*2021/04/22 15:09:25.20 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2020/02/08 22:22:38.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 22 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 933FB312 NUMBER OF CHANNELS : 22 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 1 22 2 Bottle_Number n/a 1 22 3 Bottle:Firing_Sequence n/a 1 22 4 Pressure:CTD dbar 10.1 216.8 5 Temperature:CTD deg_C_(ITS90) 8.0332 9.7344 6 Salinity:CTD PSS-78 28.9532 31.3445 7 Sigma-t:CTD kg/m^3 22.5334 24.168 8 Transmissivity:CTD:650 %/m 35.3 52.8 9 Transmissivity:CTD:530 %/m 51.1 83.6 10 Oxygen:Dissolved:CTD:Volume ml/l 0.6E-01 5.49 11 Oxygen:Dissolved:CTD:Mass µmol/kg 2.7 239.5 12 Fluorescence:CTD:Seapoint mg/m^3 0.97E-01 0.411 13 PAR:CTD µE/m^2/sec 0 1.8 14 Oxygen:Dissolved:Bottle:Volume ml/l 0 5.44 15 Oxygen:Dissolved:Bottle:Mass µmol/kg 0 237.5 16 Flag:Oxygen:Dissolved:Bottle n/a 17 Nitrate_plus_Nitrite:Bottle µmol/l 17.1 28.2 18 Flag:Nitrate_plus_Nitrite:Bottle n/a 19 Phosphate:Bottle µmol/l 2.378 6.07 20 Flag:Phosphate:Bottle n/a 21 Silicate:Bottle µmol/l 58.29 121.65 22 Flag:Silicate:Bottle n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 3 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 9 F ' ' 4 7 -99 ' ' 9 F R4 4 8 -99 ' ' 6 F ' ' 1 9 -99 ' ' 6 F ' ' 1 10 -99 ' ' 7 F ' ' 2 11 -99 ' ' 6 F ' ' 1 12 -99 ' ' 8 F ' ' 3 13 -99 ' ' 7 F ' ' 1 14 -99 ' ' 8 F R4 3 15 -99 ' ' 6 F ' ' 1 16 0 ' ' 3 NQ C ' ' 17 -99 ' ' 6 F R4 1 18 0 ' ' 3 NQ C ' ' 19 -99 ' ' 8 F R4 3 20 0 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 0 ' ' 3 NQ C ' ' $END *ADMINISTRATION MISSION : 2020-001 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : SI03 EVENT NUMBER : 1 LATITUDE : 48 35.42000 N ! (deg min) LONGITUDE : 123 30.30000 W ! (deg min) WATER DEPTH : 228 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 443 LOCATION : Mid-ship ! custom item *COMMENTS Sample Number 3: NIT:Bottle - sample not analyzed due to anoxic water. Sample Number 4: NIT:Bottle - sample analyzed, however, no result reported due to anoxic water. Sample Number 11: NIT:Bottle - value possibly incorrect due to low oxygen water. Analysis methods: ----------------- Salinity samples were collected in 200 ml type ll glass bottles with disposable nylon inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer standardized with IAPSO standard seawater 17 - 32 days after collection. For details on duplicate analysis see file 2020-001_SAL.pdf. Oxygen samples were analyzed at sea using an automated Winkler titration system (Metrohm Dosimat model 876 and a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details on duplicate analysis see file 2020-001_OXY.pdf. Nutrient samples were collected in plastic tubes. One set of samples was collected and immediately quick frozen in aluminum blocks stored in -20 freezer. Another set of samples from 400 dbar and deeper (to be used for silicate analysis) was collected and stored at 4C in the dark. All samples were returned to IOS for analysis using an Astoria analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For precision and duplicate analysis see file 2020-001_NUT.pdf. Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed at IOS ~1 to 7 weeks after the cruise, during the COVID-19 pandemic restriction. When duplicate samples were collected the average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). Flags and comments apply to chlorophyll values only. No flags or comments are assigned for Phaeopigment values. Precision Statement: Chlorophyll values ranged from 0.02-1.11 µg/l in 171 samples. Average %CV for this cruise was 2.24% with 0 out of 52 duplicate pairs having a CV > 10% and 0 duplicate pairs having a CV > 30%. Our average dataset %CV is 3.80% for 2013 - 2018 so the overall quality of this dataset is excellent. For details on duplicates see file 2020-001_CHL.pdf. DMS samples were collected in 250 ml ground glass stoppered bottles and stored in a fridge, in the dark and removed one at a time before analysis. A sample was loaded onto the stripper and purged with UHP Nitrogen for 10 minutes at ~100 ml/min. The DMS was extracted from the water and absorbed on to a Tenax TA trap kept at -80C. The trap was subsequently desorbed at 100C (with a Dewar containing boiling water) onto a Chromosil 330 column which eluted onto a Flame Photometric Detector (FPD). All samples were run as soon as possible after being collected. Many samples were run but had bad calibration and data were not logical. Many other samples were planned to be collected but were not due to the instrument problems. The minimum detectable level for DMS is 0.10 nmol/l, so “0” values should be interpreted as < 0.1 nmol/l. DMS data are limited to 2 significant figures. Unless otherwise indicated the % relative difference between duplicates is < 20%. For more details see file 2020-001_DMS_report.pdf and for duplicate analysis see 2020-001_DMS.pdf. DMSP-D: Approximately 50-75 ml of seawater were allowed to flow directly from the Niskin into a filtration funnel containing a 0.7 µm GF/F filter. The first 3.5 ml were collected in a polypropylene tube (15 ml) containing 50 µl of a 50% sulphuric acid solution. DMSP-T: 3.5 ml of seawater were collected directly from the Niskin into a polypropylene tube (15 ml) containing 50 µl of a 50% sulphuric acid solution. DMSP-D and DMSP-T: Samples were stored in the dark at 4 degrees C for a minimum of 24 hours. They were hydrolized and analyzed later at the Institute of Ocean Sciences. The minimum detectable level is 0.1 nmol/l, so “0” values should be interpreted as < 0.1 nmol/l. DMSP data are limited to 2 significant figures. Unless otherwise indicated the % relative difference between duplicates is < 20%. There were some detectable concentrations for DMSP-D & DMSP-T at 200m for this cruise. It is uncertain as to the validity of these "hits" because there are not enough historical data to support them, nor are there DMS data for this cruise due to instrument problems. For more details see file 2020-001_DMS_report.pdf and for duplicate analysis see 2020-001_DMSP.pdf. References: 1. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. Data Processing Notes: ---------------------- Transmissivity, Fluorescence and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. There were 2 WetLabs CStar transmissometers in use during this cruise: Transmissometer:CTD:530 refers to sensor #1883DG (530nm - green) Transmissometer:CTD:650 refers to sensor #1185DR (650nm - red) For comparison with other Institute of Ocean Sciences cruises, note that the transmissometer wavelength is 650 nm unless otherwise stated. NOTE: While the Fluorescence:CTD data are expressed in concentration units, they do not always compare well to extracted chlorophyll samples, particularly for casts far from shore. It is recommended that users check extracted chlorophyll values where available. For details on the processing see the report: 2020-001-proc.pdf. $REMARKS Quality flags have the following significance: ---------------------------------------------------------------------------------- 0 = Acceptable measurement with no header comment. 