*2021/10/28 09:32:04.98 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2014/02/12 05:31:11.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 16 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 8D8D26F4 NUMBER OF CHANNELS : 11 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ----------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 123 138 2 Bottle_Number n/a 1 16 3 Bottle:Firing_Sequence n/a 1 16 4 Pressure:CTD dbar 10.9 1303.8 5 Temperature:CTD deg_C_(ITS90) 2.8749 7.8106 6 Salinity:CTD PSS-78 32.2822 34.4861 7 Sigma-t:CTD kg/m^3 25.1929 27.5119 8 Transmissivity:CTD %/m 63.6 68.4 9 Oxygen:Dissolved:CTD:Volume ml/l 0.24 6.59 10 Oxygen:Dissolved:CTD:Mass µmol/kg 10.3 287 11 Fluorescence:CTD:Wetlabs mg/m^3 0.108 0.871 $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 3 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 9 F ' ' 4 7 -99 ' ' 9 F R4 4 8 -99 ' ' 6 F ' ' 1 9 -99 ' ' 7 F ' ' 2 10 -99 ' ' 6 F ' ' 1 11 -99 ' ' 8 F ' ' 3 $END *ADMINISTRATION MISSION : 2014-001 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : P4 EVENT NUMBER : 13 LATITUDE : 48 39.04000 N ! (deg min) LONGITUDE : 126 39.96000 W ! (deg min) WATER DEPTH : 1317 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0550 LOCATION : Mid-ship ! custom item *COMMENTS Analysis methods: ----------------- Salinity samples were collected in 200 ml type ll glass bottles with reusable silicone inserts supplied by Xiamen Cuten Accessories Industry Limited and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater 33 to 45 days after collection. For details on duplicate analysis see file 2014-001_SAL.pdf. Oxygen samples were analyzed at sea using an automated Winkler titration system (Brinkmann Dosimat model 665 for titrations, Dosimat model 865 for dispensing standards and a PC950 Colorimeter controlled by AutoOxy software V3.4) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). For details on duplicate analysis see file 2014-001_OXY.pdf. Nutrient samples were collected in plastic tubes. One set of samples was collected and immediately quick frozen in aluminum blocks stored in -20 freezer. Another set of samples from 400 dbar and deeper (to be used for silicate analysis) was collected and stored at 4C in the dark. All samples were returned to IOS for analysis using an Astoria analyzer following methods described in Barwell-Clarke and Whitney (1996). For precision and duplicate analysis see file 2014-001_NUT.pdf. Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -80C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours and analyzed on a Turner 10AU fluorometer calibrated annually with commercially pure chlorophyll a standard (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed at IOS. When duplicate samples were collected the average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). Flags and comments apply to chlorophyll values only. No flags or comments are assigned for Phaeopigment values. For details on duplicates see file 2014-001_CHL.pdf. The minimum detectable level for DMS is 0.10 nM, so “0” values should be interpreted as <0.10. For details on the collection and analysis of the DMS data see file 2014-001_DMS_report.pdf and for duplicates see 2014-001_DMS.pdf. DMSP-D: 20-75 ml of seawater were allowed to flow directly from the Niskin into a magnetic filtration funnel containing a 0.7 µm GF/F filter. The first 3.5 ml were collected in a polypropylene tube containing 50 µl of a 50% sulphuric acid solution. DMPS-T: 3.5 ml of seawater were collected directly from the Niskin into a polypropylene tube containing 50 µl of a 50% sulphuric acid solution. DMSP-D and DMSP-T: Samples were stored in the dark at 4 degrees C for a minimum of 24 hours. They were hydrolized and analyzed later at the Institute of Ocean Sciences. The minimum detectable level is 0.1 nM, so “0” values should be interpreted as <0.1 nM. Dissolved inorganic carbon (DIC) was determined using coulometric analysis. Total alkalinity (Alk) was determined by potentiometric titration. pH on the total hydrogen ion concentration scale was determined photometrically and is reported at 25C and surface pressure. For duplicates and precision of DIC, ALK and pH samples see files 2014-001_DIC.pdf, 2014-001_ALK.pdf, and 2014-001_pH.pdf respectively. HPLC samples were filtered onto 47mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~3 month after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide. References: 1. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 5. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. Data Processing Notes: ---------------------- Transmissivity, Fluorescence and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. For details on how the transmissivity calibration parameters were calculated see the document Transmissivity_Calculation.pdf. Oxygen:Dissolved:CTD was calibrated using the method described in the Sea-Bird Application Note #64-2 of June 2012 (Sea-Bird_64-2_Jun2012.pdf), except that a small offset in the fit was allowed. The primary Salinity:CTD channel was used for events 0041 and 0043, so it was recalibrated to match the secondary channel which was selected for all other casts. For details on the processing see the report: 2014-001-proc.pdf. $REMARKS Quality flags have the following significance: ---------------------------------------------------------------------------------- 0 = Acceptable measurement with no header comment. 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable measurement with header comment. 3 = Questionable measurement (probably good). 4 = Poor measurement (probably bad). 5 = Measurement not reported (bad). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample was planned for this measurement from this bottle but was not collected. ----------------------------------------------------------------------------------- $END !-1-- 2- 3- --4--- ---5---- ---6---- ---7---- --8-- --9--- --10- ---11-- !Samp Bo Bo Pressu Temperat Salinity Sigma-t: Trans Oxygen Oxyge Fluores !le_ tt tt re:CTD ure:CTD :CTD CTD missi :Disso n:Dis cence: !Numb ~u ~u vity: lved: solve CTD: !er mb en CTD CTD: d:CTD Wetlabs ! er ce Volume :Mass !---- -- -- ------ -------- -------- -------- ----- ------ ----- ------- *END OF HEADER 138 16 16 10.9 7.8104 32.2850 25.1952 63.9 6.58 286.7 0.846 137 15 15 11.1 7.8103 32.2849 25.1951 63.9 6.58 286.6 0.821 136 14 14 11.1 7.8104 32.2846 25.1949 63.6 6.59 286.8 0.856 135 13 13 11.1 7.8106 32.2822 25.1929 63.9 6.59 287.0 0.871 134 12 12 498.0 5.4641 34.0782 26.9159 68.3 0.83 36.0 0.109 133 11 11 495.6 5.4671 34.0776 26.9151 68.3 0.81 35.4 0.112 132 10 10 499.8 5.4604 34.0788 26.9168 68.4 0.83 36.1 0.113 131 9 9 497.7 5.4661 34.0777 26.9153 68.4 0.83 36.1 0.108 130 8 8 1001.6 3.6501 34.3847 27.3579 68.2 0.24 10.3 0.118 129 7 7 1000.0 3.6504 34.3844 27.3576 68.2 0.24 10.4 0.122 128 6 6 1000.9 3.6500 34.3849 27.3580 68.2 0.24 10.3 0.109 127 5 5 1002.5 3.6503 34.3848 27.3579 68.2 0.24 10.3 0.119 126 4 4 1302.8 2.8776 34.4857 27.5114 67.2 0.49 21.2 0.115 125 3 3 1303.8 2.8749 34.4861 27.5119 67.2 0.49 21.2 0.118 124 2 2 1303.0 2.8749 34.4860 27.5119 67.2 0.49 21.3 0.123 123 1 1 1302.0 2.8774 34.4857 27.5114 67.2 0.48 21.0 0.123