*2022/07/25 15:16:12.02 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2008/06/01 23:50:55.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 19 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 25F3B873 NUMBER OF CHANNELS : 26 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 56 74 2 Bottle_Number n/a 1 19 3 Pressure:CTD dbar 4.3 1315.5 4 Temperature:CTD deg_C_(ITS90) 3.0491 11.3337 5 Salinity:CTD PSS-78 31.9491 34.4662 6 Sigma-t:CTD kg/m^3 24.3799 27.4802 7 Transmissivity:CTD %/m 36.3 59.5 8 Oxygen:Dissolved:CTD:Volume ml/l 0.22 7.72 9 Oxygen:Dissolved:CTD:Mass µmol/kg 9.3 336.3 10 Fluorescence:CTD:Seapoint mg/m^3 0.81E-01 1.768 11 Salinity:Bottle PSS-78 31.9661 34.4651 12 Flag:Salinity:Bottle n/a 13 Oxygen:Dissolved:Bottle:Volume ml/l 0.196 7.46 14 Flag:Oxygen:Dissolved:Bottle n/a 15 Nitrate_plus_Nitrite:Bottle µmol/l 0.4 46.2 16 Flag:Nitrate_plus_Nitrite:Bottle n/a 17 Phosphate:Bottle µmol/l 0.33 3.27 18 Flag:Phosphate:Bottle n/a 19 Silicate:Bottle µmol/l 4.4 145.3 20 Flag:Silicate:Bottle n/a 21 Carbon:Dissolved:Inorganic:Bottle µmol/kg 1937.93 2383.82 22 Flag:Carbon:Dissolved:Inorganic:Bottle n/a 23 Alkalinity:Total:Bottle µmol/kg 2005.9 2388.9 24 Flag:Alkalinity:Total:Bottle n/a 25 pH:Bottle n/a 7.2861 7.9727 26 Flag:pH:Bottle n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 9 F R4 4 7 -99 ' ' 6 F ' ' 1 8 -99 ' ' 7 F ' ' 2 9 -99 ' ' 6 F ' ' 1 10 -99 ' ' 8 F ' ' 3 11 -99 ' ' 9 F R4 4 12 0 ' ' 3 NQ C ' ' 13 -99 ' ' 7 F ' ' 3 14 0 ' ' 3 NQ C ' ' 15 -99 ' ' 6 F R4 1 16 0 ' ' 3 NQ C ' ' 17 -99 ' ' 7 F R4 2 18 0 ' ' 3 NQ C ' ' 19 -99 ' ' 6 F R4 1 20 0 ' ' 3 NQ C ' ' 21 -99 ' ' 8 F R4 2 22 0 ' ' 3 NQ C ' ' 23 -99 ' ' 7 F R4 1 24 0 ' ' 3 NQ C ' ' 25 -99 ' ' ' ' F9.4 R4 ' ' 26 0 ' ' 3 NQ C ' ' $END *ADMINISTRATION MISSION : 2008-026 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : P4 EVENT NUMBER : 9 LATITUDE : 48 39.05000 N ! (deg min) LONGITUDE : 126 40.07000 W ! (deg min) WATER DEPTH : 1301 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0443 *COMMENTS Sample Number 57: SAL:Bottle - outlier in Compare but high standard deviation in Salinity:CTD; ALK:Bottle - bad calibration. Samples Number 58, 59, 61, 70: DIC:Bottle and ALK:Bottle and pH:Bottle - parameters inconsistent. Sample Number 63: ALK:Bottle - high outlier and inconsistent with DIC:Bottle and pH:Bottle. Sample Number 64: OXY:Bottle - duplicate samples differed by > 10% (1.763 and 1.582 ml/l). The second value looks better compared to the OXY:CTD. Samples Number 72 and 74: pH:Bottle - unstable analysis. Sample Number 73: ALK:Bottle - low outlier. Analysis methods: ----------------- Salinity samples were collected in glass bottles and analyzed on a Guildline model 8400B Autosal or a Guildline Portasal 8410A. Salinometers are standardized with IAPSO standard seawater. See file 2008-026_SAL.pdf for information on duplicates and note the warning below. Oxygen samples were analyzed on an automated Winkler titration system following the procedures of Carpenter (1965). Samples were analyzed at sea using an automated titration system consisting of a Brinkman Dosimat (model 665) and a PC 900 Colorimeter. For details on duplicates