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable measurement with header comment. 3 = Questionable measurement (probably good). 4 = Poor measurement (probably bad). 5 = Measurement not reported (bad). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample was planned for this measurement from this bottle but was not collected. ----------------------------------------------------------------------------------- $END !-1-- 2- 3- --4--- ---5---- ---6---- ---7---- --8-- --9-- --10-- --11- ---12-- --13-- ---14-- --15- 16 --17- 18 ---19-- 20 --21-- 22 !Samp Bo Bo Pressu Temperat Salinity Sigma-t: Trans Trans Oxygen Oxyge Fluores PAR: Oxygen: Oxyge Fl Nitra Fl Phospha Fl Silica Fl !le_ tt tt re:CTD ure:CTD :CTD CTD missi missi :Disso n:Dis cence: CTD Dissolv n:Dis ag te_pl ag te: ag te: ag !Numb ~u ~u vity: vity: lved: solve CTD: ed: ~ed:B ~o ~Nitr ~o Bottle ~o Bottle ~o !er mb en CTD: CTD: CTD: d:CTD Seapoin Bottle: ottle tt ite:B tt tt tt ! er ce 650 530 Volume :Mass t Volume :Mass le ottle le le le !---- -- -- ------ -------- -------- -------- ----- ----- ------ ----- ------- ------ ------- ----- -- ----- -- ------- -- ------ -- *END OF HEADER 22 22 22 10.1 8.1582 28.9532 22.5334 37.9 55.4 5.42 236.6 0.407 1.8 -99.000 -99.0 0 -99.0 0 -99.000 0 -99.00 0 21 21 21 10.2 8.1096 28.9618 22.5468 37.9 55.8 5.49 239.5 0.411 1.8 -99.000 -99.0 0 -99.0 0 -99.000 0 -99.00 0 20 20 20 19.9 8.0332 29.3183 22.8367 35.3 51.1 5.43 237.2 0.344 0.2 5.440 237.5 0 27.6 0 2.378 0 58.70 0 19 19 19 40.0 8.3984 29.7923 23.1570 43.8 67.9 4.95 216.2 0.230 0.0 4.780 208.6 0 28.1 0 2.464 0 59.11 0 18 18 18 60.0 8.9316 30.1360 23.3482 48.9 77.2 4.15 180.9 0.152 0.0 3.912 170.7 0 28.2 0 2.555 0 58.29 0 17 17 17 75.2 8.7513 30.4454 23.6170 47.2 74.1 4.16 181.4 0.129 0.0 4.151 181.0 0 27.8 0 2.571 0 58.72 0 16 16 16 84.9 8.7324 30.5642 23.7127 44.8 69.7 3.91 170.7 0.135 0.0 3.567 155.6 0 26.9 0 2.769 0 61.85 0 15 15 15 90.0 9.0132 30.7288 23.7995 42.2 64.8 2.92 127.2 0.125 0.0 2.693 117.4 0 25.7 0 3.040 0 66.88 0 14 14 14 97.0 9.2268 30.8413 23.8548 44.6 69.1 2.25 98.2 0.113 0.0 1.490 65.0 0 22.5 0 3.459 0 72.88 0 13 13 13 100.1 9.3807 30.9456 23.9125 44.6 69.2 1.37 59.8 0.106 0.0 -99.000 -99.0 0 -99.0 0 -99.000 0 -99.00 0 12 12 12 100.1 9.3648 30.9365 23.9078 44.6 69.5 1.36 59.3 0.105 0.0 -99.000 -99.0 0 -99.0 0 -99.000 0 -99.00 0 11 11 11 110.2 9.5650 31.0978 24.0024 42.5 64.1 0.51 22.2 0.100 0.0 0.428 18.7 0 17.1 3 4.026 0 81.32 0 10 10 10 119.8 9.6493 31.1761 24.0501 42.5 64.1 0.13 5.7 0.097 0.0 -99.000 -99.0 0 -99.0 0 -99.000 0 -99.00 0 9 9 9 119.8 9.6488 31.1753 24.0496 42.9 65.2 0.12 5.4 0.097 0.0 -99.000 -99.0 0 -99.0 0 -99.000 0 -99.00 0 8 8 8 135.0 9.7271 31.2683 24.1097 48.3 74.8 0.07 2.8 0.100 0.0 -99.000 -99.0 0 -99.0 0 -99.000 0 -99.00 0 7 7 7 135.0 9.7273 31.2690 24.1102 48.3 75.1 0.06 2.7 0.100 0.0 -99.000 -99.0 0 -99.0 0 -99.000 0 -99.00 0 6 6 6 150.0 9.7314 31.2931 24.1283 47.0 73.1 0.07 3.0 0.106 0.0 -99.000 -99.0 0 -99.0 0 -99.000 0 -99.00 0 5 5 5 150.0 9.7315 31.2926 24.1279 42.7 73.3 0.07 3.0 0.106 0.0 -99.000 -99.0 0 -99.0 0 -99.000 0 -99.00 0 4 4 4 185.0 9.7254 31.3271 24.1558 52.5 83.6 0.07 3.1 0.114 0.0 0.000 0.0 0 -99.0 1 6.070 0 121.65 0 3 3 3 185.0 9.7253 31.3271 24.1559 52.4 83.6 0.07 3.1 0.114 0.0 0.000 0.0 0 -99.0 5 6.045 0 119.65 0 2 2 2 200.3 9.7311 31.3382 24.1636 52.5 83.2 0.07 3.2 0.115 0.0 -99.000 -99.0 0 -99.0 0 -99.000 0 -99.00 0 1 1 1 216.8 9.7344 31.3445 24.1680 52.8 83.6 0.08 3.4 0.118 0.0 -99.000 -99.0 0 -99.0 0 -99.000 0 -99.00 0