*2022/11/22 13:59:09.53 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2016/02/09 14:13:56.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 13 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : B77A257F NUMBER OF CHANNELS : 54 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 16 28 2 Bottle_Number n/a 1 13 3 Bottle:Firing_Sequence n/a 1 13 4 Pressure:CTD dbar 2.5 177.3 5 Temperature:CTD deg_C_(ITS90) 8.6613 9.3086 6 Salinity:CTD PSS-78 29.4481 33.439 7 Sigma-t:CTD kg/m^3 22.8284 25.9301 8 Oxygen:Dissolved:CTD:Volume ml/l 3.54 6.56 9 Oxygen:Dissolved:CTD:Mass µmol/kg 154.1 286.2 10 Fluorescence:CTD:Seapoint mg/m^3 0.86E-01 0.826 11 PAR:CTD µE/m^2/sec 0 0.2 12 Oxygen:Dissolved:Bottle:Volume ml/l 3.506 6.541 13 Oxygen:Dissolved:Bottle:Mass µmol/kg 152.6 285.5 14 Flag:Oxygen:Dissolved:Bottle n/a 15 Nitrate_plus_Nitrite:Bottle µmol/l 15.77 23.49 16 Flag:Nitrate_plus_Nitrite:Bottle n/a 17 Phosphate:Bottle µmol/l 1.28 1.914 18 Flag:Phosphate:Bottle n/a 19 Silicate:Bottle µmol/l 28.95 41.84 20 Flag:Silicate:Bottle n/a 21 Chlorophyll:Extracted:Bottle mg/m^3 1.12 1.14 22 Flag:Chlorophyll:Extracted:Bottle n/a 23 Phaeo-Pigment:Extracted:Bottle mg/m^3 0.29 0.35 24 Carbon:Dissolved:Inorganic:Bottle µmol/kg 1914.1 2154 25 Flag:Carbon:Dissolved:Inorganic:Bottle n/a 26 Alkalinity:Total:Bottle µmol/kg 2013.3 2244.6 27 Flag:Alkalinity:Total:Bottle n/a 28 HPLC:Chl-c3:Bottle mg/m^3 0.24E-01 0.26E-01 29 HPLC:Chlide-a:Bottle mg/m^3 0 0.4E-02 30 HPLC:MgDVP:Bottle mg/m^3 0.11E-01 0.13E-01 31 HPLC:Chl-c2:Bottle mg/m^3 0.8E-01 0.9E-01 32 HPLC:Chl-c1:Bottle mg/m^3 0.4E-02 0.5E-02 33 HPLC:Me-chlide:Bottle mg/m^3 0 0 34 HPLC:Peri:Bottle mg/m^3 0.56E-01 0.63E-01 35 HPLC:Pheide-a:Bottle mg/m^3 0 0 36 HPLC:But-fuco:Bottle mg/m^3 0.11E-01 0.11E-01 37 HPLC:Fuco:Bottle mg/m^3 0.298 0.312 38 HPLC:Neo:Bottle mg/m^3 0.14E-01 0.16E-01 39 HPLC:Pras:Bottle mg/m^3 0.24E-01 0.27E-01 40 HPLC:Viola:Bottle mg/m^3 0.9E-02 0.11E-01 41 HPLC:Hex-fuco:Bottle mg/m^3 0.27E-01 0.31E-01 42 HPLC:Diadino:Bottle mg/m^3 0.34E-01 0.37E-01 43 HPLC:Allo:Bottle mg/m^3 0.44E-01 0.48E-01 44 HPLC:Diato:Bottle mg/m^3 0 0.5E-02 45 HPLC:Zea:Bottle mg/m^3 0 0 46 HPLC:Lut:Bottle mg/m^3 0 0.2E-02 47 HPLC:Chl-b:Bottle mg/m^3 0.103 0.112 48 HPLC:C2mgdg:Bottle mg/m^3 0.4E-02 0.5E-02 49 HPLC:DVChl-a:Bottle mg/m^3 0 0 50 HPLC:Chl-a:Bottle mg/m^3 0.836 0.901 51 HPLC:Phe:Bottle mg/m^3 0 0 52 HPLC:B-Car:Bottle mg/m^3 0.18E-01 0.19E-01 53 HPLC:TChl-a:Bottle mg/m^3 0.836 0.905 54 Flag:HPLC:Bottle n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 5 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 9 F ' ' 4 7 -99 ' ' 9 F R4 4 8 -99 ' ' 7 F ' ' 2 9 -99 ' ' 6 F ' ' 1 10 -99 ' ' 8 F ' ' 3 11 -99 ' ' 7 F ' ' 1 12 -99 ' ' 8 F R4 3 13 -99 ' ' 6 F ' ' 1 14 -99 ' ' 3 NQ C ' ' 15 -99 ' ' 7 F R4 2 16 -99 ' ' 3 NQ C ' ' 17 -99 ' ' 8 F R4 3 18 -99 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 -99 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 -99 ' ' 3 NQ C ' ' 23 -99 ' ' 7 F R4 2 24 -99 ' ' ' ' F7.1 R4 ' ' 25 0 ' ' 3 NQ C ' ' 26 -99 ' ' ' ' F7.1 R4 ' ' 27 0 ' ' 3 NQ C ' ' 28 -99 ' ' 8 F R4 3 29 -99 ' ' 8 F R4 3 30 -99 ' ' 8 F R4 3 31 -99 ' ' 8 F R4 3 32 -99 ' ' 8 F R4 3 33 -99 ' ' 8 F R4 3 34 -99 ' ' 8 F R4 3 35 -99 ' ' 8 F R4 3 36 -99 ' ' 8 F R4 3 37 -99 ' ' 8 F R4 3 38 -99 ' ' 8 F R4 3 39 -99 ' ' 8 F R4 3 40 -99 ' ' 8 F R4 3 41 -99 ' ' 8 F R4 3 42 -99 ' ' 8 F R4 3 43 -99 ' ' 8 F R4 3 44 -99 ' ' 8 F R4 3 45 -99 ' ' 8 F R4 3 46 -99 ' ' 8 F R4 3 47 -99 ' ' 8 F R4 3 48 -99 ' ' 8 F R4 3 49 -99 ' ' 8 F R4 3 50 -99 ' ' 8 F R4 3 51 -99 ' ' 8 F R4 3 52 -99 ' ' 8 F R4 3 53 -99 ' ' 8 F R4 3 54 -99 ' ' 3 NQ C ' ' $END *ADMINISTRATION MISSION : 2016-001 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : JF2 EVENT NUMBER : 5 LATITUDE : 48 17.93000 N ! (deg min) LONGITUDE : 124 0.04000 W ! (deg min) WATER DEPTH : 183 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0585 LOCATION : Mid-ship ! custom item *COMMENTS Analysis methods: ----------------- Salinity samples were collected in 200 ml type ll glass bottles with disposable nylon inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab at IOS on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater 12 to 21 days after collection. For details on duplicate analysis see file 2016-001_SAL.pdf. Oxygen samples were analyzed at sea using an automated Winkler titration system (Metrohm Dosimat model 876 and a UV light source and detector with a 365nm filter controlled by LV02_876 software designed and constructed by Scripps Institution of Oceanography) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details on duplicate analysis see file 2016-001_OXY.pdf. Nutrient samples were collected in plastic tubes. One set of samples was collected and immediately quick frozen in aluminum blocks stored in -20 freezer. Another set of samples from 400 dbar and deeper (to be used for silicate analysis) was collected and stored at 4C in the dark. All samples were returned to IOS for analysis using an Astoria analyzer following methods described in IOS Nutrient Methods (1996) Barwell-Clarke and Whitney. For precision and duplicate analysis see file 2016-001_NUT.pdf. Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours and analyzed on a Turner 10AU fluorometer calibrated annually with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed at IOS ~7 weeks after the cruise. When duplicate samples were collected the average of two samples is reported. Variability is assessed as the CV (std dev / mean*100). Precision Statement: Chlorophyll values ranged from 0.04-1.14 mg/m^3. Average CV for this cruise was an excellent 2.82% with 1 out of 58 duplicate pairs having a CV > 15% and 0 out of 58 duplicate pairs having a CV > 50% . Our average dataset CV is 2.83% for 2013 - 2015 so the overall quality of this dataset is excellent. For details on duplicates see file 2016-001_CHL.pdf. Flags and comments apply to chlorophyll values only. No flags or comments are assigned for Phaeopigment values. DMS samples were collected in 250 ml ground glass stoppered bottles and stored in a fridge, in the dark and removed one at a time before analysis. A sample was loaded onto the stripper and purged with UHP Nitrogen for 10 minutes at ~100 ml/min. The DMS was extracted from the water and absorbed on to a Tenax TA trap kept at -80C. The trap was subsequently desorbed at 100C (with a Dewar containing boiling water) onto a Chromasorb 330 column which eluted onto a Flame Photometric Detector (FPD). All samples were run as soon as possible after being collected. The minimum detectable level for DMS is 0.10 nmol/l, so “0” values should be interpreted as < 0.1 nmol/l. For more details see file 2016-001_DMS_report.pdf and for duplicate analysis see 2016-001_DMS.pdf. DMSP-D: Approximately 20-75 ml of seawater were allowed to flow directly from the Niskin into a filtration funnel containing a 0.7 µm GF/F filter. The first 3.5 ml were collected in a polypropylene tube (15 ml) containing 50 µl of a 50% sulphuric acid solution. DMSP-T: 3.5 ml of seawater were collected