*2021/06/08 14:06:26.82 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2019/06/09 11:25:28.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 24 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : C931C962 NUMBER OF CHANNELS : 23 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ----------------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 422 445 2 Bottle_Number n/a 1 24 3 Bottle:Firing_Sequence n/a 1 24 4 Pressure:CTD dbar 2.9 3998.9 5 Temperature:CTD deg_C_(ITS90) 1.53 11.0657 6 Salinity:CTD PSS-78 32.3266 34.677 7 Sigma-t:CTD kg/m^3 24.709 27.7743 8 Transmissivity:CTD:650 %/m 4.2 54 9 Transmissivity:CTD:530 %/m 8.2 94 10 Oxygen:Dissolved:CTD:Volume ml/l 0.3 6.86 11 Oxygen:Dissolved:CTD:Mass µmol/kg 12.9 298.5 12 Fluorescence:CTD:Seapoint mg/m^3 0.101 6.025 13 Salinity:Bottle PSS-78 32.3271 34.6713 14 Flag:Salinity:Bottle n/a 15 Nitrate_plus_Nitrite:Bottle µmol/l 2.93 2.93 16 Flag:Nitrate_plus_Nitrite:Bottle n/a 17 Phosphate:Bottle µmol/l 0.603 0.603 18 Flag:Phosphate:Bottle n/a 19 Silicate:Bottle µmol/l 0.84 0.84 20 Flag:Silicate:Bottle n/a 21 Chlorophyll:Extracted:Bottle mg/m^3 1.45 1.45 22 Flag:Chlorophyll:Extracted:Bottle n/a 23 Phaeo-Pigment:Extracted:Bottle mg/m^3 0.18 0.18 $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 3 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 9 F ' ' 4 7 -99 ' ' 9 F R4 4 8 -99 ' ' 6 F ' ' 1 9 -99 ' ' 6 F ' ' 1 10 -99 ' ' 7 F ' ' 2 11 -99 ' ' 6 F ' ' 1 12 -99 ' ' 8 F ' ' 3 13 -99 ' ' 9 F R4 4 14 0 ' ' 3 NQ C ' ' 15 -99 ' ' 7 F R4 2 16 0 ' ' 3 NQ C ' ' 17 -99 ' ' 8 F R4 3 18 0 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 0 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 0 ' ' 3 NQ C ' ' 23 -99 ' ' 7 F R4 2 $END *ADMINISTRATION MISSION : 2019-006 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : P22 EVENT NUMBER : 69 LATITUDE : 49 42.01000 N ! (deg min) LONGITUDE : 140 39.95000 W ! (deg min) WATER DEPTH : 3917 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0506 LOCATION : Mid-ship ! custom item *COMMENTS Sample Number 423: SAL:Bottle - took four conductivity readings keeping last two. Analysis methods: ----------------- Salinity samples were collected in 200 ml type ll glass bottles with disposable nylon inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer standardized with IAPSO standard seawater 31 - 50 days after collection. For details on duplicate analysis see file 2019-006_SAL.pdf. Oxygen samples were analyzed at sea using an automated Winkler titration system (Metrohm Dosimat model 876 and a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details on duplicate analysis see file 2019-006_OXY.pdf. Nutrient samples were collected in plastic tubes. One set of samples was collected and immediately quick frozen in aluminum blocks stored in -20 freezer. Another set of samples from 400 dbar and deeper (to be used for silicate analysis) was collected and stored at 4C in the dark. All samples were returned to IOS for analysis using an Astoria analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For precision and duplicate analysis see file 2019-006_NUT.pdf. Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours and analyzed on a Turner 10AU fluorometer calibrated with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed at IOS ~2 weeks after the cruise. When duplicate samples were collected the average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). Flags and comments apply to chlorophyll values only. No flags or comments are assigned for Phaeopigment values. Precision Statement: Chlorophyll values ranged from 0.04-26.35 µg/l in 108 samples. Average %CV for this cruise was 3.56% with 2 out of 33 duplicate pairs having a CV > 10% and 0 duplicate pairs having a CV > 30%. Our average dataset %CV is 3.80% for 2013 - 2018 so the overall quality of this dataset is very good. For details on duplicates see file 2019-006_CHL.pdf. DMS samples were collected in 250 ml ground glass stoppered bottles and stored in a fridge, in the dark and removed one at a time before analysis. A sample was loaded onto the stripper and purged with UHP Nitrogen for 10 minutes at ~100 ml/min. The DMS was extracted from the water and absorbed on to a