*2022/09/27 13:12:23.26 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2007/08/28 06:06:33.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 21 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : F985674F NUMBER OF CHANNELS : 22 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ----------------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 526 546 2 Bottle_Number n/a 1 21 3 Pressure:CTD dbar 5.3 2006.9 4 Temperature:CTD deg_C_(ITS90) 1.9009 15.7281 5 Salinity:CTD PSS-78 31.9577 34.594 6 Sigma-t:CTD kg/m^3 23.4956 27.6799 7 Transmissivity:CTD %/m 48.3 59.4 8 Oxygen:Dissolved:CTD:Volume ml/l 0.29 6.73 9 Oxygen:Dissolved:CTD:Mass µmol/kg 12.6 293.4 10 Fluorescence:CTD:Seapoint mg/m^3 0.9E-01 1.605 11 Salinity:Bottle PSS-78 31.9598 34.5932 12 Flag:Salinity:Bottle n/a 13 Oxygen:Dissolved:Bottle:Volume ml/l 0.276 6.768 14 Flag:Oxygen:Dissolved:Bottle n/a 15 Nitrate_plus_Nitrite:Bottle µmol/l 0 44.7 16 Flag:Nitrate_plus_Nitrite:Bottle n/a 17 Phosphate:Bottle µmol/l 0.41 3.3 18 Flag:Phosphate:Bottle n/a 19 Silicate:Bottle µmol/l 8.9 175.3 20 Flag:Silicate:Bottle n/a 21 Chlorophyll:Extracted:Bottle mg/m^3 0.1E-01 0.65 22 Flag:Chlorophyll:Extracted:Bottle n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ----- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 5 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 9 F ' ' 4 6 -99.9 ' ' 9 F R4 4 7 -99 ' ' 6 F ' ' 1 8 -99 ' ' 7 F ' ' 2 9 -99 ' ' 6 F ' ' 1 10 -99 ' ' 8 F ' ' 3 11 -99 ' ' 9 F R4 4 12 0 ' ' 3 NQ C ' ' 13 -99 ' ' 8 F ' ' 3 14 0 ' ' 3 NQ C ' ' 15 -99 ' ' 6 F R4 1 16 0 ' ' 3 NQ C ' ' 17 -99 ' ' 7 F R4 2 18 0 ' ' 3 NQ C ' ' 19 -99 ' ' 6 F R4 1 20 0 ' ' 3 NQ C ' ' 21 -99 ' ' 7 F R4 2 22 0 ' ' 3 NQ C ' ' $END *ADMINISTRATION MISSION : 2007-015 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : MJ5 EVENT NUMBER : 81 LATITUDE : 51 27.74000 N ! (deg min) LONGITUDE : 132 23.76000 W ! (deg min) WATER DEPTH : 2730 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0443 *COMMENTS Samples Number 526 to 542, 544, 545: PHOS:Bottle - new equipment caused contamination ranging from 0.07 to -0.33 µM PO4. See note below. Sample Number 526: OXY:Bottle - strange titration curve. Sample Number 545: SAL:Bottle - no screw cap. Analysis methods: ----------------- Salinity samples were collected in glass bottles and analyzed at IOS on Guildline model 8400B Autosal Salinometers which are standardized with IAPSO standard seawater. Oxygen samples were analyzed at sea on an automated Winkler titration system following the procedures of Carpenter (1965). A Brinkmann model 665 Dosimat and model PC910 Colorimeter was controlled by Visual-Basic program to titrate the oxygen samples. Nutrient samples were analyzed fresh at sea using an Astoria autoanalyzer following methods described in Barwell-Clarke and Whitney (1996). For details on nutrient duplicates and precision see file 2007-015_NUT.pdf. WARNING: All Phosphate:Bottle data are flagged “4” because new equipment caused contamination ranging from 0.07 to -0.33 µM PO4. Phosphate:Bottle data were recovered by comparing to archived data below 1000 dbar at each station and correcting accordingly. Chlorophyll samples were collected in calibrated polycarbonate bottles (~330ml), then filtered onto 25mm MFS GF/75 filters at <70mmHg vacuum. The filters were placed in glass scintillation vials and immediately frozen at -20°C until analysis. The chlorophyll was extracted in 10 ml of 90% acetone for 24h at -20ºC, then brought to room temperature and the extract was decanted and measured using a Turner Designs Model 10 fluorometer, which had been calibrated with solutions of commercially prepared chlorophyll. Chlorophyll samples were analyzed on board ship. The minimum detectable level for DMS is 0.10 nM, so “0” values should be interpreted as <0.10. For details on the collection and analysis of the DMS data see file 2007-015_DMS_report.doc. For details on duplicates see file 2007-015_DMS.pdf. Dissolved inorganic carbon (DIC) was determined using coulometric analysis. Total alkalinity (Alk) was determined by potentiometric titration. For duplicates and precision of DIC and ALK samples see files 2007-015_DIC.pdf and 2007-015_ALK.pdf respectively. HPLC samples were filtered onto 25mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~3 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a and Chlide-a. References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. J. Barwell-Clarke and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 3. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. Data Processing Notes: ---------------------- WARNING: All Phosphate:Bottle data are flagged “4” because new equipment caused contamination ranging from 0.07 to -0.33 µM PO4. Phosphate:Bottle data were recovered by comparing to archived data below 1000 dbar at each station and correcting accordingly. For details on the processing see processing report: 2007-015-proc.pdf $REMARKS Quality flags have the following significance: ---------------------------------------------------------------------------------- 0 = Acceptable measurement with no header comment. 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable measurement with header comment. 3 = Questionable measurement (probably good). 4 = Poor measurement (probably bad). 5 = Measurement not reported (bad). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample was planned for this measurement from this bottle but was not collected. ----------------------------------------------------------------------------------- $END !-1-- -2-- --3--- ---4---- ---5---- ---6---- --7-- --8--- --9-- ---10-- ---11--- 12 ---13-- 14 --15- 16 --17-- 18 --19- 20 --21-- 22 !Samp Bott Pressu Temperat Salinity Sigma-t: Trans Oxygen Oxyge Fluores Salinity Fl Oxygen: Fl Nitra Fl Phosph Fl Silic Fl Chloro Fl !le_ le_ re:CTD ure:CTD :CTD CTD missi :Disso n:Dis cence: :Bottle ag Dissolv ag te_pl ag ate: ag ate: ag phyll: ag !Numb Numb vity: lved: solve CTD: ~o ed: ~o ~Nitr ~o Bottle ~o Bottl ~o Extrac ~o !er er CTD CTD: d:CTD Seapoin tt Bottle: tt ite:B tt tt e tt ted: tt ! Volume :Mass t le Volume le ottle le le le Bottle le !---- ---- ------ -------- -------- -------- ----- ------ ----- ------- -------- -- ------- -- ----- -- ------ -- ----- -- ------ -- *END OF HEADER 546 21 5.3 15.7275 31.9578 23.4958 51.5 5.92 258.4 0.391 -99.0000 0 -99.000 0 -99.0 0 -99.00 0 -99.0 0 -99.00 0 545 20 5.4 15.7281 31.9577 23.4956 48.3 5.93 258.5 0.373 31.9598 2 5.963 0 0.0 0 0.41 4 8.9 0 0.14 0 544 19 10.0 15.7220 31.9588 23.4978 55.2 5.94 259.1 0.371 -99.0000 0 5.956 0 0.0 0 0.42 4 9.0 0 0.14 0 543 18 26.5 12.4598 32.0524 24.2406 49.9 6.73 293.4 1.605 -99.0000 0 -99.000 0 -99.0 0 -99.00 0 -99.0 0 -99.00 0 542 17 25.6 12.7724 32.0431 24.1735 50.0 6.69 291.7 1.589 -99.0000 0 6.768 0 1.5 0 0.57 4 10.7 0 0.65 0 541 16 51.1 7.9802 32.3354 25.2105 56.5 6.06 264.1 0.437 -99.0000 0 6.116 0 14.3 0 1.28 4 18.5 0 0.30 0 540 15 76.4 7.0619 32.5436 25.5018 58.1 6.11 265.9 0.159 -99.0000 0 6.237 0 14.9 0 1.34 4 17.8 0 0.08 0 539 14 101.0 6.8310 33.1425 26.0042 58.3 4.47 194.5 0.094 -99.0000 0 4.621 0 23.3 0 1.82 4 32.0 0 0.01 0 538 13 126.5 6.5730 33.5592 26.3667 58.4 3.63 158.0 0.091 -99.0000 0 3.699 0 27.6 0 2.12 4 40.7 0 -99.00 0 537 12 153.7 6.4459 33.7680 26.5481 58.4 3.01 131.1 0.095 -99.0000 0 3.043 0 30.5 0 2.31 4 47.7 0 -99.00 0 536 11 176.4 6.3260 33.8314 26.6136 58.5 2.74 119.2 0.090 -99.0000 0 2.840 0 31.7 0 2.38 4 51.3 0 -99.00 0 535 10 203.8 5.9974 33.8647 26.6817 58.7 2.60 112.9 0.090 -99.0000 0 2.620 0 33.2 0 2.44 4 55.7 0 -99.00 0 534 9 252.9 5.5964 33.8979 26.7573 58.9 2.18 94.8 0.091 -99.0000 0 2.219 0 35.1 0 2.62 4 63.6 0 -99.00 0 533 8 300.7 5.3224 33.9206 26.8080 59.0 1.82 78.9 0.092 -99.0000 0 1.873 0 36.8 0 2.73 4 69.5 0 -99.00 0 532 7 400.8 4.7528 34.0037 26.9390 59.2 1.12 48.5 0.092 -99.0000 0 1.169 0 40.9 0 2.99 4 85.1 0 -99.00 0 531 6 601.0 4.1601 34.1722 27.1368 59.3 0.45 19.7 0.098 -99.0000 0 0.479 0 43.2 0 3.22 4 109.4 0 -99.00 0 530 5 804.3 3.6182 34.2867 27.2829 59.3 0.29 12.6 0.096 -99.0000 0 0.276 0 44.7 0 3.29 4 128.2 0 -99.00 0 529 4 1001.0 3.1600 34.3667 27.3906 59.3 0.30 13.0 0.097 -99.0000 0 0.285 0 44.5 0 3.30 4 143.0 0 -99.00 0 528 3 1251.0 2.7232 34.4381 27.4870 59.4 0.40 17.4 0.097 34.4362 0 0.398 0 44.2 0 3.29 4 156.4 0 -99.00 0 527 2 1503.6 2.3516 34.5063 27.5734 59.3 0.68 29.5 0.097 34.5030 0 0.691 0 44.0 0 3.21 4 165.1 0 -99.00 0 526 1 2006.9 1.9009 34.5940 27.6799 59.4 1.40 60.9 0.094 34.5932 0 1.501 4 41.9 0 3.08 4 175.3 0 -99.00 0