directly from the Niskin into a polypropylene tube (15 ml) containing 50 µl of a 50% sulphuric acid solution. DMSP-D and DMSP-T: Samples were stored in the dark at 4 degrees C for a minimum of 24 hours. They were hydrolized and analyzed later at the Institute of Ocean Sciences. The minimum detectable level is 0.1 nmol/l, so “0” values should be interpreted as < 0.1 nmol/l. DMSP data are limited to 2 significant figures. For details on analysis see document 2016-001_DMS_report.pdf. Dissolved inorganic carbon (DIC) was determined using coulometric analysis of unfiltered samples. Total alkalinity (Alk) was determined by potentiometric titration. pH on the total hydrogen ion concentration scale was determined photometrically and is reported at 25C and surface pressure. For duplicates and precision of DIC, ALK and pH samples see files 2016-001_DIC.pdf, 2016-001_ALK.pdf, and 2016-001_pH.pdf respectively. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~3 months after collection. The average of two samples is reported. Variability is assessed as the CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide. References: 1. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 5. Nemcek, N. and Peńa, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. Data Processing Notes: ---------------------- Transmissivity, Fluorescence and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. NOTE: While the Fluorescence:CTD data are expressed in concentration units, they do not always compare well to extracted chlorophyll samples, particularly for casts far from shore. It is recommended that users check extracted chlorophyll values where available. For details on how the transmissivity calibration parameters were calculated see the document Transmissivity_Calculation.pdf. NOTE: The transmissivity data were removed for files 2016-001-0002 and 2016-001-0005 because of poor data due to a cable problem. Oxygen:Dissolved:CTD was calibrated using the method described in the Sea-Bird Application Note #64-2 of June 2012 (Sea-Bird_64-2_Jun2012.pdf), except that a small offset in the fit was allowed. For details on the processing see the report: 2016-001-proc.pdf. $REMARKS Quality flags have the following significance: ---------------------------------------------------------------------------------- 0 = Acceptable measurement with no header comment. 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable measurement with header comment. 3 = Questionable measurement (probably good). 4 = Poor measurement (probably bad). 5 = Measurement not reported (bad). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample was planned for this measurement from this bottle but was not collected. ----------------------------------------------------------------------------------- $END !-1-- -2-- -3-- --4--- ---5---- ---6---- ---7---- --8--- --9-- ---10-- --11-- ---12-- --13- 14 --15-- 16 ---17-- 18 --19-- 20 --21-- 22 --23-- --24-- 25 --26-- 27 ---28-- ---29-- ---30-- ---31-- ---32-- ---33-- ---34-- ---35-- ---36-- ---37-- ---38-- ---39-- ---40-- ---41-- ---42-- ---43-- ---44-- ---45-- ---46-- ---47-- ---48-- ---49-- ---50-- ---51-- ---52-- ---53-- 54 !Samp Bott Bott Pressu Temperat Salinity Sigma-t: Oxygen Oxyge Fluores PAR: Oxygen: Oxyge Fl Nitrat Fl Phospha Fl Silica Fl Chloro Fl Phaeo- Carbon Fl Alkali Fl HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC: HPLC:B- HPLC: Fl !le_ le_ le:F re:CTD ure:CTD :CTD CTD :Disso n:Dis cence: CTD Dissolv n:Dis ag e_plus ag te: ag te: ag phyll: ag