*2022/10/12 15:22:11.43 *IOS HEADER VERSION 2.0 2016/04/28 2016/06/13 IVF16 *FILE START TIME : UTC 2007/06/11 15:33:29.000 TIME INCREMENT : 0 0 0 0.416667E-01 0 ! (day hr min sec ms) NUMBER OF RECORDS : 24 DATA DESCRIPTION : Bottle:Rosette:Up:Stop + CTD:Up FILE TYPE : ASCII CRC : 441E809E NUMBER OF CHANNELS : 24 $TABLE: CHANNELS ! No Name Units Minimum Maximum !--- ---------------------------------------- --------------- -------------- -------------- 1 Sample_Number n/a 502 525 2 Bottle_Number n/a 1 24 3 Pressure:CTD dbar 7.5 3004.5 4 Temperature:CTD deg_C_(ITS90) 1.566 7.2973 5 Salinity:CTD PSS-78 32.5452 34.6595 6 Sigma-t:CTD kg/m^3 25.4711 27.7578 7 Transmissivity:CTD %/m 54.5 61.3 8 Oxygen:Dissolved:CTD:Volume ml/l 2.63 7.03 9 Oxygen:Dissolved:CTD:Mass µmol/kg 114.1 306.1 10 Fluorescence:CTD:Seapoint mg/m^3 0.33E-01 0.685 11 Salinity:Bottle PSS-78 32.5487 34.6645 12 Flag:Salinity:Bottle n/a 13 Nitrate_plus_Nitrite:Bottle µmol/l 12.7 12.7 14 Flag:Nitrate_plus_Nitrite:Bottle n/a 15 Phosphate:Bottle µmol/l 1.26 1.26 16 Flag:Phosphate:Bottle n/a 17 Silicate:Bottle µmol/l 20.3 20.3 18 Flag:Silicate:Bottle n/a 19 Chlorophyll:Extracted:Bottle mg/m^3 0.35 0.35 20 Flag:Chlorophyll:Extracted:Bottle n/a 21 Carbon:Dissolved:Inorganic:Bottle µmol/kg 2349.94 2352.2 22 Flag:Carbon:Dissolved:Inorganic:Bottle n/a 23 Alkalinity:Total:Bottle µmol/kg 2419 2420.92 24 Flag:Alkalinity:Total:Bottle n/a $END $TABLE: CHANNEL DETAIL ! No Pad Start Width Format Type Decimal_Places !--- ---- ----- ----- ------ ---- -------------- 1 -99 ' ' 5 I I 0 2 -99 ' ' 3 I I 0 3 -99 ' ' 7 F ' ' 1 4 -99 ' ' 9 F ' ' 4 5 -99 ' ' 9 F ' ' 4 6 -99 ' ' 9 F R4 4 7 -99 ' ' 6 F ' ' 1 8 -99 ' ' 7 F ' ' 2 9 -99 ' ' 6 F ' ' 1 10 -99 ' ' 8 F ' ' 3 11 -99 ' ' 9 F R4 4 12 0 ' ' 3 NQ C ' ' 13 -99 ' ' 6 F R4 1 14 0 ' ' 3 NQ C ' ' 15 -99 ' ' 7 F R4 2 16 0 ' ' 3 NQ C ' ' 17 -99 ' ' 6 F R4 1 18 0 ' ' 3 NQ C ' ' 19 -99 ' ' 7 F R4 2 20 0 ' ' 3 NQ C ' ' 21 -99 ' ' 8 F R4 2 22 0 ' ' 3 NQ C ' ' 23 -99 ' ' ' ' F8.2 R4 ' ' 24 0 ' ' 3 NQ C ' ' $END *ADMINISTRATION MISSION : 2007-013 AGENCY : IOS, Ocean Sciences Division, Sidney, B.C. COUNTRY : Canada PROJECT : Line P SCIENTIST : Robert M. PLATFORM : John P. Tully *LOCATION GEOGRAPHIC AREA : North-East Pacific STATION : S3 EVENT NUMBER : 84 LATITUDE : 48 29.98000 N ! (deg min) LONGITUDE : 145 0.01000 W ! (deg min) WATER DEPTH : 4337 *INSTRUMENT TYPE : Sea-Bird CTD MODEL : SBE-911plus SERIAL NUMBER : 0550 *COMMENTS Sample Number 503: ALK:Bottle - large difference between replicates. Sample Number 504: DIC:Bottle - large difference between replicates. Sample Number 524: SAL:Bottle - out of line with 22 other bottles fired at same pressure and outlier in COMPARE. Analysis methods: ----------------- Salinity samples were collected in glass bottles and analyzed on Guildline model 8400B Autosal Salinometers which are standardized with IAPSO standard seawater. Oxygen samples were analyzed at sea on an automated Winkler titration system following the procedures of Carpenter (1965). A Brinkmann model 665 Dosimat and model PC910 Colorimeter was controlled by Visual-Basic program to titrate the oxygen samples. Nutrient samples were analysed fresh at sea using the new Astoria system following methods described in Barwell-Clarke and Whitney (1996). For duplicates and precision see file 2007-013_NUT.pdf. Chlorophyll samples were collected in calibrated polycarbonate bottles (~330ml), then