677 2 0.246 10.7 0 44.8 0 3.301 0 136.91 0 288 8 8 1251.4 2.7298 34.4413 27.4890 57.0 96.2 0.37 15.9 0.072 34.4376 0 0.336 14.6 6 45.0 0 3.271 0 154.78 0 287 7 7 1500.7 2.3966 34.4997 27.5643 57.1 96.2 0.57 24.9 0.071 34.5002 0 0.540 23.5 0 44.6 0 3.212 0 163.84 0 286 6 6 2001.0 1.9550 34.5836 27.6673 57.2 96.4 1.30 56.3 0.068 34.5777 0 1.274 55.4 0 42.8 0 3.069 0 173.68 0 285 5 5 2502.3 1.7693 34.6227 27.7130 57.2 96.7 1.83 79.4 0.066 34.6187 6 1.814 78.8 6 41.4 0 2.957 0 175.93 0 284 4 4 3001.6 1.6234 34.6500 27.7459 57.2 96.7 2.35 102.2 0.065 34.6500 0 2.366 102.8 0 39.8 6 2.840 2 178.81 36 283 3 3 3498.2 1.5780 34.6636 27.7602 57.0 96.3 2.64 114.9 0.064 34.6657 0 2.656 115.4 0 -99.0 5 -99.000 5 179.02 0 282 2 2 3498.2 1.5778 34.6639 27.7605 57.0 96.3 2.64 114.6 0.064 34.6633 6 2.663 115.7 0 39.0 0 2.773 0 179.60 0 281 1 1 3684.6 1.5758 34.6668 27.7629 56.6 95.6 2.71 117.8 0.064 -99.0000 0 2.695 117.1 3 38.8 0 2.758 0 180.64 0