Pigmen :Disso ag nity: ag Chl-c3: Chlide- MgDVP: Chl-c2: Chl-c1: Me- Peri: Pheide- But- Fuco: Neo: Pras: Viola: Hex- Diadino Allo: Diato: Zea: Lut: Chl-b: C2mgdg: DVChl- Chl-a: Phe: Car: TChl-a: ag !Numb Numb ~ng_ lved: solve CTD: ed: ~ed:B ~o _Nitri ~o Bottle ~o Bottle ~o Extrac ~o t:Extr ~:Inor ~o Total: ~o Bottle a: Bottle Bottle Bottle chlide: Bottle a: fuco: Bottle Bottle Bottle Bottle fuco: :Bottle Bottle Bottle Bottle Bottle Bottle Bottle a: Bottle Bottle Bottle Bottle ~o !er er Sequ CTD: d:CTD Seapoin Bottle: ottle tt te: tt tt tt ted: tt acted: ganic: tt Bottle tt Bottle Bottle Bottle Bottle Bottle Bottle tt ! ence Volume :Mass t Volume :Mass le Bottle le le le Bottle le Bottle Bottle le le le !---- ---- ---- ------ -------- -------- -------- ------ ----- ------- ------ ------- ----- -- ------ -- ------- -- ------ -- ------ -- ------ ------ -- ------ -- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- ------- -- *END OF HEADER 28 13 13 2.5 8.8106 29.4486 22.8285 6.56 286.2 0.826 0.2 6.485 283.1 0 15.77 0 1.289 0 32.87 0 -99.00 0 -99.00 1914.8 0 2022.7 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 27 12 12 5.7 8.8089 29.4481 22.8284 6.55 285.8 0.821 0.0 6.484 283.0 0 15.77 0 1.280 0 32.94 0 1.12 6 0.29 1920.2 0 2013.3 0 0.026 0.004 0.011 0.090 0.005 0.000 0.063 0.000 0.011 0.312 0.014 0.027 0.011 0.031 0.037 0.048 0.000 0.000 0.002 0.112 0.005 0.000 0.901 0.000 0.019 0.905 6 26 11 11 10.3 8.8129 29.4518 22.8307 6.54 285.6 0.821 0.0 6.482 282.9 0 15.78 0 1.281 0 32.96 0 -99.00 0 -99.00 1916.3 0 2038.1 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 25 10 10 20.3 8.8139 29.4541 22.8323 6.54 285.4 0.823 0.0 6.541 285.5 0 15.80 0 1.287 0 32.92 0 -99.00 0 -99.00 1914.1 6 2031.5 6 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 24 9 9 30.3 8.8074 29.4999 22.8691 6.53 285.1 0.822 0.0 6.416 280.1 0 16.27 0 1.329 0 33.52 0 1.14 6 0.35 1926.8 0 2031.0 0 0.024 0.000 0.013 0.080 0.004 0.000 0.056 0.000 0.011 0.298 0.016 0.024 0.009 0.027 0.034 0.044 0.005 0.000 0.000 0.103 0.004 0.000 0.836 0.000 0.018 0.836 6 23 8 8 40.2 8.6613 30.5495 23.7117 5.90 257.5 0.388 0.0 5.821 253.9 0 23.07 0 1.914 0 41.84 0 -99.00 0 -99.00 2007.5 0 2097.2 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 22 7 7 50.5 8.7085 30.6829 23.8092 5.80 252.8 0.331 0.0 5.712 249.1 0 22.91 6 1.899 6 40.82 6 -99.00 0 -99.00 2012.7 0 2104.2 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 21 6 6 60.4 8.7894 30.8854 23.9556 5.67 247.0 0.273 0.0 5.591 243.8 0 22.44 0 1.862 0 39.14 0 -99.00 0 -99.00 2023.6 6 2114.2 6 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 20 5 5 80.5 8.8681 31.1798 24.1741 5.48 238.9 0.194 0.0 5.442 237.2 6 22.20 0 1.843 0 37.93 0 -99.00 0 -99.00 2029.8 0 2102.0 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 19 4 4 100.9 8.8828 31.2455 24.2233 5.45 237.4 0.177 0.0 5.310 231.5 0 22.03 0 1.808 0 37.15 0 -99.00 0 -99.00 2039.6 0 2123.9 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 18 3 3 125.3 9.3086 32.7351 25.3223 4.48 194.9 0.098 0.0 4.203 183.0 0 20.44 0 1.669 0 28.95 0 -99.00 0 -99.00 2110.5 0 2244.6 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 17 2 2 150.4 8.9617 33.4282 25.9194 3.56 154.9 0.086 0.0 3.519 153.1 0 23.46 0 1.835 0 30.29 0 -99.00 0 -99.00 2151.8 6 2228.4 6 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0 16 1 1 177.3 8.9478 33.4390 25.9301 3.54 154.1 0.092 0.0 3.506 152.6 0 23.49 0 1.842 0 30.41 0 -99.00 0 -99.00 2154.0 0 2226.4 0 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 -99.000 0