filtered onto 25mm MFS GF/75 filters at <70mmHg vacuum. The filters were placed in glass scintillation vials and immediately frozen at -20°C until analysis. The chlorophyll was extracted in 10 ml of 90% acetone for 24h at -20ºC, then brought to room temperature and the extract was decanted and measured using a Turner Designs Model 10 fluorometer, which had been calibrated with solutions of commercially prepared chlorophyll. Chlorophyll samples were analyzed on board ship. The minimum detectable level for DMS is 0.10 nM, so “0” values should be interpreted as <0.10. For details on the collection and analysis of the DMS data see file 2007-013_DMS_report.doc. For details on duplicates see file 2007-013_DMS.pdf. Dissolved inorganic carbon (DIC) was determined using coulometric analysis. Total alkalinity (Alk) was determined by potentiometric titration. For duplicates and precision of DIC and ALK samples see files 2007-013_DIC.pdf and 2007-013_ALK.pdf respectively. HPLC samples were filtered onto 25mm GF/F filters and stored at -80C prior to analysis. Samples were extracted in 95% methanol at -20C for 24 hours and analyzed on a WATERS 2695 HPLC separations system as detailed in Nemcek and Pena, 2014. Analysis was performed ~6-24 months after collection. The average of two samples is reported. Variability is assessed as the %CV (std dev/mean*100) for duplicate pairs. All pigments below the limit of detection (LOD) are assigned a zero value. TChl-a is the sum of Chl-a, DVchl-a and Chlide-a. References: 1. Carpenter, J.H. 1965. The Chesapeake Bay Institute Technique for the Winkler Dissolved Oxygen Method. Limmnol. & Oceanogr., 10: 141-143. 2. J. Barwell-Clarke and F. Whitney. 1996. Institute of Ocean Sciences Nutrient Methods and Analysis. Canadian Technical Report of Hydrography and Ocean Sciences, No. 182, 43 pp. 3. Nemcek, N. and Peña, M.A. 2014. Institute of Ocean Sciences Protocols for Phytoplankton Pigment Analysis by HPLC. Can. Tech. Rep. Fish. Aquat. Sci. 3117: x + 80 p. Data Processing Notes: ---------------------- For details on the processing see processing report: 2007-013-proc.pdf $REMARKS Quality flags have the following significance: ---------------------------------------------------------------------------------- 0 = Acceptable measurement with no header comment. 1 = Sample for this measurement was collected but not analyzed. Sample lost. 2 = Acceptable measurement with header comment. 3 = Questionable measurement (probably good). 4 = Poor measurement (probably bad). 5 = Measurement not reported (bad). 6 = Mean of replicate measurements. 7 = Manual chromatographic peak measurement. 8 = Irregular digital chromatographic peak integration. 9 = Sample was planned for this measurement from this bottle but was not collected. ----------------------------------------------------------------------------------- $END !-1-- 2- --3--- ---4---- ---5---- ---6---- --7-- --8--- --9-- ---10-- ---11--- 12 --13- 14 --15-- 16 --17- 18 --19-- 20 ---21-- 22 ---23-- 24 !Samp Bo Pressu Temperat Salinity Sigma-t: Trans Oxygen Oxyge Fluores Salinity Fl Nitra Fl Phosph Fl Silic Fl Chloro Fl Carbon: Fl Alkalin Fl !le_ tt re:CTD ure:CTD :CTD CTD missi :Disso n:Dis cence: :Bottle ag te_pl ag ate: ag ate: ag phyll: ag Dissolv ag ity: ag !Numb ~u vity: lved: solve CTD: ~o ~Nitr ~o Bottle ~o Bottl ~o Extrac ~o ed:Inor ~o Total: ~o !er mb CTD CTD: d:CTD Seapoin tt ite:B tt tt e tt ted: tt ganic: tt Bottle tt ! er Volume :Mass t le ottle le le le Bottle le Bottle le le !