Tenax TA trap kept at -80C. The trap was subsequently desorbed at 100C (with a Dewar containing boiling water) onto a Chromosil 330 column which eluted onto a Flame Photometric Detector (FPD). All samples were run as soon as possible after being collected. The minimum detectable level for DMS is 0.10 nmol/l, so “0” values should be interpreted as < 0.1 nmol/l. DMS data are limited to 2 significant figures. Unless otherwise indicated the % relative difference between duplicates is < 20%. For more details see file 2019-006_DMS_report.pdf and for duplicate analysis see 2019-006_DMS.pdf. DMSP-D: Approximately 50-75 ml of seawater were allowed to flow directly from the Niskin into a filtration funnel containing a 0.7 µm GF/F filter. The first 3.5 ml were collected in a polypropylene tube (15 ml) containing 50 µl of a 50% sulphuric acid solution. DMSP-T: 3.5 ml of seawater were collected directly from the Niskin into a polypropylene tube (15 ml) containing 50 µl of a 50% sulphuric acid solution. DMSP-D and DMSP-T: Samples were stored in the dark at 4 degrees C for a minimum of 24 hours. They were hydrolized and analyzed later at the Institute of Ocean Sciences. The minimum detectable level is 0.1 nmol/l, so “0” values should be interpreted as < 0.1 nmol/l. DMSP data are limited to 2 significant figures. Unless otherwise indicated the % relative difference between duplicates is < 20%. For more details see file 2019-006_DMS_report.pdf and for duplicate analysis see 2019-006_DMSP.pdf. Dissolved inorganic carbon (DIC) and Total alkalinity (Alk): Seawater samples were collected from standard depths in 500 ml borosilicate glass reagent bottles. 5 ml of water were removed to allow room for thermal expansion and the sample was preserved within 30 minutes of collection with 0.1 ml of a mercuric chloride saturated solution; then sealed with Apiezon M grease and the ground glass stoppers secured in place with electric tape. The samples were stored at 4°C and moved to cold storage on-shore before on-shore laboratory analysis. DIC: The samples were analysed for DIC using a SOMMA or VINTA sample handling system in conjunction with a coulometer (UIC Inc.) to quantify total CO2 purged from the acidified sample. Measurements of a Certified reference material seawater (CRMs; Scripps Oceanographic Institution) were used for calibrating DIC with daily duplicate CRM measurements. Alk: Alk in the sample was determined using an open cell automated potentiometric titration with a Metrohm Dosimat 665 dosing unit controlled by LabView TM software. The multi-point titration, using 0.1N HCl titrant containing 35 g of sodium chloride per litre of acid, was performed in a temperature controlled flask held at 25 C with Gran endpoint determination. Measurements of a Certified reference material seawater (CRMs; Scripps Oceanographic Institution) were used for calibrating TA using daily duplicate. References: 1. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. Data Processing Notes: ---------------------- Transmissivity, Fluorescence and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. There were 2 WetLabs CStar transmissometers in use during this cruise: Transmissometer:CTD:650 refers to sensor #1185DR (650nm - red) Transmissometer:CTD:530 refers to sensor #1883DG (530nm - green) For comparison with other Institute of Ocean Sciences cruises, note that the transmissometer wavelength is 650 nm unless otherwise stated. NOTE: While the Fluorescence:CTD data are expressed in concentration units, they do not always compare well to extracted chlorophyll samples, particularly for casts far from shore. It is recommended that users check extracted chlorophyll values where available. Oxygen:Dissolved:CTD was calibrated using the method described in Sea-Bird Application Note #64-2, June 2012 revision (Sea-Bird_64-2_Jun2012.pdf), except that a small offset in the fit was allowed. For details on the processing see the report: 2019-006-proc.pdf. $REMARKS Quality flags have the following significance: ---------------------------------------------------------------------------------- 0 = Acceptable measurement with no header comment. 