*2013/08/12 08:47:13.17 *IOS HEADER VERSION 1.10 2011/10/26 2011/10/26 *FILE START TIME : UTC 2012/02/10 12:36:19.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 12 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : A6780EA NUMBER OF CHANNELS : 19 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 107 118 2 Bottle_Number n/a 1 12 3 Bottle:Firing_Sequence n/a 1 12 4 Pressure:CTD dbar 9.7 1300.7 5 Temperature:CTD deg_C_(ITS90) 2.9355 8.3024 6 Salinity:Practical:CTD PSS-78 32.4404 34.4742 7 Sigma-t:CTD kg/m^3 25.2459 27.497 8 Transmissivity:CTD %/m 61.3 67.2 9 Oxygen:Dissolved:CTD:Volume ml/l 0.25 6.5 10 Oxygen:Dissolved:CTD:Mass µmol/kg 11 283.2 11 Fluorescence:CTD:Wetlabs mg/m^3 0.383 1.213 12 Salinity:Bottle PSS-78 32.4428 34.4741 13 Flag:Salinity:Bottle n/a 14 Nitrate_plus_Nitrite:Bottle µmol/l 8.1 46.1 15 Flag:Nitrate_plus_Nitrite:Bottle n/a 16 Phosphate:Bottle µmol/l 0.93 3.35 17 Flag:Phosphate:Bottle n/a 18 Silicate:Bottle µmol/l 10.3 144.9 19 Flag:Silicate:Bottle n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 3 I I 0 4 -99 ' ' 7 F ' ' 1 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 9 F ' ' 4 7 -99 ' ' 9 F R4 4 8 -99 ' ' 6 F ' ' 1 9 -99 ' ' 7 F ' ' 2 10 -99 ' ' 6 F ' ' 1 11 -99 ' ' 8 F ' ' 3 12 -99 ' ' 9 F R4 4 13 0 ' ' 3 NQ C ' ' 14 -99 ' ' 6 F R4 1 15 0 ' ' 3 NQ C ' ' 16 -99 ' ' 7 F R4 2 17 0 ' ' 3 NQ C ' ' 18 -99 ' ' 6 F R4 1 19 0 ' ' 3 NQ C ' ' $END *ADMINISTRATION MISSION : 2012-01 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : P4 EVENT NUMBER : 13 LATITUDE : 48 39.00000 N ! (deg min) LONGITUDE : 126 40.01000 W ! (deg min) WATER DEPTH : 1322 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0443 LOCATION : Mid-ship ! custom item *COMMENTS Sample Number 107: Silicate:Bottle - should have been kept cool instead of frozen. Analysis methods: ----------------- Chlorophyll samples were filtered onto 25mm GF/F filters and stored in glass scintillation vials at -20C prior to analysis. Samples were extracted in 90% acetone at -20C for 24 hours and analyzed on a Turner 10AU fluorometer which is calibrated annually with commercially pure chlorophyll a (Sigma). Fluorescence readings taken before and after acidification were used to calculate chlorophyll and phaeopigment concentrations (Holm-Hansen et al 1965). Chlorophyll samples were analyzed on board ship in a controlled temperature lab. When duplicate samples were collected the average of two samples is reported. Variability is assessed as the CV% (std dev / mean*100). For details see file 2012-01_CHL.pdf. Phaeopigment data are provided for information only and no quality flags are assigned to them. Oxygen samples were analyzed on an automated Winkler titration system (Brinkmann Dosimat model 765 and a PC950 Colorimeter controlled by AutoOxy software V3.4) with modifications based on Carpenter (1965) and adhering to WOCE protocols (Culberson 1991). All samples were analyzed at sea. The analysis of the duplicates is in file 2012-01_OXY.pdf. Salinity samples were collected in 200 ml type ll glass bottles with disposable plastic inserts and screw caps supplied by Ocean Scientific International Limited. They were analyzed in a temperature-controlled lab on a Guildline 8400B Salinometer (S/N 68572) standardized with IAPSO standard seawater within 9-11 days after the end of the cruise. The analysis of the duplicates is in file 2012-01_SAL.pdf. Nutrient samples were collected in plastic tubes and quick frozen in aluminum blocks stored in -20C freezer. Another set of samples from 400 dbar and deeper (to be used for silicate analysis) was collected and stored at 4C in the dark. All samples were later analyzed at IOS using the Astoria analyzer following methods described in Barwell-Clarke and Whitney (1996). See file 2012-01_NUT.pdf for duplicates and precision information. NOTE: July 2013: A correction has been applied to Nitrate_plus_Nitrite:Bottle and Phosphate:Bottle data from deep-water cruises analyzed at IOS between 2009 and 2012. For details see the report: Corrections_to_Nitrate_and_Phosphate_Data_2009-2012.pdf. References: 1. Holm-Hansen, O., Lorenzen, C.J., Holmes, R.W., and Strickland J.D.H. 1965. Fluorometric Determination of Chlorophyll. J.du Cons. Intl. Pour l’Epl. De la Mer. 30:3-15. 2. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 3. Culberson, C.H. 1991. Dissolved oxygen. WOCE Hydrographic Programme Operations and Methods (July 1991). 15pp. 4. Barwell-Clarke, J. and Whitney, F. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. --------------------------------------------------------------------------- Transmissivity and PAR data are nominal and unedited except that some records were removed in editing temperature and salinity. Fluorescence data were recalibrated to correct an error in the scale factor used in the original conversion. The data are still considered nominal and are unedited. For details on how the transmissivity calibration parameters were calculated see the document Transmissivity_Calculation.pdf. The Oxygen:Dissolved:CTD calibration was done using the method described in the Sea-Bird Application Note #64-2 (Sea-Bird_64-2_Feb2010.pdf). For details on the processing see processing report: 2012-01-proc.pdf NOTE: July 2013: A correction has been applied to Nitrate_plus_Nitrite:Bottle and Phosphate:Bottle data from deep-water cruises analyzed at IOS between 2009 and 2012. For details see the report: Corrections_to_Nitrate_and_Phosphate_Data_2009-2012.pdf $REMARKS Data quality is expressed with the following flags ---------------------------------------------------------------------------- 1 = Sample for this measurement was drawn from water bottle but not analyzed (not normally used). 2 = Acceptable measurement (not normally used). 3 = Questionable measurement (no problem observed in sampling or analysis, but value is not trusted, nonetheless; includes outlyers). 4 = Bad measurement (known problem with sampling or analysis, but not serious enough to completely discard the value). 5 = Not reported (lost sample; unredeemably bad measurement). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample not drawn for this measurement from this bottle (not normally used). ---------------------------------------------------------------------------- $END !-1-- 2- 3- --4--- ---5---- ---6---- ---7---- --8-- --9--- --10- ---11-- ---12--- 13 --14- 15 --16-- 17 --18- 19 !Samp Bo Bo Pressu Temperat Salinity Sigma-t: Trans Oxygen Oxyge Fluores Salinity Fl Nitra Fl Phosph Fl Silic Fl !le_ tt tt re:CTD ure:CTD : CTD missi :Disso n:Dis cence: :Bottle ag te_pl ag ate: ag ate: ag !Numb ~u ~u Practica vity: lved: solve CTD: ~o ~Nitr ~o Bottle ~o Bottl ~o !er mb en l:CTD CTD CTD: d:CTD Wetlabs tt ite:B tt tt e tt ! er ce Volume :Mass le ottle le le le !---- -- -- ------ -------- -------- -------- ----- ------ ----- ------- -------- -- ----- -- ------ -- ----- -- *END OF HEADER 118 12 12 10.2 8.2995 32.4423 25.2478 61.3 6.50 283.2 1.179 -99.0000 -99.0 -99.00 -99.0 117 11 11 9.7 8.3024 32.4404 25.2459 61.3 6.49 282.7 1.213 -99.0000 -99.0 -99.00 -99.0 116 10 10 10.6 8.3013 32.4408 25.2464 61.3 6.50 283.0 1.158 32.4428 8.1 0.93 10.3 115 9 9 501.7 5.1686 34.1152 26.9801 67.2 0.63 27.3 0.388 -99.0000 -99.0 -99.00 -99.0 114 8 8 502.1 5.1680 34.1153 26.9803 67.2 0.63 27.3 0.396 -99.0000 -99.0 -99.00 -99.0 113 7 7 501.6 5.1687 34.1152 26.9801 67.1 0.63 27.3 0.404 34.1147 42.7 3.14 84.1 112 6 6 1001.9 3.5430 34.3860 27.3694 67.1 0.25 11.0 0.392 -99.0000 -99.0 -99.00 -99.0 111 5 5 1003.1 3.5423 34.3861 27.3696 67.2 0.25 11.0 0.396 -99.0000 -99.0 -99.00 -99.0 110 4 4 1002.3 3.5429 34.3860 27.3694 67.1 0.25 11.0 0.383 34.3867 46.1 3.35 130.0 109 3 3 1299.8 2.9374 34.4738 27.4965 65.8 0.46 20.0 0.396 -99.0000 -99.0 -99.00 -99.0 108 2 2 1300.7 2.9355 34.4742 27.4970 65.8 0.46 20.0 0.388 -99.0000 -99.0 -99.00 -99.0 107 1 1 1298.8 2.9360 34.4740 27.4968 65.7 0.46 20.0 0.392 34.4741 45.9 3.29 144.9 3