see file 2008-026_OXY.pdf. Nutrient samples were collected in plastic tubes and analyzed fresh at sea using a Technicon AAII autoanalyzer following methods described in Barwell-Clarke and Whitney (1996). For details on nutrient duplicates and precision see file 2008-026_NUT.pdf. Chlorophyll samples were analyzed at sea using a Chemistry Turner Designs fluorometer which was calibrated in May 2007 using pure chlorophyll a. Chlorophyll precision was determined by analyzing replicate samples drawn from one Niskin. For details on duplicates see file 2008-026_CHL.pdf. The minimum detectable level for DMS is 0.10 nM, so “0” values should be interpreted as <0.10. For details on the collection and analysis of the DMS data see file 2008-026_DMS_report.pdf and for duplicates see 2008-026_DMS.pdf. DMSP-D and DMSP-T: Contamination in the blanks resulted in all data being discarded. For details on analysis see document 2008-026_DMS_report.pdf. Dissolved inorganic carbon (DIC) was determined using coulometric analysis. Total alkalinity (Alk) was determined by potentiometric titration. pH on the total hydrogren ion concentration scale was determined photometrically and is reported at 25C and surface pressure. For duplicates and precision of DIC, ALK and pH samples see files 2008-026_DIC.pdf, 2008-026_ALK.pdf, and 2008-026_pH.pdf respectively. HPLC samples were filtered onto 25mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~2 weeks after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a, Chlide-a and Me-chlide. References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. J. Barwell-Clarke and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 3. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. Data Processing Notes: ---------------------- The salinity analyses done on a Portasal salinometer at sea are considered unreliable. Many duplicate samples were run using an Autosal at IOS and the Portasal. The results showed that the Portasal read much lower than the Autosal for those samples analyzed on the Portasal on June 5th. For other days the Portasal was low by an average of 0.0016 but there was a lot of noise in the comparison with many values within 0.001 of the Autosal, while others looked unstable. Autosal values have been selected for Salinity:Bottle where possible. Where there are no Autosal values, the Portasal values were used, but were all flagged "3", except for those from June 5th which have been flagged "4". For details on the processing see processing report: 2008-026-proc.pdf $REMARKS Quality flags have the following significance: ---------------------------------------------------------------------------------- 0 = Acceptable measurement with no header comment. 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable measurement with header comment. 3 = Questionable measurement (probably good). 4 = Poor measurement (probably bad). 5 = Measurement not reported (bad). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample was planned for this measurement from this bottle but was not collected. ----------------------------------------------------------------------------------- $END !