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable measurement with header comment. 3 = Questionable measurement (probably good). 4 = Poor measurement (probably bad). 5 = Measurement not reported (bad). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample was planned for this measurement from this bottle but was not collected. ----------------------------------------------------------------------------------- $END !-1-- 2- 3- --4--- ---5---- ---6---- ---7---- --8-- --9-- --10-- --11- ---12-- ---13--- 14 --15-- 16 ---17-- 18 --19-- 20 --21-- 22 --23-- !Samp Bo Bo Pressu Temperat Salinity Sigma-t: Trans Trans Oxygen Oxyge Fluores Salinity Fl Nitrat Fl Phospha Fl Silica Fl Chloro Fl Phaeo- !le_ tt tt re:CTD ure:CTD :CTD CTD missi missi :Disso n:Dis cence: :Bottle ag e_plus ag te: ag te: ag phyll: ag Pigmen !Numb ~u ~u vity: vity: lved: solve CTD: ~o _Nitri ~o Bottle ~o Bottle ~o Extrac ~o t:Extr !er mb en CTD: CTD: CTD: d:CTD Seapoin tt te: tt tt tt ted: tt acted: ! er ce 650 530 Volume :Mass t le Bottle le le le Bottle le Bottle !---- -- -- ------ -------- -------- -------- ----- ----- ------ ----- ------- -------- -- ------ -- ------- -- ------ -- ------ -- ------ *END OF HEADER 445 24 24 2.9 11.0652 32.3266 24.7090 40.6 65.5 6.84 298.2 5.037 -99.0000 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 444 23 23 5.4 11.0651 32.3266 24.7090 40.2 65.3 6.85 298.4 5.332 32.3271 0 2.93 0 0.603 0 0.84 0 1.45 6 0.18 443 22 22 5.3 11.0649 32.3267 24.7091 39.0 65.5 6.84 297.9 5.345 -99.0000 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 442 21 21 10.0 11.0657 32.3269 24.7091 39.9 65.6 6.83 297.6 5.291 -99.0000 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 441 20 20 25.5 10.8356 32.3322 24.7536 38.4 60.0 6.83 297.7 6.025 -99.0000 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 440 19 19 50.7 7.9389 32.3683 25.2422 50.6 85.9 6.86 298.5 1.070 -99.0000 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 439 18 18 75.9 7.7510 32.3895 25.2857 52.3 90.1 6.71 292.1 0.507 -99.0000 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 438 17 17 100.4 7.2371 32.6155 25.5347 53.0 91.6 5.95 258.9 0.246 -99.0000 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 437 16 16 125.2 6.6707 33.3594 26.1964 53.5 92.7 4.11 178.6 0.146 -99.0000 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 436 15 15 150.6 6.6097 33.7305 26.4970 53.5 92.6 3.27 142.2 0.127 -99.0000 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 435 14 14 175.2 6.4226 33.8360 26.6047 53.4 92.6 3.05 132.5 0.123 -99.0000 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 434 13 13 200.1 5.8957 33.8359 26.6716 53.4 92.3 3.11 135.3 0.123 -99.0000 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 433 12 12 250.6 5.3232 33.8593 26.7593 53.4 92.3 2.51 109.1 0.119 -99.0000 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 432 11 11 300.7 4.9425 33.9013 26.8365 53.6 92.7 1.89 82.2 0.115 -99.0000 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 431 10 10 400.3 4.4909 33.9739 26.9441 53.8 93.1 1.33 58.0 0.111 -99.0000 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 430 9 9 500.8 4.2256 34.0905 27.0650 53.9 93.4 0.69 29.9 0.110 -99.0000 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 429 8 8 750.2 3.6132 34.2687 27.2691 53.8 93.3 0.34 14.7 0.110 -99.0000 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 428 7 7 1000.6 3.0942 34.3726 27.4014 53.9 93.4 0.30 12.9 0.110 -99.0000 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 427 6 6 1499.8 2.3444 34.5007 27.5695 53.2 92.0 0.55 23.9 0.110 34.5031 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 426 5 5 2000.3 1.9465 34.5819 27.6666 53.0 91.7 1.25 54.4 0.109 34.5816 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 425 4 4 2499.9 1.7189 34.6272 27.7205 53.5 93.0 1.92 83.2 0.109 34.6263 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 424 3 3 2999.5 1.5901 34.6532 27.7510 54.0 94.0 2.45 106.5 0.108 34.6541 6 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 423 2 2 3499.9 1.5300 34.6690 27.7681 53.7 93.6 2.83 122.8 0.103 34.6713 2 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00 422 1 1 3998.9 1.5322 34.6770 27.7743 4.2 8.2 2.98 129.6 0.101 -99.0000 0 -99.00 0 -99.000 0 -99.00 0 -99.00 0 -99.00