---- -- ------ -------- -------- -------- ----- ------ ----- ------- -------- -- ----- -- ------ -- ----- -- ------ -- ------- -- ------- -- *END OF HEADER 525 24 7.5 7.2973 32.5452 25.4711 54.5 7.03 306.1 0.685 32.5487 0 12.7 0 1.26 0 20.3 0 0.35 0 -99.00 0 -99.00 0 524 23 3003.9 1.5662 34.6594 27.7577 61.3 2.63 114.2 0.033 -99.0000 5 -99.0 0 -99.00 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 523 22 3004.0 1.5662 34.6594 27.7577 61.3 2.63 114.2 0.033 34.6610 0 -99.0 0 -99.00 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 522 21 3002.9 1.5664 34.6594 27.7577 61.3 2.63 114.1 0.033 34.6616 0 -99.0 0 -99.00 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 521 20 3004.5 1.5662 34.6595 27.7578 61.3 2.63 114.1 0.034 34.6645 0 -99.0 0 -99.00 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 520 19 3002.8 1.5665 34.6594 27.7577 61.3 2.63 114.2 0.033 34.6622 0 -99.0 0 -99.00 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 519 18 3004.1 1.5660 34.6595 27.7578 61.3 2.63 114.2 0.033 34.6610 0 -99.0 0 -99.00 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 518 17 3003.6 1.5661 34.6595 27.7578 61.3 2.63 114.2 0.033 34.6620 0 -99.0 0 -99.00 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 517 16 3003.7 1.5663 34.6595 27.7578 61.3 2.63 114.2 0.033 34.6609 0 -99.0 0 -99.00 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 516 15 3003.3 1.5663 34.6594 27.7577 61.3 2.63 114.2 0.033 34.6611 0 -99.0 0 -99.00 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 515 14 3003.9 1.5663 34.6595 27.7578 61.3 2.63 114.2 0.034 34.6609 0 -99.0 0 -99.00 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 514 13 3002.9 1.5664 34.6594 27.7577 61.3 2.63 114.2 0.033 34.6610 0 -99.0 0 -99.00 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 513 12 3003.7 1.5663 34.6593 27.7576 61.3 2.63 114.2 0.034 34.6610 0 -99.0 0 -99.00 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 512 11 3003.4 1.5662 34.6595 27.7578 61.3 2.63 114.2 0.033 34.6606 0 -99.0 0 -99.00 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 511 10 3002.8 1.5665 34.6594 27.7577 61.3 2.63 114.1 0.033 34.6611 0 -99.0 0 -99.00 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 510 9 3003.4 1.5663 34.6595 27.7578 61.3 2.63 114.1 0.033 34.6623 0 -99.0 0 -99.00 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 509 8 3002.4 1.5667 34.6593 27.7576 61.3 2.63 114.1 0.033 34.6615 0 -99.0 0 -99.00 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 508 7 3003.1 1.5664 34.6594 27.7577 61.3 2.63 114.1 0.033 34.6615 0 -99.0 0 -99.00 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 507 6 3002.3 1.5667 34.6594 27.7577 61.3 2.63 114.1 0.033 34.6610 0 -99.0 0 -99.00 0 -99.0 0 -99.00 0 -99.00 0 -99.00 0 506 5 3002.7 1.5666 34.6593 27.7576 61.3 2.63 114.2 0.033 34.6611 0 -99.0 0 -99.00 0 -99.0 0 -99.00 0 2350.57 6 2420.57 6 505 4 3002.1 1.5666 34.6594 27.7577 61.3 2.63 114.2 0.034 34.6613 0 -99.0 0 -99.00 0 -99.0 0 -99.00 0 2350.83 6 2419.13 6 504 3 3002.1 1.5665 34.6594 27.7577 61.3 2.63 114.2 0.033 34.6610 0 -99.0 0 -99.00 0 -99.0 0 -99.00 0 2351.11 36 2420.70 6 503 2 3001.7 1.5668 34.6593 27.7576 61.3 2.63 114.2 0.033 34.6613 0 -99.0 0 -99.00 0 -99.0 0 -99.00 0 2352.20 6 2419.00 36 502 1 3001.6 1.5667 34.6593 27.7576 61.3 2.63 114.2 0.033 34.6613 0 -99.0 0 -99.00 0 -99.0 0 -99.00 0 2349.94 6 2420.92 6