-1-- 2- --3--- ---4---- ---5---- ---6---- --7-- --8--- --9-- ---10-- ---11--- 12 --13-- 14 --15- 16 --17-- 18 --19- 20 ---21-- 22 --23-- 24 ---25--- 26 !Samp Bo Pressu Temperat Salinity Sigma-t: Trans Oxygen Oxyge Fluores Salinity Fl Oxygen Fl Nitra Fl Phosph Fl Silic Fl Carbon: Fl Alkali Fl pH: Fl !le_ tt re:CTD ure:CTD :CTD CTD missi :Disso n:Dis cence: :Bottle ag :Disso ag te_pl ag ate: ag ate: ag Dissolv ag nity: ag Bottle ag !Numb ~u vity: lved: solve CTD: ~o lved:B ~o ~Nitr ~o Bottle ~o Bottl ~o ed:Inor ~o Total: ~o ~o !er mb CTD CTD: d:CTD Seapoin tt ottle: tt ite:B tt tt e tt ganic: tt Bottle tt tt ! er Volume :Mass t le Volume le ottle le le le Bottle le le le !---- -- ------ -------- -------- -------- ----- ------ ----- ------- -------- -- ------ -- ----- -- ------ -- ----- -- ------- -- ------ -- -------- -- *END OF HEADER 74 19 4.3 11.3337 31.9647 24.3799 36.3 7.52 327.7 1.768 31.9678 0 7.433 0 0.5 0 0.36 0 4.7 0 1941.69 0 2178.0 0 7.9727 3 73 18 9.8 10.9975 31.9491 24.4272 39.7 7.72 336.3 1.648 31.9661 0 7.460 0 0.4 0 0.33 0 4.4 0 1937.93 0 2005.9 3 7.9725 0 72 17 24.7 8.7958 32.1997 24.9833 47.2 7.18 312.6 1.746 32.1905 0 7.041 0 3.4 0 0.60 0 6.6 0 1988.46 0 2210.3 0 7.8584 3 71 16 50.4 7.7298 32.4833 25.3623 56.1 7.00 304.6 0.542 32.4821 0 6.945 0 7.6 6 0.97 6 10.2 6 2025.15 0 2188.6 0 7.7979 0 70 15 75.2 6.9411 32.5398 25.5149 57.4 6.79 295.5 0.272 32.5329 0 6.663 0 11.0 0 1.09 0 13.0 0 2037.32 3 2208.1 3 7.7556 3 69 14 99.7 7.4472 33.1818 25.9510 58.0 4.58 199.3 0.101 33.1087 0 4.781 0 21.5 0 1.66 0 26.0 0 2120.96 0 2212.0 0 7.6089 0 68 13 124.9 7.4665 33.6258 26.2975 58.4 3.43 149.0 0.084 33.6401 0 3.347 0 28.4 0 2.02 0 34.8 0 2178.95 0 2241.3 0 7.5073 0 67 12 149.6 7.4336 33.8256 26.4593 58.6 2.77 120.6 0.087 33.8067 0 2.946 0 31.0 0 2.17 0 39.3 0 2202.50 0 2256.8 0 7.4694 0 66 11 174.3 7.0580 33.8600 26.5387 58.8 2.88 125.4 0.082 33.8547 0 2.867 0 31.4 0 2.17 0 41.8 0 2204.39 0 2263.6 0 7.4704 0 65 10 200.0 6.7991 33.9061 26.6102 58.7 2.46 107.2 0.082 33.9025 0 2.774 0 33.4 0 2.32 0 47.5 0 2222.26 0 2269.8 0 7.4419 0 64 9 250.2 6.5307 33.9988 26.7190 59.2 1.58 68.5 0.085 33.9947 0 1.673 3 37.4 0 2.61 0 57.0 0 2255.45 0 2276.6 0 7.3729 0 63 8 300.1 6.1764 34.0305 26.7900 59.2 1.26 54.8 0.081 34.0266 0 1.213 0 39.3 0 2.75 0 63.2 0 2270.83 0 2304.2 3 7.3460 0 62 7 399.3 5.7181 34.0659 26.8754 59.4 0.98 42.4 0.083 34.0620 0 0.944 0 41.0 0 2.89 0 71.5 0 2291.81 0 2297.1 0 7.3236 0 61 6 599.3 4.7563 34.1899 27.0864 59.4 0.38 16.5 0.084 34.1919 0 0.387 0 44.0 0 3.16 0 95.2 0 2329.71 3 2336.5 3 7.2861 3 60 5 800.2 4.1647 34.2950 27.2340 59.5 0.22 9.3 0.085 34.2964 0 0.196 0 45.3 0 3.25 0 112.2 0 2351.68 0 2349.9 0 7.2951 0 59 4 999.9 3.6747 34.3808 27.3523 59.0 0.25 10.8 0.085 34.3799 0 0.373 0 45.8 0 3.27 0 127.2 0 2367.59 3 2379.0 3 7.2994 3 58 3 999.7 3.6736 34.3810 27.3526 59.0 0.25 10.8 0.085 34.3790 0 0.252 0 45.9 0 3.27 0 127.1 0 2367.62 36 2378.5 36 7.2998 3 57 2 1249.8 3.1585 34.4530 27.4596 59.3 0.39 16.9 0.084 34.4532 3 0.369 0 45.5 0 3.24 0 142.5 0 2376.41 0 2382.4 3 7.3149 0 56 1 1315.5 3.0491 34.4662 27.4802 58.9 0.44 19.0 0.084 34.4651 0 0.424 0 46.2 0 3.24 0 145.3 0 2383.82 0 2388.9 0 7.3177 0